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The LDV gasoline emission regulation is set to be tightened for Euro7. In particular, the particulate number (PN) requirement has been significantly tightened requiring a GPF with extra - high filtration efficiency to meet the target requirement. In order to meet the stricter PN requirements, GPF substrate material improvement is necessary. However, conventional GPF material improvement for high filtration efficiency will increase the filter backpressure significantly. The relationship between pressure drop and CO2 emission is difficult to quantify but high pressure drop can potentially increase the CO2 emission. Therefore, Membrane Technology (MT) is the key to break through the trade-off between filtration performance and pressure drop. MT is thin and dense layer of small grains applied on the GPF surface. MT application can increase particulate filtration efficiency significantly with minimal pressure drop increase.

Selective catalyst reduction (SCR) using cordierite honeycomb substrate is generally used as a DeNOx catalyst for diesel engines exhaust in both on-road and commercial off-highway vehicles to meet today’s worldwide emission regulations. Worldwide NOx emission regulations will become stricter, as represented by CARB2027 and EuroVII. Technologies which can achieve further lower NOx emissions are required. Recently, several technologies, like increased SCR catalyst loading amount on honeycomb substrates, and additional SCR catalyst volume in positions closer to the engine are being considered to achieve ultra-low NOx emissions. However, undesirable pressure drop increase and enlarging after treatment systems will be caused by adopting these technologies. Therefore, optimization of the material and honeycomb cell structure for SCR is inevitable to achieve ultra-low NOx emissions, while minimizing any system drawbacks.

In order to meet the challenging CO2 targets beyond 2020 without sacrificing performance, Gasoline Direct Injection (GDI) technology, in combination with turbo charging technology, is expanding in the automotive industry. However, while this technology does provide a significant CO2 reduction, one side effect is increased Particle Number (PN) emission. As a result, from September 2017, GDI vehicles in Europe are required to meet the stringent PN emission limits of 6x1011 #/km under the Worldwide harmonized Light vehicles Test Procedure (WLTP). In addition, it is required to meet PN emission of 9x1011 #/km under Real Driving Emission (RDE) testing, which includes a Conformity Factor (CF) of 1.5 to account for current measurement inaccuracies on the road. This introduction of RDE testing in Europe and China will especially provide a unique challenge for the design of exhaust after-treatment systems due to its wide boundary conditions.

Reducing the fuel consumption of powertrains in internal combustion engines is still a major objective from an environmental viewpoint. Internal combustion engines waste a huge part of the fuel energy as heat in the exhaust line. Currently, exhaust heat recovery (EHR) systems are attracting attention as an effective means of reducing fuel consumption by collecting heat from waste exhaust gas and using it for rapid warming up of the engine and cabin heating [1, 2, 3, 4]. The benefits of the EHR system are affected by a trade-off between the efficacy of the recovered useful thermal energy and the adverse effect of the additional weight (heat mass) of the system [5]. Conventional EHR systems have a complex heat exchanger structure and a structure in which a bypass pipe and heat exchanger are connected in parallel, giving them a large size and heavy weight. We have developed a new-concept silicon carbide (SiC) heat exchanger with a dense SiC honeycomb.

With the push towards more stringent on-road US heavy duty diesel regulations (i.e. HD GHG Phase 2 and the proposed ARB 20 mg/bhp-hr NOx), emission system packaging has grown critical while improving fuel economy and NOx emissions. The ARB regulations are expected to be implemented post 2023 while regulation for EU off-road segment will begin from 2019. The regulation, called Stage V, will introduce particle number (PN) regulation requiring EU OEMs to introduce a diesel particulate filter (DPF) while customer demands will require the OEMs to maintain current emission system packaging. A viable market solution to meet these requirements, especially for EU Stage V being implemented first, is a DPF coated with a selective catalyst reduction (SCR) washcoat (i.e. SCRonDPF).

Diesel engines are widely used to reduce CO2 emission due to its higher thermal efficiency over gasoline engines. Considering long term CO2 targets, as well as tighter gas emission, especially NOx, diesel engines must become cleaner and more efficient. However, there is a tradeoff between CO2 and NOx and, naturally, engine developers choose lower CO2 because NOx can be reduced by a catalytic converter, such as a SCR catalyst. Lower CO2 engine calibration, unfortunately, leads to lower exhaust gas temperatures, which delays the activation of the catalytic converter. In order to overcome both problems, higher engine out NOx emission and lower exhaust gas temperatures, close-coupled a diesel particulate filter (DPF) system with integration of SCR catalyst technology is preferred. For SCR catalyst activity, it is known that the catalyst loading amount has an influence on NOx performance, so a high SCR catalyst loading will be required.

