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For gasoline engine, thermal efficiency can be improved by using lean burn. However, combustion instability occurs when gasoline engine is operated on lean condition. Hydrogen has features that can be used for improving combustion stability of gasoline engine. In this paper, an experimental study of hydrogen effect on lean limit was carried out using a four-cylinder 2.0L turbo gasoline direct injection engine. The engine torque was fixed at 110Nm on 1600RPM, 2000RPM and 2400RPM. The results showed that lean limit was extended and brake thermal efficiency was improved by hydrogen addition. Especially, at lower engine speed, the large improvement of lean limit was achieved. However, improvement of brake thermal efficiency was achieved at high speed. HC and CO2 emissions were decreased and NO emissions increased with hydrogen addition. CO emissions were slightly reduced with hydrogen addition.

This paper explores the benefits that would be achieved if gasoline marketers produced and offered a higher-octane gasoline to the U.S. consumer market as the standard grade. By raising octane, engine knock constraints are reduced, so that new spark-ignition engines can be designed with higher compression ratios and boost levels. Consequently, engine and vehicle efficiencies are improved thus reducing fuel consumption and greenhouse gas (GHG) emissions for the light-duty vehicle (LDV) fleet over time. The main objective of this paper is to quantify the reduction in fuel consumption and GHG emissions that would result for a given increase in octane number if new vehicles designed to use this higher-octane gasoline are deployed. GT-Power simulations and a literature review are used to determine the relative brake efficiency gain that is possible as compression ratio is increased.

An experimental study was performed in a firing SI engine at conditions representative of the warmup phase of operation in which liquid gasoline films were established at various locations in the combustion chamber and the resulting impact on hydrocarbon emissions was assessed. Unique about this study was that it combined, in a firing engine environment, direct visual observation of the liquid fuel films, measurements of the temperatures these films were subjected to, and the determination from gas analyzers of burned and unburned fuel quantities exiting the combustion chamber - all with cycle-level resolution or better. A means of deducing the exhaust hydrocarbon emissions that were due to the liquid fuel films in the combustion chamber was developed. An increase in exhaust hydrocarbon emissions was always observed with liquid fuel films present in the combustion chamber.

Passenger cars in the United States continue to incorporate increasing levels of technology and features. However, deployment of technology requires substantial development and time in the automotive sector. Prior analyses indicate that deployment of technology in the automotive sector can be described by a logistic function. These analyses refer to maximum annual growth rates as high as 17% and with developmental times of 10-15 years. However, these technologies vary widely in complexity and function, and span decades in their implementation. This work applies regression with a logistic form to a wide variety of automotive features and technologies and, using secondary regression, identifies broader trends across categories and over time.

Transport policy research seeks to predict and substantially reduce the future transport-related greenhouse gas emissions and fuel consumption to prevent negative climate change impacts and protect the environment. However, making such predictions is made difficult due to the uncertainties associated with the anticipated developments of the technology and fuel situation in road transportation, which determine the total fuel use and emissions of the future light-duty vehicle fleet. These include uncertainties in the performance of future vehicles, fuels' emissions, availability of alternative fuels, demand, as well as market deployment of new technologies and fuels. This paper develops a methodology that quantifies the impact of uncertainty on the U.S. transport-related fuel use and emissions by introducing a stochastic technology and fleet assessment model that takes detailed technological and demand inputs.

The high concentration of particulate matter (PM) in diesel exhaust gas causes significant soot deposition on the wall of EGR cooler, and reduces the heat transfer performance of the EGR cooler and the reduction rate of NOx. The deposition of PM tends to be occurred more severely with "heavy wet PM," which is more frequently at the LTC (low temperature combustion) engine. The objective of this work is to evaluate the effects of soluble organic fraction (SOF) on deposit characteristics of the EGR cooler. To measure reliable mean particle concentration values and surrogate SOFs, the soot generator with SOF vaporizer was used. As for two surrogate SOFs, n-dodecane and diesel lube oil, deposit mass increased when they were injected. Especially from the experiment results, it was found that the lube oil effect was more significant than the n-dodecane effect and lube oil also had a stronger effect on reduction of thermal conductivity by filling pores in deposits.

