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Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

Unburned hydrocarbon (UHC) and carbon monoxide (CO) emission sources are examined in an optical, light-duty diesel engine operating under low load and engine speed, while employing a highly dilute, partially premixed low-temperature combustion (LTC) strategy. The impact of engine load and charge dilution on the UHC and CO sources is also evaluated. The progression of in-cylinder mixing and combustion processes is studied using ultraviolet planar laser-induced fluorescence (UV PLIF) to measure the spatial distributions of liquid- and vapor-phase hydrocarbon. A separate, deep-UV LIF technique is used to examine the clearance volume spatial distribution and composition of late-cycle UHC and CO. Homogeneous reactor simulations, utilizing detailed chemical kinetics and constrained by the measured cylinder pressure, are used to examine the impact of charge dilution and initial stoichiometry on oxidation behavior.

It has been known from multi-zone simulations that HCCI combustion can be significantly affected by temperature stratification of the in-cylinder gas. With the same combustion timing (i.e. crank angles at 50% heat release, denoted as CA50), large temperature stratification tends to prolong the combustion duration and lower down the in-cylinder pressure-rise-rate. With low pressure-rise-rate HCCI engines can be operated at high load, therefore it is of practical importance to look into more details about how temperature stratification affects the auto-ignition process. It has been realized that multi-zone simulations can not account for the effects of spatial structures of the stratified temperature field, i.e. how the size of the hot and cold spots in the temperature field could affect the auto-ignition process. This question is investigated in the present work by large eddy simulation (LES) method which is capable of resolving the in-cylinder turbulence field in space and time.

Power supply systems play a very important role in applications of everyday life. Mainly, for low power generation, there are two ways of producing energy: electrochemical batteries and small engines. In the last few years many improvements have been carried out in order to obtain lighter batteries with longer duration but unfortunately the energy density of 1 MJ/kg seems to be an asymptotic value. If the energy source is an organic fuel with an energy density of around 29 MJ/kg and a minimum overall efficiency of only 3.5%, this device can surpass the batteries. Nowadays the most efficient combustion process is HCCI combustion which is able to combine high energy conversion efficiency and low emission levels with a very low fuel consumption. In this paper, an investigation has been carried out concerning the effects of the compression ratio on the performance and emissions of a mini, Vd = 4.11 [cm3], HCCI engine fueled with diethyl ether.

An experimental study of a glow plug engine combustion process has been performed by applying chemiluminescence imaging. The major intent was to understand what kind of combustion is present in a glow plug engine and how the combustion process behaves in a small volume and at high engine speed. To achieve this, images of natural emitted light were taken and filters were applied for isolating the formaldehyde and hydroxyl species. Images were taken in a model airplane engine, 4.11 cm3, modified for optical access. The pictures were acquired using a high speed camera capable of taking one photo every second or fourth crank angle degree, and consequently visualizing the progress of the combustion process. The images were taken with the same operating condition at two different engine speeds: 9600 and 13400 rpm. A mixture of 65% methanol, 20% nitromethane and 15% lubricant was used as fuel.

Experiments on a modern DI Diesel engine were carried out: The engine was fuelled with standard Diesel fuel, RME and a mixture of 85% standard Diesel fuel, 5% RME and 10% higher alcohols under low load conditions (4 bar IMEP). During these experiments, different external EGR levels were applied while the injection timing was chosen in a way to keep the location of 50% heat release constant. Emission analysis results were in accordance with widely known correlations: Increasing EGR rates lowered NOx emissions. This is explained by a decrease of global air-fuel ratio entailing longer ignition delay. Local gas-fuel ratio increases during ignition delay and local combustion temperature is lowered. Exhaust gas analysis indicated further a strong increase of CO, PM and unburned HC emissions at high EGR levels. This resulted in lower combustion efficiency. PM emissions however, decreased above 50% EGR which was also in accordance with previously reported results.

In this paper a fast NOx model is presented which can be used for engine optimization, aftertreatment control or virtual mapping. A cylinder pressure trace is required as input data. High calculation speed is obtained by using table interpolation to calculate equilibrium temperatures and species concentrations. Test data from a single-cylinder engine and from a complete six-cylinder engine have been used for calibration and validation of the model. The model produces results of good agreement with emission measurements using approximately 50 combustion product zones and a calculation time of one second per engine cycle. Different compression ratios, EGR rates, injection timing, inlet pressures etc. were used in the validation tests.

