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Journal Article

Evaluation of Diesel Oxidation Catalyst Conversion of Hydrocarbons and Particulate Matter from Premixed Low Temperature Combustion of Biodiesel

2011-04-12
2011-01-1186
Premixed low temperature combustion (LTC) in diesel engines simultaneously reduces soot and NOx at the expense of increased hydrocarbon (HC) and CO emissions. The use of biodiesel in the LTC regime has been shown to produce lower HC emissions than petroleum diesel; however, unburned methyl esters from biodiesel are more susceptible to particulate matter (PM) formation following atmospheric dilution due to their low volatility. In this study, the efficacy of a production-type diesel oxidation catalyst (DOC) for the conversion of light hydrocarbons species and heavier, semi-volatile species like those in unburned fuel is examined. Experimental data were taken from a high speed direct-injection diesel engine operating in a mid-load, late injection partially premixed LTC mode on ultra-low sulfur diesel (ULSD) and neat soy-based biodiesel (B100). Gaseous emissions were recorded using a conventional suite of analyzers and individual light HCs were measured using an FT-IR analyzer.
Technical Paper

Turbulence Intensity Calculation from Cylinder Pressure Data in a High Degree of Freedom Spark-Ignition Engine

2010-04-12
2010-01-0175
The number of control actuators available on spark-ignition engines is rapidly increasing to meet demand for improved fuel economy and reduced exhaust emissions. The added complexity greatly complicates control strategy development because there can be a wide range of potential actuator settings at each engine operating condition, and map-based actuator calibration becomes challenging as the number of control degrees of freedom expand significantly. Many engine actuators, such as variable valve actuation and flow control valves, directly influence in-cylinder combustion through changes in gas exchange, mixture preparation, and charge motion. The addition of these types of actuators makes it difficult to predict the influences of individual actuator positioning on in-cylinder combustion without substantial experimental complexity.
Journal Article

Premixed Low Temperature Combustion of Biodiesel and Blends in a High Speed Compression Ignition Engine

2009-04-20
2009-01-0133
The effects of combining premixed, low temperature combustion (LTC) with biodiesel are relatively unknown to this point. This mode allows simultaneously low soot and NOx emissions by using high rates of EGR and increasing ignition delay. This paper compares engine performance and emissions of neat, soy-based methyl ester biodiesel (B100), B20, B50, pure ultra low sulfur diesel (ULSD) and a Swedish, low aromatic diesel in a multi-cylinder diesel engine operating in a late-injection premixed LTC mode. Using heat release analysis, the progression of LTC combustion was explored by comparing fuel mass fraction burned. B100 had a comparatively long ignition delay compared with Swedish diesel when measured by start of ignition (SOI) to 10% fuel mass fraction burned (CA10). Differences were not as apparent when measured by SOI to start of combustion (SOC) even though their cetane numbers are comparable.
Technical Paper

Optimal Engine Calibration for Individual Driving Styles

2008-04-14
2008-01-1367
Increasing functionality of electronic control units has enhanced our ability to control engine operation utilizing calibration static maps that provide the values of several controllable variables. State-of-the-art simulation-based calibration methods permit the development of these maps with respect to extensive steady-state and limited transient operation of particular driving cycles. However, each individual driving style is different and rarely meets those test conditions. An alternative approach was recently implemented that considers the derivation of these maps while the engine is running the vehicle. In this approach, a self-learning controller selects in real time the optimum values of the controllable variables for the sequences of engine operating point transitions, corresponding to the driver's driving style.
Technical Paper

Control of a Multi-Cylinder HCCI Engine During Transient Operation by Modulating Residual Gas Fraction to Compensate for Wall Temperature Effects

2007-04-16
2007-01-0204
The thermal conditions of an engine structure, in particular the wall temperatures, have been shown to have a great effect on the HCCI engine combustion timing and burn rates through wall heat transfer, especially during transient operations. This study addresses the effects of thermal inertia on combustion in an HCCI engine. In this study, the control of combustion timing in an HCCI engine is achieved by modulating the residual gas fraction (RGF) while considering the wall temperatures. A multi-cylinder engine simulation with detailed geometry is carried out using a 1-D system model (GT-Power®) that is linked with Simulink®. The model includes a finite element wall temperature solver and is enhanced with original HCCI combustion and heat transfer models. Initially, the required residual gas fraction for optimal BSFC is determined for steady-state operation. The model is then used to derive a map of the sensitivity of optimal residual gas fraction to wall temperature excursions.
Technical Paper

