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The Particle Number–Portable Emission Measurement System (PN-PEMS) came into force with Euro VI Phase E regulations starting January 1, 2022. However, positive ignition (PI) engines must comply from January 1, 2024. The delay was due to the unavailability of the PN-PEMS system that could withstand high concentrations of water typically present in the tailpipe (TP) of CNG vehicles, which was detrimental to the PN-PEMS systems. Thus, this study was designed to evaluate the condensation particle counter (CPC)-based PN-PEMS measurement capabilities that was upgraded to endure high concentration of water. The PN-PEMS measurement of solid particle number (SPN23) greater than 23 nm was compared against the laboratory-grade PN systems in four phases. Each phase differs based upon the PN-PEMS and PN system location and measurements were made from three different CNG engines. In the first phase, systems measured the diluted exhaust through constant volume sampler (CVS) tunnel.

Biodiesel is a promising alternative to traditional diesel fuel due to its similar combustion properties to diesel and lower carbon emissions on a well-to-wheel basis. However, combusting biodiesel still generates hydrocarbon (HC), CO, NOx and particulate matter (PM) emissions, similar to those from traditional diesel fuel usage. Therefore, aftertreatment systems will be required to reduce these emissions to meet increasingly stringent emission regulations to minimize the impact to the environment. Diesel oxidation catalysts (DOC) are widely used in modern aftertreatment systems to convert unburned HC and CO, to partially convert NO to NO2 to enhance downstream selective catalytic reaction (SCR) catalyst efficiency via fast SCR and to periodically clean-up DPF via controlled soot oxidation. In this work, we focus on the performance difference between biodiesel and diesel over a commercial DOC catalyst to identify the knowledge gap during the transition from diesel fuel to biodiesel.

The steam reforming of CH4 plays a crucial role in the high-temperature activity of natural gas three-way catalysts. Despite existing reports on sulfur inhibition in CH4 steam reforming, there is a limited understanding of sulfur storage and removal dynamics under various lambda conditions. In this study, we utilize a 4-Mode sulfur testing approach to elucidate the dynamics of sulfur storage and removal and their impact on three-way catalyst performance. We also investigate the influence of sulfur on CH4 steam reforming by analyzing CH4 conversions under dithering, rich, and lean reactor conditions. In the 4-Mode sulfur test, saturating the TWC with sulfur at low temperatures emerges as the primary cause of significant three-way catalyst performance degradation. After undergoing a deSOx treatment at 600 °C, NOx conversions were fully restored, while CH4 conversions did not fully recover.

The prediction accuracy of a three-way catalyst (TWC) model is highly associated with the ability of the model to incorporate the reaction kinetics of the emission process as a lambda function. In this study, we investigated the O2 and H2 concentration profiles of TWC reactions and used them as critical inputs for the development of a global TWC model. We presented the experimental data and global kinetic model showing the impact of thermal degradation on the performance of the TWC. The performance metrics investigated in this study included CH4, NOx, and CO conversions under lean, rich, and dithering light-off conditions to determine the kinetics of oxidation reactions and reduction/reforming/water-gas shift reactions as a function of thermal aging. The O2 and H2 concentrations were measured using mass spectrometry to track the change in the oxidation state of the catalyst and to determine the mechanism of the reactions under these light-off conditions.

Three-way catalysts have been used in a variety of stoichiometric natural gas engines for emission control. During real-world operation, these catalysts have experienced a large number of temporary and permanent deactivations including thermal aging and chemical contamination. Thermal aging is typically induced either by high engine-out exhaust temperatures or the reaction exotherm generated on the catalysts. Chemical contamination originates from various inorganic species such as Phosphorous (P) and Sulfur (S) that contain in engine fluids, which can poison and/or mask the catalyst active components. Such deactivations are quite difficult to simulate under laboratory conditions, due to the fact that multiple deactivation modes may occur at the same time in the real-world operations. In this work, a set of field-aged TWCs has been analyzed through detailed laboratory research in order to identify and quantify the real-world aging mechanisms.

