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This work experimentally investigates the impact of premixed fuel composition (methane/ethane, methane/propane, and methane/hydrogen mixtures having equivalent chemical energy) and pilot reactivity (cetane number) on diesel-pilot injection (DPI) combustion performance and emissions, with an emphasis on the pilot ignition delay (ID). To support the experimental pilot ignition delay trends, an analysis technique known as Mixing Line Concept (MLC) was adopted, where the cold diesel surrogate and hot premixed charge are envisioned to mix in a 0-D constant volume reactor to account for DPI mixture stratification. The results show that the dominant effect on pilot ignition is the pilot fuel cetane number, and that the premixed fuel composition plays a minor role. There is some indication of a physical effect on ignition for cases containing premixed hydrogen.

In this study, the impacts of fuel volatility and reactivity on combustion stability and emissions were studied in a light-duty single-cylinder research engine for a three-injection catalyst heating operation strategy with late post-injections. N-heptane and blends of farnesane/2,2,4,4,6,8,8-heptamethylnonane were used to study the impacts of volatility and reactivity. The effect of increased chemical reactivity was also analysed by comparing the baseline #2 diesel operation with a pure blend of mono-ether components (CN > 100) representative of potential high cetane oxygenated bioblendstocks and a 25 vol.% blend of the mono-ether blend and #2 diesel with a cetane number (CN) of 55. At constant reactivity, little to no variation in combustion performance was observed due to differences in volatility, whereas increased reactivity improved combustion stability and efficiency at late injection timings.

The effect of low level ethanol fuel on the power and emissions characteristics was studied in a small, mass produced, carbureted, spark-ignited, Briggs and Stratton Vanguard 19L2 engine. Ethanol has been shown to be an attractive renewable fuel by the automotive industry; having anti-knock properties, potential power benefits, and emissions reduction benefits. With increasing availability and the possible mandates of higher ethanol content in pump gasoline, there is interest in exploring the effect of using higher content ethanol fuels in the small utility engine market. The fuels in this study were prepared by gravimetrically mixing 98.7% ethanol with a balance of 87 octane no-ethanol gasoline in approximately 5% increments from pure gasoline to 25% ethanol. Alcor Petrolab performed fuel analysis on the blended fuels and determined the actual volumetric ethanol content was within 2%.

The effects of hydrogen ratio and exhaust gas recirculation (EGR) on combustion and emissions in a hydrogen/diesel dual-fuel premixed charge compression ignition (PCCI) engine were investigated. The control of combustion phasing could be improved using hydrogen enrichment and EGR due to the retarded combustion phasing with a higher hydrogen ratio. The indicated mean effective pressure (IMEP) was increased with a higher hydrogen ratio because the hydrogen enrichment intensified the high temperature reactions and thus decreased the combustion duration. Hydrocarbon (HC) and carbon monoxide (CO) emissions were reduced significantly in a hydrogen/diesel dual-fuel PCCI mode with a similar NOx emissions level as that of the diesel PCCI mode.

Transient tests in a 2.0 liter in-line 4 cylinder downsizing gasoline direct injection engine were conducted under various transient conditions in order to investigate effects of lower rotational inertia of titanium aluminide alloy (TiAl) turbine wheel on engine and turbocharger performances. As a representative result, fast boost pressure build up was achieved in case of TiAl turbocharger compared to Inconel turbocharger. This result was mainly due to lower rotational inertia of TiAl turbine wheel. Engine torque build up response was also improved with TiAl turbocharger even though engine torque response gap between both turbochargers was slightly reduced due to retarded combustion phase. In addition, with advanced ignition timing, fuel consumption became less than that of Inconel turbocharger with similar engine torque response.

A Three-Way Catalyst (TWC) model with global TWC kinetics for lean burn DISI engines were developed and validated. The model incorporates kinetics of hydrocarbons and carbon monoxide oxidations, NOx reduction, water-gas and steam reforming and oxygen storage. Ammonia (NH₃) and new nitrous oxide (N₂O) kinetics were added into the model to study NH₃ and N₂O formation in TWC systems. The model was validated over a wide range of engine operating conditions using various types of experimental data from a lean burn automotive SIDI engine. First, well-controlled time-resolved steady state data were used for calibration and initial model tests. In these steady state operations, the engine was switched between lean and rich conditions for NOx emission control. Then, the model was further validated using a large set of time-averaged steady state data. Temperature dependencies of NH₃ and N₂O kinetics in the TWC model were examined and well captured by the model.

A kinetic carbon monoxide (CO) emission model is developed to simulate engine out CO emissions for conventional diesel combustion. The model also incorporates physics governing CO emissions for low temperature combustion (LTC). The emission model will be used in an integrated system level model to simulate the operation and interaction of conventional and low temperature diesel combustion with aftertreatment devices. The Integrated System Model consists of component models for the diesel engine, engine-out emissions (such as NOx and Particulate Matter), and aftertreatment devices (such as DOC and DPF). The addition of CO emissions model will enhance the capability of the Integrated System Model to predict major emission species, especially for low temperature combustion. In this work a CO emission model is developed based on a two-step global kinetic mechanism [8].

