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Quasicrystalline (QC) coatings were evaluated as leading-edge protection materials for rotor craft blades. The QC coatings were deposited using high velocity oxy-fuel thermal spray and predominantly Al-based compositions. Ice adhesion, interfacial toughness with ice, wettability, topography, and durability were assessed. QC-coated sand-blasted carbon steel exhibited better performance in terms of low surface roughness (Sa ~ 0.2 μm), liquid repellency (water contact angles: θadv ~85°, θrec ~23°), and better substrate adhesion compared to stainless steel substrates. To enhance coating performance, QC-coated sand-blasted carbon steel was further exposed to grinding and polishing, followed by measuring surface roughness, wettability, and ice adhesion strength. This reduced the surface roughness of the QC coating by 75%, resulting in lower ice adhesion strengths similar to previously reported values (~400 kPa).

Experiments were performed on a small-bore optically accessible engine to investigate diesel pilot ignition (DPI) and reactivity controlled compression ignition (RCCI) dual-fuel combustion strategies with direct injection of natural gas and diesel. Parametric variations of pilot ratio were performed. Natural luminosity and OH chemiluminescence movies of the combustion processes were captured at 28.8 and 14.4 kHz, respectively. These data were used to create ignition maps, which aided in comparing the propagation modes of the two combustion strategies. Lower pilot ratios resulted in lower initial heat release rates, and the initial ignition sites were generally smaller and less luminous; for increased pilot ratios the initial portion of the heat release was larger, and the ignition sites were large and bright. Comparisons between diesel pilot ignition and reactivity controlled compression ignition showed differences in combustion propagation mechanisms.

Particulate matter emissions from gasoline direct injection engines are a concern due to the health effects associated with ultrafine particles. This experimental study investigated sources of particulate matter emissions variability observed in previous tests and also examined the effect of ethanol content in gasoline on particle number (PN) concentrations and particle mass (PM) emissions. FTIR measurements of gas phase hydrocarbon emissions provided evidence that changes in fuel composition were responsible for the variability. Exhaust emissions of toluene and ethanol correlated positively with emitted PN concentrations, while emissions of isobutylene correlated negatively. Exhaust emissions of toluene and isobutylene were interpreted as markers of gasoline aromatic content and gasoline volatility respectively.

Metallic open-cell foams have proven to be valuable for many engineering applications. Their success is mainly related to mechanical strength, low density, high specific surface, good thermal exchange, low flow resistance and sound absorption properties. The present work aims to investigate three principal aspects of real foams: the geometrical characterization, the flow regime characterization, the effects of the pore size and the porosity on the pressure drop. The first aspect is very important, since the geometrical properties depend on other parameters, such as porosity, cell/pore size and specific surface. A statistical evaluation of the cell size of a foam sample is necessary to define both its geometrical characteristics and the flow pattern at a given input velocity. To this purpose, a procedure which statistically computes the number of cells and pores with a given size has been implemented in order to obtain the diameter distribution.

Widely used in automotive industry, lightweight metallic structures are a key contributor to fuel efficiency and reduced emissions of vehicles. Lightweight structures are traditionally designed through employing the material distribution techniques sequentially. This approach often leads to non-optimal designs due to constricting the design space in each step of the design procedure. The current study presents a novel Multidisciplinary Design Optimization (MDO) framework developed to address this issue. Topology, topography, and gauge optimization techniques are employed in the development of design modules and Particle Swarm Optimization (PSO) algorithm is linked to the MDO framework to ensure efficient searching in large design spaces often encountered in automotive applications. The developed framework is then further tailored to the design of an automotive Cross-Car Beam (CCB) assembly.

Large-scale emergency or off-grid power generation is typically achieved through diesel or natural gas generators. To meet governmental emission requirements, emission control systems (ECS) are required. In operation, effective control over the generator’s acoustic emission is also necessary, and can be accomplished within the ECS system. Plug flow mufflers are commonly used, as they provide a sufficient level of noise attenuation in a compact structure. The key design parameter is the transmission loss of the muffler, as this dictates the level of attenuation at a given frequency. This work implements an analytically decoupled solution, using multiple perforate impedance models, through the transfer matrix method (TMM) to predict the transmission loss based on the muffler geometry. An equivalent finite element model is implemented for numerical simulation. The analytical results and numerical results are then evaluated against experimental data from literature.