Oxygen storage capacity (OSC) is one of the most critical characteristics of a three-way catalyst (TWC) and is closely related to the catalyst aging and performance. In this study, a dynamic OSC model involving two oxygen storage sites with distinct kinetics was developed. The dual-site OSC model was validated on a bench reactor and a natural gas engine. The model was capable of predicting temperature dependence on OSC with H2, CO and CH4 as reductants. Also, the effects of oxygen concentration and space velocity on the amount of OSC were captured by the model. The validated OSC model was applied to simulate lean breakthrough phenomena with varied space velocities and oxygen concentrations. It is found that OSC during lean breakthrough is not a constant for a particular TWC catalyst and is dependent on space velocity and oxygen concentration. Specifically, breakthrough time exhibits a non-linear, inverse correlation to oxygen flux.

This paper examines the combustion and emissions produced using a prototype fuel injector nozzle for pilot-ignited direct-injection natural gas engines. In the new geometry, 7 individual equally-spaced gas injection holes were replaced by 7 pairs of closely-aligned holes (“paired-hole nozzle”). The paired-hole nozzle was intended to reduce particulate formation by increasing air entrainment due to jet interaction. Tests were performed on a single-cylinder research engine at different speeds and loads, and over a range of fuel injection and air handling conditions. Emissions were compared to those resulting from a reference injector with equally spaced holes (“single-hole nozzle”). Contrary to expectations, the CO and PM emissions were 3 to 10 times higher when using the paired-hole nozzles. Despite the large differences in emissions, the relative change in emissions in response to parametric changes was remarkably similar for single-hole and paired-hole nozzles.

Conditional source-term estimation (CSE) is a novel chemical closure method for the simulation of turbulent combustion. It is less restrictive than flamelet-based models since no assumption is made regarding the combustion regime of the flame; moreover, it is computationally cheaper than conventional conditional moment closure (CMC) models. To date, CSE has only been applied for simulating canonical laboratory flames such as steady Bunsen burner flames. Industry-relevant problems pose the challenge of accurately modelling a transient ignition process in addition to involving complex domaingeometries. In this work, CSE is used to model combustion in a homogeneous-charge natural gas fuelled SI engine. The single cylinder Ricardo Hydra research engine studied here has a relatively simple chamber geometry which is represented by an axisymmetric mesh; moving-mesh simulations are conducted using the open-source computational fluid dynamics software, OpenFOAM.

Dual-fuel combustion strategies combining a premixed charge of natural gas and a pilot injection of diesel fuel offer the potential to reduce CO2 emissions as a result of the high Hydrogen/Carbon (H/C) ratio of methane gas. Moreover, the high octane number of methane means that dual-fuel combustion strategies can be employed on compression ignition engines without the need to vary the engine compression ratio, thereby significantly reducing the cost of engine hardware modifications. The aim of this investigation is to explore the fundamental combustion phenomena occurring when methane is ignited with a pilot injection of diesel fuel. Experiments were performed on a single-cylinder optical research engine which is typical of modern, light-duty diesel engines. A high-speed digital camera recorded time-resolved combustion luminosity and an intensified CCD camera was used for single-cycle OH*chemiluminescence imaging.

To maximize payback for operators, it is important that natural gas engines for heavy-duty on-road applications minimize fuel consumption. To directly replace a diesel engine for a given vehicle mass and duty cycle, the natural gas engine also needs to match the diesel's power and torque characteristics. This paper reports the results of a development project to increase the torque and power of Westport's 15L 356 kW pilot-ignited, late cycle direct injection of natural gas engine by 10%, while matching or improving efficiency and maintaining emissions compliance. The strategies evaluated to achieve these objectives were to recover some of the exhaust energy with a power turbine, to increase the injector flow area to avoid excessively long combustion durations and to reduce the compression ratio to keep peak cylinder pressure below its maximum limit.