HC-SCR is more convenient when compared to urea-SCR, since for HC-SCR, diesel fuel can be used as the reductant which is already available onboard the vehicle. However, the DeNOX efficiency for HC-SCR is lower than that of urea-SCR in both low and high temperature windows. In an attempt to improve the DeNOX efficiency of HC-SCR, the effect of hydrogen were evaluated for the fresh and aged catalyst over 2 wt.% Ag/Al₂O₃ using a Euro-4 diesel engine. In this engine bench test, diesel fuel as the reductant was injected directly into the exhaust gas stream and the hydrogen was supplied from a hydrogen bomb. The engine was operated at 2,500 rpm and BMEP 4 bar. The engine-out NOX was around 180 ppm-200 ppm. H₂/NOX and HC₁/NOX ratios were 5, 10, 20, and 3, 6, 9, respectively. The HC-SCR inlet exhaust gas temperatures were around 215°C, 245°C, and 275°C. The catalyst volumes used in this test were 2.5L and 5L for both fresh and aged catalysts.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Diesel particulate filter (DPF) systems are being used to reduce the particulate matter emissions of diesel vehicles. The DPF should be regenerated after certain driving hours or distance to eliminate soot in the filter. The most widely used method is active regeneration with oxygen at 550~650°C. Fuel penalty occurs when the exhaust gas temperature is increased. The low temperature oxidation technique is needed to reduce fuel consumption. In this study, we found that hydrogen could be used to decrease the PM oxidation temperature significantly on a catalyzed DPF (CDPF). The oxidation characteristics of PM with hydrogen supplied to CDPF were studied using a partial flow system. The partial flow system was used to control temperature and a flow rate independently. The CDPF was coated with Pt/Al₂O₃ 25g/ft₃, and a multi-channel CDPF (MC CDPF) with a square cross section of 1.65 cm width and length of 10 cm was used.

The oxidation of soot (carbon black) which is assisted by Pt/CeO2 catalyst is studied using a flow reactor system simulating the condition of diesel exhaust. In this study, the temperature programmed oxidation (TPO) scheme is mainly used for different NO and O2 concentrations and soot oxidation rate is evaluated by monitoring both CO and CO2 concentrations. Pt/CeO2 catalyst lowers the temperature of the peak CO/CO2 concentrations significantly when there is either NO or O2. Oxidation starts at 200°C and the peak CO2 concentration is observed at 360°C, which depends on the amount of catalyst and NO concentration. The effect of catalyst on NO2 recycling is also investigated. For this purpose, two different types of sample have been prepared. For the mixed case, 10mg of carbon black is mixed with 50mg of Pt/CeO2 catalyst under conditions of loose contact. For the unmixed case, the catalyst layer is placed on top of soot layer without mixing.

This vehicle simulation study estimates the fuel economy benefits of an HCCI engine system and assesses the NOx, HC and CO aftertreatment performance required for compliance with emissions regulations on U.S. and European regulatory driving cycles. The four driving cycles considered are the New European Driving Cycle, EPA City Driving Cycle, EPA Highway Driving Cycle, and US06 Driving Cycle. For each driving cycle, the following influences on vehicle fuel economy were examined: power-to-weight ratio, HCCI combustion mode operating range, driving cycle characteristics, requirements for transitions out of HCCI mode when engine speeds and loads are within the HCCI operating range, fuel consumption and emissions penalties for transitions into and out of HCCI mode, aftertreatment system performance and tailpipe emissions regulations.

This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.

Today's diesel PM reduction systems are mainly based on catalyzed particulate filter(CPF) systems. However, most of their reaction kinetics remain unresolved. Among others, the soot oxidation rate over catalyst is particularly important in the evaluation of the performance of the catalysts and the efficient control of CPF regeneration. This study, therefore, investigated the oxidation rate of carbon black (Printex-U) over various Pt supported catalysts using a flow reactor setup simulating diesel exhaust conditions. Compared to non-catalyzed soot oxidation, the oxidation rate of carbon black over Pt catalysts was to an extent shifted towards low temperatures. This activity enhancement of soot oxidation over a catalyst can be attributed principally to NO to NO2 conversion because NO2 oxidizes soot with much lower activation energy (Ea=60kJ/mol) than O2 (Ea=177kJ/mol).

