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Technical Paper

Onboard Ethanol-Gasoline Separation System for Octane-on-Demand Vehicle

2020-04-14
2020-01-0350
Bioethanol is being used as an alternative fuel throughout the world based on considerations of reduction of CO2 emissions and sustainability. It is widely known that ethanol has an advantage of high anti-knock quality. In order to use the ethanol in ethanol-blended gasoline to control knocking, the research discussed in this paper sought to develop a fuel separation system that would separate ethanol-blended gasoline into a high-octane-number fuel (high-ethanol-concentration fuel) and a low-octane-number fuel (low-ethanol-concentration fuel) in the vehicle. The research developed a small fuel separation system, and employed a layout in which the system was fitted in the fuel tank based on considerations of reducing the effect on cabin space and maintaining safety in the event of a collision. The total volume of the components fitted in the fuel tank is 6.6 liters.
Technical Paper

Analysis of the Pressure Drop Increase Mechanism by Ash Accumulated of Coated GPF

2019-04-02
2019-01-0981
With accelerating exhaust gas regulations in recent years, not only CO / HC / NOx but also PN regulation represented by Euro 6 d, China 6 are getting stricter. PN reduction by engine combustion technology development also progresses, but considering RDE, PN reduction by after treatment technology is also indispensable. To reduce PN exhausted from the gasoline engine, it is effective to equip GPF with a filter structure. Considering the installation of GPF in limited space, we developed a system that so far replaces the second TWC with GPF for the TWC 2 bed system. In order to replace the second TWC with GPF, we chose the coated GPF with filtering and TWC functions. Since the initial pressure drop and the catalyst amount (purification performance) of coated GPF have a conflicting relationship, we developed the coated GPF that can achieve both the low initial pressure drop and high purification performance.
Technical Paper

Design of High Performance Coated GPF with 2D/3D Structure Analysis

2019-04-02
2019-01-0977
In recent years along with stringent the regulations, vehicles equipped with gasoline particulate filter (GPF) have started to launch. Compared to bare GPF, coated GPF (cGPF) requires not only PN filtration efficiency, low pressure drop, but also purification performance. In the wall flow type cGPF having a complicated the pore shape, the pore structure further irregularly changes depending on the coated state of the catalyst, so it is difficult to understand the matter of in-wall. In order to advance of cGPF function, it was researched that revealing the relevance between pore structure change in the wall and GPF function. Therefore, to understand the catalyst coated state difference, cGPF of several coating methods were prepared, and their properties were evaluated by various analyses, and performance was tested.
Technical Paper

Numerical Modeling Study of Detailed Gas Diffusivity into Catalyst Washcoat for Lean NOx Catalyst

2019-04-02
2019-01-0993
To evaluate the relationship between the exhaust gas purification performance and the catalyst pore properties related to gas diffusion, an elementary reaction model was combined with gas diffusion into catalyst pores, referred to as the pseudo-2D gas diffusion/reaction model. It was constructed for Pt/Al2O3 + CeO2 catalyst as lean NOx catalyst. The gas diffusion was described as macro pore diffusion between the catalyst particles and meso pore diffusion within the particle. The kinetic model was composed of 26 reactions of NO/CO/O2 chemistry including 17 Pt/Al2O3 catalyst reactions and 9 CeO2 reactions. Arrhenius parameters were optimized using activity measurement results from various catalysts with various pore properties, meso pore volume and diameter, macro pore volume and diameter, particle size, and washcoat thickness. Good agreement was achieved between the measured and calculated values.
Technical Paper

Development of Low Temperature Active Three Way Catalyst

2019-04-02
2019-01-1293
In recent years, fuel efficiency has been improved by using many technologies such as downsizing engine, turbocharger and direct injection to reduce CO2 emissions from vehicle. However, the temperature of the exhaust gas from the engines using these technologies becomes lower than that form conventional one. That increases the difficulty for three-way catalyst (TWC) to purify CO, HC and NOx enough because TWC is not warmed up just after engine starting. In order to reduce cold emission mentioned above, we have been studying the warmup strategy of which the key property is thermal mass of TWC. To achieve early warmup, thermal mass of TWC is reduced by lightening the weight of (1) substrate and (2) catalytic materials, namely washcoat amount. Along with the strategy, we have developed TWC with lightweight substrate and applied it from the 2016 model year CIVIC.
Technical Paper

