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It is a very challenging problem to reliably ignite extremely lean mixtures, especially for the low speed, high load conditions of large-bore natural gas engines. If these engines are to be use for the distributed power generation market, it will require operation with higher boost pressures and even leaner mixtures. Both place greater demands on the ignition system. The railplug is a very promising ignition system for lean burn natural gas engines with its high-energy deposition and high velocity plasma arc. It requires care to properly design railplugs for this new application, however. For these engines, in-cylinder pressure and mixture temperature are very high at the time of ignition due to the high boost pressure. Hot spots may exist on the electrodes of the ignitor, causing pre-ignition problems. A heat transfer model is proposed in this paper to aid the railplug design. The electrode temperature was measured in an operating natural gas engine.

The On-Board Distillation System (OBDS) extracts, from gasoline, a highly volatile crank fuel that enables simultaneous reduction of start-up fuel enrichment and significant ignition timing retard during cold-starting. In a previous paper we reported reductions in catalyst light-off time of >50% and THC emissions reductions >50% over Phase I of the FTP drive cycle. The research presented herein is a further development of the OBDS concept. For this work, OBDS was improved to yield higher-quality start-up fuel. The PCM calibration was changed as well, in order to improve the response to intake manifold pressure transients. The test vehicle was tested over the 3-phase FTP, with exhaust gases speciated to determine NMOG and exhaust toxics emissions. Also, the effectiveness of OBDS at generating a suitable starting fuel from a high driveability index test gasoline was evaluated.

An On-Board Distillation System (OBDS) was developed to extract, from gasoline, a highly volatile crank fuel that allows the reduction of startup fuel enrichment and significant spark retard during cold starts and warm-up. This OBDS was installed on a 2001 Lincoln Navigator to explore the emissions reductions possible on a large vehicle with a large-displacement engine. The fuel and spark calibration of the PCM were modified to exploit the benefits of the OBDS startup fuel. Three series of tests were performed: (1) measurement of the OBDS fuel composition and distillation curve per ASTM D86, (2) measurement of real-time cold start (20 °C) tailpipe hydrocarbon emissions for the first 20 seconds of engine operation, and (3) FTP drive cycles at 20 °C with engine-out and tailpipe emissions of gas-phase species measured each second. Baseline tests were performed using stock PCM calibrations and certification gasoline.

Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. All of our prior tests with the injector probe used California Phase 2 reformulated gasoline as the liquid fuel. In the present study, a variety of pure liquid hydrocarbon fuels are used to examine the influence of fuel volatility and structure. Additionally, the exhaust hydrocarbons are speciated to differentiate between the emissions resulting from the gaseous fuel and those resulting from the liquid fuel. It is shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs.

An optical access engine was used to image the liquid film evaporation off the piston of a simulated direct injected gasoline engine. A directional injector probe was used to inject liquid fuel (gasoline, i-octane and n-pentane) directly onto the piston of an engine primarily fueled on propane. The engine was run at idle conditions (750 RPM and closed throttle) and at the Ford World Wide Mapping Point (1500 RPM and 262 kPa BMEP). Mie scattering images show the liquid exiting the injector probe as a stream and directly impacting the piston top. Schlieren imaging was used to show the fuel vaporizing off the piston top late in the expansion stroke and during the exhaust stroke. Previous emissions tests showed that the presence of liquid fuel on in-cylinder surfaces increases engine-out hydrocarbon emissions.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested over the Federal Test Procedure (FTP) driving cycle. Speciated engine-out hydrocarbon emissions were measured. Seven fuels were used for these tests: five blended fuels and two pure hydrocarbon fuels. One of the blended fuels was CARB Phase 2 reformulated gasoline which was used as the reference fuel. The remaining four blended fuels were made from refinery components to meet specified distillation profiles. The pure hydrocarbon fuels were iso-octane and toluene - an alkane and an aromatic with essentially identical boiling points. The five blended fuels can be grouped to examine the effects of fuel volatility and MTBE. Additionally, correlations were sought between the fuel properties and the Specific Reactivity, the exhaust “toxics”, and the pass-through of unburned fuel species.

An original equipment gasoline-fueled 1999 Chevrolet Silverado pickup with a 5.3-liter, V8 engine was converted to operate on E85 (85% denatured ethanol and 15% gasoline). The simplest conversion of a gasoline-fueled vehicle to E85 requires modification to the fuel system, including use of components that are compatible with ethanol and fuel injectors that provide sufficient E85 for the stock engine control module (ECM) to effectively control engine operation. To retain the stock ECM, higher flow rate fuel injectors that provide approximately 40% more E85 than gasoline are required. With no engine modifications and similar engine control strategies, performance predictions show an approximate 7% torque and power increase for E85 over gasoline. The increase is primarily due to the specific energy differences between E85 and gasoline, although there should be a slight charge cooling benefit for E85 as a result of its higher heat of vaporization.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested via a variety of driving cycles using California Phase 2 reformulated gasoline. A comparable PFI vehicle was also evaluated. The standard driving cycles examined were the Federal Test Procedure (FTP), Highway Fuel Economy Test, US06, simulated SC03, Japanese 10-15, New York City Cycle, and European ECE+EDU. Engine-out and tailpipe emissions of gas phase species were measured each second. Hydrocarbon speciations were performed for each phase of the FTP for both the engine-out and tailpipe emissions. Tailpipe particulate mass emissions were also measured. The results are analyzed to identify the emissions challenges facing the DISI engine and the factors that contribute to the particulates, NOx, and hydrocarbon emissions problems of the DISI engine.