Low temperature diesel combustion with a large amount of exhaust gas recirculation in a direct injection diesel engine was investigated. Tests were carried out under various engine speeds, injection pressures, injection timings, and injection quantities. Exhaust emissions and brake specific fuel consumption were measured at different torque and engine speed conditions. High rates of exhaust gas recirculation led to the simultaneous reduction of nitrogen oxide and soot emissions due to a lower combustion temperature than conventional diesel combustion. However, hydrocarbon and carbon monoxide emissions increased as the combustion temperature decreased because of incomplete combustion and the lack of an oxidation reaction. To overcome the operating range limits of low temperature diesel combustion, increased intake pressure with a modified turbocharger was employed.

A continuous multi-component fuel evaporation model has been integrated with an improved G-equation combustion and detailed chemical kinetics model. The integrated code has been successfully used to simulate a gasoline direct injection engine. In the multi-component fuel model, the theory of continuous thermodynamics is used to model the properties and composition of multi-component fuels such as gasoline. In the improved G-equation combustion model a flamelet approach based on the G-equation is used that considers multi-component fuel effects. To precisely calculate the local and instantaneous residual which has a great effect on the laminar flame speed, a “transport equation residual” model is used. A Damkohler number criterion is used to determine the combustion mode in flame containing cells.

The effect of the ring pack storage mechanism on the hydrocarbon (HC) emissions from an air-cooled utility engine has been studied using a simplified ring pack model. Tests were performed for a range of engine load, two engine speeds, varied air-fuel ratio and with a fixed ignition timing using a homogeneous, pre-vaporized fuel mixture system. The integrated mass of HC leaving the crevices from the end of combustion (the crank angle that the cumulative burn fraction reached 90%) to exhaust valve closing was taken to represent the potential contribution of the ring pack to the overall HC emissions; post-oxidation in the cylinder will consume some of this mass. Time-resolved exhaust HC concentration measurements were also performed, and the instantaneous exhaust HC mass flow rate was determined using the measured exhaust and cylinder pressure.

The combustion and exhaust emission characteristics of a DME fueled HCCI engine were investigated. Different fuel injection strategies were tested under various injection quantities and timings with exhaust gas recirculation (EGR). The combustion phase in HCCI was changed by an in-cylinder direct injection and EGR, due to changes in the in-cylinder temperature and mixture homogeneity. The gross indicated mean effective pressure (IMEPgross) increased and the hydrocarbon (HC) and carbon monoxide (CO) emissions decreased as the equivalence ratio was augmented. The IMEPgross with direct injection was greater than with the port injection due to retarded ignition timing resulting from latent heat of direct injected DME fuel. It was because that most of burn duration was completed before top dead center owing to higher ignitability for DME with high cetane number. However, HC and CO emissions were similar for both injection locations.

Diesel particulate filters are designed to reduce the mass emissions of diesel particulate matter and have been proven to be effective in this respect. Not much is known, however, about their effects on other unregulated chemical species. This study utilized source dilution sampling techniques to evaluate the effects of a catalyzed diesel particulate filter on a wide spectrum of chemical emissions from a heavy-duty diesel engine. The species analyzed included both criteria and unregulated compounds such as particulate matter (PM), carbon monoxide (CO), hydrocarbons (HC), inorganic ions, trace metallic compounds, elemental and organic carbon (EC and OC), polycyclic aromatic hydrocarbons (PAHs), and other organic compounds. Results showed a significant reduction for the emissions of PM mass, CO, HC, metals, EC, OC, and PAHs.

Dimethyl-ether combustion with pilot injection was investigated in a single cylinder direct injection diesel engine equipped with a common-rail injection system. Combustion characteristics and emissions were tested with dimethyl-ether and compared with diesel fuel. The main injection timing was fixed to have the best timings for maximum power output. The total injected fuel mass corresponded to a low heating value of 405 joules per cycle at 800 rpm. The fuel quantity and the injection timing of the pilot injection were varied from 8 to 20% of the total injected mass and from 50 to 10 crank angle degrees before the main injection timing, respectively. Ignition delay decreased with pilot injection. The effects of pilot injection were less significant with DME combustion than with diesel. Pilot injection caused the main combustion to increase in intensity resulting in decreased emissions of hydrocarbons, carbon monoxide and particulate matter.

The combustion, knock characteristics and exhaust emissions in an engine were investigated under homogeneous charge compression ignition operation fueled with liquefied petroleum gas with regard to variable valve timing and the addition of di-methyl ether. Liquefied petroleum gas was injected at an intake port as the main fuel in a liquid phase using a liquefied injection system, while a small amount of di-methyl ether was also injected directly into the cylinder during the intake stroke as an ignition promoter. Different intake valve timings and fuel injection amount were tested in order to identify their effects on exhaust emissions, combustion and knock characteristics. The optimal intake valve open timing for the maximum indicated mean effective pressure was retarded as the λTOTAL was decreased. The start of combustion was affected by the intake valve open timing and the mixture strength (λTOTAL) due to the volumetric efficiency and latent heat of vaporization.