Diesel CAI Combustion in Uniflow Scavenging 2-Stroke Engine Provided with Port Fuel Injection Device

2018-10-30
2018-32-0015
We studied a simple and cost effective controlled auto ignition (CAI) combustion engine in order to achieve simultaneous reduction of NOx and soot, which are issues in diffusion combustion. The engine type was a uniflow scavenging 2-stroke engine, and the fuel used was diesel, as is common in diesel engines. We examined the position of the injector that effectively forms the premixture and realized stable operation with diesel fuel by the low pressure fuel injection device for port fuel injection (PFI), and it was found that the CAI combustion ignition timing can be controlled through setting the air/fuel ratio that obtains the optimal ignition timing per operation conditions.
Journal Article

Ag-Type PM Oxidation Catalyst with Nd Added to Increase Contact Property between PM and Catalyst

2018-04-03
2018-01-0328
Honda diesel engine vehicles that go on the market in 2018 will be equipped with a newly developed silver (Ag)-type catalyzed diesel particulate filter (cDPF). Ag has high particulate matter (PM) oxidation performance, but conventional catalyst-carrying methods cause weak contact property between PM and Ag; therefore, the newly Ag-type cDPF was developed on the concept of enhancing the property of contact between PM and the catalyst to realize contact property enhancement at the macro, meso, and nano scales. As a result, the newly developed catalyst showed an enhancement of T90 performance by a factor of approximately 2 relative to the conventional Ag-type catalyst in fresh condition. Durability in the environment of an automobile in use was examined through hydrothermal aging, lean-rich (L/R) aging, sulfur (S) poisoning, and ash deposition. The results have confirmed that hydrothermal aging is the greatest factor in deterioration.
Technical Paper

Study of an Aftertreatment System for HLSI Lean-burn Engine

2018-04-03
2018-01-0945
Lean-burn is an effective means of reducing CO2 emissions. To date, Homogenous Lean Charge Spark Ignition (HLSI) combustion, which lowers emissions of both CO2 and NOx, has been studied. Although HLSI realizes lower emission, it is a major challenge for lean-burn engines to meet SULEV regulations, so we have developed a new aftertreatment system for HLSI engines. It consists of three types of catalysts that have different functions, as well as special engine control methods. As the first stage in achieving SULEV emissions, this study focused on enhancing performance under lean conditions. HLSI engine exhaust gases contain high concentrations of hydrocarbons, including a large amount of paraffin, which are difficult to purify, rather than low concentrations of NOx. Therefore, the key point in low emissions is to purify not only NOx, but also high concentrations of paraffin at the same time.
Technical Paper

Dynamic Simulation Software for Prediction of Hydrogen Temperature and Pressure during Fueling Process

2018-04-03
2018-01-1304
In this study, in order to relax the pre-cooling regulations at hydrogen fueling stations, we develop a software algorithm to simulate an actual hydrogen fueling process to Fuel Cell Vehicle (FCV) tanks. The simulation model in the software consists of the same filling equipment found at an actual hydrogen fueling station. Additionally, the same supply conditions (pre-cooling temperature, pressure and mass flow rate) as at a hydrogen fueling station were set to the simulation model. Based on the supply conditions, the software simulates the temperature and pressure of hydrogen in each part of filling equipment. In order to verify the accuracy of the software, we compare the temperature and pressure simulated at each stage of the filling process with experimental data. We show that by using the software it is possible to accurately calculate the hydrogen temperature and pressure at each point during the fueling process.
Technical Paper

Numerical Simulations of Mixture Formation in Combustion Chambers of Lean-Burn Natural Gas Engines Incorporating a Sub-Chamber

2017-10-08
2017-01-2280
The aim of this study is to clarify the mixture formation in the combustion chamber of our developed natural gas engine incorporating the sub-chamber injection system, in which natural gas is directly injected into a combustion sub-chamber in order to completely separate rich mixture in the sub-chamber, suitable for ignition, from ultra-lean mixture in the main chamber. Mixture distributions in chambers with and without sub-chamber were numerically simulated at a variety of operating conditions. The commercial software of Fluent 16.0 was used to conduct simulations based on Reynolds averaged Navier-Stokes equations in an axial 2 dimensional numerical domain considering movements of piston. Non-reactive flow in the combustion chamber was simulated before the ignition timing at an engine speed of 2000 rpm. The turbulence model employed here is standard k-ε model. Air-fuel ratio is set with a lean condition of 30.
Journal Article

