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In the urea SCR system, urea solution is injected by injector installed in the front stage of the SCR catalyst, and NOx can be purified on the SCR catalyst by using NH3 generated by the chemical reaction of urea. NH3 is produced by thermolysis of urea and hydrolysis of isocyanic acid after evaporation of water in the urea solution. But, biuret and cyanuric acid which may cause deposit are sometimes generated by the chemical reactions without generating NH3. Spray behavior and chemical reaction of urea solution injected into the tail-pipe are complicated. The purpose of this study is to reveal the spray behavior and NH3 generation process in the tail-pipe, and to construct the model capable of predicting those accurately. In this report, the impingement spray behavior is clarified by scattered light method in high temperature flow field. Liquid film adhering to the wall and deposit generated after evaporation of water from the liquid film are photographed by the digital camera.

Diesel Particulate Filter (DPF) is a very effective aftertreatment device to limit particulate emissions from diesel engines. As the amount of soot collected in the DPF increases, the pressure loss increases. Therefore, DPF regeneration needs to be performed. Injected fuel into the exhaust line upstream of the Diesel Oxidation Catalyst (DOC), hydrocarbons are oxidized on the DOC, which increases the exhaust gas temperature at the DPF inlet. It is also necessary that the injected fuel is completely vaporized before entering the DOC, and uniformly mixed with the exhaust gases in order to make the DOC work efficiency. However, ensuring complete evaporation and an optimum mixture distribution in the exhaust line are challenging. Therefore, it is important that the fuel spray feature is grasped to perform DPF regeneration effectively. The purpose of this study is the constructing a simulation model.

In this study, it is purpose to make clear the effect of cavitation phenomenon on the spray atomization. In this report, the cavitation phenomenon inside the nozzle hole was visualized and the pressure measurements along the wall of the nozzle hole were carried out by use of 25-times enlarged acrylic nozzle. For the representatives of regular gasoline, single and two-component fuels were used as a test fuel. In addition, various cavitating flow patterns same as experimental conditions were simulated by use of Barotropic model incorporated in commercial code of Star-CD scheme, and compared with experimental results.

Methyl butanoate (MB) and methyl decanoate (MD) are surrogates for biodiesel fuels. According to computational results with their detailed reaction mechanisms, MB and MD indicate shorter ignition delays than long alkanes such as n-heptane and n-dodecane do at an initial temperature over 1000 K. The high ignitability of these methyl esters was computationally analyzed by means of contribution matrices proposed by some of the authors. Due to the high acidity of an α-H atom in a carbonyl compound, hydroperoxy radicals are generated out of the equilibrium between forward and backward reactions of O₂ addition to methyl ester radicals by the internal transfer of an α-H atom in the initial stage of an ignition process. Some of the hydroperoxy methyl ester radicals can generate OH to activate initial reactions. MB has an efficient CH₃O formation path via CH₃ generated by the β-scission of an MB radical which has a radical site on the α-C atom to the carbonyl group.

A diesel engine operating in premixed charge compression ignition (PCCI) mode promises the reduction of engine-out emissions of NOx and particulate matter. A serious issue for PCCI operation with the early injection timing during the compression stroke is the difficulty of controlling the mixture formation process. In this study, a mixed fuel consisting of high volatility fuel and high ignitability one is applied in order to develop a control technique for the mixture preparation. In particular, we focuses on a flash boiling phenomenon of mixed fuel. For pure substance, the quality of flashing spray is dominated by the degree of superheat. In contrast, that of mixed fuel is affected much by low boiling point fuel.

Authors propose the reformulation technique of physical properties of Biodiesel Fuel (BDF) by mixing lower boiling point fuels. In this study, waste cooking oil methyl ester (B100), which have been produced in Kyoto city, is used in behalf of BDF. N-Heptane (C7H16) and n-Dodecane (C12H26) are used as low and medium boiling point fuel. Mixed fuel of BDF with lower boiling point fuels have lighter quality as compared with neat BDF. This result is based on the chemical-thermo dynamical liquid-vapor equilibrium theory. This paper describes fundamental spray and combustion characteristics of mixed fuel of B100 with lower boiling point fuels as well as the reformulation technique. By mixing lower boiling point fuel, lighter quality fuels can be refined. Thus, mixed fuels have higher volatility and lower viscosity. Therefore, vaporization of mixed fuel spray is promoted and liquid phase penetration of mixed fuel shortens as compared with that of neat BDF.