This study investigates the life cycle greenhouse gas (GHG) emissions of a set of vehicles using two real-world gliders (vehicles without powertrains or batteries); a steel-intensive 2013 Ford Fusion glider and a multi material lightweight vehicle (MMLV) glider that utilizes significantly more aluminum and carbon fiber. These gliders are used to develop lightweight and conventional models of internal combustion engine vehicles (ICV), hybrid electric vehicles (HEV), and battery electric vehicles (BEV). Our results show that the MMLV glider can reduce life cycle GHG emissions despite its use of lightweight materials, which can be carbon intensive to produce, because the glider enables a decrease in fuel (production and use) cycle emissions. However, the fuel savings, and thus life cycle GHG emission reductions, differ substantially depending on powertrain type. Compared to ICVs, the high efficiency of HEVs decreases the potential fuel savings.

Biodiesel and other renewable fuels are of interest due to their impact on energy supplies as well as their potential for carbon emissions reductions. Waste animal fats from meat processing facilities, which would otherwise be sent to landfill, have been proposed as a feedstock for biodiesel production. Emissions from biodiesel fuels derived from vegetable oils have undergone intense study, but there remains a lack of data describing the emissions implications of using animal fats as a biodiesel feedstock. In this study, emissions of NOx, unburned hydrocarbons and particulate matter from a compression ignition engine were examined. The particulate matter emissions were characterized using gravimetric analysis, elemental carbon analysis and transmission electron microscopy. The emissions from an animal fat derived B20 blend were compared to those from petroleum diesel and a soy derived B20 blend.

Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

Reactivity Controlled Compression Ignition (RCCI) is an engine combustion strategy that produces low NO and PM emissions with high thermal efficiency. Previous RCCI research has been investigated in single-cylinder heavy-duty engines. The current study investigates RCCI operation in a light-duty multi-cylinder engine at 3 operating points. These operating points were chosen to cover a range of conditions seen in the US EPA light-duty FTP test. The operating points were chosen by the Ad Hoc working group to simulate operation in the FTP test. The fueling strategy for the engine experiments consisted of in-cylinder fuel blending using port fuel-injection (PFI) of gasoline and early-cycle, direct-injection (DI) of diesel fuel. At these 3 points, the stock engine configuration is compared to operation with both the original equipment manufacturer (OEM) and custom-machined pistons designed for RCCI operation.

This paper presents a large eddy simulation study of the liquid spray mixing with hot ambient gas in a constant volume vessel under engine-like conditions with the injection pressure of 1500 bar, ambient density 22.8 kg/m₃, ambient temperature of 900 K and an injector nozzle of 0.09 mm. The simulation results are compared with the experiments carried out by Pickett et al., under similar conditions. Under modern direct injection diesel engine conditions, it has been argued that the liquid core region is small and the droplets after atomization are fine so that the process of spray evaporation and mixing with the air is controlled by the heat and mass transfer between the ambient hot gas and central fuel flow. To examine this hypothesis a simple spray breakup model is tested in the present LES simulation. The simulations are performed using an open source compressible flow solver, in OpenFOAM.

More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number-based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample-handling methods have been implemented in an engine test cell with a spark-ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion.

This study investigates the potential of controlling premixed charge compression ignition (PCCI and HCCI) combustion strategies by varying fuel reactivity. In-cylinder fuel blending using port fuel injection of gasoline and early cycle direct injection of diesel fuel was used for combustion phasing control at both high and low engine loads and was also effective to control the rate of pressure rise. The first part of the study used the KIVA-CHEMKIN code and a reduced primary reference fuel (PRF) mechanism to suggest optimized fuel blends and EGR combinations for HCCI operation at two engine loads (6 and 11 bar net IMEP). It was found that the minimum fuel consumption could not be achieved using either neat diesel fuel or neat gasoline alone, and that the optimal fuel reactivity required decreased with increasing load. For example, at 11 bar net IMEP, the optimum fuel blend and EGR rate for HCCI operation was found to be PRF 80 and 50%, respectively.

This article presents nondestructive neutron computed tomography (nCT) measurements of Diesel Particulate Filters (DPFs) as a method to measure ash and soot loading in the filters. Uncatalyzed and unwashcoated 200cpsi cordierite DPFs exposed to 100% biodiesel (B100) exhaust and conventional ultra low sulfur 2007 certification diesel (ULSD) exhaust at one speed-load point (1500 rpm, 2.6 bar BMEP) are compared to a brand new (never exposed) filter. Precise structural information about the substrate as well as an attempt to quantify soot and ash loading in the channel of the DPF illustrates the potential strength of the neutron imaging technique.