A naturally aspirated in-line six-cylinder 2.9-litre Volvo engine is operated in Homogeneous Charge Compression Ignition (HCCI) mode, using camshafts with low lift and short duration generating negative valve overlap. Standard port fuel injection is used and pistons and cylinder head are unchanged from the automotive application. HCCI through negative valve overlap is recognized as one of the possible implementation strategies of HCCI closest to production. It is important to gain knowledge of the constraints and limits on the possible operating region. In this work, the emphasis is on investigating how cycle-to-cycle and cylinder-to-cylinder deviations limit the operating region, how these effects change in different parts of the operating region and how they can be controlled. At low load the cycle-to-cycle phenomena cause periodic behavior in combustion timing; together with cylinder deviations this is found responsible for decreasing the operating regime.

Exhaust Emissions from lean burn natural gas engines may not always be as low as the potential permits, especially engines with open loop lambda control. These engines can produce much higher emissions than a comparable diesel engine without exhaust gas after treatment. Even if the engine has closed loop lambda control, emissions are often unacceptably high for future emission regulations. A three way catalyst is, today, the best way to reduce hazardous emissions. The drawback is that the engine has to operate with a stoichiometric mixture and this leads to; higher heat losses, higher pumping work at low to medium loads, higher thermal stress on the engine and higher knock tendency (requiring lower compression ratio, and thus lower brake efficiency). One way to reduce these drawbacks is to dilute the stoichiometric mixture with EGR. This paper compares lean burn operation with operation at stoichiometric conditions diluted with EGR, and using a three way catalyst.

Homogeneous Charge Compression Ignition (HCCI) has a great potential for low NOx emissions but problems with emissions of unburned hydrocarbons (HC). One way of reducing the HC is to use direct injection. The purpose of this paper is to present experimental data on the trade off between NOx and HC. Injection timing, injection pressure and nozzle configuration all effect homogeneity of the mixture and thus the NOx and HC emissions. The engine studied is a single cylinder version of a Scania D12 that represents a modern heavy-duty truck size engine. A common rail (CR) system has been used to control injection pressure and timing. The combustion using injectors with different nozzle hole diameters and spray angle, both colliding and non-colliding, has been studied. The NOx emission level changes with start of injection (SOI) and the levels are low for early injection timing, increasing with retarded SOI. Different injectors produce different NOx levels.

Ion current measurements can give information useful for controlling the combustion stability in a multi-cylinder engine. Operation near the dilution limit (air or EGR) can be achieved and it can be optimized individually for the cylinders, resulting in a system with better engine stability for highly diluted mixtures. This method will also compensate for engine wear, e.g. changes in volumetric efficiency and fuel injector characteristics. Especially in a port injected engine, changes in fuel injector characteristics can lead to increased emissions and deteriorated engine performance when operating with a closed-loop lambda control system. One problem using the ion-current signal to control engine stability near the lean limit is the weak signal resulting in low signal to noise ratio. Measurements presented in this paper were made on a turbocharged 9.6 liter six cylinder natural gas engine with port injection.

A specially designed cylinder head, enabling unthrottled operation with a standard cam-phasing mechanism, was tested in an optical single-cylinder engine. The in-cylinder flow was measured with particle image velocimetry (PIV) and the results were compared with heat release and emission measurements. The article also discusses effects of residual gas and effective compression ratio on heat-release and emissions. The special design of the cylinder head, with one inlet and one exhaust valve per camshaft, made it possible to operate the engine unthrottled at part load. Cam phasing led to late inlet valve closing, but also to increased valve overlap. The exhaust valve closing was late in the intake stroke, resulting in high amounts of residual gases. Two different camshafts were used with late inlet valve closing. One of the camshafts had shorter valve open duration on the phased exhaust cam lobe.

One way to extend the lean burn limit of a natural gas engine is by addition of hydrogen to the primary fuel. This paper presents measurements made on a one cylinder 1.6 liter natural gas engine. Two combustion chambers, one slow and one fast burning, were tested with various amounts of hydrogen (0, 5, 10 and 15 %-vol) added to natural gas. Three operating points were investigated for each combustion chamber and each hydrogen content level; idle, part load (5 bar IMEP) and 13 bar IMEP (simulated turbocharging). Air/fuel ratio was varied between stoichiometric and the lean limit. For each operating point, a range of ignition timings were tested to find maximum brake torque (MBT) and/or knock. Heat-release rate calculations were made in order to assess the influence of hydrogen addition on burn rate. Addition of hydrogen showed an increase in burn rate for both combustion chambers, resulting in more stable combustion close to the lean limit.

