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Forthcoming worldwide emissions regulations will start regulating ammonia emissions from light duty vehicles. At present, most light duty vehicles are powered by gasoline spark ignition engines. Sources of ammonia emission from such engines can be in-cylinder reactions (i.e. combustion) or downstream reactions across aftertreatment devices, particularly three-way catalysts. The latter has been known to be a major source of ammonia emissions from gasoline vehicles and has been extensively investigated. The former (combustion), less so, and thus is the subject of this work. A two-zone thermodynamic spark ignition engine model with a comprehensive chemical kinetics framework (C3MechV3.3 mechanism), after being validated against experimental ammonia emissions data, is used to study ammonia formation during combustion.

High altitude ice crystals have led to instances of ice accretion on stationary compressor surfaces in aeroengines. Rollback, surge and stall events are known to have been instigated through such accretions due to aerodynamic losses related to ice growth, damage and flameout due to ice shedding. The prevalence of these events has led to a change in certification requirements for icing conditions. Development of accurate numerical models allows the costs of certification and testing to be minimised. An in-house computational code was developed at the Oxford Thermofluids Institute to model glaciated and mixed-phase ice crystal icing. The Ice Crystal Icing ComputationaL Environment (ICICLE) code, comprises a frozen 2D flowfield solution, Lagrangian particle tracking, particle heat transfer and phase change and particle surface interaction modelling.

Extending the planar Particle Image Velocimetry (PIV) technique to enable measurements on multiple planes simultaneously allows for some of the 3 dimensional nature of unsteady flow fields to be investigated. This requires less hardware and retains the typically higher spatial resolution of planar PIV compared to fully 3-dimensional PIV techniques. Performing multi-plane PIV measurements requires the light scattered from the different measurement planes to be distinguishable. This may be achieved by using different laser wavelengths which adds significantly to the expense and complexity of the system, by using different light sheet polarisations which is challenging for engine measurements through windows due to stress-induced birefringence, or by making alternating measurements of each plane which sacrifices the simultaneity of the flow measurement across multiple planes.

Low temperature heat release (LTHR) has been of interest to researchers for its potential to mitigate knock in spark ignition (SI) engines and control auto-ignition in advanced compression ignition (ACI) engines. Previous studies have identified and investigated LTHR in both ACI and SI engines before the main high temperature heat release (HTHR) event by appropriately curating the in-cylinder thermal state during compression, or in the case of SI engines, timing the spark discharge late to reveal LTHR (sometimes referred to as pre-spark heat release). In this work, LTHR is demonstrated in isolation from HTHR events. Tests were run on motored single-cylinder engines and inlet air temperatures and pressures were adjusted to realise LTHR from n-heptane and iso-octane (2,2,4-trimethylpentane) without entering the HTHR regime. LTHR was observed for a lean n-heptane-air mixture at inlet temperatures ranging from 60°C to 100°C and inlet pressures of 0.9 bar (absolute).

In this study, the role of turbulence-chemistry interaction in diesel spray auto-ignition, flame stabilization and end of injection phenomena is investigated under engine relevant “Spray A” conditions. A recently developed diesel spray combustion modeling approach, Conditional Source-term Estimation (CSE-FGM), is coupled with Reynolds-averaged Navier-Stokes simulation (RANS) framework to study the details of spray combustion. The detailed chemistry mechanism is included through the Flamelet Generated Manifold (FGM) method. Both unsteady and steady flamelet solutions are included in the manifold to account for the auto-ignition process and the subsequent flame propagation in a diesel spray. Conditionally averaged chemical source terms are closed by the conditional scalars obtained in the CSE routine. Both non-reacting and reacting spray jets are computed over a wide range of Engine Combustion Network (ECN) diesel. “Spray A” conditions.

This study looked into the application of active thermal coatings on the surfaces of the combustion chamber as a method of improving the thermal efficiency of internal combustion engines. The active thermal coating was applied to a production aluminium piston and its performance was compared against a reference aluminium piston on a single-cylinder diesel engine. The two pistons were tested over a wide range of speed/load conditions and the effects of EGR and combustion phasing on engine performance and tailpipe emissions were also investigated. A detailed energy balance approach was employed to study the thermal behaviour of the active thermal coating. In general, improvements in indicated specific fuel consumption were not statistically significant for the coated piston over the whole test matrix. Mean exhaust temperature showed a marginal increase with the coated piston of up to 6 °C.

High altitude ice crystals can pose a threat to aircraft engine compression and combustion systems. Cases of engine damage, surge and rollback have been recorded in recent years, believed due to ice crystals partially melting and accreting on static surfaces (stators, endwalls and ducting). The increased awareness and understanding of this phenomenon has resulted in the extension of icing certification requirements to include glaciated and mixed phase conditions. Developing semi-empirical models is a cost effective way of enabling certification, and providing simple design rules for next generation engines. A comprehensive ice crystal icing model is presented in this paper, the Ice Crystal Icing ComputationaL Environment (ICICLE). It is modular in design, comprising a baseline code consisting of an axisymmetric or 2D planar flowfield solution, Lagrangian particle tracking, air-particle heat transfer and phase change, and surface interactions (bouncing, fragmentation, sticking).

