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Calibration of automotive engines to ensure compliance with emission regulations is a critical phase in product development. Control of engine-out particulate emissions, which directly impact the environment and public health, is particularly important. Detailed physics-based models are typically used to gain a rich understanding of the complex physical phenomena that drive the soot particle formation in an engine cylinder. However, such models often fail to correctly represent the highly dynamic nature of the underlying mechanisms under transient combustion conditions. Moreover, most physics-based models were initially developed for diesel engine applications and their applicability to gasoline engines remains questionable due to differences in flame structure and fuel-wall interactions. Black-box models have been previously proposed to predict engine-out soot emissions, but their lack of physical interpretability is an unsolved drawback.

A limitation currently facing internal combustion engine research and development is the lack of a direct method to accurately measure in-cylinder temperature. The rate at which an engine cycle evolves is too rapid for conventional, direct measurement transducers such as thermocouples or thermistors. This paper presents the experimental results of a novel method for determining time-resolved in-cylinder temperature using ultrasonic thermometry. The technique involved sampling an ultrasonic signal reflected from the top of the moving piston and measuring piston position using an optical encoder connected to the engine crankshaft. The known flight distance and measured time of flight (ToF) was used to determine path-averaged temperature. ToF of the ultrasonic signal was precisely determined using an unscented Kalman filtering technique. Experiments were conducted using a motored (non-combusting) engine without compression at two engine speeds and three known intake temperatures.

Diesel knock and ringing combustion in compression ignition (CI) engines are largely an unavoidable phenomenon and are partially related to the overall effectiveness of the fuel injection process. Modern electronic fuel injection systems have been effective at reducing the intensity of knock in CI engines, largely through optimization of fuel injection timing, as well as higher operating pressures that promote enhanced fuel and air mixing. In this effort, a single-cylinder CI engine was tested under a number of different combustion strategies, including a comparison of mechanical and electronic injection systems, increasing fuel injection pressures for biodiesel fuels, and the usage of dual-fuel combustion with compressed natural gas (CNG). Using in-cylinder pressure traces and engine operational data, the difference in injection mechanisms, fuel preparation, and their effects on knock intensity is clearly illustrated.

Utilizing a higher compression ratio in a Compression Ignition (CI) engine grants an obvious advantage of improved thermal efficiency. However, the resulting combustion temperatures promote dissociation ensuing in increased nitrogen oxide (NOx) emissions. Unfortunately, due to the inherent properties of CI combustion, it is difficult to achieve simultaneous reduction of NOx and particulate matter (PM) through conventional combustion methods. Taking a different route though accomplishing Homogeneous Charge Compression Ignition (HCCI) in CI engines will largely eliminate NOx and PM; however, combustion can result in a significant increase in hydrocarbon (HC) and carbon monoxide (CO) emissions due to the low volatility of diesel fuel. Hence, this work attempts another avenue of Low Temperature Combustion (LTC) by employing Pre-mixed Charge Compression Ignition (PCI) combustion on a comparatively higher compression ratio (21.2) single cylinder CI engine.

The recent increase in natural gas availability has made compressed natural gas (CNG) an option for fueling the transportation sector of the United States economy. In particular, CNG is advantageous in dual-fuel operation alongside ultra low sulfur diesel (ULSD) for compression ignition (CI) engines. This work investigates the usage of natural gas mixtures at varying Energy Substitution Rates (ESRs) within a high compression ratio single-cylinder CI engine, including performance and heat release modeling of dual-fuel combustion. Results demonstrate the differing behavior of utilizing CNG at various substitution rates.

A key challenge for the practical introduction of dual-fuel reactivity controlled compression ignition (RCCI) combustion modes in diesel engines is the requirement to store two fuels on-board. This work demonstrates that partially reforming diesel fuel into less reactive products is a promising method to allow RCCI to be implemented with a single stored fuel. Experiments were conducted using a thermally integrated reforming reactor in a reformed exhaust gas recirculation (R-EGR) configuration to achieve RCCI combustion using a light-duty diesel engine. The engine was operated at a low engine load and two reformed fuel percentages over ranges of exhaust gas recirculation (EGR) rate and main diesel fuel injection timing. Results show that RCCI-like emissions of NOx and soot were achieved load using the R-EGR configuration. It was also shown that complete fuel conversion in the reforming reactor is not necessary to achieve sufficiently low fuel reactivity for RCCI combustion.

As climate change drives the exploration into new and alternative fuels, biodiesel has emerged as a promising alternative to traditional diesel fuel. To further increase the viability of biodiesel, a unique system at the University of Kansas utilizes glycerin, the primary byproduct of biodiesel production, for power generation. This system converts glycerin into a hydrogen-rich gas (syngas) that is sent to an engine-generator system in one continuous flow process. The current setup allows for running the engine-generator system on pure propane, reformed propane, or reformed glycerin, with each fuel serving a unique purpose. This paper discusses upgrades in pure propane operation that serves the intent of preheating the engine prior to syngas operation and establishing the baseline energy requirement for fueling the system.

