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Sub-23nm particles emission from the light-duty vehicle is widely discussed now and possible to be counted into the next stage emission legislation, such as Euro7. In this article, 16 China6 gasoline vehicles were tested over the WLTC and two surrogate RDE lab cycles for particulate number (PN) emission, the difference between PN23 (particle size >23nm) and PN10 (particle size>10nm) emission was analyzed. Testing results showed that the average PN10 emission increased 59% compared to PN23, which will bring great challenges for those vehicles to meet the future regulation requirement if sub-23nm particle is counted. The sub-23nm particles emission was proportional to the PN23 particles emission and generated mostly from the cold start or the transient engine conditions with rich combustion. Compared to the proposal of Euro 7, PN10 emission from some tested vehicles will need further two orders of magnitude reduction.

China 6 (CN6) emission legislation for light duty vehicles was published in 2016, which introduced real driving emissions (RDE) requirements for new type-approval content. Nitrogen oxides (NOx) and particle number (PN) of RDE test are required to be monitored and reported from July 2020 in CN6a phase, fulfilled from July 2023 in CN6b phase. To meet the PN limitation of CN6 RDE, the optimized engine combustion and advanced emission control system like gasoline particle filter (GPF) are encouraged. Compared to traditional vehicle platform emission compliance which could be done in lab, much more vehicle development and validation efforts are expected on the open road for RDE compliance. High cost and complexity are expected to conduct a complete validation test matrix covering all the RDE critical boundary conditions on the open road.

Conventional diesel engines will continue to hold a vital role in the heavy- and medium-duty markets for the transportation of goods along with many other uses. The ability to offset traditional diesel fuels with low-net-carbon biofuels could have a significant impact on reducing the carbon footprint of these vehicles. A prior study screened several hundred candidate biofuel blendstocks based on required diesel blendstock properties and identified 12 as the most promising. Eight representative biofuel blendstocks were blended at a 30% volumetric concentration with EPA certification ultra-low-sulfur diesel (ULSD) and were investigated for emissions and fuel efficiency performance. This study used a single cylinder engine (based on the Ford 6.7L engine) using Conventional Diesel Combustion (CDC), also known as Mixing Control Compression Ignition (MCCI). The density, cetane number, distillation curve and sooting tendency (using the yield sooting index method) of the fuels were measured.

Mixing controlled compression ignition, i.e., diesel engines are efficient and are likely to continue to be the primary means for movement of goods for many years. Low-net-carbon biofuels have the potential to significantly reduce the carbon footprint of diesel combustion and could have advantageous properties for combustion, such as high cetane number and reduced engine-out particle and NOx emissions. We developed a list of over 400 potential biomass-derived diesel blendstocks and populated a database with the properties and characteristics of these materials. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a blendstock met the basic requirements for handling in the diesel distribution system and use as a blend with conventional diesel. Criteria included cetane number ≥40, flashpoint ≥52°C, and boiling point or T90 ≤338°C.

Almost one-third of the fuel energy is wasted through the exhaust of a vehicle. An efficient waste heat recovery (WHR) process will undoubtedly lead to improved fuel efficiency and reduced greenhouse gases (GHG) emission. Currently, there are multiple WHR technologies that are being investigated by various entities in the auto industry. One relatively simple device to extract heat energy from the exhaust is a heat exchanger. Heat exchangers are used in some automotive applications to transfer heat from the hot exhaust gas to the colder coolant fluid to raise the coolant temperature. The warmer coolant fluid can be used for several purposes such as; faster heating of the engine’s lubrication oil and transmission fluids during cold starts, and faster cabin heating, which in turn, can potentially improve the overall engine efficiency and reduce exhaust emissions.

Sustained NOx reduction at low temperatures, especially in the 150-200 °C range, shares some similarities with the more commonly discussed cold-start challenge, however, poses a number of additional and distinct technical problems. In this project, we set a bold target of achieving and maintaining 90% NOx conversion at the SCR catalyst inlet temperature of 150 °C. This project is intended to push the boundaries of the existing technologies, while staying within the realm of realistic future practical implementation. In order to meet the resulting challenges at the levels of catalyst fundamentals, system components, and system integration, Cummins has partnered with the DOE, Johnson Matthey, and Pacific Northwest National Lab and initiated the Sustained Low-Temperature NOx Reduction program at the beginning of 2015 and completed in 2017.

