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Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

The paper describes a novel method for calculating the residual gas fraction and the trapping efficiency in a 2 stroke engine. Assuming one dimensional compressible flow through the inlet and exhaust ports, the method estimates the instantaneous mass flowing in and out from the combustion chamber; later the residual gas fraction and trapping efficiency are estimated combining together the perfect displacement and perfect mixing scavenging models. It is assumed that when the intake port opens, the fresh mixture is pushing out the burned charge without any mixing and after a multiple of the time needed for the largest eddy to perform one rotation, the two gasses are instantly mixed up together and expelled. The result is a very simple algorithm that does not require much computational time and is able to estimate with high level of precision the trapping efficiency and the residual gas fraction in 2 stroke engines.

Nowadays for small-scale power generation there are electrochemical batteries and mini engines. Many efforts have been done for improving the power density of the batteries but unfortunately the value of 1 MJ/kg seems to be asymptotic. If the energy source is an organic fuel which has an energy density of around 29 MJ/kg with a minimum overall efficiency of only 3.5%, this device would surpass the batteries. This paper is the fifth of a series of publications aimed to study the HCCI combustion process in the milli domain at high engine speed in order to design and develop VIMPA, Vibrating Microengine for Low Power Generation and Microsystems Actuation. Previous studies ranged from general characterization of the HCCI combustion process by using metal and optical engines, to more specific topics for instance the influence of the boundary layer and quenching distance on the quality of the combustion.

Power supply systems play a very important role in applications of everyday life. Mainly, for low power generation, there are two ways of producing energy: electrochemical batteries and small engines. In the last few years many improvements have been carried out in order to obtain lighter batteries with longer duration but unfortunately the energy density of 1 MJ/kg seems to be an asymptotic value. If the energy source is an organic fuel with an energy density of around 29 MJ/kg and a minimum overall efficiency of only 3.5%, this device can surpass the batteries. Nowadays the most efficient combustion process is HCCI combustion which is able to combine high energy conversion efficiency and low emission levels with a very low fuel consumption. In this paper, an investigation has been carried out concerning the effects of the compression ratio on the performance and emissions of a mini, Vd = 4.11 [cm3], HCCI engine fueled with diethyl ether.

Experiments on a modern DI Diesel engine were carried out: The engine was fuelled with standard Diesel fuel, RME and a mixture of 85% standard Diesel fuel, 5% RME and 10% higher alcohols under low load conditions (4 bar IMEP). During these experiments, different external EGR levels were applied while the injection timing was chosen in a way to keep the location of 50% heat release constant. Emission analysis results were in accordance with widely known correlations: Increasing EGR rates lowered NOx emissions. This is explained by a decrease of global air-fuel ratio entailing longer ignition delay. Local gas-fuel ratio increases during ignition delay and local combustion temperature is lowered. Exhaust gas analysis indicated further a strong increase of CO, PM and unburned HC emissions at high EGR levels. This resulted in lower combustion efficiency. PM emissions however, decreased above 50% EGR which was also in accordance with previously reported results.

The main benefit of HCCI engines compared to SI engines is improved fuel economy. The drawback is the diluted combustion with a substantially smaller operating range if not some kind of supercharging is used. The reasons for the higher brake efficiency in HCCI engines can be summarized in lower pumping losses and higher thermodynamic efficiency, due to higher compression ratio and higher ratio of specific heats if air is used as dilution. In the low load operating range, where HCCI today is mainly used, other parameters as friction losses, and cooling losses have a large impact on the achieved brake efficiency. To initiate the auto ignition of the in-cylinder charge a certain temperature and pressure have to be reached for a specific fuel. In an engine with high in-cylinder cooling losses the initial charge temperature before compression has to be higher than on an engine with less heat transfer.

In this paper the combustion chamber wall temperature was measured by the use of thermographic phosphor. The temperature was monitored over a large time window covering a load transient. Wall temperature measurement provide helpful information in all engines. This temperature is for example needed when calculating heat losses to the walls. Most important is however the effect of the wall temperature on combustion. The walls can not heat up instantaneously and the slowly increasing wall temperature following a load transient will affect the combustion events sucseeding the transient. The HCCI combustion process is, due to its dependence on chemical kinetics more sensitive to wall temperature than Otto or Diesel engines. In depth knowledge about transient wall temperature could increase the understanding of transient HCCI control. A “black box” state space model was derived which is useful when predicting transient wall temperature.

