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This paper presents an improvement in the accuracy of NOx sensors at high NOx concentration regions by optimizing the manufacturing process, sensor electrode materials and structure, in order to suppress the deterioration mechanism of sensor electrodes. Though NOx sensors generally consist of Pt/Au alloy based oxygen pump electrodes and Pt/Rh alloy based sensor electrodes, detailed experimental analysis of aged NOx sensors showed changes in the surface composition and morphology of the sensor electrode. The surface of the sensor electrode was covered with Au, which is not originally contained in the electrode, resulting in a diminished active site for NOx detection on the sensor electrode and a decrease in sensor output. Theoretical analysis using CAE with molecular dynamics supported that Au tends to be concentrated on the surface of the sensor electrode.

The use of exhaust gas recirculation (EGR) in spark ignition engines has been shown to have a number of beneficial effects under specific operating conditions. These include reducing pumping work under part load conditions, reducing NOx emissions and heat losses by lowering peak combustion temperatures, and by reducing the tendency for engine knock (caused by end-gas autoignition) under certain operating regimes. In this study, the effects of EGR addition on knocking combustion are investigated through a combined experimental and modeling approach. The problem is investigated by considering the effects of individual EGR constituents, such as CO2, N2, and H2O, on knock, both individually and combined, and with and without traces species, such as unburned hydrocarbons and NOx. The effects of engine compression ratio and fuel composition on the effectiveness of knock suppression with EGR addition were also investigated.

Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.

Toyota Motor Corporation is developing a series of engines belonging to its ESTEC (Economy with Superior Thermal Efficient Combustion) development concept. This paper describes the development of 8NR-FTS after the subsequent launch of the 2.0-liter DI Turbocharged 8AR-FTS. 8NR-FTS is a 1.2-liter inline 4-cylinder spark ignition downsized turbocharged direct injection (DI) gasoline engine. By following the same basic concepts as 8AR-FTS engine [1], the 8NR-FTS incorporates various fuel efficient technologies such as a cylinder head with an integrated exhaust manifold, the Atkinson cycle using the center-spooled variable valve timing with mid-position lock system (VVT-iW), and intensified in-cylinder turbulence to achieve high-speed combustion.

This paper presents the effects of a lubricant oil droplet on the start of combustion of a fuel-air mixture. Lubricant oil is thought to be a major source of low-speed pre-ignition in highly boosted spark ignition engines. However, the phenomenon has not yet been fully understood because its unpredictability and the complexity of the mixture in the engine cylinder make analysis difficult. In this study, a single oil droplet in a combustion cylinder was considered as a means of simplifying the phenomenon. The conditions under which a single oil droplet ignites earlier than the fuel-air mixture were investigated. Tests were conducted by using a rapid compression expansion machine. A single oil droplet was introduced into the cylinder through an injector developed for this study. The ignition and the flame propagation were observed through an optical window, using a high-speed video camera.

In this paper, a control strategy to switch NSR (NOx storage and reduction) function from standard DeNOx by rich combustion to DiAir (Diesel NOx After-treatment by Adsorbed Intermediate Reductants) and additional advantages to use HCI (Hydrocarbon Injector) during desulfation were introduced. Investigations under a transient cycle suggest that NOx conversion with DiAir is strongly affected by preliminary NOx storage condition in the NSR catalyst. To avoid NOx breakthrough just after starting HC dosing for DiAir, a rich operation to reduce stored NOx was shown to be important and high NOx conversion could be maintained using this control strategy under a transient cycle. Furthermore, by combining HCI and in-cylinder post injection, usage of rich condition for NSR DeSOx can be expand to wider engine speed and load area.

This paper focuses on the fuel contribution to crankcase engine oil degradation in gasoline fueled engines in view of insoluble formation. The polymerization of degraded fuel is responsible for the formation of insoluble which is considered as a possible cause of low temperature sludge in severe vehicle operating conditions. The main objective of the study is to understand the mechanism of formation of partially oxidized compounds from fuel during the combustion process, before their accumulation in the crankcase oil. A numerical method has been established to calculate the formation of partially oxidized compounds in spark ignition engines directly, by using 3D CFD. To further enable the possibility of running a large number of simulations with a realistic turn-around time, a coupled approach of 3D CFD (with simplified chemical mechanism) and 0D Kinetics (with full chemical mechanism) is proposed here.