Development of New Hydrogen Fueling Method for Fuel Cell Motorcycle

2017-03-28
2017-01-1184
A new hydrogen fueling protocol named MC Formula Moto was developed for fuel cell motorcycles (FCM) with a smaller hydrogen storage capacity than those of light duty FC vehicles (FCV) currently covered in the SAE J2601 standard (over than 2kg storage). Building on the MC Formula based protocol from the 2016 SAE J2601 standard, numerous new techniques were developed and tested to accommodate the smaller storage capacity: an initial pressure estimation using the connection pulse, a fueling time counter which begins the main fueling time prior to the connection pulse, a pressure ramp rate fallback control, and other techniques. The MC Formula Moto fueling protocol has the potential to be implemented at current hydrogen stations intended for fueling of FCVs using protocols such as SAE J2601. This will allow FCMs to use the existing and rapidly growing hydrogen infrastructure, precluding the need for exclusive dispensers or stations.
Technical Paper

Research on Combustion Noise for Controlled Auto Ignition Engine Fueled with Natural Gas Effect of Stroke Bore Ratio and Ignition Timing

2016-11-08
2016-32-0044
One of the issues involved in compression ignition combustion is the increase in combustion noise from engine mechanical systems caused by rapid combustion. When the fuel used is natural gas, with its high ignition temperature, the compression is increased relative to gasoline, so that combustion becomes even more rapid. The present research pursues the issue of noise by clarifying the distinctive features of combustion noise through tests focused on the two topics of stroke-bore ratio (S/B ratio) and ignition timing for engine structures deformation mode. From these results, we verified combustion noise trend and occurrence factor.
Journal Article

Development of Base Metal Catalyst and Its Compatibility Study for Motorcycle Applications

2016-11-08
2016-32-0071
We developed a copper catalyst using zero Platinum group metals (hereafter PGMs) to fit motorcycle specific emission gas environment. Though many research reports to develop catalyst without using PGMs that are precious and costly resources are available, no reports had proven Base Metal Catalyst development to meet actual emission regulation equivalent to PGM catalysts. Compared to conventional PGM catalysts, higher temperature is required to keep high catalytic conversion efficiency by utilizing properties of this Base Metal Catalyst. Thus, this Base Metal Catalyst is located in cross coupling position, though it is rare case in motorcycle. This catalyst location could cause negative impacts on engine knocking, engine performance and drivability. This time, to overcome such negative impacts we optimized whole exhaust system, including parts around catalyst.
Technical Paper

On Demand Octane Number Enhancement Technology by Aerobic Oxidation

2016-10-17
2016-01-2167
For the purpose of developing onboard gasoline reforming technology for higher octane number fuel on demand, octane number enhancement of gasoline surrogate by aerobic oxidation using N-hydroxyphthalimide catalyst was investigated. At first, octane numbers of the oxygen-containing products from alkane and aromatic compound were estimated using a fuel ignition analyzer. As a result, not only alcohol but also ketones and aldehydes have higher octane numbers than the original alkanes and aromatic compound. Next, gasoline surrogate was oxidized aerobically with N-hydroxyphthalimide derivative catalyst and cobalt catalyst at conditions below 100 °C. As a result, fuel molecules were oxidized to produce alcohols, ketones, aldehydes, and carboxylic acids. N-hydroxyphthalimide derivative catalyst with higher solubility in gasoline surrogate has higher oxidation ability. Furthermore, the estimated octane number of the oxidized gasoline surrogate improves 17 RON.
Technical Paper

Effect of Mixture Stratification and Fuel Reactivity on Dual-Fuel Compression Ignition Combustion Process for SI-Based Engine

2016-10-17
2016-01-2304
Compression ignition combustion with a lean mixture has high potential in terms of high theoretical thermal efficiency and low NOx emission characteristics due to low combustion temperatures. In particular, a Dual-Fuel concept is proposed to achieve high ignition timing controllability and an extended operation range. This concept controls ignition timing by adjusting the fraction of two fuels with different ignition characteristics. However, a rapid combustion process after initial ignition cannot be avoided due to the homogenous nature of the fuel mixture, because the combustion process depends entirely on the high reaction rate of thermal ignition. In this study, the effect of mixture stratification in the cylinder on the combustion process after ignition based on the Dual-Fuel concept was investigated. Port injection of one fuel creates the homogeneous mixture, while direct injection of the other fuel prepares a stratified mixture in the cylinder at the compression stroke.
Technical Paper

