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With ongoing concerns about the elevated levels of ambient air pollution in urban areas and the contribution from heavy-duty diesel vehicles, hybrid electric vehicles are considered as a potential solution as they are perceived to be more fuel efficient and less polluting than their conventional engine counterparts. However, recent studies have shown that real-world emissions may be substantially higher than those measured in the laboratory, mainly due to operating conditions that are not fully accounted for in dynamometer test cycles. At the U.S. EPA National Fuel and Vehicle Emissions Laboratory (NVFEL) the in-use criteria emissions and energy efficiency of heavy-duty class 8 vehicles (up to 36280 kg) can be evaluated under controlled conditions in the heavy-duty chassis dynamometer test.

Early exhaust valve opening (eEVO) increases the exhaust gas temperature by faster termination of the power stroke and is considered as a potential warm up strategy for diesel engines aftertreatment thermal management. In this study, first, it is shown that when eEVO is applied, the engine main variables such as the boost pressure, exhaust gas recirculation (EGR) and injection (timing and quantity) must be re-calibrated to develop the required torque, avoid exceeding the exhaust temperature limits and keep the air fuel ratio sufficiently high. Then, a two-step procedure is presented to optimize the engine operation after the eEVO system is introduced, using a validated diesel engine model. In the first step, the engine variables are optimized at a constant eEVO shift. In the second step, optimal eEVO trajectories are calculated using Dynamic Programming (DP) for a transient test cycle.

Lean NOx Traps (LNTs) are one type of lean NOx reduction technology typically used in smaller diesel passenger cars where urea-based Selective Catalytic Reduction (SCR) systems may be difficult to package . However, the performance of lean NOx traps (LNT) at temperatures above 400 C needs to be improved. The use of Rapidly Pulsed Reductants (RPR) is a process in which hydrocarbons are injected in rapid pulses ahead of a LNT in order to expand its operating window to higher temperatures and space velocities. This approach has also been called Di-Air (diesel NOx aftertreatment by adsorbed intermediate reductants) by Toyota. There is a vast parameter space which could be explored to maximize RPR performance and reduce the fuel penalty associated with injecting hydrocarbons. In this study, the mixing uniformity of the injected pulses, the type of reductant, and the concentration of pulsed reductant in the main flow were investigated.

Advanced engine combustion strategies, such as HCCI and SACI, allow engines to achieve high levels of thermal efficiency with low levels of engine-out NOx emissions. To maximize gains in fuel efficiency, HCCI combustion is often run at lean operating conditions. However, lean engine operation prevents the conventional TWC after-treatment system from reaching legislated tailpipe emissions due to oxygen saturation. One potential solution for handling this challenge without the addition of costly NOx traps or on-board systems for urea injection is the passive TWC-SCR concept. This concept includes the integration of an SCR catalyst downstream of a TWC and the use of periods of rich or stoichiometric operation to generate NH3 over the TWC to be stored on the SCR catalyst until it is needed for NOx reduction during subsequent lean operation.

Selective Catalytic Reduction (SCR) catalysts used in Lean NOx Trap (LNT) - SCR exhaust aftertreatment systems typically encounter alternating oxidizing and reducing environments. Reducing conditions occur when diesel fuel is injected upstream of a reformer catalyst, generating high concentrations of hydrogen (H₂), carbon monoxide (CO), and hydrocarbons to deNOx the LNT. In this study, the functionality of an iron (Fe) zeolite SCR catalyst is explored with a bench top reactor during steady-state and cyclic transient SCR operation. Experiments to characterize the effect of an LNT deNOx event on SCR operation show that adding H₂ or CO only slightly changes SCR behavior with the primary contribution being an enhancement of nitrogen dioxide (NO₂) decomposition into nitric oxide (NO). Exposure of the catalyst to C₃H₆ (a surrogate for an actual exhaust HC mixture) leads to a significant decrease in NOx reduction capabilities of the catalyst.

Diesel exhaust aftertreatment systems are required for meeting Final Tier 4 emission regulations. This paper addresses an aftertreatment system designed to meet the Final Tier 4 emission standards for nonroad vehicle markets. The aftertreatment system consists of a fuel dosing system, mixing elements, fuel vaporizer, fuel reformer, lean NOx trap (LNT), diesel particulate filter (DPF), and an optional selective catalytic reduction (SCR) catalyst. Aftertreatment system performance, both with and without the SCR, was characterized in an engine dynamometer test cell, using a 4.5 liter, pre-production diesel engine. The engine out NOx nominally ranged between 1.6 and 2.0 g/kW-hr while all operating modes ranged between 1.2 and 2.8 g/kW-hr. The engine out particulate matter was calibrated to approximately 0.1 g/kW-hr for various power ratings. Three engine power ratings of 104 kW, 85 kW and 78 kW were evaluated.

Diesel exhaust aftertreatment systems are required for meeting both EPA 2010 and final Tier 4 emission regulations. This paper addresses aftertreatment system performance of a fuel reformer, lean NOx trap (LNT) and selective catalytic reduction (SCR) system designed to meet the EPA 2010 emission standards for an on-highway heavy-duty vehicle. The aftertreatment system consists of a fuel dosing system, mixing elements, fuel reformer, LNT, diesel particulate filter (DPF), and SCR for meeting NOx and particulate emissions. System performance was characterized in an engine dynamometer test cell, using a development, 13L, heavy-duty engine. The catalyst performance was evaluated using degreened catalysts. Test results show that system performance met the EPA 2010 emission standards under a range of test conditions that were reflective of actual vehicle operation.

