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Three jet fuel surrogates were compared against their target fuels in a compression ignited optical engine under a range of start-of-injection temperatures and densities. The jet fuel surrogates are representative of petroleum-based Jet-A POSF-4658, natural gas-derived S-8 POSF-4734 and coal-derived Sasol IPK POSF-5642, and were prepared from a palette of n-dodecane, n-decane, decalin, toluene, iso-octane and iso-cetane. Optical chemiluminescence and liquid penetration length measurements as well as cylinder pressure-based combustion analyses were applied to examine fuel behavior during the injection and combustion process. HCHO* emissions obtained from broadband UV imaging were used as a marker for low temperature reactivity, while 309 nm narrow band filtered imaging was applied to identify the occurrence of OH*, autoignition and high temperature reactivity.

The presence of OH radicals as a marker of the high temperature reaction region usually has been used to determine the lift-off length (LOL) in diesel engines. Both OH Laser Induced Fluorescence (LIF) and OH* chemiluminescence diagnostics have been widely used in optical engines for measuring the LOL. OH* chemiluminescence is radiation from OH being formed in the exited states (OH*). As a consequence OH* chemiluminescence imaging provides line-of-sight information across the imaged volume. In contrast, OH-LIF provides information on the distribution of radicals present in the energy ground state. The OH-LIF images only show OH distribution in the thin cross-section illuminated by the laser. When both these techniques have been applied in earlier work, it has often been reported that the chemiluminescence measurements result in shorter lift-off lengths than the LIF approach.

This study evaluates the performance of an indirect injection (IDI) diesel engine fueled with cotton seed biodiesel while assessing the engine's multi-fuel capability. Millions of tons of cotton seeds are available in the south of the US every year and approximately 10% of oil contained in the seeds can be extracted and transesterified. An investigation of combustion, emissions, and efficiency was performed using mass ratios of 20-50% cotton seed biodiesel (CS20 and CS50) in ultra-low sulfur diesel #2 (ULSD#2). Each investigation was run at 2400 rpm with loads of 4.2 - 6.3 IMEP and compared to the reference fuel ULDS#2. The ignition delay ranged in a narrow interval of 0.8-0.97ms across the blends and the heat release rate showed comparable values and trends for all fuel blends. The maximum volume averaged cylinder temperature increased by approximately 100K with each increase in 1 bar IMEP load but the maximum remained constants across the blends.

As engine efficiency targets continue to rise, additional improvements must consider reduction of heat transfer losses. The development of advanced heat transfer models and realistic boundary conditions for simulation based engine design both require accurate in-cylinder wall temperature measurements. A novel dual wavelength infrared diagnostic has been developed to measure in-cylinder surface temperatures with high temporal resolution. The diagnostic has the capability to measure low amplitude, high frequency temperature variations, such as those occurring during the gas exchange process. The dual wavelength ratio method has the benefit of correcting for background scattering reflections and the emission from the optical window itself. The assumption that background effects are relatively constant during an engine cycle is shown to be valid over a range of intake conditions during motoring.

Emissions of Unburned Hydrocarbons (UHC) from diesel engines are a particular concern during the starting process, when after-treatment devices are typically below optimal operating temperatures. Drivability in the subsequent warm-up phase is also impaired by large cyclic fluctuations in mean effective pressure (MEP). This paper discusses in-cylinder wall temperature influence on unburned hydrocarbon emissions and combustion stability during the starting and warm-up process in an optical engine. A laser-induced phosphorescence technique is used for quantitative measurements of in-cylinder wall temperatures just prior to start of injection (SOI), which are correlated to engine out UHC emission mole fractions and combustion phasing during starting sequences over a range of charge densities, at a fixed fueling rate. Squish zone cylinder wall temperature shows significant influence on engine out UHC emissions during the warm-up process.

Development of in-cylinder spray targeting, plume penetration and atomization of the gasoline direct-injection (GDi) multi-hole injector is a critical component of combustion developments, especially in the context of the engine downsizing and turbo-charging trend that has been adopted in order to achieve the European target CO2, US CAFE, and concomitant stringent emissions standards. Significant R&D efforts are directed towards the optimization of injector nozzle designs in order to improve spray characteristics. Development of accurate predictive models is desired to understand the impact of nozzle design parameters as well as the underlying physical fluid dynamic mechanisms resulting in the injector spray characteristics. This publication reports Large Eddy Simulation (LES) analyses of GDi single-hole skew-angled nozzles, with β=30° skew (bend) angle and different nozzle geometries.

As a result of recent focus on the control of Low Temperature Combustion (LTC) modes, dual-fuel combustion strategies such as Reactivity Controlled Compression Ignition (RCCI) have been developed. Reactivity stratification of the auto-igniting mixture is thought to be responsible for the increase in allowable engine load compared to other LTC combustion modes such as Homogenous Charge Compression Ignition (HCCI). The current study investigates the effect of ethanol intake fuel injection on in-cylinder formaldehyde formation and stratification within an optically accessible engine operated with n-heptane direct injection using optical measurements and zero-dimensional chemical kinetic models. Images obtained by Planar Laser Induced Fluorescence (PLIF) of formaldehyde using the third harmonic of a pulsed Nd:YAG laser indicate an increase in formaldehyde heterogeneity as measured by the fluorescence signal standard deviation.