Combustion recession, an end of injection (EOI) diesel spray phenomenon, has been found to be a robust correlation parameter for UHC in diesel LTC strategies. Previous studies have shown that the likelihood of capturing combustion recession in numerical simulations is highly dependent on the details of the low-temperature chemistry reaction mechanisms employed. This study aims to further the understanding of the effects of different chemical mechanisms in the prediction of a reactive diesel spray and its EOI process: combustion recession. Studies were performed under the Engine Combustion Network’s (ECN) “Spray A” conditions using the Reynolds-Averaged Navier-Stokes simulation (RANS) and the Flamelet Generated Manifold (FGM) combustion model with four different chemical mechanisms for n-dodecane that are commonly used in the engine simulation communities - including recently developed reduced chemistry mechanisms.

Chromium-molybdenum alloy steel pistons, which have been used in commercial vehicle applications for some time, have more recently been proposed as a means of improving thermal efficiency in light-duty applications. This work reports a comparison of the effects of geometrically similar aluminium and steel pistons on the combustion characteristics and energy flows on a single cylinder high-speed direct injection diesel research engine tested at two speed / load conditions (1500 rpm / 6.9 bar nIMEP and 2000 rpm/25.8 bar nIMEP) both with and without EGR. The results indicate that changing to an alloy steel piston can provide a significant benefit in brake thermal efficiency at part-load and a reduced (but non-negligible) benefit at the high-load condition and also a reduction in fuel consumption. These benefits were attributed primarily to a reduction in friction losses.

In-cylinder temperatures and their cyclic variations strongly influence many aspects of internal combustion engine operation, from chemical reaction rates determining the production of NOx and particulate matter to the tendency for auto-ignition leading to knock in spark ignition engines. Spatially resolved measurements of temperature can provide insights into such processes and enable validation of Computational Fluid Dynamics simulations used to model engine performance and guide engine design. This work uses a combination of Two-Colour Planar Laser Induced Fluorescence (TC-PLIF) and Laser Induced Grating Spectroscopy (LIGS) to measure the in-cylinder temperature distributions of a firing optically accessible spark ignition engine. TC-PLIF performs 2-D temperature measurements using fluorescence emission in two different wavelength bands but requires calibration under conditions of known temperature, pressure and composition.

Accurate measurement of exhaust gas temperature in internal combustion engines is essential for a wide variety of monitoring and design purposes. Typically these measurements are made with thermocouples, which may vary in size from 0.05 mm (for fast response applications) to a few millimetres. In this work, the exhaust of a single cylinder diesel engine has been instrumented both with a fast-response probe (comprising of a 50.8 μm, 127 μm and a 254 μm thermocouple) and a standard 3 mm sheathed thermocouple in order to assess the performance of these sensors at two speed/load conditions. The experimental results show that the measured time-average exhaust temperature is dependent on the sensor size, with the smaller thermocouples indicating a lower average temperature for both speed/load conditions. Subject to operating conditions, measurement discrepancies of up to ~80 K have been observed between the different thermocouples used.

Diesel engine designers often use swirl flaps to increase air motion in cylinder at low engine speeds, where lower piston velocities reduce natural in-cylinder swirl. Such in-cylinder motion reduces smoke and CO emissions by improved fuel-air mixing. However, swirl flaps, acting like a throttle on a gasoline engine, create an additional pressure drop in the inlet manifold and thereby increase pumping work and fuel consumption. In addition, by increasing the fuel-air mixing in cylinder the combustion duration is shortened and the combustion temperature is increased; this has the effect of increasing NOx emissions. Typically, EGR rates are correspondingly increased to mitigate this effect. Late inlet valve closure, which reduces an engine’s effective compression ratio, has been shown to provide an alternative method of reducing NOx emissions.

The analysis of thermal fields in the underhood region is complicated by the complex geometry and the influence of a multitude of different heat sources. This complexity means that running full CFD analyses to predict the thermal field in this region is both computationally expensive and time consuming. A method of predicting the thermal field using linear superposition has been developed in order to analyse the underhood region of a simplified Formula One race car, though the technique is applicable to all vehicles. The use of linear superposition allows accurate predictions of the thermal field within a complex geometry for varying boundary conditions with negligible computational costs once the initial characterisation CFD has been run. A quarter scale, rear end model of a Formula One race car with a simplified internal assembly is considered for analysis, though the technique can also be applied to commercial and industrial vehicles.