Comparison of Diesel Oxidation Catalyst Performance on an Engine and a Gas Flow Reactor

2007-04-16
2007-01-0231
This paper analyzes and compares reactor and engine behavior of a diesel oxidation catalyst (DOC) in the presence of conventional diesel exhaust and low temperature premixed compression ignition (PCI) diesel exhaust. Surrogate exhaust mixtures of n-undecane (C11H24), ethene (C2H4), CO, O2, H2O, NO and N2 are defined for conventional and PCI combustion and used in the gas flow reactor tests. Both engine and reactor tests use a DOC containing platinum, palladium and a hydrocarbon storage component (zeolite). On both the engine and reactor, the composition of PCI exhaust increases light-off temperature relative to conventional combustion. However, while nominal conditions are similar, the catalyst behaves differently on the two experimental setups. The engine DOC shows higher initial apparent HC conversion efficiencies because the engine exhaust contains a higher fraction of trappable (i.e., high boiling point) HC.
Technical Paper

Characterizing Light-Off Behavior and Species-Resolved Conversion Efficiencies During In-Situ Diesel Oxidation Catalyst Degreening

2006-04-03
2006-01-0209
Degreening is crucial in obtaining a stable catalyst prior to assessing its performance characteristics. This paper characterizes the light-off behavior and conversion efficiency of a Diesel Oxidation Catalyst (DOC) during the degreening process. A platinum DOC is degreened for 16 hours in the presence of actual diesel engine exhaust at 650°C and 10% water (H2O) concentration. The DOC's activity for carbon monoxide (CO) and for total hydrocarbons (THC) conversion is checked at 0, 1, 2, 3, 4, 6, 8, 10, 12, and 16 hours of degreening. Pre-and post-catalyst hydrocarbon species are analyzed via gas chromatography at 0, 4, 8, and 16 hours of degreening. It is found that both light-off temperature and species-resolved conversion efficiencies change rapidly during the first 8 hours of degreening and then stabilize to a large degree. T50, the temperature where the catalyst is 50% active towards a particular species, increases by 14°C for CO and by 11°C for THC through the degreening process.
Technical Paper

Speciated Hydrocarbon Emissions from an Automotive Diesel Engine and DOC Utilizing Conventional and PCI Combustion

2006-04-03
2006-01-0201
Premixed compression ignition low-temperature diesel combustion (PCI) can simultaneously reduce particulate matter (PM) and oxides of nitrogen (NOx). Carbon monoxide (CO) and total hydrocarbon (THC) emissions increase relative to conventional diesel combustion, however, which may necessitate the use of a diesel oxidation catalyst (DOC). For a better understanding of conventional and PCI combustion, and the operation of a platinum-based production DOC, engine-out and DOC-out exhaust hydrocarbons are speciated using gas chromatography. As combustion mode is changed from lean conventional to lean PCI to rich PCI, engine-out CO and THC emissions increase significantly. The relative contributions of individual species also change; increasing methane/THC, acetylene/THC and CO/THC ratios indicate a richer combustion zone and a reduction in engine-out hydrocarbon incremental reactivity.
Technical Paper

Simulation of an Integrated Starter Alternator (ISA) System for the HMMWV

2006-04-03
2006-01-0442
The development and use of a simulation of an Integrated Starter Alternator (ISA) for a High Mobility Multi-purpose Wheeled Vehicle (HMMWV) is presented here. While the primary purpose of an ISA is to provide electric power for additional accessories, it can also be utilized for mild hybridization of the powertrain. In order to explore ISA's potential for improving HMMWV's fuel economy, an ISA model capable of both producing and absorbing mechanical power has been developed in Simulink. Based on the driver's power request and the State of Charge of the battery (SOC), the power management algorithm determines whether the ISA should contribute power to, or absorb power from the crankshaft. The system is also capable of capturing some of the braking energy and using it to charge the battery. The ISA model and the power management algorithm have been integrated in the Vehicle-Engine SIMulation (VESIM), a SIMULINK-based vehicle model previously developed at the University of Michigan.
Technical Paper