This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.

In this paper an online method for automatically reducing complex chemical mechanisms for simulations of combustion phenomena has been developed. The method is based on the Quasi Steady State Assumption (QSSA). In contrast to previous reduction schemes where chemical species are selected only when they are in steady state throughout the whole process, the present method allows for species to be selected at each operating point separately generating an adaptive chemical kinetics. The method is used for calculations of a natural gas fueled engine operating under Homogenous Charge Compression Ignition (HCCI) conditions. We discuss criteria for selecting steady state species and the influence of these criteria on the results such as concentration profiles and temperature.

A newly developed cross flow cylinder head has been used for comparison between throttled and unthrottled operation using late intake valve closing. Pressure measurements have been used for calculations of indicated load and heat-release. Emission measurements has also been made. A model was used for estimating the amount of residual gases resulting from the different load strategies. Unthrottled operation using late intake valve closing resulted in lower pumping losses, but also in increased amounts of residual gases, using this cylinder head. This is due to the special design, with one intake valve and one exhaust valve per camshaft. Late intake valve closing was achieved by phasing one of the camshafts, resulting in late exhaust valve closing as well. With very late phasing - i.e. low load - the effective compression ratio was reduced. This, in combination with high amount of residual gases, resulted in a very unstable combustion.

Although there seems to be a consensus regarding the low emission potential of DME, there are still different opinions about why the low NOx emissions can be obtained without negative effects on thermal efficiency. Possible explanations are: The physical properties of DME affecting the spray and the mixture formation Different shape and duration of the heat release in combination with reduced heat losses In this paper an attempt is made to increase the knowledge of DME in relation to diesel fuel with respect to heat release and NOx formation. The emphasis has been to create injection conditions as similar as possible for both fuels. For that purpose the same injection system (CR), injection pressure (270 bar), injection timing and duration have been used for the two fuels. The only differences were the diameters of the nozzle holes, which were chosen to give the same fuel energy supply, and the physical properties of the fuels.

Laser-Rayleigh imaging has been employed to measure the relative fuel concentration in the gaseous jet region of DME sprays. The measurements were performed in an optically accessible diesel truck engine equipped with a common rail injection system. A one-hole nozzle was used to guarantee that the recorded pressure history was associated with the heat release in the imaged spray. To compensate for the low compression ratio in the modified engine the inlet air was preheated. Spray development was studied for two levels of preheating, from the start of injection to the point where all fuel was consumed. The results indicate that there is a strong correlation between the amount of unburned fuel present in the cylinder and the rate of heat release at a given time. The combustion can not be described as purely premixed or purely mixing-controlled at any time, but always has an element of both. After all fuel appears to have vanished there is still an extended period of heat release.

An ionization sensor has been used to study the combustion process in a six-cylinder lean burn, truck-sized engine fueled with natural gas and optimized for low emissions of nitric oxides. The final goal of the investigations is to study the prospects of using the ionization sensor for finding the optimal operating position with respect to low NOx emission and stable engine operation. The results indicate that unstable combustion can be detected by analyzing the coefficient of variation (CoV) of the detector current amplitude. Close relationships between this measure and the CoV of the indicated mean effective pressure have been found during an air-fuel ratio scan with fixed ignition advance.

In this paper, a theoretical study is presented where fuel rate shaping is analyzed in combination with EGR as a method for reducing NOx formation. The analytical tools used include an empirically based model to convert fuel rate to heat release rate, and a zero dimensional multizone combustion model to calculate combustion products, local flame temperatures and NOx emissions at a given heat release rate. The multizone model, which has been presented earlier, includes flame radiation and convective heat losses. Several geometrical shapes of the fuel rate are tested for different combustion timings and EGR rates. It is found that the fuel rate giving the lowest NOx formation varies with the injection timing. In order to lower the NOx emissions at normal and advanced injection timings, the fuel rate should have a rather long duration, and start at its maximum level followed by a slow decay.