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Technical Paper

Stress Generation in Large Pouch Cells Under Cycling and Abuse Conditions

2024-04-09
2024-01-2196
Pouch cells are increasingly popular form factors for the construction of energy storage systems in electric vehicles of all classes. Knowledge of the stress generated by these higher capacity pouch cells is critical to properly design battery modules and packs for both normal and abnormal operation. Existing literature predominantly offers data on smaller pouch cells with capacities of less than 10 Ah, leaving a gap in our understanding of the behavior of these larger cells. This experimental study aimed to bridge this knowledge gap by measuring loads and stresses in constrained 65 Ah pouch cells under both cycling and abuse conditions. To capture the desired responses, a load cell was located within a robust fixture to measure cell stress in real time after the application of a preload of approximately 30 kilograms or 294 N, equivalent to a pressure of 0.063 bar, with a fixed displacement.
Technical Paper

Combustion Chamber Development for Flat Firedeck Heavy-Duty Natural Gas Engines

2024-04-09
2024-01-2115
The widely accepted best practice for spark-ignition combustion is the four-valve pent-roof chamber using a central sparkplug and incorporating tumble flow during the intake event. The bulk tumble flow readily breaks up during the compression stroke to fine-scale turbulent kinetic energy desired for rapid, robust combustion. The natural gas engines used in medium- and heavy-truck applications would benefit from a similar, high-tumble pent-roof combustion chamber. However, these engines are invariably derived from their higher-volume diesel counterparts, and the production volumes are insufficient to justify the amount of modification required to incorporate a pent-roof system. The objective of this multi-dimensional computational study was to develop a combustion chamber addressing the objectives of a pent-roof chamber while maintaining the flat firedeck and vertical valve orientation of the diesel engine.
Technical Paper

CARB Off-Road Low NOx Demonstration Program - Engine Calibration and Initial Test Results

2024-04-09
2024-01-2130
Off-road diesel engines remain one of the most significant contributors to the overall oxides of nitrogen (NOX) inventory and the California Air Resources Board (CARB) has indicated that reductions of up to 90% from current standards may be necessary to achieve its air quality goals. In recognition of this, CARB has funded a program aimed at demonstrating emission control technologies for off-road engines. This program builds on previous efforts to demonstrate Low NOX technologies for on-road engines. The objective was to demonstrate technologies to reduce tailpipe NOX and particulate matter (PM) emissions by 90 and 75%, respectively, from the current Tier 4 Final standards. In addition, the emission reductions were to be achieved while also demonstrating a 5 to 8.6% carbon dioxide (CO2) reduction and remaining Greenhouse Gas (GHG) neutral with respect to nitrous oxide (N2O) and methane (CH4).
Technical Paper

System Level Simulation of H2 ICE after Treatment System

2024-04-09
2024-01-2625
Hydrogen Internal Combustion Engines (H2 ICE) are gaining recognition as a nearly emission-free alternative to traditional ICE engines. However, H2 ICE systems face challenges related to thermal management, N2O emissions, and reduced SCR efficiency in high humidity conditions (15% H2O). This study assesses how hydrogen in the exhaust affects after-treatment system components for H2 ICE engines, such as Selective Catalytic Reduction (SCR), Hydrogen Oxidation Catalyst (HOC), and Ammonia Slip Catalyst (ASC). Steady-state experiments with inlet H2 inlet concentrations of 0.25% to 1% and gas stream moisture levels of up to 15% H2O were conducted to characterize the catalyst response to H2 ICE exhaust. The data was used to calibrate and validate system component models, forming the basis for a system simulation.
Technical Paper

Analysis of overcharge tolerance of aged LMO cells with Examples

2023-09-29
2023-32-0108
The capacity of a lithium-ion battery decreases during cycling. This capacity loss or fade occurs due to several different mechanisms associated with unwanted side reactions that occur in these batteries. The same reactions occur during overcharge and cause electrolyte decomposition, passive film formation, active material dissolution, and other phenomena. As the battery ages the accuracy of state of charge prediction decreases and vulnerability to persistent overcharge increases. Moreover, as the battery ages, its tolerance to such unintended overcharge changes. This tolerance depends on the nature of the history of cycle and calendar aging. A map of this tolerance in the BMS can provide awareness of the factor of safety due to overcharge as battery ages. Signatures of early warning signs of incipient thermal runaway due to overcharge can also be very useful features in a BMS.
Journal Article

A One-Way Coupled Modeling Method to Simulate Battery Pack Thermal Runaway Initiated by an External Impact