The University of Wisconsin-Madison Snowmobile Team designed and constructed a hybrid-electric snowmobile for the 2005 Society of Automotive Engineers' Clean Snowmobile Challenge. Built on a 2003 cross-country touring chassis, this machine features a 784 cc fuel-injected four-stroke engine in parallel with a 48 V electric golf cart motor. The 12 kg electric motor increases powertrain torque up to 25% during acceleration and recharges the snowmobile's battery pack during steady-state operation. Air pollution from the gasoline engine is reduced to levels far below current best available technology in the snowmobile industry. The four-stroke engine's closed-loop EFI system maintains stoichiometric combustion while dual three-way catalysts reduce NOx, HC and CO emissions by up to 94% from stock. In addition to the use of three way catalysts, the fuel injection strategy has been modified to further reduce engine emissions from the levels measured in the CSC 2004 competition.

Engine-out CO emission and fuel conversion efficiency were measured in a highly-dilute, low-temperature diesel combustion regime over a swirl ratio range of 1.44-7.12 and a wide range of injection timing. At fixed injection timing, an optimal swirl ratio for minimum CO emission and fuel consumption was found. At fixed swirl ratio, CO emission and fuel consumption generally decreased as injection timing was advanced. Moreover, a sudden decrease in CO emission was observed at early injection timings. Multi-dimensional numerical simulations, pressure-based measurements of ignition delay and apparent heat release, estimates of peak flame temperature, imaging of natural combustion luminosity and spray/wall interactions, and Laser Doppler Velocimeter (LDV) measurements of in-cylinder turbulence levels are employed to clarify the sources of the observed behavior.

The effects of charge dilution on low-temperature diesel combustion and emissions were investigated in a small-bore single-cylinder diesel engine over a wide range of injection timing. The fresh air was diluted with additional N2 and CO2, simulating 0 to 65% exhaust gas recirculation in an engine. Diluting the intake charge lowers the flame temperature T due to the reactant being replaced by inert gases with increased heat capacity. In addition, charge dilution is anticipated to influence the local charge equivalence ratio ϕ prior to ignition due to the lower O2 concentration and longer ignition delay periods. By influencing both ϕ and T, charge dilution impacts the path representing the progress of the combustion process in the ϕ-T plane, and offers the potential of avoiding both soot and NOx formation.

A multi-zone model has been developed that accurately predicts HCCI combustion and emissions. The multi-zone methodology is based on the observation that turbulence does not play a direct role on HCCI combustion. Instead, chemical kinetics dominates the process, with hotter zones reacting first, and then colder zones reacting in rapid succession. Here, the multi-zone model has been applied to analyze the effect of piston crevice geometry on HCCI combustion and emissions. Three different pistons of varying crevice size were analyzed. Crevice sizes were 0.26, 1.3 and 2.1 mm, while a constant compression ratio was maintained (17:1). The results show that the multi-zone model can predict pressure traces and heat release rates with good accuracy. Combustion efficiency is also predicted with good accuracy for all cases, with a maximum difference of 5% between experimental and numerical results.

The present study investigated HCCI combustion in a heavy-duty diesel engine both experimentally and numerically. The engine was equipped with a hollow-cone pressure-swirl injector using gasoline direct injection. Characteristics of HCCI combustion were obtained by very early injection with a heated intake charge. Experimental results showed an increase in NOx emission and a decrease in UHC as the injection timing was retarded. It was also found that optimization can be achieved by controlling the intake temperature together with the start-of-injection timing. The experiments were modeled by using an engine CFD code with detailed chemistry. The CHEMKIN code was implemented into KIVA-3V such that the chemistry and flow solutions were coupled. The model predicted ignition timing, cylinder pressure, and heat release rates reasonably well. The NOx emissions were found to increase as the injection timing was retarded, in agreement with experimental results.

To meet stringent emission standards, a considerable amount of development work is necessary to ensure suitable efficiency and durability of catalyst systems. The main challenge is to reduce the engine cold-start emissions. Close-coupled catalyst (CCC) provides fast light-off time by utilizing the energy in the exhaust gas. However, if some malfunction occurred during engine operation and the catalyst temperature exceeds 1050°C, the catalytic converter becomes deactivated and shows poor conversion efficiency. Close-coupled catalyst temperature was investigated under various engine operating conditions. All of the experiments were conducted with a 1.0L SI engine at 1500-4000 rpm. The engine was operated at no load to full load conditions. Exhaust gas temperature and catalyst temperature were measured as a function of lambda value (0.8-1.2), ignition timing (BTDC 30°-ATDC 30°) and misfire rates (0-28%).