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Use of ethanol as gasoline replacement can contribute to the reduction of nitrogen oxide (NOx) and carbon oxide (CO) emissions. Depending on ethanol production, significant reduction of greenhouse-gas emissions is possible. Concentration of certain species, such as unburned ethanol and acetaldehyde in the engine-out emissions are known to rise when ratio of ethanol to gasoline increases in the fuel. This research explores on hydrous ethanol fueled port-fuel injection (PFI) spark ignition (SI) engine emissions that contribute to photochemical formation of ozone, or so-called ozone precursors and the precursor of peroxyacetyl nitrates (PANs). The results are compared to engine operation on gasoline. Concentration obtained by FTIR gas analyzer, and mass-specific emissions of formaldehyde (HCHO), acetaldehyde (MeCHO) and methane (CH4) under two engine speed, four load and two spark advance settings are analyzed and presented.

The present study helps to understand the local combustion characteristics of PREmixed Mixture Ignition in the End-gas Region (PREMIER) combustion mode while using increasing amount of natural gas as a diesel substitute in conventional CI engine. In order to reduce NOx emission and diesel fuel consumption micro-pilot diesel injection in premixed natural gas-air mixture is a promising technique. New strategy has been employed to simulate dual fuel combustion which uses well established combustion models. Main focus of the simulation is at detection of an end gas ignition, and creating an unified modeling approach for dual fuel combustion. In this study G-equation flame propagation model is used with detailed chemistry in order to detect end-gas ignition in overall low temperature combustion. This combustion simulation model is validated using comparison with experimental data for dual fuel engine.

Three jet fuel surrogates were compared against their target fuels in a compression ignited optical engine under a range of start-of-injection temperatures and densities. The jet fuel surrogates are representative of petroleum-based Jet-A POSF-4658, natural gas-derived S-8 POSF-4734 and coal-derived Sasol IPK POSF-5642, and were prepared from a palette of n-dodecane, n-decane, decalin, toluene, iso-octane and iso-cetane. Optical chemiluminescence and liquid penetration length measurements as well as cylinder pressure-based combustion analyses were applied to examine fuel behavior during the injection and combustion process. HCHO* emissions obtained from broadband UV imaging were used as a marker for low temperature reactivity, while 309 nm narrow band filtered imaging was applied to identify the occurrence of OH*, autoignition and high temperature reactivity.

Using natural gas in an internal combustion engine (ICE) is emerging as a promising way to improve thermal efficiency and reduce exhaust emissions. In the development of such engine platforms, computational fluid dynamics (CFD) plays a fundamental role in the optimization of geometries and operating parameters. One of the most relevant issues in the simulation of direct injection (DI) gaseous processes is the accurate prediction of the gas jet evolution. The simulation of the injection process for a gaseous fuel does not require complex modeling, nevertheless properly describing high-pressure gas jets remains a challenging task. At the exit of the nozzle, the injected gas is under-expanded, the flow becomes supersonic and shocks occur due to compressibility effects. These phenomena lead to challenging computational requirements resulting from high grid resolution and low computational time-steps.

With increasing interest to reduce the dependency on gasoline and diesel, alternative energy source like compressed natural gas (CNG) is a viable option for internal combustion engines. Spark-ignited (SI) CNG engine is the simplest way to utilize CNG in engines, but direct injection (DI) Diesel-CNG dual-fuel engine is known to offer improvement in combustion efficiency and reduction in exhaust gases. Dual-fuel engine has characteristics similar to both SI engine and diesel engine which makes the combustion process more complex. This paper reports the computational fluid dynamics simulation of both DI dual-fuel compression ignition (CI) and SI CNG engines. In diesel-CNG dual-fuel engine simulations and comparison to experiments, attention was on ignition delay, transition from auto-ignition to flame propagation and heat released from the combustion of diesel and gaseous fuel, as well as relevant pollutants emissions.

The presence of OH radicals as a marker of the high temperature reaction region usually has been used to determine the lift-off length (LOL) in diesel engines. Both OH Laser Induced Fluorescence (LIF) and OH* chemiluminescence diagnostics have been widely used in optical engines for measuring the LOL. OH* chemiluminescence is radiation from OH being formed in the exited states (OH*). As a consequence OH* chemiluminescence imaging provides line-of-sight information across the imaged volume. In contrast, OH-LIF provides information on the distribution of radicals present in the energy ground state. The OH-LIF images only show OH distribution in the thin cross-section illuminated by the laser. When both these techniques have been applied in earlier work, it has often been reported that the chemiluminescence measurements result in shorter lift-off lengths than the LIF approach.

Recent advances in x-ray spray diagnostics at Argonne National Laboratory's Advanced Photon Source have made absorption measurements of individual spray events possible. A focused x-ray beam (5×6 μm) enables collection of data along a single line of sight in the flow field and these measurements have allowed the calculation of quantitative, shot-to-shot statistics for the projected mass of fuel sprays. Raster scanning though the spray generates a two-dimensional field of data, which is a path integrated representation of a three-dimensional flow. In a previous work, we investigated the shot-to-shot variation over 32 events by visualizing the ensemble standard deviations throughout a two dimensional mapping of the spray. In the current work, provide further analysis of the time to steady-state and steady-state spatial location of the fluctuating field via the transverse integrated fluctuations (TIF).