2023-04-11
2023-01-0593
There is an ongoing proliferation of electric and electrified vehicles as manufacturers seek to reduce their carbon footprint and meet the carbon reduction targets mandated by governments around the world. An ongoing challenge in electric vehicle design is the efficient and safe design of battery packs. There are significant safety challenges for lithium battery packs relating to thermal runaway, which can be initiated through overheating and internal short from defects or external damage. This work proposes a robust method to couple the mechanical damage in a battery module calculated from a dynamic model with a thermal model of the battery that includes heating from electro-chemical sources as well as Arrhenius reactions from the battery cells. The authors identify the main sources of thermal runaway initiation and propagation in an impact scenario simulating a vehicle collision. The modeling approach was developed and validated using test data.
Technical Paper

Comparison of Representative Wet and Dry Fire Suppressants to Retard Fire Propagation in Lithium-Ion Modules Initiated by Overcharge Abuse

2023-04-11
2023-01-0520
Overcharging lithium-ion batteries is a failure mode that is observed if the battery management system (BMS) or battery charger fails to stop the charging process as intended. Overcharging can easily lead to thermal runaway in a battery. In this paper, nickel manganese cobalt (NMC) battery modules from the Chevrolet Bolt, lithium manganese oxide (LMO) battery modules from the Chevrolet Volt, and lithium iron phosphate (LFP) battery modules from a hybrid transit bus were overcharged. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages, gaseous emissions, and feedback from volatile organic compound (VOC) sensors. Overcharging a battery can cause lithium plating and other exothermic reactions that will lead to thermal runaway.
Technical Paper

Greenhouse Gas Reduction from EnviroKool Piston in Lean Burn Natural Gas and Diesel Dual Fuel Heavy Duty Engine

2022-06-14
2022-37-0004
Heavy-duty (HD) internal combustion engines (ICE) have achieved quite high brake thermal efficiencies (BTE) in recent years. However, worldwide GHG regulations have increased the pace towards zero CO2 emissions. This, in conjunction with the ICE reaching near theoretical efficiencies means there is a fundamental lower limit to the GHG emissions from a conventional diesel engine. A large factor in achieving lower GHG emissions for a given BTE is the fuel, in particular its hydrogen to carbon ratio. Substituting a fuel like diesel with compressed natural gas (CNG) can provide up to 25% lower GHG at the same BTE with a sufficiently high substitution rate. However, any CNG slip through the combustion system is penalized heavily due to its large global warming potential compared to CO2. Therefore, new technologies are needed to reduce combustion losses in CNG-diesel dual fuel engines.
Technical Paper

Benefits of a Dual HP and LP EGR Circuit on a Turbocharged Direct Injection Gasoline Engine

2022-03-29
2022-01-0429
Internal combustion engines (ICE) will be a part of personal transportation for the foreseeable future. One recent trend for engines has been downsizing which enables the engine to be run more efficiently over regulatory drive cycles. Due to downsizing, engine power density has increased which leads to problems with engine knock. Therefore, there is an increasing need to find a means to reduce the knock propensity of downsized engines. One of the ways of reducing knock propensity is by introducing Exhaust Gas Recirculation (EGR) into the combustion chamber, however, volumetric efficiency also reduces with EGR which places challenges on the boosting system. The individual benefits of high-pressure (HP-EGR) and low-pressure (LP-EGR) loop EGR system to assist the boosting system of a 2.0 L Gasoline Direct Injection (GDI) production engine are explored in this paper.
Journal Article

A Comparative Study of Lithium-Ion Cathode Chemistry Correlations with Emissions Initiated by Nail Penetration Abuse in the Presence of an Immersive Coolant

2022-03-29
2022-01-0707
Internal short-circuit in cells/batteries is a phenomenon where there is direct electrical contact between the positive and negative electrodes leading to thermal runaway. The nail penetration tests were used to simulate an internal short circuit within the battery, where a conductive nail was used to pierce the battery cell separator membrane which provided direct electrical contact between the positive and negative electrodes. The batteries tested during this work were common batteries used in existing automotive applications, and they included a nickel manganese cobalt (NMC) battery from a Chevrolet Bolt, a lithium manganese oxide (LMO) battery from a Chevrolet Volt, and a lithium iron phosphate (LFP) battery in a hybrid transit bus. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages and gaseous emissions.
Journal Article