An advanced exhaust aftertreatment system is characterized following end-of-life catalyst aging to meet final Tier 4 off-highway emission requirements. This system consists of a fuel dosing system, mixing elements, fuel reformer, lean NOx trap (LNT), diesel particulate filter (DPF), and a selective catalytic reduction (SCR) catalyst. The fuel reformer is used to generate hydrogen (H2) and carbon monoxide (CO) from injected diesel fuel. These reductants are used to regenerate and desulfate the LNT catalyst. NOx emissions are reduced using the combination of the LNT and SCR catalysts. During LNT regeneration, ammonia (NH3) is intentionally released from the LNT and stored on the downstream SCR catalyst to further reduce NOx that passed through the LNT catalyst. This paper addresses system durability as the catalysts were aged to 500 desulfation events using an off-highway diesel engine.

This paper addresses Hardware-In-the-Loop modeling and simulation for Diesel aftertreatment controls system development. Lean NOx Trap (LNT) based aftertreatment system is an efficient way to reduce NOx emission from diesel engines. From control system perspective, the main challenge in aftertreatment system is to predict temperature at various locations and estimate the stored NOx in LNT. Accurate estimation of temperatures and NOx stored in the LNT will result in an efficient system control with less fuel penalty while still maintaining the emission requirements. The optimization of the controls will prolong the lifespan of the system by avoiding overheating the catalysts, and slow the progressive process of component aging. Under real world conditions, it is quite difficult and costly to test the performance of a such complex controller by using only vehicle tests and engine cells.

An LNT + SCR diesel aftertreatment system was developed in order to meet the 2010 US HD EPA on-road, and tier 4 US HD EPA off-road emission standards. This system consists of a fuel reformer (REF), lean NOx trap (LNT), catalyzed diesel particulate filter (DPF), and selective catalytic reduction (SCR) catalyst arranged in series to reduce tailpipe nitrogen oxides (NOx) and particulate matter (PM). This system utilizes a REF to produce hydrogen (H2), carbon monoxide (CO) and heat to regenerate the LNT, desulfate the LNT, and actively regenerate the DPF. The NOx stored on the LNT is reduced by the H2 and CO generated in the REF converting it to nitrogen (N2) and ammonia (NH3). NH3, which is normally an undesired byproduct of LNT regeneration, is stored in the downstream SCR which is utilized to further reduce NOx that passes through the LNT. Engine exhaust PM is filtered and trapped by the DPF reducing the tailpipe PM emissions.

The paper covers the NOx performance evaluation of an LNT + SCR system designed to meet the 2010 on-highway heavy-duty (HD) US EPA emission standards. The system combines a fuel reformer catalyst (REF), lean NOx trap (LNT), diesel particulate filter (DPF), and selective catalytic reduction (SCR) in series, to reduce engine-out NOx and PM. System NOx reduction performance was verified in an engine dynamometer test cell, using a 2007 7.6L medium-duty engine. System NOx performance was characterized using fresh LNT and SCR along with hydrothermal aged LNT and fresh SCR. Test results show levels consistent with EPA 2010 limits under various test conditions. Catalysts performance was characterized at eight steady engine-operating conditions (A100, B50, B75, A75, B100, C100, C75, C50, across a 13-mode Supplemental Emission Test (SET), and an on-highway Heavy Duty Federal Test Procedure (HD-FTP).

An advanced exhaust aftertreatment system is being developed using a fuel dosing system, mixing elements, fuel reformer, lean NOx trap (LNT), diesel particulate filter (DPF) and a selective catalytic reduction (SCR) catalyst arranged in series for both on- and off- highway diesel engines to meet the upcoming emissions regulations. This system utilizes a fuel reformer to generate hydrogen (H2) and carbon monoxide (CO) from injected diesel fuel. These reductants are used to regenerate and desulfate the LNT catalyst. NOx emissions are reduced using the combination of the LNT and SCR catalysts. During LNT regeneration, ammonia is intentionally released from the LNT and stored on the downstream SCR catalyst to further reduce NOx that passed through the LNT catalyst. This paper addresses LNT and SCR catalyst degradation as these were subjected to 150 desulfation events using a pre-production 2007 medium heavy-duty, on-highway diesel engine.

An aftertreatment system for medium and heavy-duty diesel engines has been modeled for U.S. 2010 application. The aftertreatment system is comprised of a lean NOx trap (LNT) and an ammonia selective catalytic reduction (SCR) catalyst in series. Descriptions of the fully transient, one-dimensional LNT and SCR models are presented. The models simulate flow, heat transfer, and chemical reactions in the LNT and SCR catalysts. The models can be used to predict catalyst performance over a range of operating conditions and driving cycles. Simulated results of NOx conversion efficiency, species concentrations, and gas temperature were compared to experimental data for a 13-mode test. The model results showed the LNT-SCR model predicts system performance with reasonable accuracy in comparison to experimental data. Therefore, two model applications were investigated. First, LNT and SCR volumes were varied to examine the effect on NOx conversion efficiency and NH3 production.

An aftertreatment system involving a LNT followed by a SCR catalyst is proposed for treating the NOx emissions from a diesel engine. NH3 (or urea) is injected between the LNT and the SCR. The SCR is used exclusively below 400°C due to its high NOx activity at low temperatures and due to its ability to store and release NH3 below 400°C, which helps to minimize NH3 and NOx slip. Above 400°C, where the NH3 storage capacity of the SCR falls to low levels, the LNT is used to store the NOx. A potassium-based LNT is utilized due to its high temperature NOx storage capability. Periodically, hydrocarbons are oxidized on the LNT under net lean conditions to promote the thermal release of the NOx. NH3 is injected simultaneously to reduce the released NOx over the SCR. The majority of the hydrocarbons are oxidized on the front portion of the LNT, resulting in the rapid release of stored NOx from that portion of the LNT.