This study evaluates the performance of an indirect injection (IDI) diesel engine fueled with cotton seed biodiesel while assessing the engine's multi-fuel capability. Millions of tons of cotton seeds are available in the south of the US every year and approximately 10% of oil contained in the seeds can be extracted and transesterified. An investigation of combustion, emissions, and efficiency was performed using mass ratios of 20-50% cotton seed biodiesel (CS20 and CS50) in ultra-low sulfur diesel #2 (ULSD#2). Each investigation was run at 2400 rpm with loads of 4.2 - 6.3 IMEP and compared to the reference fuel ULDS#2. The ignition delay ranged in a narrow interval of 0.8-0.97ms across the blends and the heat release rate showed comparable values and trends for all fuel blends. The maximum volume averaged cylinder temperature increased by approximately 100K with each increase in 1 bar IMEP load but the maximum remained constants across the blends.

As engine efficiency targets continue to rise, additional improvements must consider reduction of heat transfer losses. The development of advanced heat transfer models and realistic boundary conditions for simulation based engine design both require accurate in-cylinder wall temperature measurements. A novel dual wavelength infrared diagnostic has been developed to measure in-cylinder surface temperatures with high temporal resolution. The diagnostic has the capability to measure low amplitude, high frequency temperature variations, such as those occurring during the gas exchange process. The dual wavelength ratio method has the benefit of correcting for background scattering reflections and the emission from the optical window itself. The assumption that background effects are relatively constant during an engine cycle is shown to be valid over a range of intake conditions during motoring.

Emissions of Unburned Hydrocarbons (UHC) from diesel engines are a particular concern during the starting process, when after-treatment devices are typically below optimal operating temperatures. Drivability in the subsequent warm-up phase is also impaired by large cyclic fluctuations in mean effective pressure (MEP). This paper discusses in-cylinder wall temperature influence on unburned hydrocarbon emissions and combustion stability during the starting and warm-up process in an optical engine. A laser-induced phosphorescence technique is used for quantitative measurements of in-cylinder wall temperatures just prior to start of injection (SOI), which are correlated to engine out UHC emission mole fractions and combustion phasing during starting sequences over a range of charge densities, at a fixed fueling rate. Squish zone cylinder wall temperature shows significant influence on engine out UHC emissions during the warm-up process.

This study is concerned with quantitative analysis of the primary atomization, regarding the droplet size-velocity distribution function, of a multi-hole GDi plume through application of the Volume-of-Fluid Large Eddy Simulation (VOF-LES) method. The distinguishing feature of this study is the inclusion of an accurate seat /nozzle flow domain into the simulation. A VOF-LES study of the seat-nozzle flow and the near-field primary atomization of a single plume of a GDi multi-hole seat is performed. The geometry pertains to a purpose-built 3-hole GDi seat with three identical flow hole and counter-bore nozzles, arranged with 120° circumferential spacing. The VOF-LES prediction of the jet primary breakup structure and near-field macroscale is compared with spray imaging data. The droplet size and velocity distributions within a 4mm vicinity of the nozzle are analyzed. The results show production of a wide droplet size distribution through the jet primary atomization.

The need for using alternative fuel sources continues to grow as industry looks towards enhancing energy security and lowering emissions levels. In order to capture the potential of these megatrends, this study focuses on the relationship between ignition energy, thermal efficiency, and combustion stability of a 0.5 L single cylinder engine powered by compressed natural gas (CNG) at steady state operation. The goal of the experiment was to increase ignition energy at fixed lambda values to look for gains in thermal efficiency. Secondly, a lambda sweep was performed with criteria of maintaining a 4% COVIMEP by increasing the ignition energy until an appropriate threshold for stable combustion was found. The engine performance was measured with a combustion analysis system (CAS), to understand the effects of thermal efficiency and combustion stability (COVIMEP). Emissions of the engine were measured with an FTIR.

Development of in-cylinder spray targeting, plume penetration and atomization of the gasoline direct-injection (GDi) multi-hole injector is a critical component of combustion developments, especially in the context of the engine downsizing and turbo-charging trend that has been adopted in order to achieve the European target CO2, US CAFE, and concomitant stringent emissions standards. Significant R&D efforts are directed towards the optimization of injector nozzle designs in order to improve spray characteristics. Development of accurate predictive models is desired to understand the impact of nozzle design parameters as well as the underlying physical fluid dynamic mechanisms resulting in the injector spray characteristics. This publication reports Large Eddy Simulation (LES) analyses of GDi single-hole skew-angled nozzles, with β=30° skew (bend) angle and different nozzle geometries.