Autoignition of a homogeneous mixture is very sensitive to operating conditions. Therefore fast combustion phasing control is necessary for reliable operation. There are several means to control the combustion phasing of a Homogeneous Charge Compression Ignition (HCCI) engine. This paper presents cycle-to-cycle cylinder individual control results from a six-cylinder HCCI engine using a Variable Valve Actuation (VVA) system. As feedback signal, the crank angle for 50% burned, based on cylinder pressure, is used. Three control structures are evaluated, Model Predictive Control (MPC), Linear Quadratic Gaussian control (LQG) and PID control. In the control design of the MPC and LQG controller, dynamic models obtained by system identification were used. Successful experiments were performed on a port-injected six-cylinder heavy-duty Diesel engine operating in HCCI mode.

Exhaust Emissions from lean burn natural gas engines may not always be as low as the potential permits, especially engines with open loop lambda control. These engines can produce much higher emissions than a comparable diesel engine without exhaust gas after treatment. Even if the engine has closed loop lambda control, emissions are often unacceptably high for future emission regulations. A three way catalyst is, today, the best way to reduce hazardous emissions. The drawback is that the engine has to operate with a stoichiometric mixture and this leads to; higher heat losses, higher pumping work at low to medium loads, higher thermal stress on the engine and higher knock tendency (requiring lower compression ratio, and thus lower brake efficiency). One way to reduce these drawbacks is to dilute the stoichiometric mixture with EGR. This paper compares lean burn operation with operation at stoichiometric conditions diluted with EGR, and using a three way catalyst.

A known problem of the HCCI engine is its lack of direct control and its requirements of feedback control. Today there exists several different means to control an HCCI engine, such as dual fuels, variable valve actuation, inlet temperature and compression ratio. Independent of actuation method a sensor is needed. In this paper we perform closed-loop control based on two different sensors, pressure and ion current sensor. Results showing that they give similar control performance within their operating range are presented. Also a comparison of two methods of designing HCCI timing controller, manual tuning and model based design is presented. A PID controller is used as an example of a manually tuned controller. A Linear Quadratic Gaussian controller exemplifies model based controller design. The models used in the design were estimated using system identification methods. The system used in this paper performs control on cycle-to-cycle basis. This leads to fast and robust control.

Homogeneous Charge Compression Ignition (HCCI) holds great promises for good fuel economy and low emissions of NOX and soot. The concept of HCCI is premixed combustion of a highly diluted mixture. The dilution limits the combustion temperature and thus prevents extensive NOX production. Load is controlled by altering the quality of the charge, rather than the quantity. No throttling together with a high compression ratio to facilitate auto ignition and lean mixtures results in good brake thermal efficiency. However, HCCI also presents challenges like how to control the combustion and how to achieve an acceptable load range. This work is focused on solutions to the latter problem. The high dilution required to avoid NOX production limits the mass of fuel relative to the mass of air or EGR. For a given size of the engine the only way to recover the loss of power due to dilution is to force more mass through the engine.

Ion current measurements can give information useful for controlling the combustion stability in a multi-cylinder engine. Operation near the dilution limit (air or EGR) can be achieved and it can be optimized individually for the cylinders, resulting in a system with better engine stability for highly diluted mixtures. This method will also compensate for engine wear, e.g. changes in volumetric efficiency and fuel injector characteristics. Especially in a port injected engine, changes in fuel injector characteristics can lead to increased emissions and deteriorated engine performance when operating with a closed-loop lambda control system. One problem using the ion-current signal to control engine stability near the lean limit is the weak signal resulting in low signal to noise ratio. Measurements presented in this paper were made on a turbocharged 9.6 liter six cylinder natural gas engine with port injection.

One way to extend the lean burn limit of a natural gas engine is by addition of hydrogen to the primary fuel. This paper presents measurements made on a one cylinder 1.6 liter natural gas engine. Two combustion chambers, one slow and one fast burning, were tested with various amounts of hydrogen (0, 5, 10 and 15 %-vol) added to natural gas. Three operating points were investigated for each combustion chamber and each hydrogen content level; idle, part load (5 bar IMEP) and 13 bar IMEP (simulated turbocharging). Air/fuel ratio was varied between stoichiometric and the lean limit. For each operating point, a range of ignition timings were tested to find maximum brake torque (MBT) and/or knock. Heat-release rate calculations were made in order to assess the influence of hydrogen addition on burn rate. Addition of hydrogen showed an increase in burn rate for both combustion chambers, resulting in more stable combustion close to the lean limit.