Due to the single fuel concept implemented by the US military, the soot production of diesel engines fueled with JP-8 has important implications for military vehicle visual signature and survivability. This work compares in-cylinder soot formation and oxidation of JP-8 and ULSD in a small-bore, optical diesel engine. Experimental engine-out soot emission measurements are compared to crank-angle resolved two-color measurements of soot temperature and optical thickness, KL. A 3-D chemical kinetic-coupled CFD model with line of sight integration is employed in order to investigate the soot distribution in a 2-D projection associated with the imaging plane, as well as to aid in interpreting the third dimension along the optical depth which is not available within the experimental work. The study also examines the effect of volatility on soot emission characteristics by CFD simulation.

Biodiesel is a desirable alternative fuel for the diesel engine due to its low engine-out soot emission tendency. When blended with petroleum-based diesel fuels, soot emissions generally decrease in proportion to the volume fraction of biodiesel in the mixture. This paper presents an experimental investigation of biodiesel impact on in-cylinder soot temperature and concentrations in a single-cylinder, small-bore, optical access, compression ignition engine. While in-cylinder soot measurements have been widely performed with two-color thermometry implemented on digital cameras, their finite dynamic range limits the observation of soot due to its dramatically different radiation intensities. To expand the dynamic range of two-color measurements, this investigation utilizes three cameras. A high-speed CMOS color camera with a wide-band Bayer filter is used to obtain simultaneous measurements of soot temperature and KL factor for high intensity soot clouds within one cycle.

Multi-hole DI injectors are being adopted in the advanced downsized DISI ICE powertrain in the automotive industry worldwide because of their robustness and cost-performance. Although their injector design and spray resembles those of DI diesel injectors, there are many basic but distinct differences due to different injection pressure and fuel properties, the sac design, lower L/D aspect ratios in the nozzle hole, closer spray-to-spray angle and hense interactions. This paper used Phase-Contrast X ray techniques to visualize the spray near a 3-hole DI gasoline research model injector exit and compared to the visible light visualization and the internal flow predictions using with multi-dimensional multi-phase CFD simulations. The results show that strong interactions of the vortex strings, cavitation, and turbulence in and near the nozzles make the multi-phase turbulent flow very complicated and dominate the near nozzle breakup mechanisms quite unlike those of diesel injections.

Advanced valvetrain coupled with Direct Injection (DI) provides an opportunity to simultaneous reduction of fuel consumption and emissions. Because of their robustness and cost performance, multi-hole injectors are being adopted as gasoline DI fuel injectors. Ethanol and ethanol-gasoline blends synergistically improve the performance of a turbo-charged DI gasoline engine, especially in down-sized, down-sped and variable-valvetrain engine architecture. This paper presents Mie-scattering spray imaging results taken with an Optical Accessible Engine (OAE). OAE offers dynamic and realistic in-cylinder charge motion with direct imaging capability, and the interaction with the ethanol spray with the intake air is studied. Two types of cams which are designed for Early Intake Valve Close (EIVC) and Later Intake Valve Close (LIVC) are tested, and the effect of variable valve profile and deactivation of one of the intake valves are discussed.

Misfiring or partial combustion during diesel engine operation results in the production of partial oxidation products such as ethylene (C₂H₄), carbon monoxide and aldehydes, in particular formaldehyde (HCHO). These compounds remain in the cylinder as residual gases to participate in the following engine cycle. Carbon monoxide and formaldehyde have been shown to exhibit a dual nature, retarding ignition in one temperature regime, yet decreasing ignition delay periods of hydrocarbon mixtures as temperatures exceed 1000°K. Largely unknown is the synergistic effects of such species. In this work, varying amounts of C₂H₄ and HCHO are added to the intake air of a naturally aspirated optical diesel engine and their combined effect on autoignition and subsequent combustion is examined. To observe the effect of these dopants on the low-temperature heat release (LTHR), ultraviolet chemiluminescent images are recorded using intensified CCD cameras.

Advances in engine technology including Gasoline Direct injection (GDi), Dual Independent Cam Phasing (DICP), advanced valvetrain and boosting have allowed the simultaneous reductions of fuel consumption and emissions with increased engine power density. The utilization of fuels containing ethanol provides additional improvements in power density and potential for lower emissions due to the high octane rating and evaporative cooling of ethanol in the fuel. In this paper results are presented from a flexible fuel engine capable of operating with blends from E0-E85. The increased geometric compression ratio, (from 9.2 to 11.85) can be reduced to a lower effective compression ratio using advanced valvetrain operating on an Early Intake Valve Closing (EIVC) or Late Intake Valve Closing (LIVC) strategy. DICP with a high authority intake phaser is used to enable compression ratio management.