A Comparative Study of Lithium-Ion Cathode Chemistry Correlations with Emissions Initiated by Nail Penetration Abuse in the Presence of an Immersive Coolant

2022-03-29
2022-01-0715
Internal short-circuit in cells/batteries is a phenomenon where there is direct electrical contact between the positive and negative electrodes leading to thermal runaway. The nail penetration tests were used to simulate an internal short circuit within the battery, where a conductive nail was used to pierce the battery cell separator membrane which provided direct electrical contact between the positive and negative electrodes. The batteries tested during this work were common batteries used in existing automotive applications, and they included a nickel manganese cobalt (NMC) battery from a Chevrolet Bolt, a lithium manganese oxide (LMO) battery from a Chevrolet Volt, and a lithium iron phosphate (LFP) battery in a hybrid transit bus. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages and gaseous emissions.
Technical Paper

Improving Brake Thermal Efficiency Using High-Efficiency Turbo and EGR Pump While Meeting 2027 Emissions

2021-09-21
2021-01-1154
Commercial vehicles are moving in the direction of improving brake thermal efficiency while also meeting future diesel emission requirements. This study is focused on improving efficiency by replacing the variable geometry turbine (VGT) turbocharger with a high-efficiency fixed geometry turbocharger. Engine-out (EO) NOX emissions are maintained by providing the required amount of exhaust gas recirculation (EGR) using a 48 V motor driven EGR pump downstream of the EGR cooler. This engine is also equipped with cylinder deactivation (CDA) hardware such that the engine can be optimized at low load operation using the combination of the high-efficiency turbocharger, EGR pump and CDA. The exhaust aftertreatment system has been shown to meet 2027 emissions using the baseline engine hardware as it includes a close coupled light-off SCR followed by a downstream SCR system.
Technical Paper

Light Duty Vehicle Life Cycle Analysis

2021-04-06
2021-01-0789
The short-term future direction of the automotive transportation sector is uncertain. Many governments and environmental localities around the world are proposing internal combustion engine (ICE) bans and enacting large subsidy programs for zero-tailpipe emissions vehicles powered by batteries or fuel-cells. Such policies can be effective in driving the consumer towards specific powertrains. The reason for such aggressive change is to reduce the sector’s carbon footprint. However, it is not clear if these proposals will reduce greenhouse gas (GHG) emissions. Emissions from raw material extraction, manufacturing, and power generation are shadowed by the focus on reducing the reliance on fossil fuel use. Emissions from non-tailpipe sources should also be considered before pushing for a rapid change to powertrains. Life-cycle analysis (LCA) can assess the GHG emissions produced before, during and after the life of a vehicle in a cradle-to-grave analysis.
Technical Paper

Advanced 1-D Ignition and Flame Growth Modeling for Ignition and Misfire Predictions in Spark Ignition Engines

2021-04-06
2021-01-0376
Simulating high amounts of exhaust gas recirculation in spark ignited engines to predict combustion using the currently available CFD modeling approaches is a challenge and does not always give reasonable matches with experimental observations. One of the reasons for the mismatch lies with the secondary circuit treatment of the ignition coil and the resulting energy deposition or a complete lack of it thereof. An ignition modeling approach is developed in this work which predicts the energy transfer from the electrical circuit to the gases in the combustion chamber leading to flame kernel growth under high EGR and high gas flow velocity conditions. Secondary circuit sub-model includes secondary side of the coil, spark plug and spark gap. The sub-model calculates the delivered energy to the gas based on given circuit properties and total initial electrical energy.
Technical Paper

Reduced Piston Oil Cooling for Improved Heavy-Duty Vehicle Fuel Economy

2021-04-06
2021-01-0387
Increased electrification of future heavy-duty engines and vehicles can enable many new technologies to improve efficiency. Electrified oil pumps are one such technology that provides the ability to reduce or turn off the piston oil cooling jets and simultaneously reduce the oil pump flow to account for the reduced flow rate required. This can reduce parasitic losses and improve overall engine efficiency. In order to study the potential impact of reduced oil cooling, a GT-Power engine model prediction of piston temperature was calibrated based on measured piston temperatures from a wireless telemetry system. A simulation was run in which the piston oil cooling was controlled to target a safe piston surface temperature and the resulting reduction in oil cooling was determined. With reduced oil cooling, engine BSFC improved by 0.2-0.8% compared to the baseline with full oil cooling, due to reduced heat transfer from the elevated piston temperatures.
Technical Paper

A Comprehensive Numerical Approach to Predict Thermal Runaway in Li-Ion Battery Packs