In the actual spray combustion fields, coupled combustion process should be occurred, between the pre-evaporate fuel component and remaining liquid droplets. Therefore it is insufficient to clarify the fundamental spray combustion mechanism with use of only droplet or only premixed mixture analyze method. In this study, the premixed mixture - droplets coupled combustion field was focused as a model of the actual spray combustion field. In the experiments, the effect of the flame pattern and the combustion rate constant by the interference between the droplets were clarified with the variation of fuels used by droplets. Besides, the effect of the premixed gas surrounding the droplets was clarified by the experiment on coupled combustion. The experiments were carried out under the normal gravity field and the micro gravity field to estimate the effect of convection in combustion field

Soot formation process inside the combustion chamber of an DI diesel engine is focused as a phenomenological basic scheme by using several optical diagnostics technique for the improvement of diesel exhaust emission. We have conducted the series of optical measurement research for the clarification of combustion field in an DI diesel engine. Then, this paper is a kind of review by adding the fuel vapor properties and particle image velocimetry (PIV) analysis with focusing the soot formation process. The experiments were carried out in a small sized high-speed DI diesel engine installed with an optical access view. The spray characteristics and its flow field in 2-D field were measured by laser sheet scattering (LIS) method and PIV scheme.

A phenomenological or empirical model based on experimental results obtained from various optical measurements is critical for the understanding of DI diesel combustion phenomena as well as for the improvement of its emission characteristics. Such a model could be realized by the application of advanced optical measurement, which is able to isolate a particular phenomenon amongst complicated physical and chemical interactions, to a DI diesel combustion field. The authors have conducted experimental studies to clarify the combustion characteristics of unsteady turbulent diffusion flames in relation to the soot formation and oxidation process in a small-sized DI diesel engine. In the present study, the effect of fuel vapor concentration on the process of early combustion and soot formation has been investigated using several optical measurements.

It is expected that the analysis of the evaporation process for multicomponent fuels such as actual fuels like gasoline and diesel gas oil could be performed to assess more accurately the mixture preparation field inside the cylinder of D.I.S.I engines and diesel engines. In this paper, we suggested the importance of this multicomponent fuel consideration relating to the mixture formation and combustion characteristics from the basis of their own fuel physical and chemical properties. Then, we introduce a treatment for the phase change of a multicomponent solution through the formation of two-phase regions with the basis of chemical-thermodymical liquid-vapor equilibrium. Next, we analyze the distillation properties of a multicomponent fuel as well as the evaporation process of a multicomponent single droplet by use of the chemical-thermodymical analysis.

This paper confirms a structure for the soot formation process inside a burning diesel jet plume of oxygenated fuels. An explanation of how the soot formation process changes by the use of oxygenated fuel in comparison with that for using a conventional diesel fuel, and why oxygenated fuel drastically suppresses the soot formation has been derived from the chemical kinetic analysis. A detailed chemical kinetic mechanism, which is combined with various proposed chemical kinetic models including normal paraffinic hydrocarbon oxidation, oxygenated hydrocarbon oxidation, and poly-aromatic hydrocarbon (PAH) formation, was developed in present study. The calculated results are presented to elucidate the influence of fuel mixture composition and fuel structure, especially relating to oxygenated fuels, on PAH formation. The analysis also provides a new insight into the initial soot formation process in terms of the temperature range of PAH formation.

A transient gas jet and its flame are the most fundamental phenomena of a transient spray and its flame breaking out in a CI engine and an SI engine with the direct injection system. In the case of CNG and LNG engines, the fuel itself is just gaseous state. The 2-LIF technique was applied to the transient gas jet to obtain the mixing process between the surroundings and it, and the simultaneous application of LII and LIS techniques were applied to the transient gas jet flame to obtain the soot formation process.

Four kinds of optical measurements were performed to investigate the process of soot formation and oxidation in a direct-injection (DI) diesel engine. Measurements were carried out in an optically accessible DI diesel engine that allows planar laser sheet for combustion diagnostics to enter the combustion chamber either horizontally or along the axis of the fuel jet. The temporal and spatial distribution of soot particles has been investigated using the laser- induced incandescence (LII) and high-speed direct photography. Fuel vapor concentration, which is directly linked to the soot formation process in diesel combustion, has been deduced from the images obtained by the measurements of laser shadowgraph and elastic Mie scattering. According to the experimental results, soot formation begins to occur near the injector nozzle in which a fuel-rich mixture is distributed with a homogeneous condition. LII signal is dominated by the fuel vapor concentration in initial combustion period.