An experimental and theoretical study of the effect of thermal barriers and catalytic coatings in a Homogeneous Charge Compression Ignition (HCCI) engine has been conducted. The main intent of the study was to investigate if a thermal barrier or catalytic coating of the wall would support the oxidation of the near-wall unburned hydrocarbons. In addition, the effect of these coatings on thermal efficiency due to changed heat transfer characteristics was investigated. The experimental setup was based on a partially coated combustion chamber. The upper part of the cylinder liner, the piston top including the top land, the valves and the cylinder head were all coated. As a thermal barrier, a coating based on plasma-sprayed Al2O3 was used. The catalytic coating was based on plasma-sprayed ZrO2 doped with Platinum. The two coatings tested were of varying thickness' of 0.15, 0.25 and 0.6 mm. The compression ratio was set to 16.75:1.

The cylinder to cylinder and cycle to cycle variations were measured in a production type Volvo natural gas engine. Cylinder pressure was measured in all six cylinders. Emission measurements were performed individually after all cylinders, and commonly after the turbocharger. Measurements (ECE R49 13-mode) were performed with different spark gap and two different locations for fuel injection, one before the throttle and one before the turbocharger. Heat-release and lambda calculations show substantial cylinder to cylinder variations, due to lambda variations between the cylinders. The slow burn combustion chamber, with low turbulence, results in high cycle to cycle variations (> 100% COV imep) for some of the load cases.

The potential of a Homogeneous Charge Compression Ignition (HCCI) engine with variable compression ratio has been experimentally investigated. The experiments were carried out in a single cylinder engine, equipped with a modified cylinder head. Altering the position of a secondary piston in the cylinder head enabled a change of the compression ratio. The secondary piston was controlled by a hydraulic system, which was operated from the control room. Dual port injection systems were used, which made it possible to change the ratio of two different fuels with the engine running. By mixing iso-octane with octane number 100 and normal heptane with octane number 0, it was possible to obtain any octane rating between 0 and 100. By using an electrical heater for the inlet air, it was possible to adjust the inlet air temperature to a selected value.

An experimental study of the Homogeneous Charge Compression Ignition (HCCI) combustion process has been conducted by using chemiluminescence imaging. The major intent was to characterize the flame structure and its transient behavior. To achieve this, time resolved images of the naturally emitted light were taken. Emitted light was studied by recording its spectral content and applying different filters to isolate species like OH and CH. Imaging was enabled by a truck-sized engine modified for optical access. An intensified digital camera was used for the imaging. Some imaging was done using a streak-camera, capable of taking eight arbitrarily spaced pictures during a single cycle, thus visualizing the progress of the combustion process. All imaging was done with similar operating conditions and a mixture of n-heptane and iso-octane was used as fuel. Some 20 crank angles before Top Dead Center (TDC), cool flames were found to exist.

This work is a continuation of earlier research conducted on the effects of different combustion chambers on turbulence, combustion, emissions and efficiency for natural gas converted diesel bus engines. In this second measurement series the engine (Volvo TD102) was supercharged to enable bmep up to 18 bar at λ = 1.6-1.9. Six different combustion chambers were used. The results show that different geometrical combustion chambers, with the same compression ratio (12:1), have very different combustion performance. A high rate of heat release is favorable for lean operation, and the design of the combustion chamber is very important for the knock and misfire limits.

This study is focused on the effect of different valve strategies on the in-cylinder flow and combustion A conventional four-valve pentroof engine was modified to enable optical access to the combustion chamber To get information on the flow, a two-component LDV system was applied The combustion was monitored by the use of cylinder pressure in a one-zone heat release model The results show that the flow in the cylinder with the valves operating in the standard configuration has an expected tumble characteristic In this case the high frequency turbulence is homogeneous and has a peak approximately 20 CAD BTDC With one valve deactivated, the flow shows a swirling pattern The turbulence is then less homogeneous but the level of turbulence is increased When the single inlet valve was phased late against the crankshaft dramatic effects on the flow resulted The late inlet valve opening introduced a low cylinder pressure before the valve opened The high pressure difference across the valve introduced a high-velocity jet into the cylinder Turbulence was increased by a factor of two by this operational mode When two inlet valves were used, a reduction of turbulence resulted from a very late inlet cam phase

The most economical way to convert truck and bus DI-diesel engines to natural gas operation is to replace the injector with a spark plug and modify the combustion chamber in the piston crown for spark ignition operation. The modification of the piston crown should give a geometry well suited for spark ignition operation with the original swirling inlet port. Ten different geometries were tried on a converted VOLVO TD102 engine and a remarkably large difference in the rate of combustion was noted between the chambers. To find an explanation for this difference a cycle resolved measurement of the in-cylinder mean velocity and turbulence was performed with Laser Doppler Velocimetry (LDV). The results show a high correlation between in cylinder turbulence and rate of heat release in the main part of combustion.