Compression ignition engines, including those that use natural gas as the major fuel, produce emissions of NOx and particulate matter (PM). Westport Inc. has developed the pilot-ignited high-pressure direct-injection (HPDI) natural gas engine system. Although HPDI engines produce less soot than comparable conventional diesel engines, further reductions in engine-out soot emissions is desired. In diesel engines, multiple injections can help reduce both NOx and PM. The effect of post injections on HPDI engines was not studied previously. The present research shows that late injection of a second gas pulse can significantly reduce PM and CO from HPDI engines without significantly increasing NOx or fuel consumption. In-cylinder pressure measurements were used to characterize the heat release resulting from the multiple injections. Experiments showed that most close-coupled split injection strategies provided no significant emissions benefit and less stable operation.

Development status and insight on a “research level” piezoelectric direct injection fuel injection system for prototype hydrogen Internal Combustion Engines (ICEs) is described. Practical experience accumulated from specialized material testing, bench testing and engine operation have helped steer research efforts on the fuel injection system. Recent results from a single cylinder engine are also presented, including demonstration of 45% peak brake thermal efficiency. Developing ICEs to utilize hydrogen can result in cost effective power plants that can potentially serve the needs of a long term hydrogen roadmap. Hydrogen direct injection provides many benefits including improved volumetric efficiency, robust combustion (avoidance of pre-ignition and backfire) and significant power density advantages relative to port-injected approaches with hydrogen ICEs.

Effects of methyl ester biodiesel fuel blends on NOx emissions are studied experimentally and analytically. A precisely controlled single cylinder diesel engine experiment was conducted to determine the impact of a 20% blend of soy methyl ester biodiesel (B20) on NOx emissions. The data were then used to calibrate KIVA chemical kinetics models which were used to determine how the biodiesel blend affects NOx production during the combustion process. In addition, the impact on the engine control system of the lower specific energy content of biodiesel was determined. Both factors, combustion and controls, must be taken into account when determining the net NOx effect of biodiesel compared to conventional diesel fuel. Because the magnitude and even direction of NOx effect changes with engine load, the NOx effect associated with burning biodiesel blends over a duty cycle depends on the duty cycle average power and fuel cetane number.

In the early years of antifreeze/coolants (1920s & 30s) glycerin saw some usage, but because of higher cost and weaker freeze point depression, it was not competitive with ethylene glycol. Glycerin is a by-product of the manufacture of biodiesel (fatty acid methyl esters) made by reacting natural vegetable or animal fats with methanol. Biodiesel fuel is becoming increasingly important and is expected to gain a large market share in the next several years. Regular diesel fuels blended with 2%, 5%, and 20% biodiesel are now commercially available. The large amount of glycerin generated from high volume usage of biodiesel fuel has resulted in this chemical becoming cost competitive with the glycols currently used in engine coolants. For this reason, and lower toxicity comparable to that of propylene glycol, glycerin deserves to be reconsidered as a base for antifreeze/coolant.

The use of biodiesel requires the development of proper quantification procedures for biodiesel content in blends and in lubricants (fuel dilution in oil). Although the ester carbonyl stretch at 1746 wavenumbers (cm-1) is the most prominent band in the IR spectrum of biodiesel, it is difficult to use for quantification purposes due to a severe fluctuation of absorption strength from sample to sample, even at the same biodiesel content. We have demonstrated that the ester carbonyl fluctuation is not caused by variation in the ester alkyl chain length; but is most likely caused by the degree of hydrogen bonding of the ester functional group with water in the sample. Water molecules can form complexes with the ester compound affecting the strength of the ester carbonyl band. The impact of water on quantification of the biodiesel content of blends was significant, even for B100 samples that met the proposed ASTM D6751 water limit of 500 ppm by D6304 (Karl Fischer Methdod).