In previous multi-dimensional modeling on spray dynamics and vapor formation, single component fuel with pure substance has been analyzed to assess the mixture formation. Then it should be expected that the evaporation process could be performed for the multicomponent fuel such as actual Gasoline and Diesel gas oil. In this study, vapor-liquid equilibrium prediction was conducted for multicomponent fuels such as 3 and 10 components mixed solution with ideal solution analysis and non-ideal solution analysis. And the computation of distillation characteristics was conducted for the steady state fuel condition fuel condition to understand the evaporation process. As a result, calculated distillation characteristics are consistent well with experiment results. And the evaporation process of a multicomponent droplet in the combustion chamber has been calculated with the variation of ambient pressure and temperature.

This paper deals with the particle distribution in Diesel spray under the non-evaporating condition from the analytical aspect based on our experimental results. In the analysis, TAB method of KIVA II code and the k-ε turbulent model were used, and the mono-disperse distribution of the initial parcel's diameter, whose size equals to the nozzle hole diameter, was utilized in conjunction with the breakup model. The size distribution of atomized droplets (i.e. the χ-squared distribution function) is justified with the degree of freedom. It is shown that the ambient gas, which is initially quiescent, is induced and led to a turbulent gas jet. The turbulent gas jet which has a equivalent momentum with the Diesel spray was also examined by Discrete Vortex method. The quantitative jet growth was shown to be possible for the estimation and determination in its initial boundary values at the nozzle.

A transient gas jet seems to be a model of a diesel spray because it has no vaporization process. Recently, CNG is utilized in a diesel engine. In the case of diesel engine, sprays or jets have the free state in some cases, and they are impinging surely on the piston surface in the other cases. The 2-D image of acetylene gas with tracer particles was taken by high-speed photography. In both jets, the outer shape was measured on the images and the characteristics of the internal flow was obtained by particle image velocimetry. Then, the physical models of these jets were constructed by use of experimental results.

In this paper, spray characteristics were examined to deduce the effect of ambient gas properties. Considered ambient properties were the viscosity μa and density ρa, and thus the kinematic viscosity νa. The objective of this paper is to reveal the effect of compressibility of the ambient gas to spray formation. In the experiments, the changed ranges were And a standard-sac volume nozzle of hole diameter dn =0.25 mm (ln/dn=3.0) was used at constant injection pressure difference (Δp=16.2 MPa). Also the injection pressure was varied in the range of 55 to 120 MPa with a mini-sac volume nozzle of hole diameter dn =0.20 mm (ln/dn =5.5). Several different gases were used to change the ambient viscosity at a room temperature. From the experiments, it is obtained that larger the viscosity, the more the spray spreads in the radial direction, thus the spray angle gets larger and the tip penetration became shorter.

We propose a new concept on simultaneous reduction of NO and soot emissions in Diesel engine exhaust by the diesel fuel oil (n-Tridecane) with liquefied CO2 dissolved. The CO2 dissolved fuel is expected to undergo flash boiling or gas separation when being injected into the combustion chamber and improve spray atomization and mixing process both of which are primary factors to govern soot formation. Also the internal EGR effect caused by CO2 injected with the fuel is expected to NO formation. In order to assess this concept, combustion experiments were carried out using a rapid compression and expansion machine. Thus, flame characteristics and heat release rate were analyzed for the combustion process of diesel fuel and CO2 mixed fuel. And, it is revealed that the diesel fuel-liquefied CO2 mixed fuel can successfully reduce NO emission in a diesel combustion system.

One of countermeasures for exhaust emissions from a diesel engine, especially, DI diesel engine, is the use of a super high pressure injection system with a small hole diameter. However, the system needs greater driving force than that with normal injection pressure, and its demerit is increase in NOx, although soot is decreasing. Then, authors propose the new concept on the simultaneous reduction of NOx and soot. The concept is that the utilization of flash boiling phenomenon in a diesel engine. The phenomenon can be realized by use of the injection of fuel oil with CO2 gas dissolved. Flash boiling facilitates the distinguished atomization of fuel oil and CO2 gas contributes to realizes the internal EGR during combustion. Fundamental information on the characteristics of a flash boiling spray of n-tridecane with CO2 gas dissolved is described in this paper, as a first step.

The combustion of a diesel spray includes very complex processes, that is, atomization, evaporation, diffusion, turbulent mixing and burning. On the other hand, there are no phenomena of atomization and evaporation in the combustion of a transient gas jet. However, the latter jet can be treated as a fundamental of the former spray. From the standpoint mentioned above, acetylene gas was injected into the ambient during short duration as a transient gas jet and its flow characteristics were investigated by means of photography with a sheet of laser light and LDV to detect the turbulent vortex generated in the boundary layer between it and surroundings, in the experiments presented here. And the experimental results show that the jet itself is divided into four peculiar regions and the modelling of each region is carried out by use of the results to understand the mixture formation process owing to the turbulent diffusive mixing.