Engine-in-the-Loop Testing for Evaluating Hybrid Propulsion Concepts and Transient Emissions - HMMWV Case Study

2006-04-03
2006-01-0443
This paper describes a test cell setup for concurrent running of a real engine and a vehicle system simulation, and its use for evaluating engine performance when integrated with a conventional and a hybrid electric driveline/vehicle. This engine-in-the-loop (EIL) system uses fast instruments and emission analyzers to investigate how critical in-vehicle transients affect engine system response and transient emissions. Main enablers of the work include the highly dynamic AC electric dynamometer with the accompanying computerized control system and the computationally efficient simulation of the driveline/vehicle system. The latter is developed through systematic energy-based proper modeling that tailors the virtual model to capture critical powertrain transients while running in real time. Coupling the real engine with the virtual driveline/vehicle offers a chance to easily modify vehicle parameters, and even study two different powertrain configurations.
Technical Paper

Analysis of Premixed Charge Compression Ignition Combustion With a Sequential Fluid Mechanics-Multizone Chemical Kinetics Model

2005-04-11
2005-01-0115
We have developed a methodology for analysis of Premixed Charge Compression Ignition (PCCI) engines that applies to conditions in which there is some stratification in the air-fuel distribution inside the cylinder at the time of combustion. The analysis methodology consists of two stages: first, a fluid mechanics code is used to determine temperature and equivalence ratio distributions as a function of crank angle, assuming motored conditions. The distribution information is then used for grouping the mass in the cylinder into a two-dimensional (temperature-equivalence ratio) array of zones. The zone information is then handed on to a detailed chemical kinetics model that calculates combustion, emissions and engine efficiency information. The methodology applies to situations where chemistry and fluid mechanics are weakly linked.
Technical Paper

Using Artificial Neural Networks for Representing the Air Flow Rate through a 2.4 Liter VVT Engine

2004-10-25
2004-01-3054
The emerging Variable Valve Timing (VVT) technology complicates the estimation of air flow rate because both intake and exhaust valve timings significantly affect engine's gas exchange and air flow rate. In this paper, we propose to use Artificial Neural Networks (ANN) to model the air flow rate through a 2.4 liter VVT engine with independent intake and exhaust camshaft phasers. The procedure for selecting the network architecture and size is combined with the appropriate training methodology to maximize accuracy and prevent overfitting. After completing the ANN training based on a large set of dynamometer test data, the multi-layer feedforward network demonstrates the ability to represent air flow rate accurately over a wide range of operating conditions. The ANN model is implemented in a vehicle with the same 2.4 L engine using a Rapid Prototype Controller.
Technical Paper

Modeling of Diesel Combustion and NO Emissions Based on a Modified Eddy Dissipation Concept

2004-03-08
2004-01-0107
This paper reports the development of a model of diesel combustion and NO emissions, based on a modified eddy dissipation concept (EDC), and its implementation into the KIVA-3V multidimensional simulation. The EDC model allows for more realistic representation of the thin sub-grid scale reaction zone as well as the small-scale molecular mixing processes. Realistic chemical kinetic mechanisms for n-heptane combustion and NOx formation processes are fully incorporated. A model based on the normalized fuel mass fraction is implemented to transition between ignition and combustion. The modeling approach has been validated by comparison with experimental data for a range of operating conditions. Predicted cylinder pressure and heat release rates agree well with measurements. The predictions for NO concentration show a consistent trend with experiments. Overall, the results demonstrate the improved capability of the model for predictions of the combustion process.
Technical Paper

Modeling HCCI Combustion With High Levels of Residual Gas Fraction - A Comparison of Two VVA Strategies

2003-10-27
2003-01-3220
Adjusting the Residual Gas Fraction (RGF) by means of Variable Valve Actuation (VVA) is a strong candidate for controlling the ignition timing in Homogeneous Charge Compression Ignition (HCCI) engines. However, at high levels of residual gas fraction, insufficient mixing can lead to the presence of considerable temperature and composition variations. This paper extends previous modeling efforts to include the effect of RGF distribution on the onset of ignition and the rate of combustion using a multi-dimensional fluid mechanics code (KIVA-3V) sequentially with a multi-zone code with detailed chemical kinetics. KIVA-3V is used to simulate the gas exchange processes, while the multi-zone code computes the combustion event. It is shown that under certain conditions the effect of composition stratification is significant and cannot be captured by a single-zone model or a multi-zone model using only temperature zones.
Technical Paper