Engine optimization requires a good understanding of the in-cylinder heat transfer since it affects the power output, engine efficiency and emissions of the engine. However little is known about the convective heat transfer inside the combustion chamber due to its complexity. To aid the understanding of the heat transfer phenomena in a Spark Ignition (SI) engine, accurate measurements of the local instantaneous heat flux are wanted. An improved understanding will lead to better heat transfer modelling, which will improve the accuracy of current simulation software. In this research, prototype thin film gauge (TFG) heat flux sensors are used to capture the transient in-cylinder heat flux within a Cooperative Fuel Research (CFR) engine. A two-zone temperature model is linked with the heat flux data. This allows the distinction between the convection coefficient in the unburned and burned zone.

Model M15 gasoline fuels have been created from pure fuel components, to give independent control of volatility, the heavy end content and the aromatic content, in order to understand the effect of the fuel properties on Gasoline Direct Injection (GDI) fuel spray behaviour and the subsequent particulate number emissions. Each fuel was imaged at a range of fuel temperatures in a spray rig and in a motored optical engine, to cover the full range from non-flashing sprays through to flare flashing sprays. The spray axial penetration (and potential piston and liner impingement), and spray evaporation rate were extracted from the images. Firing engine tests with the fuels with the same fuel temperatures were performed and exhaust particulate number spectra captured using a DMS500 Mark II Particle Spectrometer.

To optimize internal combustion engines (ICEs), a good understanding of engine operation is essential. The heat transfer from the working gases to the combustion chamber walls plays an important role, not only for the performance, but also for the emissions of the engine. Besides, thermal management of ICEs is becoming more and more important as an additional tool for optimizing efficiency and emission aftertreatment. In contrast little is known about the convective heat transfer inside the combustion chamber due to the complexity of the working processes. Heat transfer measurements inside the combustion chamber pose a challenge in instrumentation due to the harsh environment. Additionally, the heat loss in a spark ignition (SI) engine shows a high temporal and spatial variation. This poses certain requirements on the heat flux sensor. In this paper we examine the heat transfer in a production SI ICE through the use of Thin Film Gauge (TFG) heat flux sensors.

Knocking combustion places a major limit on the performance and efficiency of spark ignition engines. Spontaneous ignition of the unburned air-fuel mixture ahead of the flame front leads to a rapid release of energy, which produces pressure waves that cause the engine structure to vibrate at its natural frequencies and produce an audible ‘pinging’ sound. In extreme cases of knock, increased temperatures and pressures in the cylinder can cause severe engine damage. Damage is thought to be caused by thermal strain effects that are directly related to the heat flux. Since it will be the maximum values that are potentially the most damaging, then the heat flux needs to be measured on a cycle-by-cycle basis. Previous work has correlated heat flux with the pressure fluctuations on an average basis, but the work here shows a correlation on a cycle-by-cycle basis. The in-cylinder pressure and surface temperature were measured using a pressure transducer and eroding-type thermocouple.

Homogeneous charge compression ignition (HCCI) engines are a promising alternative to traditional spark- and compression-ignition engines, due to their high thermal efficiency and near-zero emissions of NOx and soot. Simulation software is an essential tool in the development and optimization of these engines. The heat transfer submodel used in simulation software has a large influence on the accuracy of the simulation results, due to its significant effect on the combustion. In this work several empirical heat transfer models are assessed on their ability to accurately predict the heat flux in a CFR engine during HCCI operation. Models are investigated that are developed for traditional spark- and compression-ignition engines such as those from Annand [1], Woschni [2] and Hohenberg [3] and also models developed for HCCI engines such as those from Chang et al. [4] and Hensel et al. [5].

Models for the convective heat transfer from the combustion gases to the walls inside a spark ignition engine are an important keystone in the simulation tools which are being developed to aid engine optimization. The existing models have, however, been cited to be inaccurate for hydrogen, one of the alternative fuels currently investigated. One possible explanation for this inaccuracy is that the models do not adequately capture the effect of the gas properties. These have never been varied in a wide range because air and ‘classical’ fossil fuels have similar values, but they are significantly different in the case of hydrogen. As a first step towards a fuel independent heat transfer model, we have investigated the effect of the gas properties on the heat flux in a spark ignition engine.

Planar Laser-Induced Fluorescence has been widely accepted and applied to measurements of fuel concentration distributions in IC engines. The need for such measurements has increased with the introduction of Direct Injection (DI) gasoline engines, where it is critical to understand the influence of mixture inhomogeneity on ignition and subsequent combustion, and in particular the implications for cyclic variability. The apparent simplicity of PLIF has led to misunderstanding of the technique when applied to quantitative measurements of fuel distributions. This paper presents a series of engineering methods for optimizing, calibrating and referencing, which together demonstrate a quantitative measure of fuel concentration with an absolute accuracy of 10%. PLIF is widely used with single component fuels as carriers for the fluorescent tracers.