Given the need of the automotive industry to improve fuel efficiency, many companies are moving towards lean burn and low temperature combustion regimes. Critical control of these methods requires an accurate Exhaust Gas Recirculation (EGR) system that can maintain its desired rate and temperature. In this area, the literature illustrates different methodologies to control and monitor this EGR system; however, it lacks a discussion of how the non-linear nature of wave dynamics and time responses of an engine must be taken into account. In order to perform research into the use of EGR for these combustion regimes, an automated, closed-loop EGR system that uses a microprocessor to compute the slope change of the EGR rate and temperature as part of its feedback algorithm was constructed for use in a teaching and research laboratory. The findings illustrate that the system works as intended by replicating known combustion trends with EGR.

Fuel reforming during a Negative Valve Overlap (NVO) period is an effective approach to control Low Temperature Gasoline Combustion (LTGC) ignition. Previous work has shown through experiments that primary reference fuels reform easily and produce several species that drastically affect ignition characteristics. However, our previous research has been unable to accurately predict measured reformate composition at the end of the NVO period using simple single-zone models. In this work, we use a stochastic reactor model (SRM) closed cycle engine simulation to predict reformate composition accounting for in-cylinder temperature and mixture stratification. The SRM model is less computationally intensive than CFD simulations while still allowing the use of large chemical mechanisms to predict intermediate species formation rates.

In-cylinder engine modeling is a necessary aspect of combustion research. In particular, simulating heat release connects variable combustion behavior to fuel properties through the 1st Law of Thermodynamics. One extension of such models is to evaluate changes to in-cylinder behavior using the Second Law of Thermodynamics in order to identify the peak period of availability for work extraction. Thus, Second Law models are a useful tool to augment research into alternative fuel usage and optimization. These models also help identify internal irreversibilities that are separate from heat transfer and exhaust gas losses. This study utilizes a multi-zone 1st and 2nd Law Heat Release model to characterize the changes in combustion behavior of a number of neat fuels used in a single-cylinder compression ignition (CI) engine.

Biodiesel is a potential alternative to Ultra Low Sulfur Diesel (ULSD); however, it often suffers from increased fuel consumption in comparison to ULSD when injection timings and/or pressures are similar. To decrease fuel consumption, increasing biodiesel injection pressure has been found to mitigate the issues associated with its relatively high viscosity and lower energy content. When doing so, the literature indicates decreased emissions, albeit with potentially greater nitrogen oxide (NOx) emissions in contrast to ULSD. In order to better understand the trade-off between fuel consumption and NOx emissions, this study explores the influence of fuel injection pressure on ULSD, Waste Cooking Oil (WCO) biodiesel, and their blends in a single-cylinder compression ignition (CI) engine. In particular, fuel injection pressures and timings for WCO biodiesel and blended fuels are adjusted to attempt to mimic the in-cylinder pressure profile of operation using ULSD.

The use of Compressed Natural Gas (CNG) has demonstrated the potential to decrease Particulate Matter (PM) and nitrogen oxide (NOx) emissions simultaneously when used in a dual-fuel application with diesel fuel functioning as the ignition source. However, some authors do find that NOx emissions can increase. One postulation is that the conflicting results in the literature may be due to the difference in composition of natural gas around the world. Therefore, in order to investigate if CNG composition influences combustion performance and emissions, four unique mixtures of CNG were tested (i.e., 87% to 96% methane) while minimizing the combined difference of the density, heating value, and constant pressure specific heat of each mixture. This was accomplished at moderate energy substitution ratios (up to 40%) in a single cylinder engine operating at various loads.

The impact of compression ratio on engine efficiency is well known. A plethora of mechanical concepts have been proposed for altering engine compression ratio in real time. Some of these, like free-piston configurations or complex crank-slider mechanisms have the added ability to alter piston trajectory along with compression ratio. This secondary modality raises the question: Is there a more optimal piston position versus crank-angle profile for spark-ignition (SI) engines than the near-sinusoidal motion produced by a traditional four-bar crank-slider mechanism? Very little published literature directly addresses this question. This work presents the results of a quasi-dimensional SI engine model using piston trajectory as an input. Specific trajectory traits including increased dwell at top dead center and asymmetric compression and expansion strokes were swept. The trajectory also was optimized using a single objective genetic algorithm with 60 individuals and 40 generations.

The growth of hydraulic fracking has resulted in a dramatic cost reduction of Compressed Natural Gas (CNG), a low carbon fuel. CNG cannot be used as singular fuel in conventional Compression Ignition (CI) engines because of its high auto-ignition characteristics. However, CNG-assisted diesel combustion represents a means to shift the energy consumption of CI engines away from liquid fossil fuels. Calculation of the rate of heat release is vital for understanding and optimizing this mode of engine operation. A previously constructed three-zone equilibrium heat release model that is calibrated to engine exhaust emission measurements was augmented in order to allow for the addition of CNG in the engine intake. The model was also adapted to permit reuse of unburned CNG gas with other exhaust species via exhaust gas recirculation. This is because experiments demonstrated a potentially significant increase in methane emissions under high CNG flowrates.