Requirements for reduced fuel consumption with simultaneous reductions in regulated emissions require more efficient operation of Spark Ignited (SI) engines. An advanced valvetrain coupled with Gasoline Direct injection (GDi) provide an opportunity to simultaneously reduce fuel consumption and emissions. Work on a flex fuel GDi engine has identified significant potential to reduce throttling by using Early Intake Valve Closing (EIVC) and Late Intake Valve Closing (LIVC) strategies to control knock and load. High loads were problematic when operating on gasoline for particulate emissions, and low loads were not able to fully minimize throttling due to poor charge motion for the EIVC strategy. The use of valve deactivation was successful at reducing high load particulate emissions without a significant airflow penalty below 3000 RPM. Valve deactivation did increase the knocking tendency for knock limited fuels, due to increased heat transfer that increased charge temperature.

Under the borderline autoignition conditions experienced during cold-starting of diesel engines, the amount and composition of residual gases may play a deterministic role. Among the intermediate species produced by misfiring and partially firing cycles, formaldehyde (HCHO) is produced in significant enough amounts and is sufficiently stable to persist through the exhaust and intake strokes to kinetically affect autoignition of the following engine cycle. In this work, the effect of HCHO addition at various phases of autoignition of n-heptane-air mixtures is kinetically modeled. Results show that HCHO has a retarding effect on the earliest low-temperature heat release (LTHR) phase, largely by competition for hydroxyl (OH) radicals which inhibits fuel decomposition. Conversely, post-LTHR, the presence of HCHO accelerates the occurrence of high-temperature ignition.

Because of their robustness and cost performance, multi-hole gasoline injectors are being adopted as the direct injection (DI) fuel injector of choice as vehicle manufacturers look for ways to reduce fuel consumption without sacrificing power and emission performance. To realize the full benefits of direct injection, the resulting spray needs to be well targeted, atomized, and appropriately mixed with charge air for the desirable fuel vapor concentration distributions in the combustion chamber. Ethanol and ethanol-gasoline blends synergistically improve the turbo-charged DI gasoline performance, especially in down-sized, down-sped and variable-valve-train engine architecture. This paper presents the spray imaging results from two multi-hole DI gasoline injectors with different design, fueled with pure ethanol (E100) or gasoline (E0), under homogeneous and stratified-charge conditions that represent typical engine operating points.

Operation of flex fuel vehicles requires operation with a range of fuel properties. The significant differences in the heat of vaporization and energy density of E0-E100 fuels and the effect on spray development need to be fully comprehended when developing engine control strategies. Limited enthalpy for fuel vaporization needs to be accounted for when developing injection strategies for cold start, homogeneous and stratified operation. Spray imaging of multi-hole gasoline injectors with fuels ranging from E0 to E100 and environmental conditions that represent engine operating points from ambient cold start to hot conditions was performed in a spray chamber. Schlieren visualization technique was used to characterize the sprays and the results were compared with Laser Mie scattering and Back-lighting technique. Open chamber experiments were utilized to provide input and validation of a CFD model.

In present GDI engines, multiple injection strategies are often employed for engine cold start mixture formation. In the future, these strategies may also be used to control the combustion process, and to prevent misfiring or high emission levels. While the processes occurring during individual injections of GDI injectors have been investigated by a number of researchers, this paper concentrates on the interactions of multiple injection events. Even though multiple injection strategies are already applied in most GDI engines, the impact of the first injection event on the second injection event has not been analyzed in detail yet. Different optical measurement techniques are used in order to investigate the interaction of the two closely timed injection events, as well as the effect of dwell time and the in-cylinder conditions. The injector investigated is a GDI piezo injector with an outwardly opening needle.

Effects of fuel cell material properties on water management were numerically investigated using Volume of Fluid (VOF) method in the FLUENT. The results show that the channel surface wettability is an important design variable for both serpentine and interdigitated flow channel configurations. In a serpentine air flow channel, hydrophilic surfaces could benefit the reactant transport to reaction sites by facilitating water transport along channel edges or on channel surfaces; however, the hydrophilic surfaces would also introduce significantly pressure drop as a penalty. For interdigitated air flow channel design, it is observable that liquid water exists only in the outlet channel; it is also observable that water distribution inside GDL is uneven due to the pressure distribution caused by interdigitated structure. An in-situ water measurement method, neutron imaging technique, was used to investigate the water behavior in a PEM fuel cell.

By taking advantage of high-intensity and high-brilliance x-ray beams available at the Advanced Photon Source (APS), ultrafast (150 ps) propagation-based phase-enhanced imaging was developed to visualize high-pressure high-speed diesel sprays in the optically dense near-nozzle region. The sub-ns temporal and μm spatial resolution allows us to capture the morphology of the high-speed fuel sprays traveling at 500 m/s with a negligible motion blur. Both quality and quantitative information about the spray feature can be readily obtained. In the experiment, two types of single-hole nozzles have been used, one with a hydroground orifice inlet and the other with a sharp one. Within 3 mm from the nozzle, the sprays from these nozzles behave differently, ranging from laminar flow with surface instability waves to turbulent flow. The sprays are correlated with the nozzle internal geometry, which provides practical information for both nozzle design and supporting numerical simulation models.