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In this study, we determined the detailed reaction mechanism of CO/NO/O2 for automotive three way catalysts. The N2O formation process obtained from measurements of the reaction properties and the formation process of adsorbed NCO species obtained from surface analysis of platinum group metals were added to a previous detailed surface reaction mechanism. The computational accuracy of the developed reaction mechanism was verified by the one-dimensional simulation software BOOST, and it was found to be sufficient for any combination of platinum group metals and gas concentrations.

To achieve carbon-neutrality, internal combustion engines need to further improve their thermal efficiency to reduce CO2 emissions. To accomplish this, it is necessary to quantify and enhance five factors that control indicated thermal efficiency: compression ratio, specific heat ratio, combustion duration, combustion timing, and heat transfer to wall. In this work, quantitative targets for each factor were defined, which were derived from a simulation that considered the influence of heterogeneity of diesel combustion on thermal efficiency. The simulation utilized a two-zone combustion model. In particular, the targets for the combustion duration, combustion timing and heat transfer to wall were increased significantly compared to those for a conventional engine, in anticipation of an expansion of the load range of premixed charge compression ignition (PCI) combustion to higher loads.

Automobiles will have to be applied strict regulations such as Euro7 against PM, HC, CO. The generation of these components are related to fuel deposition to the wall surface of the combustion chamber. Therefore, the fuel injection model of engine combustion CFD requires accurate prediction about the deposition and vaporization of fuel on the combustion chamber. In this study, multiphase flow numerical analysis that simulates fuel behavior on the wall surface was conducted first. Then, two model formulae about the contact area and the heat flux of a liquid film was constructed based on the result of multiphase flow numerical analysis method. Finally, the new film heat transfer model was constructed from these model formulae. In addition, it was confirmed that new heat transfer model can predict the liquid film temperature obtained by multiphase flow numerical analysis method accurately.

As a technology to reduce the heat loss of engines, heat insulation coating to the surface of combustion chamber has been received a lot of attention. In order to maximize the thermal efficiency improvements by the technology, it is important to clarify the location where heat insulation coating can reduce heat loss more effectively, considering the impact on abnormal combustion etc. In this study, transient behavior of wall heat flux distribution on the piston was analyzed using 3D Computational Fluid Dynamics (CFD) for three combustion modes (spark ignition combustion (SI), homogenous charge compression Ignition (HCCI) and spark controlled compression ignition (SPCCI)).

To get a better understanding of the characteristics of the high pressure gasoline sprays impinging on a wall, a fundamental study was conducted in a high-temperature high-pressure constant volume vessel under the simulated engine conditions of in-cylinder pressures, temperatures, and wall temperatures. The injection pressure was varied from 20 to 120 MPa. The spray tip penetration, vapor mass distribution, and vaporization rate were quantitatively measured with the laser absorption-scattering (LAS) technique. The velocity fields of the wall-impinging sprays under vaporizing conditions were measured with the particle image velocimetry (PIV) technique using silicone oil droplets as tracers. The effects of injection pressure and spray/wall interactions on spray characteristics were investigated. The results showed that the increased injection pressure improved penetration, vaporization, and turbulence of the sprays.

It was important for predicting wall heat flux to apply wall heat transfer model by taking into account of the behavior of turbulent kinetic energy and density change in wall boundary layer. Although energy equation base wall heat transfer model satisfied above requirements, local physical amounts such as turbulent kinetic energy in near wall region should be applied. In this study, in order to predict wall heat transfer by zero dimensional analysis, how to express wall heat transfer by using mean physical amounts in engine combustion chamber was considered by experimental and numerical approaches.

Control of self-ignition timing in a HCCI engine is still a major technical issue. Recently, the application of a non-equilibrium plasma using repetitively discharge has been proposed as the promising technology. However, non-equilibrium plasma reaction in higher hydrocarbon fuel mixture is very complicated. Hence, there have been few calculation reports considering a series of reactions from non-equilibrium plasma production to high temperature oxidation process. In this study, 0-dimensional numerical simulation model was developed in which both reactions of plasma chemistry and high temperature oxidation combustion was taken into account simultaneously. In addition, an ODEs solver has been applied for the reduction of calculation time in the simulation. By comparing calculation results with experiment such as self-ignition timing, the validity of the developed numerical model has been evaluated.