Fuel Spray Simulation of High-Pressure Swirl-Injector for DISI Engines and Comparison with Laser Diagnostic Measurements

2003-03-03
2003-01-0007
A comprehensive model for sprays emerging from high-pressure swirl injectors in DISI engines has been developed accounting for both primary and secondary atomization. The model considers the transient behavior of the pre-spray and the steady-state behavior of the main spray. The pre-spray modeling is based on an empirical solid cone approach with varying cone angle. The main spray modeling is based on the Liquid Instability Sheet Atomization (LISA) approach, which is extended here to include the effects of swirl. Mie Scattering, LIF, PIV and Laser Droplet Size Analyzer techniques have been used to produce a set of experimental data for model validation. Both qualitative comparisons of the evolution of the spray structure, as well as quantitative comparisons of spray tip penetration and droplet sizes have been made. It is concluded that the model compares favorably with data under atmospheric conditions.
Technical Paper

Estimation of Air Fuel Ratio of a SI Engine from Exhaust Gas Temperature at Cold Start Condition

2002-05-06
2002-01-1667
Wall wetting of injected fuel onto the intake manifold and cylinder wall causes unpredictable transient behavior of air-fuel mixing which results in a significant emission of unburned hydrocarbon (HC) emission during cold start operation. Heated exhaust gas oxygen (HEGO) sensors cannot measure the air-fuel ratio (A/F) of exhaust gas during cold start condition. Precise and fast estimation of air/fuel ratio of the exhaust gas is required to elucidate the wall wetting phenomena and subsequent HC formation. Refined A/F estimation can enable the control of fuel injection minimizing HC emissions during cold start conditions so that HC emissions can be minimized. A new estimator for A/F of the exhaust gas has been developed. The A/F estimator described in this study utilizes measured exhaust gas temperature and general engine parameters such as engine speed, airflow, coolant temperature, etc.
Technical Paper

Compression Ratio Influence on Maximum Load of a Natural Gas Fueled HCCI Engine

2002-03-04
2002-01-0111
This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.
Technical Paper

System Efficiency Issues for Natural Gas Fueled HCCI Engines in Heavy-Duty Stationary Applications

2002-03-04
2002-01-0417
Homogeneous Charge Compression Ignition (HCCI) has been proposed for natural gas engines in heavy duty stationary power generation applications. A number of researchers have demonstrated, through simulation and experiment, the feasibility of obtaining high gross indicated thermal efficiencies and very low NOx emissions at reasonable load levels. With a goal of eventual commercialization of these engines, this paper sets forth some of the primary challenges in obtaining high brake thermal efficiency from production feasible engines. Experimental results, in conjunction with simulation and analysis, are used to compare HCCI operation with traditional lean burn spark ignition performance. Current HCCI technology is characterized by low power density, very dilute mixtures, and low combustion efficiency. The quantitative adverse effect of each of these traits is demonstrated with respect to the brake thermal efficiency that can be expected in real world applications.
Technical Paper

Multi-Dimensional Modeling of NO and Soot Emissions with Detailed Chemistry and Mixing in a Direct Injection Natural Gas Engine

2002-03-04
2002-01-1112
This work reports the development and application of multi-dimensional ignition, combustion and emissions models that account for detailed chemistry and mixing effects in a direct injection engine simulation. A detailed chemical reaction mechanism, consisting of 24 species and 104 reactions, is used for increased accuracy of emissions predictions. Turbulent combustion is represented using a modified Eddy Dissipation Concept (EDC) model to account for mixing effects. The soot model includes all aspects of soot formation and destruction. Particle transport equations are used to realistically track transport of the soot particles formed. All computational sub-models developed in this work have been implemented in a modified version of the KIVA-3V code. In order to illustrate the behavior of the new models, soot and NO emissions have been predicted at different operating conditions by varying injection timing, exhaust gas recirculation (EGR) and injection pressure.
Technical Paper

Experimental and Simulated Results Detailing the Sensitivity of Natural Gas HCCI Engines to Fuel Composition

2001-09-24
2001-01-3609
Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.
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