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It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.

Modern Diesel Engines equipped with Common-Rail Direct Injection and EGR are characterized by an increasingly high combustion efficiency. Consequently the exhaust gas temperature, especially during a cold start, is significantly reduced compared to typical values measured in previous engine generations. This leads to a potential problem with CO emission limit compliance. The present paper deals with an experimental investigation of turbulent-flow metal substrates, carried out on a vehicle roller bench using a production 1.3 Liter diesel engine equipped passenger car. The tested metal supported catalysts proved to yield extremely high conversion rates both during cold start and in warm operation phase. The improved mass transfer efficiency of the advanced metal substrates is related on one hand to the optimized coating technology and, on the other hand, to the enhanced flow performance in the single converter channels which is caused by structured metal foils.