The Texas Project was a multi-year study of aftermarket conversions of a variety of light-duty vehicles to CNG or LPG. Emissions and fuel economy when using these fuels are compared to the results for the same vehicles operating on certification gasoline and Federal Phase 1 RFG. Since 1993, 1,040 tests were conducted on 10 models, totally 86 light-duty vehicles. The potential for each vehicle model/kit combination to attain LEV certification was assessed. Also, comparisons of emissions and fuel economy between converted vehicles when operating on gasoline and nominally identical un-converted gasoline control vehicles were analyzed. Additional evaluations were performed for a subfleet that was subjected to exhaust speciations for operation over the Federal Test Procedure cycle and also for off-cycle tests.

This paper presents the results of an experimental investigation of the fuel-air mixing process in a port-fuel-injected, 4-valve, spark-ignited engine that was motored to simulate cold cranking and start-up conditions. An infrared fiber-optic instrumented spark plug probe was used to measure the local, crank angle resolved, fuel concentration in the vicinity of the spark gap of a single-cylinder research engine with a production head and fuel injector. The crank-angle resolved fuel concentrations were compared for various injection timings including open-intake-valve (OIV) and closed-intake-valve (CIV) injection, using federal certification gasoline. In addition, the effects of speed, intake manifold pressure, and injected fuel mass were examined.

Off-cycle emissions from seven different types of 1994 light-duty vehicles were examined The test fleet consisted of 19 individual vehicles including a passenger car, two makes of light light-duty trucks, and five types of heavy light-duty trucks The driving cycles used for these tests were the US06(hard acceleration, high speed) cycle and the 20 °F FTP (the “Cold FTP”) Conventional FTPs were done for comparison Each vehicle was usually operated on at least two of the following CNG, LPG, Federal Phase 1 reformulated gasoline (FP1 RFG), and a low sulfur certification gasoline For both the conventional FTP and the US06 cycles, the alternative fuels produce statistically significant benefits in Ozone Forming Potential and exhaust toxics but the NOx emissions are not statistically different from those when operating on FP1 RFG with at least 90% confidence During Cold FTP tests, the emissions of CO and of toxics when operating on FP1 RFG are not statistically different from those when operating on a low sulfur certification gasoline In contrast the alternative fuels produce statistically significant benefits in the emissions of both CO and toxics compared to either of the gasolines during Cold FTP tests The Reactivity Adjustment Factor calculated from the present conventional FTP results for CNG agrees closely with the CARB value However, the present RAF for LPG is about half CARB s value, which is believed to be a consequence of the low propene in Texas LPG compared to the high propene in California LPG The effects of the test type on the emissions are also discussed

The Texas Project is a multi-year study of the emissions and fuel economy of aftermarket conversions of light-duty vehicles, including passenger cars, light light-duty trucks, and heavy light-duty trucks. The test fleet, consisting of 86 mostly 1994 model year vehicles, includes eight different types of light-duty vehicles that have been converted to dual fueled operation for either CNG or LPG and corresponding gasoline controls. Virtually every type of aftermarket conversion technology (referred to as a “kit” for convenience) is represented in the test matrix: eight different CNG kits and seven different LPG kits, all of which have closed loop control systems. One goal of The Texas Project is to evaluate the different kits for each of the applications. One method used for evaluating the different kits was by assessing their potential for attaining LEV certification for each of the vehicle applications.

The Texas Project involves the conversion of light-duty vehicles, up to and heavy light-duty trucks, to bi-fueled vehicles using commercially available aftermarket CNG and LPG conversion systems. The test fleet includes 68 dual fueled conversions. Virtually every type of aftermarket conversion technology for CNG and LPG was evaluated: eight different CNG and seven different LPG conversion “kits”, all of which are modern systems incorporating closed-loop control. The kits were installed and calibrated according to the manufacturer's guidelines and recommendations. The emissions when operating on the alternative fuel were compared to those when operating on certification gasoline to determine the “success” of the conversion. Many of these conversions, performed according to the manufacturer's requirements, were not “successful” (worse emissions than for gasoline operation). In almost all cases, the problem was NOx emissions that were too high when operating on the alternative fuel.

A survey of the CNG compositions within NGV driving range of Houston was performed. It was found that the statistics for the Texas CNGs were very similar to those from a previous national survey Based upon the present survey results, two extremes of CNG composition were chosen for a study of the effects of composition on emissions, fuel economy, and driveability. Two other CNG compositions were also included to provide for comparisons with the recently completed Auto/Oil Air Quality Improvement Research Program (AQIRP) and to extend the AQIRP database. One of the vehicles used in the AQIRP study was also used in the present investigation. Correlations were investigated for the relationships between the CNG composition and tailpipe emissions, fuel economy, and driveability.