The method described in this paper has been proposed to analyze the heat balance of diesel combustion from engine measurement data considering the heterogeneity of this type of combustion with use of a two-zone model composed of unburned and burned zones. This method is intended for practical application to an engine bench test during an engine development process and is characterized by the following features: A representative excess air ratio of the burned zone is set and assumed to be constant throughout the combustion period, and the ratio is estimated from NOx emission amount. The authors performed heat balance analyses on engine measurement data using the proposed method and made a comparison with the results of analyses that assumed a combustion chamber to be one homogenous zone.

In the development of fuel tank systems, it is important to maintain fuel system integrity even if a car accident occurs. When a fuel tank undergoes a sudden change in velocity, the fuel starts to move and deforms the tank walls and baffle plates, and then the deformation changes the flow pattern of fuel. Because interaction of fuel with tank components is the main cause of fuel spillage upon crash, it is important to predict complex fluid-structure interaction responses at an early stage of crash safety development with a multiphysics simulation. Development of the multiphysics simulation technique was conducted stepwise by examining “fluid motion” and “tank deformation.” First, a sled test of a rigid-wall tank with observation window was conducted to evaluate the fluid motion inside the tank. A numerical model was developed based on an ALE (Arbitrary Lagrangian Eulerian) algorithm for the fluid and a Lagrangian algorithm for the structure.

A mixed time-scale subgrid large eddy simulation was used to simulate mixture formation, combustion and soot formation under the influence of turbulence during diesel engine combustion. To account for the effects of engine wall heat transfer on combustion, the KIVA code's standard wall model was replaced to accommodate more realistic boundary conditions. This were carried out by implementing the non-isothermal wall model of Angelberger et al. with modifications and incorporating the log law from Pope's method to account for the wall surface roughness. Soot and NOx emissions predicted with the new model are compared to experimental data acquired under various EGR conditions.

Coating the heat insulation materials on the combustion chamber walls is one of the solutions to reduce the cooling loss of internal combustion engines. In order to examine the coatings, the evaluation of the heat transfer coefficient and the analysis of the heat transfer phenomena on the heat insulated walls are important. Firstly, the highly-responsive wall temperature sensor is developed, and the instantaneous wall heat flux is measured to evaluate the heat transfer coefficient on the heat insulated walls. The results show that the Nusselt number on the heat insulated walls is less influenced by the Reynolds number variation than that on the metal walls. Secondly, the high speed µ-PIV is employed to analyze the various turbulent flow characteristics. The results show that the turbulent dissipation on the heat insulated walls is smaller than that on the metal walls.

The reduced chemical reaction scheme which can take the effect of major fuel components on auto ignition timing into account has been developed. This reaction scheme was based on the reduced reaction mechanism for the primary reference fuels (PRF) proposed by Tsurushima [1] with 33 species and 38 reactions. Some pre-exponential factors were modified by using Particle Swarm Optimization to match the ignition delay time versus reciprocal temperature which was calculated by the detailed scheme with 2,301 species and 11,116 elementary chemical reactions. The result using the present reaction scheme shows good agreements with that using the detailed scheme for the effects of EGR, fuel components, and radical species on the ignition timing under homogeneous charge compression ignition combustion (HCCI) conditions.

The purpose of this study is to define requirements for technological and business success in the world's first implementation of Reverse-Supply-Chain, in which bumper materials of end-of-life vehicles (ELV) are recycled for use as ingredients in new bumper materials. In Japan, ELVs are recovered following to the government regulation. About 20% (700,000 ton) of such collected ELVs are automotive shredder residues (ASR), most of which are burnt as fuel or used as landfill trash. ASRs are mainly plastics, which are largely used as materials of bumpers. The reverse-supply-chain was started as a small business by a collaboration between the car manufacture (Mazda), dismantler, and resource-recycling business operator, and enhanced by the development of easy-to-recycle bumpers, technologies of paint removal from crushed bumpers and sorting-out, a material quality control method, and improvement in transportation efficiency.

