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Advanced combustion engines, as power sources, dominate all aspects of the transportation sector. Stringent emission and fuel efficiency standards have promoted the research interest in advanced combustion strategies and alternative fuels. Owing to the comparable energy density to the existing fossil fuels and renewable production, alcohol and ether fuels may be a suitable replacement, or an additive to the gasoline/diesel fuels to meet the future emission standards with minimal modification to current engine geometry. Furthermore, lean and diluted combustion are well-researched pathways for efficiency improvement and reduction of engine-out emissions of modern engines. However, lean-burn or EGR dilution can introduce combustion inefficiencies in the form of excessive hydrocarbon, carbonyl species and carbon monoxide emissions.

Low temperature combustion (LTC) has been proved to overcome the trade-off between NOx and soot emissions in direct injection compression ignition engines. However, the lowered NOx emissions are accompanied by high hydrocarbon and CO emissions. Moreover, the NOx emissions under LTC has much higher NO2 concentrations compared with traditional high temperature combustion conditions. Experimental investigations have been carried out to show the hydrocarbon impact on NOx emissions and NO-NO2 conversion under various engine operation conditions, but the mechanism is less understood. The article includes numerical studies of the impact of hydrocarbons in the in-cylinder conversion of NO to NO2 during low temperature conditions in a compression ignition engine. In the present work, a stochastic reactor model with detailed chemical kinetics is utilized to investigate the reaction pathways during the NOx reduction and NO2 conversion processes.

The ever-stringent emission regulations are major challenges for the diesel fueled engines in automotive industry. The applications of advanced after-treatment technologies as well as alternative fuels [1] are considered as promising methodology to reduce exhaust emission from compression ignition (CI) engines. Using dimethyl ether (DME) as an alternative fuel has been extensively studied by many researchers and automotive manufactures since DME has demonstrated enormous potential in terms of emission reduction, such as low CO emission, and soot and sulfur free. However, the effect of employing DME in a lean NOX trap (LNT) based after-treatment system has not been fully addressed yet. In this work, investigations of the long breathing LNT system using DME as a reductant were performed on a heated after-treatment flow bench with simulated engine exhaust condition.

Dual fuel applications of alcohol fuels such as ethanol or butanol through port injection with direct injection of diesel can be effective in reduction of NOx. However, these dual fuel applications are usually associated with an increase in the incomplete combustion products such as hydrocarbons (HC), carbon monoxide (CO), and hydrogen (H2) emissions. An analysis of these products of incomplete combustion and the resulting combustion efficiency penalty was made in the diesel ignited alcohol combustion modes. The effect of EGR application was evaluated using ethanol and butanol as the port injected fuel, with varying alcohol fractions at the mid-load condition (10 -12 bar IMEP). The impact of varying the engine load (5 bar to 19 bar IMEP) in the diesel ignited ethanol mode on the incomplete combustion products was also studied. Emission measurements were taken and the net fuel energy loss as a result of the incomplete combustion was estimated.

An experimental investigation of low temperature combustion (LTC) cycles is conducted with diesel and ethanol fuels on a high compression ratio (18.2:1), common-rail diesel engine. Two LTC modes are studied; near-TDC injection of diesel with up to 60% exhaust gas recirculation (EGR), and port injected ethanol ignited by direct injection of diesel with moderate EGR (30-45%). Indicated mean effective pressures up to 10 bar in the diesel LTC mode and 17.6 bar in the dual-fuel LTC mode have been realized. While the NOx and smoke emissions are significantly reduced, a thermal efficiency penalty is observed from the test results. In this work, the efficiency penalty is attributed to increased HC and CO emissions and a non-conventional heat release pattern. The influence of heat release phasing, duration, and shape, on the indicated performance is explained with the help of parametric engine cycle simulations.

Experimental testing was done with a modern compression ignition engine to study the effect of the engine load and the effect of different fuels on the post injection characteristics. Two different fuels were utilized; ultra-low sulphur diesel and n-butanol. The results showed that a post injection can be an effective method for increasing the operating range of the engine load. Engine operation at high load can be limited by the peak cylinder pressure but the test results showed that an early post injection can increase the engine load without increasing the peak in-cylinder pressure. Neat butanol combustion may have a very high peak in-cylinder pressure and a very high peak pressure rise rate even at low load conditions. The test results showed that a butanol post injection can contribute to engine power without significantly affecting the peak pressure rise rate and the peak in-cylinder pressure.

This study investigates neat n-butanol, as a cleaner power source, to directly replace conventional diesel fuels for enabling low temperature combustion on a modern common-rail diesel engine. Engine tests are performed at medium engine loads (6∼8 bar IMEP) with the single-shot injection strategy for both n-butanol and diesel fuels. As indicated by the experimental results, the combustion of neat n-butanol offers comparable engine efficiency to that of diesel while producing substantially lower NOx emissions even without the use of exhaust gas recirculation. The greater resistance to auto-ignition allows n-butanol to undergo a prolonged ignition delay for air-fuel mixing; the high volatility helps to enhance the cylinder charge homogeneity; the fuel-borne oxygen contributes to smoke reduction and, as a result, the smoke emissions of n-butanol combustion are generally at a near-zero level under the tested engine operating conditions.

Diesel aided by gasoline low temperature combustion offers low NOx and low soot emissions, and further provides the potential to expand engine load range and improve engine efficiency. The diesel-gasoline operation however yields high unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions. This study aims to correlate the chemical origins of the key hydrocarbon species detected in the engine exhaust under diesel-gasoline operation. It further aims to help develop strategies to lower the hydrocarbon emissions while retaining the low NOx, low soot, and efficiency benefits. A single-cylinder research engine was used to conduct the engine experiments at a constant engine load of 10 bar nIMEP with a fixed engine speed of 1600 rpm. Engine exhaust was sampled with a FTIR analyzer for speciation investigation.