Recently, ozone addition has come under scrutiny as a means of controlling ignition timing for Low Temperature (LTC) combustion, which defeats the NOx-PM tradeoff using a highly dilute, homogeneous mixture. This is because ozone decomposes into atomic oxygen and hydroxyl radicals that influence the early phases of the ignition delay process. In order to understand ozone's influence on combustion better, this work analyzes the effects of ozone-assisted combustion for a single-cylinder, direct-injection Compression Ignition engine via a mechanical pump-line-nozzle fuel system and an electronically controlled common-rail fuel injection system. Experimental outcomes indicate a relatively small influence of ozone for the mechanical injection system with a comparably decreased effect for the common rail system.

Significant progress towards reducing diesel engine fuel consumption and emissions is possible through the simultaneous Waste Heat Recovery (WHR) and Particulate Matter (PM) filtration in a novel device described here as a Diesel Particulate Filter Heat Exchanger (DPFHX). This original device concept is based on the shell-and-tube heat exchanger geometry, where enlarged tubes contain DPF cores, allowing waste heat recovery from engine exhaust and allowing further energy capture from the exothermic PM regeneration event. The heat transferred to the working fluid on the shell side of the DPFHX becomes available for use in a secondary power cycle, which is an increasingly attractive method of boosting powertrain efficiency due to fuel savings of around 10 to 15%. Moreover, these fuel savings are proportional to the associated emissions reduction after a short warm-up period, with startup emissions relatively unchanged when implementing a WHR system.

A timing sweep to correlate the location of Maximum Brake Torque (MBT) was completed on a single-cylinder, direct injected compression ignition engine that was recently upgraded to a high-pressure rail injection system for better engine control. This sweep included emissions monitoring for carbon dioxide, carbon monoxide, particulate matter, hydrocarbons, and oxides of nitrogen for the calibration of a heat release model, as well as the opportunity to relate MBT timing to brake-specific emissions production. The result of this timing sweep was a relatively linear correlation between injection delay and peak pressure timing. In addition, a number of other MBT timing methodologies were tested indicating their applicability for immediate feedback upon engine testing, particularly mass fraction burned correlations. Emissions were either strongly correlated to MBT timing (with emissions being minimized in the vicinity of MBT), or were completely independent of MBT.

Selective Catalytic Reduction (SCR) catalysts used in Lean NOx Trap (LNT) - SCR exhaust aftertreatment systems typically encounter alternating oxidizing and reducing environments. Reducing conditions occur when diesel fuel is injected upstream of a reformer catalyst, generating high concentrations of hydrogen (H₂), carbon monoxide (CO), and hydrocarbons to deNOx the LNT. In this study, the functionality of an iron (Fe) zeolite SCR catalyst is explored with a bench top reactor during steady-state and cyclic transient SCR operation. Experiments to characterize the effect of an LNT deNOx event on SCR operation show that adding H₂ or CO only slightly changes SCR behavior with the primary contribution being an enhancement of nitrogen dioxide (NO₂) decomposition into nitric oxide (NO). Exposure of the catalyst to C₃H₆ (a surrogate for an actual exhaust HC mixture) leads to a significant decrease in NOx reduction capabilities of the catalyst.

With the rapid growth of biodiesel production, it is prudent to research ways to improve its operation and performance in an engine, especially concerning fuel economy and exhaust emissions. This requires a thorough understanding of both the biodiesel production and engine operating processes. Completion of a published study of the impact of biodiesel fuel properties on engine operation indicated that it is difficult to draw conclusions about the exact causes of increased NOx emissions with respect to biodiesel properties without the capability of measuring engine cylinder pressures. As improvements were made to the authors' laboratory, a system to monitor and record pressure inside a diesel engine during operation was constructed to test dissimilar fuels. In the current work, three different fuels were tested in order to investigate combustion phasing, emissions, and fuel consumption as a function of fuel properties such as density, viscosity, Cetane Number, and energy content.

It is advantageous to increase the specific power output of diesel engines and to operate them at higher load for a greater portion of a driving cycle to achieve better thermal efficiency and thus reduce vehicle fuel consumption. Such operation is limited by excessive smoke formation at retarded injection timing and high rates of cylinder pressure rise at more advanced timing. Given this window of operation, it is desired to understand the influence of fuel properties such that optimum combustion performance and emissions can be retained over the range of fuels commonly available in the marketplace. Data are examined from a direct-injection single-cylinder research engine for eight common diesel fuels including soy-based biodiesel blends at two high load operating points with no exhaust gas recirculation (EGR) and at a moderate load with four levels of EGR.