A reduced autoignition mechanism for iso-octane has been developed by identifying paths to formation of the stable species measured during motoring knock experiments and eliminating paths to formation of species that were not measured. The resulting mechanism includes low-, intermediate-, and high-temperature reactions and consists of 103 species and 131 reactions. This mechanism differs from detailed models not only in the number of reactions and species, but most importantly, in the nature and rates of the degenerate chain branching reactions. To implement this mechanism, a knock subroutine has been added to a quasidimensional spark ignition engine model that accounts for heat losses, blowby, etc. Thus, errors in the reactivity predictions can be assigned almost exclusively to the kinetics. Numerical predictions of the exhaust composition during motoring knock are compared with experimental measurements as a function of compression ratio for several operating conditions.

Species analyses have been performed on engine-out and tailpipe hydrocarbon mass emissions to help understand why fuels with higher T50 and/or T90 distillation temperatures produce higher engine-out and tailpipe hydrocarbon emissions and why fuels with higher T90 distillation temperatures produce higher engine-out and tailpipe specific reactivities. Species analyses were also performed to examine the effects of fuel sulfur level on engine-out and tailpipe species and specific reactivities. These analyses were performed on three different test-vehicle fleets representing varying levels of emissions control technology and the effect of emissions control technology was examined. Individual hydrocarbon species concentrations in both the engine-out and tailpipe were found to correlate linearly with the concentrations of the same species in the fuel, implying that a small fraction of the fuel escapes the combustion process and conversion over the catalyst.

Modal analyses have been performed on engine-out and tailpipe hydrocarbon mass emissions to help understand why fuels with higher T50 and/or T90 distillation temperatures produce somewhat higher engine-out hydrocarbon emissions and substantially higher tailpipe hydrocarbon emissions. Modal analyses were also performed to examine how increased fuel sulfur increases tailpipe hydrocarbon emissions and to identify which gasoline properties in this study are responsible for the lower tailpipe hydrocarbon emissions with reformulated gasolines. These analyses were performed on three different test vehicle fleets representing varying levels of emissions control technology. The modal analyses showed that the substantially higher tailpipe hydrocarbon emissions from fuels with high T50 and/or T90 distillation temperatures result primarily from these fuels producing substantially higher engine-out hydrocarbon emissions during the first cycle of the Federal Test Procedure (FTP).

Engine-out and tailpipe exhaust, and hot soak evaporative emissions of two reformulated test gasolines and an Industry Average reference gasoline were compared in four vehicle fleets designed for progressively lower emission standards. The two reformulated gasolines included: 1) a gasoline meeting 1996 California Phase 2 regulatory requirements, and 2) a gasoline blended to the same specifications but without an oxygenated component. These two gasolines were compared with the Auto-Oil Air Quality Improvement Research Program's (AQIRP) Industry Average gasoline representing 1988 national average composition. The vehicle fleets were the AQIRP Older (1983 to 85MY) and Current (1989MY) vehicle fleets used in prior studies, and two new AQIRP test fleets, one designed to 1994 Federal Tier 1 standards and a prototype Advanced Technology fleet designed for lower emission levels of 1995 and later.

Exhaust emissions of three vehicles fueled with compressed natural gas (CNG) were compared with emissions of three counterpart gasoline vehicles. The natural gas vehicles were tested on four CNG fuels covering a wide range of pipeline natural gas compositions. The gasoline vehicles were tested on AQIRP Industry Average gasoline and a reformulated gasoline meeting California 1996 regulatory requirements. Nonmethane hydrocarbon (NMHC) and toxic air pollutant emissions of the CNG vehicles were about one-tenth those of their counterpart gasoline vehicles, while methane emissions were about ten times those of the gasoline vehicles. Carbon monoxide (CO) and nitrogen oxides (NOx) emissions were more variable among the three vehicle pairs. CO emissions ranged from 20 to 80% lower with CNG than with gasoline, and NOx ranged from 80% lower with CNG to equivalent to gasoline.

Exhaust and evaporative emissions from three flexible/variable fuel vehicles (FFV/VFV) were measured as the vehicles operated on E85 fuel (a mixture of 85% ethanol and 15% gasoline) or on gasoline. One vehicle was a production vehicle designed for ethanol fuels and sold in 1992-93 and the other two vehicles were prototypes which were recalibrated 1992 model year methanol FFV's. The gasolines tested were Industry Average Fuel A and a reformulated gasoline Fuel C2 that met California 1996 regulatory requirements. The gasoline component of Fuel E85 was based on the reformulated gasoline. The major findings from this three-vehicle program were that E85 reduced NOx 49% compared to Fuel A and 37% compared to Fuel C2, but increased total toxics 108% (5 mg/mi) and 255% (20 mg/mi), respectively, primarily by increasing acetaldehyde. The NOx effect was significant for both engine-out and tailpipe emissions.