Natural gas has been considered to be one of the most promising alternative fuels due to its lower NOx and soot emissions, less carbon footprint as well as attractive price. Furthermore, higher octane number makes it suitable for high compression ratio application compared with other gaseous fuels. For better economical and lower emissions, a turbocharged, four strokes, direct injection, high pressure common rail diesel engine has been converted into a diesel/natural gas dual-fuel engine. For dual-fuel engine operation, natural gas as the main fuel is sequentially injected into intake manifold, and a very small amount of diesel is directly injected into cylinder as the ignition source. In this paper, a dual-fuel electronic control unit (ECU) based on the PowerPC 32-bit microprocessor was developed. It cooperates with the original diesel ECU to control the fuel injection of the diesel/natural gas dual-fuel engine.

As a result of recent focus on the control of Low Temperature Combustion (LTC) modes, dual-fuel combustion strategies such as Reactivity Controlled Compression Ignition (RCCI) have been developed. Reactivity stratification of the auto-igniting mixture is thought to be responsible for the increase in allowable engine load compared to other LTC combustion modes such as Homogenous Charge Compression Ignition (HCCI). The current study investigates the effect of ethanol intake fuel injection on in-cylinder formaldehyde formation and stratification within an optically accessible engine operated with n-heptane direct injection using optical measurements and zero-dimensional chemical kinetic models. Images obtained by Planar Laser Induced Fluorescence (PLIF) of formaldehyde using the third harmonic of a pulsed Nd:YAG laser indicate an increase in formaldehyde heterogeneity as measured by the fluorescence signal standard deviation.

Due to the single fuel concept implemented by the US military, the soot production of diesel engines fueled with JP-8 has important implications for military vehicle visual signature and survivability. This work compares in-cylinder soot formation and oxidation of JP-8 and ULSD in a small-bore, optical diesel engine. Experimental engine-out soot emission measurements are compared to crank-angle resolved two-color measurements of soot temperature and optical thickness, KL. A 3-D chemical kinetic-coupled CFD model with line of sight integration is employed in order to investigate the soot distribution in a 2-D projection associated with the imaging plane, as well as to aid in interpreting the third dimension along the optical depth which is not available within the experimental work. The study also examines the effect of volatility on soot emission characteristics by CFD simulation.

Multi-hole DI injectors are being adopted in the advanced downsized DISI ICE powertrain in the automotive industry worldwide because of their robustness and cost-performance. Although their injector design and spray resembles those of DI diesel injectors, there are many basic but distinct differences due to different injection pressure and fuel properties, the sac design, lower L/D aspect ratios in the nozzle hole, closer spray-to-spray angle and hense interactions. This paper used Phase-Contrast X ray techniques to visualize the spray near a 3-hole DI gasoline research model injector exit and compared to the visible light visualization and the internal flow predictions using with multi-dimensional multi-phase CFD simulations. The results show that strong interactions of the vortex strings, cavitation, and turbulence in and near the nozzles make the multi-phase turbulent flow very complicated and dominate the near nozzle breakup mechanisms quite unlike those of diesel injections.

Advanced valvetrain coupled with Direct Injection (DI) provides an opportunity to simultaneous reduction of fuel consumption and emissions. Because of their robustness and cost performance, multi-hole injectors are being adopted as gasoline DI fuel injectors. Ethanol and ethanol-gasoline blends synergistically improve the performance of a turbo-charged DI gasoline engine, especially in down-sized, down-sped and variable-valvetrain engine architecture. This paper presents Mie-scattering spray imaging results taken with an Optical Accessible Engine (OAE). OAE offers dynamic and realistic in-cylinder charge motion with direct imaging capability, and the interaction with the ethanol spray with the intake air is studied. Two types of cams which are designed for Early Intake Valve Close (EIVC) and Later Intake Valve Close (LIVC) are tested, and the effect of variable valve profile and deactivation of one of the intake valves are discussed.

Under the borderline autoignition conditions experienced during cold-starting of diesel engines, the amount and composition of residual gases may play a deterministic role. Among the intermediate species produced by misfiring and partially firing cycles, formaldehyde (HCHO) is produced in significant enough amounts and is sufficiently stable to persist through the exhaust and intake strokes to kinetically affect autoignition of the following engine cycle. In this work, the effect of HCHO addition at various phases of autoignition of n-heptane-air mixtures is kinetically modeled. Results show that HCHO has a retarding effect on the earliest low-temperature heat release (LTHR) phase, largely by competition for hydroxyl (OH) radicals which inhibits fuel decomposition. Conversely, post-LTHR, the presence of HCHO accelerates the occurrence of high-temperature ignition.

Because of their robustness and cost performance, multi-hole gasoline injectors are being adopted as the direct injection (DI) fuel injector of choice as vehicle manufacturers look for ways to reduce fuel consumption without sacrificing power and emission performance. To realize the full benefits of direct injection, the resulting spray needs to be well targeted, atomized, and appropriately mixed with charge air for the desirable fuel vapor concentration distributions in the combustion chamber. Ethanol and ethanol-gasoline blends synergistically improve the turbo-charged DI gasoline performance, especially in down-sized, down-sped and variable-valve-train engine architecture. This paper presents the spray imaging results from two multi-hole DI gasoline injectors with different design, fueled with pure ethanol (E100) or gasoline (E0), under homogeneous and stratified-charge conditions that represent typical engine operating points.