Diesel particulate filters (DPF) are a common component in emission-control systems of modern clean diesel vehicles. Several DPF materials have been used in various applications. Silicone Carbide (SiC) is common for passenger vehicles because of its thermal robustness derived from its high specific gravity and heat conductivity. However, a segmented structure is required to relieve thermal stress due to SiC's higher coefficient of thermal expansion (CTE). Cordierite (Cd) is a popular material for heavy-duty vehicles. Cordierite which has less mass per given volume, exhibits superior light-off performance, and is also adequate for use in larger monolith structures, due to its lower CTE. SiC and cordierite are recognized as the most prevalent DPF materials since the 2000's. The DPF traps not only combustible particles (soot) but also incombustible ash. Ash accumulates in the DPF and remains in the filter until being physically removed.

Diesel engines are more fuel efficient due to their high thermal efficiency, compared to gasoline engines and therefore, have a higher potential to reduce CO2 emissions. Since diesel engines emit higher amounts of Particulate Matter (PM), DPF systems have been introduced. Today, DPF systems have become a standard technology. Nevertheless, with more stringent NOx emission limits and CO2 targets, additional NOx emission control is needed. For high NOx conversion efficiency, SCR catalysts technology shows high potential. Due to higher temperature at the close coupled position and space restrictions, an integrated SCR concept on the DPFs is preferred. A high SCR catalyst loading will be required to have high conversion efficiency over a wide range of engine operations which causes high pressure for conventional DPF materials.

This session focuses on particle emissions from combustion engines, including measurement methods and fuel effects. Presenter Leonidas D. Ntziachristos, Aristotle University Thessaloniki

The reduction of greenhouse gas is becoming increasingly important for humankind, and vehicles with low CO₂ emissions have a part to play in any reduction initiatives. Diesel engines emit 30% less CO₂ than gasoline engines, so diesel engines will make an important contribution to the overall decrease. Unfortunately diesel exhaust gas contains particulate matter (PM) which may cause health problems, and such PM emissions are regulated by law. In order to reduce PM, especially soot, diesel particulate filters (DPFs) are widely fitted to diesel vehicles. A DPF can remove more than 99% by weight of soot from exhaust gas under normal operating conditions, and they are one of the most important methods to achieve any regulation targets. But if the system malfunctions, the PM emissions may exceed the regulation limit. To detect such PM leakage, on-board diagnostics (OBD) are required.

Although diesel engines are superior to gasoline engines in terms of the demand to reduce CO2 emissions, diesel engines suffer from the problem of emitting Particulate Matter (PM). Therefore, a Diesel Particulate Filter (DPF) has to be fitted in the engine exhaust aftertreatment system. From the viewpoint of reducing CO2 emissions, there is a strong demand to reduce the exhaust system pressure drop and for DPF designs that are able to help reduce the pressure drop. A wall flow DPF having a novel wall pore structure design for reducing pressure drop, increasing robustness and increasing filtration efficiency is presented. The filter offers a linear relationship between PM loading and pressure drop, offering lower pressure drop and greater accuracy in estimating the accumulated PM amount from pressure drop. First, basic experiments were performed on small plate test samples having various pore structure designs.

Among the durability items of the DPF (Diesel Particulate Filter), high accumulated soot mass limit is important for the low fuel consumption and also for the robustness. In case of catalyzed DPF, it depends on the following two properties during soot regeneration. One is the lower maximum-temperature inside of the DPF during usual regeneration in order to preserve the catalyst performance. The other is the higher thermal resistance against the unusual regeneration of excess amount of soot. This paper presents the improvement in the soot mass limit of Si bonded SiC DPF. Maximum-temperature inside of the DPF was lowered by the improvement of thermal conductivity of the material, resulted from the controlling of the microstructure. Additionally the thermal resistance was improved by the surface treatment of the Si and SiC.

Modern filter systems allow a significant reduction of diesel particulate emissions. The new silicon bonded silicon carbide particulate filters (Si-SiC filters) play an important role in this application, because they provide flexibility in terms of mean pore size and porosity and also have a high thermal shock capability to meet both engineering targets and emission limits for 2005 and beyond. Particulate filters are exposed to high temperatures and a harsh chemical environment in the exhaust gas of diesel vehicles. This paper will present further durability evaluation results of the new Si bonded SiC particulate filters which have been collected in engine bench tests and vehicle durability runs. The Si-SiC filters passed both 100 and 200 regeneration cycles under severe ageing conditions and without any problems. The used filters were subjected to a variety of analytical tests. The back pressure and ash distribution were determined. The filter material was also analysed.