Modern diesel engines were known for producing ultra-low levels of hydrogen and hydrocarbons. However, as emission control techniques such as exhaust gas recirculation (EGR) are implemented to meet stringent NOx standards, the resulting increase in partial-combustion products can be significant in quantity both as pollutants and sources of lost engine efficiency. In this work, a modern common-rail diesel engine was configured to investigate the EGR threshold for elevated carbon monoxide, hydrocarbon, and hydrogen emissions at fixed loads and fixed heat-release phasing. It is noted that increase in hydrocarbons, in particular light hydrocarbons (such as methane, ethylene, and acetylene) was concurrent with ultra-low NOx emissions. Hydrogen gas can be emitted in significant quantities with the application of very high EGR. Under ultra-low NOx production conditions for medium and high load conditions, the light hydrocarbon species can account for the majority of hydrocarbon emissions.

Diesel engines operating in the low-temperature combustion (LTC) mode generally tend to produce very low levels of NOx and soot. However, the implementation of LTC is challenged by the higher cycle-to-cycle variation with heavy EGR operation and the narrower operating corridors. Small variations in the intake charge dilution can significantly increase the unburnt hydrocarbon and carbon monoxide emissions as well as escalate the consecutive cyclic fluctuations of the cylinder charge. This in turn adversely affects the robustness and efficiency of the LTC operation. However, Improvements in the promptness and accuracy of combustion control as well as tightened control on the intake oxygen concentration can enhance the robustness and efficiency of the LTC operation in diesel engines. In this work, a set of field programmable gate array (FPGA) modules were coded and interlaced to suffice on-the-fly combustion event modulations on a cycle-by-cycle basis.

Exhaust gas recirculation, fuel injection strategy and boost pressure are among the key enablers to attain low NOx and soot emissions simultaneously on modern diesel engines. In this work, the individual influence of these parameters on the emissions are investigated independently for engine loads up to 8 bar IMEP. A single-shot fuel injection strategy has been deployed to push the diesel cycle into low temperature combustion with EGR. The results indicated that NOx was a stronger respondent to injection pressure levels than to boost when the EGR ratio is relatively low. However, when the EGR level was sufficiently high, the NOx was virtually grounded and the effect of boost or injection pressure becomes irrelevant. Further tests indicated that a higher injection pressure lowered soot emissions across the EGR sweeps while the effect of boost on the soot reduction appeared significant only at higher soot levels.

Simultaneous low NOx (< 0.15 g/kWh) & soot (< 0.01 g/kWh) are attainable for enhanced premixed combustion that may lead to higher levels of hydrocarbons and carbon monoxide emissions as the engine cycles move to low temperature combustion, which is a departure from the ultra low hydrocarbon and carbon monoxide emissions, typical of the high compression ratio diesel engines. As a result, the fuel efficiency of such modes of combustion is also compromised (up to 5%). In this paper, advanced strategies for fuel injection are devised on a modern 4-cylinder common rail diesel engine modified for single cylinder research. Thermal efficiency comparisons are made between the low temperature combustion and the conventional diesel cycles. The fuel injection strategies include single injection with heavy EGR, and early multi-pulse fuel injection under low or medium engine loads respectively.

Extensive empirical work indicates that the exhaust emission and fuel efficiency of modern common-rail diesel engines characterise strong resilience to biodiesel fuels when the engines are operating in conventional high temperature combustion cycles. However, as the engine cycles approach the low temperature combustion (LTC) mode, which could be implemented by the heavy use of exhaust gas recirculation (EGR) or the homogeneous charge compression ignition (HCCI) type of combustion, the engine performance start to differ between the use of conventional and biodiesel fuels. Therefore, a set of fuel injection strategies were compared empirically under independently controlled EGR, intake boost, and exhaust backpressure in order to improve the neat biodiesel engine cycles.

Previous work indicated that low temperature combustion (LTC) in diesel engines was capable of reducing nitrogen oxides and soot simultaneously, when implemented with highly premixed lean cylinder charge or by the use of high exhaust gas recirculation. However, the fuel efficiency of the low temperature combustion cycles was commonly compromised by the high levels of hydrocarbon and carbon monoxide emissions. Additionally, in cases of diesel homogeneous charge cycles, the combustion process may even occur before the piston completes the compression stroke, which may cause excessive efficiency reduction and combustion roughness. Empirical procedures were implemented to better phase and complete the combustion process. The impact of heat release phasing, duration, shaping, and splitting on the thermal efficiency has also been analyzed with zero-dimensional engine cycle simulations. This paper intends to identify the pathways to improve the fuel efficiency of diesel LTC cycles.

Diesel engine exhausts commonly contain a high level of surplus oxygen and a significant amount of thermal energy. In this study the authors have theoretically investigated a way of utilizing the thermal energy and the surplus oxygen of exhaust gases to produce gaseous fuel in a rich combustor placed in an exhaust gas recirculation (EGR) loop. In the rich combustor, a small amount of diesel fuel will be catalytically reformed on a palladium/platinum based catalyst to produce hydrogen and carbon monoxide. Since the catalytic EGR reformer is incorporated in the EGR loop, it enables the partial recovery of exhaust heat. The gaseous fuel produced in the rich combustor can be brought back into the engine in a pre-mixed condition, potentially reducing soot formation. The preliminary energy efficiency analysis has been performed by using CHEMKIN and an in-house engine simulation software SAES.