A newly developed three-way catalyst (TWC) has excellent thermal durability with an ultra low amount of platinum group metals (PGM). The performance of the new catalyst is similar to that of a conventional TWC but with only 1/10 of the typical PGM loading. In the conventional TWC, the PGM particles are simply deposited on the surface of the support material; the particles sinter during thermal aging, resulting in significant thermal deterioration. The new developed catalyst contains small nano-sized PGM particles with a unique microstructure and support materials. With this material, the PGM particles remain at the single nano size after high temperature aging.

Experimental and computational studies were carried out to characterize the spray development and evaporation processes of multi-hole injector for direct injection spark ignition (DISI) engines. The main injector parameter to be investigated in this study is a diverging angle between neighboring two holes. In the experimental study, the influence of the diverging angle on evaporation process of fuel spray from two-hole injector was investigated using Laser Absorption Scattering (LAS) measurement. Smaller diverging angle causes larger spray tip penetration because the momentum of the spray from one hole emphasizes another, when two spray merge to one. Moreover, spray tip penetration decreases at certain diverging angle due to the negative pressure region between two sprays. Mechanisms behind the above spray behaviors were discussed using the detailed information on the spray and ambient gas flow fields obtained by the three dimensional computational fluid dynamics (CFD).

The new shape ceria-based support material for a lean NOx trap catalyst (LNT) was developed and its catalytic characteristics were investigated. It has a unique shape that each fine particle of raw material is formed into hollow sphere. Samples of platinum loaded powder catalysts were obtained with either the hollow sphere ceria-based material or two kinds of the conventional shape one, and their catalytic activities were evaluated with the synthetic gas. The aged powder catalyst using the hollow sphere ceria-based material had higher CO oxidation performance at low temperature as compared to the conventional shape one with the same composition. The characterization results indicated that the hollow sphere ceria-based material had high thermal stability.

An experimental and numerical study was conducted on the spray and mixture properties of a hole-type injector for direct injection (D. I.) gasoline engines. The Laser Absorption Scattering (LAS) technique was adopted to simultaneously measure the spatial concentration distributions and the mass of the liquid and vapor phases in the fuel spray injected into a high-pressure and high-temperature constant volume vessel. The experimental results were compared to the numerical calculation results using three-dimensional CFD and the multi-objective optimization. In the numerical simulation, the design variable of the spray model was optimized by choosing spray tip penetration, and mass of liquid and vapor phases as objective functions.

In the previous study of the authors, it was found that some benefits for the mixture preparation of DI gasoline engines can be offered by splitting the fuel injection, such as the phenomenon of high density liquid phase fuel piling up at the leading edge of the spray can be circumvented. In a further analysis, the vapor quantity in the “stable operating” range (equivalence ratio of vapor ϕv in a range of 0.7≤ϕv≤1.3) was significantly increased by the split injection compared to the single injection. In this work, the mechanism of the effect of the split injection on the mixture formation process was studied by combining the laser-sheet imaging, LIF-PIV and the LAS (Laser Absorption Scattering) technique. As a result, it is found that the spray-induced ambient air motion can help the formation of the more combustible mixture of the split injection whereas it played a minus role of diluting the spray by the single injection.

A new nitrogen oxide (NOx) reduction concept is suggested. A strong vertical vortex generated within the combustion bowl can mix hot burned gas into the cold excess air at the center of the combustion-bowl. This makes the burned gas cool rapidly. Therefore, it is possible to reduce NOx, which would be produced if the burned gas remained hot. In this paper the effect was verified with a 3D-CFD analysis of spray, air, combustion gas, and thermal efficiency as well as experiments on a 4-cylinder 2.0-liter direct injection diesel engine. The results confirmed that the vertical vortex was able to be strengthened with the change of spray characteristics and the combustion bowl shapes. This strengthened vertical vortex was able to reduce NOx by approximately 20% without making smoke and thermal-efficiency worse. Above results proved the effectiveness of this method.

In order to reduce the emission of both VOC (Volatile Organic Compounds) included in paint and CO2 which is generated from operating painting booth and baking oven, low solvent content paint and new coating system which make it possible to apply primer coating, base coating, and clear coating continuously before baked at once have been developed. With these technologies, it is possible to eliminate primer baking process, and reduce coating cost, while maintaining the film properties.