The use of exhaust gas recirculation (EGR) to control NOx emissions from direct-injection engines results in the reintroduction of exhaust particulate matter (PM) into the intake manifold. The influence of this recirculated PM on emissions from a pilot-ignited direct injection of natural gas engine was studied by installing a filter in the EGR system. Comparison tests at fixed engine conditions were conducted to identify differences between filtered and unfiltered EGR. No significant variations in gaseous or PM mass emissions were detected. This indicates that the recirculated PM is not contributing substantially to the increases in PM mass emissions commonly observed with EGR. Reductions in black carbon and ultra-fine particle exhaust concentrations in the exhaust were observed at the highest EGR fractions with the filter installed.

A diesel pilot-ignited, high-pressure direct-injection of natural gas heavy-duty single-cylinder engine was fuelled with both natural gas and blends of 10% and 23% by volume hydrogen in methane. A single operating condition (6 bar GIMEP, 0.5 ϕ, 800 RPM, 40%EGR) was selected, and the combustion phasing was varied from advanced (mid-point of combustion at top-dead-center) to late (mid-point of combustion at 15°ATDC). Replacing the natural gas with hydrogen/methane blend fuels was found to have a significant influence on engine emissions and on combustion stability. The use of 10%hydrogen was found to slightly reduce PM, CO, and tHC emissions, while improving combustion stability. 23%hydrogen was found to substantially reduce CO and tHC emissions, while slightly increasing NOx. The greatest reductions in CO and tHC, along with a significant reduction in PM, were observed at the latest combustion timings, where combustion stability was lowest.

The use of pilot-ignited, direct-injected natural gas in a heavy-duty compression-ignition engine has been shown to reduce emissions while maintaining performance and efficiency. Adding recirculated exhaust gas (EGR) has been shown to further reduce emissions of nitric oxides (NOx), albeit at the cost of increased hydrocarbons (tHC), carbon monoxide (CO), and particulate matter (PM) emissions at high EGR fractions. Previous tests have suggested that reducing the delay between the diesel and natural gas injections, increasing the injection pressure, or adjusting the combustion timing have individually achieved substantial emissions benefits. To investigate the effectiveness of combining these techniques, and of using them over a wide range of operating conditions, a series of tests were carried out. The first set of tests investigated the interactions between these effects and the EGR fraction.

A heavy-duty compression ignition engine using EGR and pilot-ignited directly injected natural gas fueling was calibrated for low NOx emissions. A Cummins ISX engine using cooled EGR was fitted with a Westport HPDI™ fuel system and an oxidation catalyst. The base engine hardware was modified to increase EGR rates (up to 40%). The engine, rated at 336 kW (450 hp) and 2236Nm (1650 ft-lbs), was calibrated and tested over steady state and transient test cycles. Steady state testing over the ESC 13-mode test cycle resulted in weighted composite NOx emissions of 0.36 g/bhp-hr and particulate matter emissions of 0.04 g/bhp-hr. Transient testing over the US EPA specified FTP cycle resulted in average NOx emissions of 0.6 g/bhp-hr and PM emissions of 0.03 g/bhp-hr.

Determining what exhaust gas recirculation (EGR) control parameters have the largest impact on engine performance and emissions is of critical importance when developing an EGR-equipped engine. These tests studied the effects of varying the net charge mass, the fresh air charge mass, the indicated power, and the oxygen equivalence ratio at various EGR fractions. The research was carried out on a direct-injection, natural gas fuelled, pilot-ignited four-stroke heavy-duty engine using Westport Innovations Inc.'s pilot-ignited, direct injection of natural gas technology. The testing was carried out using a prototype injector and the standard diesel-fuelled engine's combustion chamber. The results indicate that fuel efficiency, as well as emissions of Nitrogen Oxides (NOx) and Carbon Monoxide (CO) depend primarily on the EGR level, and not on the values of the EGR control parameters.