As one of spark ignition (SI) engine solutions to improve fuel economy while maintaining drivability, concept of combing turbocharging and direct injection (DI) fuel injection system with engine down-sizing has increased its application in the market. Abnormal combustion phenomena referred to as Low Speed Pre-Ignition (LSPI) has been recognized as potential restriction to improve low speed engine torque that contributes fuel economy improvement. As reported in the part 1 [1], the study showed that engine oil composition had significant influence on the frequency of LSPI in both preventive and contributory effects. Further investigation was conducted to evaluate engine oil formulation variables and other factors that may have influences on the LSPI, such as engine oil degradation. Engine test that consisted of 2 phases was designed in order to confirm the correlation between LSPI frequency and engine oil degradation.

In this study, we combined a diesel engine with the Toyota Hybrid System (THS). Utilizing the functions of the THS, reducing engine friction, lowering the compression ratio, and adopting a low pressure loop exhaust gas recirculation system (LPL-EGR) were examined to achieve both low fuel consumption and low nitrogen oxides (NOx) emissions over a wide operating range. After applying this system to a test vehicle it was verified that the fuel economy greatly surpassed that of a conventional diesel engine vehicle and that NOx emissions could be reduced below the value specified in the Euro 6 regulations without DeNOx catalysts.

Over the last few decades, in-cylinder visualization using optically accessible engines has been an important tool in the detailed analysis of the in-cylinder phenomena of internal combustion engines. However, most current optically accessible engines are recognized as being limited in terms of their speed and load, because of the fragility of certain components such as the elongated pistons and transparent windows. To overcome these speed and load limits, we developed a new generation of optically accessible engines which extends the operating range up to speeds of 6000 rpm for the SI engine version, and up to in-cylinder pressures of 20 MPa for the CI engine version. The main reason for the speed limitation is the vibration caused by the inertia force arising from the heavy elongated piston, which increases with the square of the engine speed.

An unprecedented phenomenon that achieves high NOx conversion was found over an NSR catalyst. This phenomenon occurs when continuous short cycle injections of hydrocarbons (HCs) are supplied at a predetermined concentration in lean conditions. Furthermore, this phenomenon has a wider range of applicability for different catalyst temperatures (up to 800 degrees Celsius) and SVs, and for extending thermal and sulfur durability than a conventional NOx storage and reduction system. This paper analyzes the reaction mechanism and concludes it to be highly active HC-deNOx by intermediates generated from adsorbed NOx over the base catalysts and HCs partially oxidized by oscillated HC injection. Subsequently, a high performance deNOx system named Di-Air (diesel NOx aftertreatment by adsorbed intermediate reductants) was demonstrated that applies this concept to high speed driving cycles.

This research aimed to identify how combustion characteristics are affected by the addition of hydrogen to methane, which is the main components of natural gas, and to study a combustion method that takes advantage of the properties of the blended fuel. It was found that adding hydrogen did not achieve a thermal efficiency improvement effect under stoichiometric conditions because cooling loss increased. The same result was obtained under EGR stoichiometric conditions. In contrast, under lean burn conditions, higher thermal efficiency and lower NOx than with methane combustion was achieved by utilizing the wide flammability range of hydrogen to expand the lean limit. Although NOx can be decreased easily by the addition of large quantities of hydrogen, the substantially lower energy density of the fuel causes a substantial reduction in cruising range. Consequently, this research improved the combustion of a CNG engine by increasing the tumble ratio to 1.8.

This paper describes the development of a High Speed Calculation Diesel Combustion Model that predicts combustion-related behaviors of diesel engines from passenger cars. Its output is dependent on the engine's operating parameters and on input from on-board pressure and temperature sensors. The model was found to be capable of predicting the engine's in-cylinder pressure, rate of heat release, and NOx emissions with a high degree of accuracy under a wide range of operating conditions at a reasonable computational cost. The construction of this model represents an important preliminary step towards the development of an integrated Model Based Control system for controlling combustion in diesel engines used in passenger cars.

