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While metal fiber filters have successfully shown a high degree of particle retention functionality for various sizes of diesel engines with a low pressure drop and a relatively high filtration efficiency, little is known about the effects of lubricant-derived ash on the fiber filter systems. Sintered metal fiber filters (SMF-DPF), when used downstream from a diesel engine, effectively trap and oxidize diesel particulate matter via an electrically heated regeneration process where a specific voltage and current are applied to the sintered alloy fibers. In this manner the filter media essentially acts as a resistive heater to generate temperatures high enough to oxidize the carbonaceous particulate matter, which is typically in excess of 600°C.

This paper explores the benefits that would be achieved if gasoline marketers produced and offered a higher-octane gasoline to the U.S. consumer market as the standard grade. By raising octane, engine knock constraints are reduced, so that new spark-ignition engines can be designed with higher compression ratios and boost levels. Consequently, engine and vehicle efficiencies are improved thus reducing fuel consumption and greenhouse gas (GHG) emissions for the light-duty vehicle (LDV) fleet over time. The main objective of this paper is to quantify the reduction in fuel consumption and GHG emissions that would result for a given increase in octane number if new vehicles designed to use this higher-octane gasoline are deployed. GT-Power simulations and a literature review are used to determine the relative brake efficiency gain that is possible as compression ratio is increased.

An experimental study was performed in a firing SI engine at conditions representative of the warmup phase of operation in which liquid gasoline films were established at various locations in the combustion chamber and the resulting impact on hydrocarbon emissions was assessed. Unique about this study was that it combined, in a firing engine environment, direct visual observation of the liquid fuel films, measurements of the temperatures these films were subjected to, and the determination from gas analyzers of burned and unburned fuel quantities exiting the combustion chamber - all with cycle-level resolution or better. A means of deducing the exhaust hydrocarbon emissions that were due to the liquid fuel films in the combustion chamber was developed. An increase in exhaust hydrocarbon emissions was always observed with liquid fuel films present in the combustion chamber.

Passenger cars in the United States continue to incorporate increasing levels of technology and features. However, deployment of technology requires substantial development and time in the automotive sector. Prior analyses indicate that deployment of technology in the automotive sector can be described by a logistic function. These analyses refer to maximum annual growth rates as high as 17% and with developmental times of 10-15 years. However, these technologies vary widely in complexity and function, and span decades in their implementation. This work applies regression with a logistic form to a wide variety of automotive features and technologies and, using secondary regression, identifies broader trends across categories and over time.

Transport policy research seeks to predict and substantially reduce the future transport-related greenhouse gas emissions and fuel consumption to prevent negative climate change impacts and protect the environment. However, making such predictions is made difficult due to the uncertainties associated with the anticipated developments of the technology and fuel situation in road transportation, which determine the total fuel use and emissions of the future light-duty vehicle fleet. These include uncertainties in the performance of future vehicles, fuels' emissions, availability of alternative fuels, demand, as well as market deployment of new technologies and fuels. This paper develops a methodology that quantifies the impact of uncertainty on the U.S. transport-related fuel use and emissions by introducing a stochastic technology and fleet assessment model that takes detailed technological and demand inputs.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Recent studies have shown that for a given RON, fuels with a higher sensitivity (RON-MON) tend to have better antiknock performance at most knock-limited conditions in modern engines. The underlying chemistry behind fuel sensitivity was therefore investigated to understand why this trend occurs. Chemical kinetic models were used to study fuels of varying sensitivities; in particular their autoignition delay times and chemical intermediates were compared. As is well known, non-sensitive fuels tend to be paraffins, while the higher sensitivity fuels tend to be olefins, aromatics, diolefins, napthenes, and alcohols. A more exact relationship between sensitivity and the fuel's chemical structure was not found to be apparent. High sensitivity fuels can have vastly different chemical structures. The results showed that the autoignition delay time (τ) behaved differently at different temperatures. At temperatures below 775 K and above 900 K, τ has a strong temperature dependence.

The use of hydrogen as a fuel supplement for lean-burn engines at higher compression ratios has been studied extensively in recent years, with good promise of performance and efficiency gains. With the advances in reformer technology, the use of a gaseous fuel stock, comprising of substantially higher fractions of hydrogen and other flammable reformate species, could provide additional improvements. This paper presents the performance and emission characteristics of a gas mixture of equal volumes of hydrogen, CO, and methane. It has recently been reported that this gas mixture can be produced by reforming of ethanol at comparatively low temperature, around 300C. Experiments were performed on a 1.8-liter passenger-car Nissan engine modified for single-cylinder operation. Special pistons were made so that compression ratios ranging from CR= 9.5 to 17 could be used. The lean limit was extended beyond twice stoichiometric (up to lambda=2.2).

This vehicle simulation study estimates the fuel economy benefits of an HCCI engine system and assesses the NOx, HC and CO aftertreatment performance required for compliance with emissions regulations on U.S. and European regulatory driving cycles. The four driving cycles considered are the New European Driving Cycle, EPA City Driving Cycle, EPA Highway Driving Cycle, and US06 Driving Cycle. For each driving cycle, the following influences on vehicle fuel economy were examined: power-to-weight ratio, HCCI combustion mode operating range, driving cycle characteristics, requirements for transitions out of HCCI mode when engine speeds and loads are within the HCCI operating range, fuel consumption and emissions penalties for transitions into and out of HCCI mode, aftertreatment system performance and tailpipe emissions regulations.