We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins.

In this paper, a three-dimensional (3D) microstructure-based finite element modeling method (i.e., extrinsic modeling method) is developed, which can be used in examining the effects of porosity on the ductility/fracture of Mg castings. For this purpose, AM60 Mg tensile samples were generated under high-pressure die-casting in a specially-designed mold. Before the tensile test, the samples were CT-scanned to obtain the pore distributions within the samples. 3D microstructure-based finite element models were then developed based on the obtained actual pore distributions of the gauge area. The input properties for the matrix material were determined by fitting the simulation result to the experimental result of a selected sample, and then used for all the other samples’ simulation. The results show that the ductility and fracture locations predicted from simulations agree well with the experimental results.

Diesel particulate filters (DPF) have become a standard aftertreatment component for a majority of current on-road/non-road diesel engines used in the US and Europe. The upcoming Stage V emissions regulations in Europe will make DPFs a standard component for emissions reductions for non-road engines. The tightening in NOx emissions standard has resulted in the use of selective catalytic reduction (SCR) technology for NOx reduction and as a result the general trend in engine technology as of today is towards a higher engine-out NOx/PM ratio enabling passive regeneration of the DPF. The novel filter concept discussed in this paper is optimized for low pressure drop, high filtration efficiency, and low thermal mass for optimized regeneration and fast heat-up, therefore reducing CO2 implications for the DPF operation.

This review paper summarizes major developments in vehicular emissions regulations and technologies (light-duty, heavy-duty, gasoline, diesel) in 2012. First, the paper covers the key regulatory developments in the field, including finalized criteria pollutant tightening in California; and in Europe, the development of real-world driving emissions (RDE) standards. The US finalized LD (light-duty) greenhouse gas (GHG) regulation for 2017-25. The paper then gives a brief, high-level overview of key developments in LD and HD engine technology, covering both gasoline and diesel. Marked improvements in engine efficiency are summarized for gasoline and diesel engines to meet both the emerging NOx and GHG regulations. HD engines are just starting to demonstrate 50% brake thermal efficiency. NOx control technologies are then summarized, including SCR (selective catalytic reduction) with ammonia, and hydrocarbon-based approaches.

Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number-based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample-handling methods have been implemented in an engine test cell with a spark-ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion.

This paper is the second in the series of documents designed to record the progress of a series of SAE documents - SAE J2836™, J2847, J2931, & J2953 - within the Plug-In Electric Vehicle (PEV) Communication Task Force. This follows the initial paper number 2010-01-0837, and continues with the test and modeling of the various PLC types for utility programs described in J2836/1™ & J2847/1. This also extends the communication to an off-board charger, described in J2836/2™ & J2847/2 and includes reverse energy flow described in J2836/3™ and J2847/3. The initial versions of J2836/1™ and J2847/1 were published early 2010. J2847/1 has now been re-opened to include updates from comments from the National Institute of Standards Technology (NIST) Smart Grid Interoperability Panel (SGIP), Smart Grid Architectural Committee (SGAC) and Cyber Security Working Group committee (SCWG).

The objective of this research is a detailed investigation of particulate sizing and number count from a spark-ignited, direct-injection (SIDI) engine at different operating conditions. The engine is a 549 [cc] single-cylinder, four-valve engine with a flat-top piston, fueled by Tier II EEE. A baseline engine operating condition, with a low number of particulates, was established and repeatability at this condition was ascertained. This baseline condition is specified as 2000 rpm, 320 kPa IMEP, 280 [°bTDC] end of injection (EOI), and 25 [°bTDC] ignition timing. The particle size distributions were recorded for particle sizes between 7 and 289 [nm]. The baseline particle size distribution was relatively flat, around 1E6 [dN/dlogDp], for particle diameters between 7 and 100 [nm], before dropping off to decreasing numbers at larger diameters. Distributions resulting from a matrix of different engine conditions were recorded.