The goal of this research is to investigate the physical parameters of stoichiometric operation of a diesel engine under a light load operating condition (6∼7 bar IMEP). This paper focuses on improving the fuel efficiency of stoichiometric operation, for which a fuel consumption penalty relative to standard diesel combustion was found to be 7% from a previous study. The objective is to keep NOx and soot emissions at reasonable levels such that a 3-way catalyst and DPF can be used in an aftertreatment combination to meet 2010 emissions regulation. The effects of intake conditions and the use of group-hole injector nozzles (GHN) on fuel consumption of stoichiometric diesel operation were investigated. Throttled intake conditions exhibited about a 30% fuel penalty compared to the best fuel economy case of high boost/EGR intake conditions. The higher CO emissions of throttled intake cases lead to the poor fuel economy.

It has been known from multi-zone simulations that HCCI combustion can be significantly affected by temperature stratification of the in-cylinder gas. With the same combustion timing (i.e. crank angles at 50% heat release, denoted as CA50), large temperature stratification tends to prolong the combustion duration and lower down the in-cylinder pressure-rise-rate. With low pressure-rise-rate HCCI engines can be operated at high load, therefore it is of practical importance to look into more details about how temperature stratification affects the auto-ignition process. It has been realized that multi-zone simulations can not account for the effects of spatial structures of the stratified temperature field, i.e. how the size of the hot and cold spots in the temperature field could affect the auto-ignition process. This question is investigated in the present work by large eddy simulation (LES) method which is capable of resolving the in-cylinder turbulence field in space and time.

Homogeneous charge compression ignition (HCCI) combustion is considered to be an attractive alternative to traditional internal combustion engine operation because of its extremely low levels of pollutant emissions. However, there are several difficulties that must be overcome for HCCI practical use, such as difficult ignition timing controllability. Indeed, too early or too late ignition can occur with obvious drawbacks. In addition, the increase in cyclic variation caused by the ignition timing uncertainty can lead to uneven engine operation. As a way to solve the combustion phasing control problem, dual-fuel combustion has been proposed. It consists of a diesel pilot injection used to ignite a pre-mixture of gasoline (or other high octane fuel) and air. Although dual-fuel combustion is an attractive way to achieve controllable HCCI operation, few studies are available to help the understanding of its in-cylinder combustion behavior.

Prior HCCI optical engine experiments utilizing laser-induced fluorescence (LIF) measurements of stratified fuel-air mixtures have demonstrated the utility of probability density function (PDF) statistics for correlating mixture preparation with combustion. However, PDF statistics neglect all spatial details of in-cylinder fuel distribution. The current computational paper examines the effects of spatial fuel distribution on combustion using a novel combination of a 3-D CFD model with a 1-D linear-eddy model of turbulent mixing. In the simulations, the spatial coarseness of initial fuel distribution prior to the start of heat release is varied while keeping PDF statistics constant. Several cases are run, and as the initial mixture is made coarser, combustion phasing monotonically advances due to high local equivalence ratios that persist longer. The effect of turbulent mixing is more complex.

Power supply systems play a very important role in applications of everyday life. Mainly, for low power generation, there are two ways of producing energy: electrochemical batteries and small engines. In the last few years many improvements have been carried out in order to obtain lighter batteries with longer duration but unfortunately the energy density of 1 MJ/kg seems to be an asymptotic value. If the energy source is an organic fuel with an energy density of around 29 MJ/kg and a minimum overall efficiency of only 3.5%, this device can surpass the batteries. Nowadays the most efficient combustion process is HCCI combustion which is able to combine high energy conversion efficiency and low emission levels with a very low fuel consumption. In this paper, an investigation has been carried out concerning the effects of the compression ratio on the performance and emissions of a mini, Vd = 4.11 [cm3], HCCI engine fueled with diethyl ether.

Power supply systems play a very important role in everyday life applications. There are mainly two ways of producing energy for low power generation: electrochemical batteries and small engines. In the last few years, many improvements have been carried out in order to obtain lighter batteries with longer durations but unfortunately the energy density of 1 MJ/kg seems to be an asymptotic value. An energy source constituted of an organic fuel with an energy density around 29 MJ/kg and a minimum overall efficiency of only 3.5% could surpass batteries. Nowadays, the most efficient combustion process is HCCI combustion which has the ability to combine a high energy conversion efficiency with low emission levels and a very low fuel consumption. The present paper describes an investigation carried out on a modified model airplane engine, on how a pure HCCI combustion behaves in a small volume, Vd = 4.11 cm3, at very high engine speeds (up to 17,500 [rpm]).