In this paper a method of DPF(Diesel Particulate Filter) lifetime estimation against the thermal stress is presented. In the method, experimentally measured material fatigue property and DPF temperature distributions under various conditions including regeneration mode were used to perform FEM stress analyses and the estimation of DPF lifetime and allowable stresses. From the viewpoint of the system design, to prevent DPF damages such as cracks created through thermal stress or melting, controlling the amount of PM accumulation is important. In this study, the pressure difference behavior under each of PM accumulation mode and regeneration mode was investigated experimentally. The experimental results showed different pressure drop behaviors in accumulation and regeneration. DPFs were observed in detail after PM accumulation and during regeneration to discuss mechanisms of the pressure difference behavior.

As emissions regulations are becoming more stringent, various efforts to improve emission performance have been carried out in different areas including the honeycomb structure of catalytic converters. This report describes the development of a simulation tool to predict emission performance and simulation results for different cell structures. The simulation model was developed based on global kinetic chemical reaction model [1]. Having tuned the reaction parameters through a light-off test and estimated oxygen storage capacity through an oxygen storage test, we ultimately tuned the model in a vehicle test (with Bags 1 and 2, FTP 75). As a result, the simulated cumulative tailpipe emissions are within ±25 percent of the test results. Parameter analyses indicate that the amount of emissions decreased as the density of cells increased and that the amount of emissions also decreased the thinner the wall thicknesses were.

Developing ultra thin wall ceramic substrates is necessary to meet stricter emissions regulations, in part because substrate cell walls need to be thinner in order to improve warm-up and light-off characteristics and lower exhaust system backpressure. However, the thinner the cell wall becomes, the poorer the mechanical and thermal characteristics of the substrate. Furthermore, the conditions under which the ultra thin wall substrates are used are becoming more severe. Therefore both the mechanical and thermal characteristics are becoming important parameters in the design of advanced converter systems. Whereas square cells are used world-wide in conjunction with oxidation and/or three-way catalysts, hexagonal cells, with features promoting a homogeneous catalyst coating layer, have found limited use as a NOx absorber due to its enhanced sulfur desorption capability.

To meet stringent emissions regulations, high conversion efficiency is required. This calls for advanced catalyst substrates with thinner walls and higher cell density. Higher cell density is needed because it brings higher mass transfer from the gas to the substrate wall. Basically, the increase in total surface area (TSA) causes higher mass transfer. However, not only the TSA, but the cell shape also has a great effect on mass transfer. There are two main kinds of substrates. One is the extruded ceramic substrate and the other is the metal foil type substrate. These have different cell shapes due to different manufacturing processes. For the extruded ceramic substrate, it is possible to fabricate various cell shapes such as triangle, hexagon, etc. as well as the square shape. The difference in the cell shape changes not only the mass transfer rate, but also causes pressure loss change. This is an important item to be considered in the substrate design.

DPF substrate is exposed to high temperature during regeneration and to acid components in exhaust gas. Therefore, DPF material needs to have an excellent thermal shock resistance, thermal and chemical stability to the sulfuric acid. This paper presents the durability test results of the Si-SiC DPF material. In particular, thermal shock resistance, oxidation resistance and acid resistance parameters have been evaluated by comparison with recrystallized-SiC and cordierite materials. As the results, the strength of Si-SiC decreased between ΔT=500 and 600deg.C, while that of recrystallized-SiC decreased between ΔT=300 and 400deg.C. The result is attributed to the difference in the elastic modulus. About oxidation resistance, material properties of Si-SiC, compared between pre- and post- oxidation, have greater stability than those of recrystallized SiC. And naturally, both SiC materials have superior acid resistance to cordierite.

The DPF(Diesel Particulate Filter) has been established as a key technology in reducing diesel PM emission. Also Catalyzed-DPF Systems are viewed as the next generation DPF System in the automotive sector, replacing the current Fuel Additive System. The performance requirements of the DPF-equipped vehicle are good fuel economy, good driving performance, high PM regeneration performance of accumulated soot and high durability. In this paper the effect of Catalyzed-DPF characteristics, such as porosity, pore size, cell structure and catalyst loading have been defined on pressure drop, filtration efficiency, regeneration efficiency and regeneration behavior.

Further stringent emission legislation requires advanced technologies, such as sophisticated engine management and advanced catalyst and substrate to achieve high catalytic performance, especially during the light-off phase. This paper presents the results of calculations and measurements of hydrocarbon and carbon monoxide light-off performance for substrates of different wall thickness, cell density and cell shapes. The experimental data from catalyst light-off testing on an engine dynamometer are compared with theoretical results of computer modeling under different temperature ramps and flow rates. The reaction kinetics in the computer modeling are derived from the best fit for the performance of conventional ceramic substrate (6mil/400cpsi), by comparing the theoretical and experimental results on both HC and CO emissions. The calibrated computer model predicts the effects of different wall thickness, cell density and cell shape.