Influences of Turbulence Scale on Development of Spherically Propagating Flame under High EGR Conditions

2015-09-01
2015-01-1868
EGR (Exhaust gas recirculation) can reduce the pumping loss and improve the thermal efficiency of spark ignition engines. The techniques for combustion enhancement under high EGR rate condition has been required for further improvement of the thermal efficiency. In order to develop the technique of combustion enhancement by turbulence, the influences of turbulence scale on combustion properties, such as probability of flame propagation, EGR limit of flame propagation, flame quenching and combustion duration were investigated under the condition of same turbulence intensity. Experiments were carried out for stoichiometric spherically propagating turbulent i-C8H18/Air/N2 flames using a constant volume vessel. It was clarified that all of these combustion properties were affected by the turbulence scale. The development of spherically propagating turbulent flame during flame propagation was affected by the turbulence scale.
Technical Paper

Study of Ethanol-Gasoline Onboard Separation System for Knocking Suppression

2015-09-01
2015-01-1954
Bio-ethanol is used worldwide in fuel mixtures such as E10 gasoline. In this study, an onboard fuel system employing a pervaporation membrane was investigated to separate E10 into high-octane-number fuel (high-concentration ethanol fuel) and low-octane-number fuel (low-concentration ethanol fuel). The optimal operation conditions and size of the membrane unit for the separation system were determined in consideration of the separation rate and vehicle installation. This system can supply separated ethanol with sufficient speed and quantity to improve engine performance under practical driving conditions. In addition, the study was conducted to confirm that separated fuels have properties sufficient for use in automobiles. This separation rate enabled 5-cycle-mode driving without temporary shortage of permeated fuel.
Journal Article

Effect of Surface Heat Treatment on Corrosion-Related Failure of the Suspension Spring

2015-04-14
2015-01-0518
In this research, a new wire material made using surface-reforming heat treatment was developed in order to enhance the corrosion fatigue resistance of suspension springs. The aim of surface reforming is to improve hydrogen embrittlement characteristics through grain refinement and to improve crack propagation resistance by partial softening of hardness. The grain refinement method used an α'→γ reversed transformation by rapid short-term heating in repeated induction heating and quenching (R-IHQ) to refine the crystal grain size of SAE 9254 steel spring wire to 4 μm or less. In order to simultaneously improve the fatigue crack propagation characteristics, the possibility of reducing the hardness immediately below the spring surface layer was also examined. By applying contour hardening in the second IHQ cycle, a heat affected zone (HAZ) is obtained immediately below the surface.
Journal Article

Friction Behavior of Diamond-Like Carbon Coated Ball Joint: Approach to Improving Vehicle Handling and Ride-Comfort

2015-04-14
2015-01-1507
Research to respond to demands for improving usability of passenger vehicles has played important roles. Some aspects can be attributed to friction behavior of the steering and suspension components. In this study, we focus on an approach to improve handling, steering feel and ride-comfort of a vehicle by applying the appropriate friction behavior to tie-rod end ball joint. To control not only friction coefficient but also static-kinetic transient behavior, we investigate the potential use of diamond-like carbon (DLC) coatings. Different DLC coatings varied widely in hydrogen content, mechanical properties and micro-surface roughness are applied to the ball studs. Friction behavior corresponds to material characteristics and surface roughness of DLC.
Journal Article

NOx Trap Three-Way Catalyst (N-TWC) Concept: TWC with NOx Adsorption Properties at Low Temperatures for Cold-Start Emission Control

2015-04-14
2015-01-1002
A new concept for trapping NOx and HC during cold start, the NOx Trap Three-Way Catalyst (N-TWC), is proposed. N-TWC adsorbs NOx at room temperature, and upon reaching activation temperature under suitable air-fuel ratio conditions, it reduces the adsorbed NOx. This allows a reduction in NOx emissions during cold start. N-TWC's reduction mechanism relies on NOx adsorption sites which are shown to be highly dispersed palladium on acid sites in the zeolite. Testing on an actual vehicle equipped with N-TWC confirmed that N-TWC is able to reduce emissions of NOx and HC during cold start, which is a challenge for conventional TWCs.
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