The challenge posed by the long run times necessary to accurately quantify ash effects on diesel aftertreatment systems has led to numerous efforts to artificially accelerate ash loading, with varying degrees of success. In this study, a heavy-duty diesel engine was outfitted with a specially designed rapid lubricant degradation and aftertreatment ash loading system. Unlike previous attempts, the proposed methodology utilizes a series of thermal reactors and combustors to simulate all three major oil consumption mechanisms, namely combustion in the power cylinder, evaporative and volatile losses, and liquid losses through the valve and turbocharger seals. In order to simulate these processes, each thermal reactor allows for the precise control of the level of lubricant additive degradation, as well as the form and quantity of degradation products introduced into the exhaust upstream of the aftertreatment system.

This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.

The increased use of biodiesel fuels has raised concerns over the fuel's impact on engine performance and hardware compatibility. While these issues have received much attention in recent years, less well-known are the effects of biodiesel on engine-out ash emissions and lubricant properties. Significant differences in composition between biodiesel and petroleum diesel fuels have the potential to influence ash emissions, thereby affecting aftertreatment system performance. Further, the fuel also interacts directly with the lubricant through fuel dilution, and may impact lubricant properties. In this study, a 5.9L, 6 cylinder, Cummins ISB 300 diesel engine was outfitted with a specially designed rapid lubricant aging system and subjected to a set of steady-state engine operating conditions. The lubricant aging system allows for the investigation of the interactions of emissions and combustion products, as well as fuel dilution, on lubricant properties in an accelerated manner.

Irreversible plugging of diesel particulate filters caused by lubricant-derived metallic ash is the single most important factor responsible for long-term performance degradation and reduction in the service life of these filters. While a number of studies in the open literature have already demonstrated the benefits of diesel particulate traps and highlighted some of the difficulties associated with trap operation, many specific factors affecting trap performance and service life are still not well understood. The exact composition and nature of the exhaust entering the trap is one of the most important parameters affecting both short-term trap operation and long-term durability. In this study a fully instrumented Cummins ISB 300 six-cylinder, 5.9 liter, diesel engine was outfitted with a diesel particulate filter and subjected to a subset of the Euro III 13-mode stationary test cycle.

The life of an automotive engine is often limited by the ability of its components to resist wear. Zinc dialkyldithiophosphate (ZDDP) is an engine oil additive that reduces wear in an engine by forming solid antiwear films at points of moving contact. The effects of this additive are fairly well understood, but there is little theory behind the kinetics of antiwear film formation and removal. This lack of dynamic modeling makes it difficult to predict the effects of wear at the design stage for an engine component or a lubricant formulation. The purpose of this discussion is to develop a framework for modeling the formation and evolution of ZDDP antiwear films based on the relevant chemical pathways and physical mechanisms at work.

This paper assesses the potential improvement of automotive powertrain technologies 25 years into the future. The powertrain types assessed include naturally-aspirated gasoline engines, turbocharged gasoline engines, diesel engines, gasoline-electric hybrids, and various advanced transmissions. Advancements in aerodynamics, vehicle weight reduction and tire rolling friction are also taken into account. The objective of the comparison is the potential of anticipated improvements in these powertrain technologies for reducing petroleum consumption and greenhouse gas emissions at the same level of performance as current vehicles in the U.S.A. The fuel consumption and performance of future vehicles was estimated using a combination of scaling laws and detailed vehicle simulations. The results indicate that there is significant potential for reduction of fuel consumption for all the powertrains examined.

An experimental study was performed to investigate the effects of various intake charge motion control valves (CMCVs) on mixture preparation, combustion, and hydrocarbon (HC) emissions during the cold start-up process of a port fuel injected spark ignition (SI) engine. Different charge motions were produced by three differently shaped plates in the CMCV device, each of which blocked off 75% of the engine's intake ports. Time-resolved HC, CO and CO2 concentrations were measured at the exhaust port exit in order to achieve cycle-by-cycle engine-out HC mass and in-cylinder air/fuel ratio. Combustion characteristics were examined through a thermodynamic burn rate analysis. Cold-fluid steady state experiments were carried out with the CMCV open and closed. Enhanced charge motion with the CMCV closed was found to shorten the combustion duration, which caused the location of 50% mass fraction burned (MFB) to occur up to 5° CA earlier for the same spark timing.

Dilute operation of a SI engine offers attractive performance incentives. Lowered combustion temperatures and changes in the mixture composition inhibit NOx formation and increase the effective value of the ratio of burned gas specific heats, increasing gross indicated efficiency. Additionally, reduced intake manifold throttling minimizes pumping losses, leading to higher net indicated efficiency. These benefits are offset by the reduced combustion speed of dilute fuel-air mixtures, which can lead to high cycle-to-cycle variation and unacceptable engine behavior characteristics. Hydrogen enhancement can suppress the undesirable consequences of dilute operation by accelerating the combustion process, thereby extending the dilution limit. Hydrogen would be produced on-board the vehicle with a gasoline reforming device such as the plasmatron. High dilution at higher loads would necessitate boosting to meet the appropriate engine specific power requirements.

A study at MIT of the energy consumption and greenhouse gas emissions from advanced technology future automobiles has compared fuel cell powered vehicles with equivalent gasoline and diesel internal combustion engine (ICE) powered vehicles [1][2]. Current data regarding IC engine and fuel cell vehicle performance were extrapolated to 2020 to provide optimistic but plausible forecasts of how these technologies might compare. The energy consumed by the vehicle and its corresponding CO2 emissions, the fuel production and distribution energy and CO2 emissions, and the vehicle manufacturing process requirements were all evaluated and combined to give a well-to-wheels coupled with a cradle-to-grave assessment. The assessment results show that significant opportunities are available for improving the efficiency of mainstream gasoline and diesel engines and transmissions, and reducing vehicle resistances.