2021-04-06
2021-01-0748
With the increasing level of electrification of on-road, off-road and stationary applications, use of larger lithium-ion battery packs has become essential. These packs require large capital investments on the order of millions of dollars and pose a significant risk of self-annihilation without rigorous safety evaluation and management. Testing these larger battery packs to validate design changes can be cost prohibitive. A reliable numerical simulation tool to predict battery thermal runaway under various abuse scenarios is essential to engineer safety into the battery pack design stage. A comprehensive testing & simulation workflow has been established to calibrate and validate the numerical modeling approach with the test data for each of the individual sub model - electrochemical, internal short circuit and thermal abuse model. A four-equation thermal abuse model was built and validated for lithium-ion 21700 form factor cylindrical cells using NCA cathodes.
Technical Paper

Oil Consumption Pathway Impact on SCR-on-Filter Functional Performance and Lubricant Derived Ash Characteristics

2021-04-06
2021-01-0578
SCR-on-filter, or SCRoF, is an emerging technology for different market segments and vehicle applications. The technology enables simultaneous particulate matter trapping and NOX reduction, and provides thermal management and aftertreatment packaging benefits. However, there is little information detailing the lubricant derived exposure effects on functional SCR performance. A study was conducted to evaluate the impact of various oil consumption pathways on a light duty DOC and SCRoF aftertreatment system. This aftertreatment system was aged utilizing an engine test bench modified to enable increased oil consumption rates via three unique oil consumption pathways. The components were characterized for functional SCR performance, ash morphology, and ash deposition characteristics. This included utilizing techniques, such as SEM / EDS, to evaluate the ash structures and quantify the ash elemental composition.
Technical Paper

Development of an In-Situ Diagnostic to Detect Lithium Plating in Commercial Automotive Battery Cells

2021-04-06
2021-01-0749
Lithium plating refers to the phenomenon where lithium metal is deposited onto the surface of the anode instead of being intercalated into the carbon sites of the graphite. The lithium metal will cover a portion of the surface area of the anode, which blocks intercalation sites and increases charge gradients. Lithium plating most often occurs when charging the battery at low ambient temperatures or at a high current rate, but lithium plating formation has also been linked to solid electrolyte interface (SEI) growth towards the later stages of life. Lithium plating may significantly reduce a battery cell’s performance in terms of charge capacity, and if severe enough, the lithium metal may form a bridge across the separator of the cell, leading to short circuits and potential safety concerns. The internal research performed by Southwest Research Institute explored how to create a battery model to detect the formation of lithium plating in real time.
Journal Article

On Optical Semi-Quantitative Spectral Study of Low-Speed Pre-Ignition Sources in Spark Ignition Engines

2021-04-06
2021-01-0486
Low-Speed pre-ignition (LSPI) in modern-day, heavily downsized, boosted, and direct-injection spark ignition (SI) engines is a well-known problem. Several mechanisms contribute towards stochastic pre-ignition (SPI), the most prominent being crevice material droplet induced and deposit induced pre-ignition mechanisms. The droplet mechanism is typically dominated by the detergent additives present in the lubricant formulation; more specifically calcium and sodium-based detergent additives correlate strongly with the increased LSPI rates. Deposits flaking off the combustion chamber surfaces can also induce LSPI under certain conditions. This study aimed to develop an optical method designed to investigate the nature of pre-ignition precursors. Southwest Research Institute (SwRI) utilized an optically accessible GM 2.0 L LHU engine to study the pre-ignition phenomenon and studied the nature of pre-ignition precursors using spectral information from one of the cylinders in this engine.
Technical Paper

Modeling and Predicting Mechanically Induced Internal Short Circuits in Lithium Ion Battery Packs

2021-04-06
2021-01-0750
As advances in electrification continue within the vehicle industry, improving the front-end design process and managing the safety aspects of lithium-ion batteries is increasingly important. Structural damage to lithium-ion batteries can cause internal short circuit, leading to a large energy release that can lead to fire and thermal runaway that propagates throughout the battery pack. Southwest Research Institute has developed a mechanical model that can accurately predict mechanically-induced damage to lithium-ion battery cells and battery packs. This model also predicts whether the external damage will cause an internal short-circuit. This modeling process was illustrated using 21700 cylindrical cells with NCA cathode chemistry. High-speed impact tests were used to calibrate a single cell model, which was then scaled to a 12-cell battery module. This model was then used to accurately predict the outcome of an impact test on a 72-cell battery module.
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