The efficiency of the NOx Storage and Reduction (NSR) catalysts used in the aftertreatment of diesel engine exhaust gases can potentially be increased by using reactive reductants such as CO and H₂ that are formed during in-cylinder combustion. In this study, a multi-dimensional computational fluid dynamics (CFD) code coupled with complex chemical analysis was used to study combustion with various fuel after-injection patterns. The results obtained will be useful in designing fuel injection strategies for the efficient formation of CO.

To avoid knocking phenomena, a special crank mechanism for gasoline engine that allowed the piston to move rapidly near TDC (Top Dead Center) was developed and experimentally demonstrated in the previous study. As a result, knocking was successfully mitigated and indicated thermal efficiency was improved [1],[2],[3],[4]. However, performance of the proposed system was evaluated at only limited operating conditions. In the present study, to investigate the effect of piston movement near TDC on combustion characteristics and indicated thermal efficiency and to clarify the knock mitigation mechanism of the proposed method, experimental studies were carried out using a single cylinder engine with a compression ratio of 13.7 at various engine speeds and loads. The special crank mechanism, which allows piston to move rapidly near TDC developed in the previous study, was applied to the test engine with some modification of tooling accuracy.

Diesel engines with relatively good fuel economy are known as an effective means of reducing CO₂ emissions. It is expected that diesel engines will continue to expand as efforts to slow global warming are intensified. Diesel particulate and NOx reduction system (DPNR), which was first developed in 2003 for introduction in the Japanese and European markets, shows high purification performance which can meet more stringent regulations in the future. However, it is poisoned by sulfur components in exhaust gas derived from fuel and lubricant. We then developed the sulfur trap DPNR with a sulfur trap catalyst that traps sulfur components in the exhaust gas. High purification performance could be achieved with a small amount of platinum group metal (PGM) due to prevention of sulfur poisoning and thermal deterioration.

The emission regulations for diesel engines are continually becoming stricter to reduce pollution and conserve energy. To meet these increasingly stringent regulations, a new exhaust after-treatment device is needed. Recently, the authors proposed the simultaneous electrochemical reduction (ECR) system for diesel particulate matter (PM) and NOx. In this method, a gas-permeable electrochemical cell with a porous solid oxide electrolyte is used for PM filtering on the anode. Alkaline earth metal is coated on the cathode for NOx storage. Application of voltage to both electrodes enables the simultaneous reduction of PM and NOx by the forced flow of oxygen ions from the cathode to the anode (oxygen pumping). In this study, the basic characteristics of the ECR system were investigated, and a disk-shaped electrochemical cell was evaluated.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

Premixed diesel combustion modes including low temperature combustion and MK combustion are expected to realize smokeless and low NOx emissions. As ignition must be delayed until after the end of fuel injection to establish these combustion modes, methods for active ignition control are being actively pursued. It is reported that alcohols including methanol and ethanol strongly inhibit low temperature oxidation in HCCI combustion offering the possibility to control ignition with alcohol induction. In this research improvement of diesel combustion and emissions by ethanol intake port injection for the promotion of premixing of the in-cylinder injected diesel fuel, and by increased EGR for the reduction of combustion temperature.

The compression ratio and expansion ratio are fundamental parameters that determine the thermal efficiency of an SI engine, and the potential of setting these ratios to arbitrary values was studied as a way of improving engine efficiency. First, the efficiency resulting from different compression and expansion ratios was calculated from a theoretical formula. As a result, it was verified that a 20% improvement in thermal efficiency could be expected by adopting a super-high expansion ratio of 20 or higher, which is an extremely large value for an SI engine, while keeping the compression ratio within a range that can ensure appropriate combustion. Subsequently, this research calculated the possibility of improving engine efficiency under a condition that constrains the swept volume to a constant value in consideration of practicability.