Diesel particulate samples were collected from a light duty engine operated at a single speed-load point with a range of biodiesel and conventional fuel blends. The oxidation reactivity of the samples was characterized in a laboratory reactor, and BET surface area measurements were made at several points during oxidation of the fixed carbon component of both types of particulate. The fixed carbon component of biodiesel particulate has a significantly higher surface area for the initial stages of oxidation, but the surface areas for the two particulates become similar as fixed carbon oxidation proceeds beyond 40%. When fixed carbon oxidation rates are normalized to total surface area, it is possible to describe the oxidation rates of the fixed carbon portion of both types of particulates with a single set of Arrhenius parameters. The measured surface area evolution during particle oxidation was found to be inconsistent with shrinking sphere oxidation.

In this paper, results of finite element crash simulation are presented for a TRIP steel side rail with and without considering the phase transformation during forming operations. A homogeneous phase transformation model is adapted to model the mechanical behavior of the austenite-to-martensite phase. The forming process of TRIP steels is simulated with the implementation of the material model. The distribution and volume fraction of the martensite in TRIP steels may be greatly influenced by various factors during forming process and subsequently contribute to the behavior of the formed TRIP steels during the crushing process. The results indicate that, with the forming induced phase transformation, higher energy absorption of the side rail can be achieved. The phase transformation enhances the strength of the side rail.

Synergies between various catalytic converters such as SCR and DPF are vital to the success of an integrated aftertreatment system for simultaneous NO and particulate matter control in diesel engines. Several issues such as hydrocarbon poisoning, thermal aging and other coupled aftertreatment dynamics need to be addressed to develop an effective emission control system. This work is significant especially in an integrated DPF-SCR aftertreatment scenario where the SCR catalyst on the filter substrate is exposed to un-burnt diesel hydrocarbons during active regeneration of the particulate filter. This paper reports an experimental and modeling study to understand the effect of hydrocarbons on a Fe-zeolite urea-SCR catalyst. Several bench-reactor tests to understand the inhibition of NO oxidation, to characterize hydrocarbon storage and to investigate the impact of hydrocarbons on SCR reactions were conducted.

The CRC Fuels for Advanced Combustion Engines working group has worked to identify a matrix of research diesel fuels for use in advanced combustion research applications. Nine fuels were specified and formulated to investigate the effects of cetane number aromatic content and 90% distillation fraction. Standard ASTM analyses were performed on the fuels as well as GC/MS and1H/13C NMR analyses and thermodynamic characterizations. Details of the actual results of the fuel formulations compared with the design values are presented, as well as results from standard analyses, such as heating value, viscosity and density. Cetane number characterizations were accomplished by using both the engine method and the Ignition Quality Tester (IQT™) apparatus.

Diesel fuels derived from different types of crude oil can exhibit different chemistry while still meeting market requirements and specifications. Oil sands derived fuels typically contain a larger proportion of cycloparaffinic compounds, which result from the cracking and hydrotreating of bitumens in the crude. In the current study, 17 refinery streams consisting of finished fuels and process streams were obtained from a refinery using 100% oil sands derived crude oil. All samples except one met the ULSD standard of 15 ppm sulfur. The samples were characterized for properties and chemistry and run in a simple premixed HCCI engine using intake heating for combustion phasing control. Results indicate that the streams could be equally well characterized by chemistry or properties, and some simple correlations are presented. Cetane number was found to relate mainly to mono-aromatic content and the cycloparaffins did not appear to possess any unique diesel related chemical effects.

Development status and insight on a “research level” piezoelectric direct injection fuel injection system for prototype hydrogen Internal Combustion Engines (ICEs) is described. Practical experience accumulated from specialized material testing, bench testing and engine operation have helped steer research efforts on the fuel injection system. Recent results from a single cylinder engine are also presented, including demonstration of 45% peak brake thermal efficiency. Developing ICEs to utilize hydrogen can result in cost effective power plants that can potentially serve the needs of a long term hydrogen roadmap. Hydrogen direct injection provides many benefits including improved volumetric efficiency, robust combustion (avoidance of pre-ignition and backfire) and significant power density advantages relative to port-injected approaches with hydrogen ICEs.