Diesel engines are the most commonly used power plant of freight and public transportations in the world. Also, the newly developed injection system, Common Rail system, increases the demands for both light and heavy duty diesel vehicles. On the other hand, stringent emission regulations are being proposed with growing concern on NOx and PM emissions from diesel engines. Future emission regulations require advanced emission control technologies, such as EGR and SCR. Exhaust gas recirculation (EGR) is a commonly used technique to reduce NOx emission. In this paper, a model-based investigation was conducted to compare the effect of high pressure loop (HPL) EGR and low pressure loop (LPL) EGR system on NOx level and BSFC of a heavy-duty diesel engine. A WAVE model was created to simulate EURO 3 engine and each component of the engine was modeled using CATIA and WaveMesher.

In this study, compositions, size distributions and activation energy in oxidation of diesel PM were investigated. Benzene (C6H6) was mixed to diesel fuel as a promoter of PM formation, and further, ferrocene (Fe(C5H5)2) was added as a promoter for oxidation processes during in-cylinder combustion and after-treatment. The effect of those additions on the PM characteristics was discussed on the basis of measured results such as SOF and dry-soot ratio in PM, primary and aggregate particle size distributions of PM, activation energy of PM oxidation, and PM components with elemental analysis. As a result, it was shown that ferrocene had special effect on the PM size distribution and the activation energy.

Characteristics of soot oxidation were investigated with a carbon black (Printex-U). A flow reactor system which can simulate the condition of diesel particulate filter and diesel exhaust gas (1 bar, O2 0 ∼ 10%, NO2 200 ∼ 900ppm) was designed and used with the temperature programmed oxidation (TPO) and constant temperature oxidation (CTO) techniques. The temperature increase rate was 5°C/min for TPO experiments. From the experiments, the apparent activation energy for carbon oxidation with nitrogen dioxide was determined as 60 ± 3 kJ/mol with the first order of carbon in the range of 10∼90% oxidation and the temperature range of 250∼500°C. This value was exceedingly lower than the activation energy of oxygen oxidation which was 177 ± 1 kJ/mol. When oxygen exists with nitrogen dioxide, the reaction rate increased with the concentration of oxygen. Its rate of increase was faster for low oxygen concentration and slower for high concentration.

This paper assesses the potential improvement of automotive powertrain technologies 25 years into the future. The powertrain types assessed include naturally-aspirated gasoline engines, turbocharged gasoline engines, diesel engines, gasoline-electric hybrids, and various advanced transmissions. Advancements in aerodynamics, vehicle weight reduction and tire rolling friction are also taken into account. The objective of the comparison is the potential of anticipated improvements in these powertrain technologies for reducing petroleum consumption and greenhouse gas emissions at the same level of performance as current vehicles in the U.S.A. The fuel consumption and performance of future vehicles was estimated using a combination of scaling laws and detailed vehicle simulations. The results indicate that there is significant potential for reduction of fuel consumption for all the powertrains examined.

An experimental study was performed to investigate the effects of various intake charge motion control valves (CMCVs) on mixture preparation, combustion, and hydrocarbon (HC) emissions during the cold start-up process of a port fuel injected spark ignition (SI) engine. Different charge motions were produced by three differently shaped plates in the CMCV device, each of which blocked off 75% of the engine's intake ports. Time-resolved HC, CO and CO2 concentrations were measured at the exhaust port exit in order to achieve cycle-by-cycle engine-out HC mass and in-cylinder air/fuel ratio. Combustion characteristics were examined through a thermodynamic burn rate analysis. Cold-fluid steady state experiments were carried out with the CMCV open and closed. Enhanced charge motion with the CMCV closed was found to shorten the combustion duration, which caused the location of 50% mass fraction burned (MFB) to occur up to 5° CA earlier for the same spark timing.

Dilute operation of a SI engine offers attractive performance incentives. Lowered combustion temperatures and changes in the mixture composition inhibit NOx formation and increase the effective value of the ratio of burned gas specific heats, increasing gross indicated efficiency. Additionally, reduced intake manifold throttling minimizes pumping losses, leading to higher net indicated efficiency. These benefits are offset by the reduced combustion speed of dilute fuel-air mixtures, which can lead to high cycle-to-cycle variation and unacceptable engine behavior characteristics. Hydrogen enhancement can suppress the undesirable consequences of dilute operation by accelerating the combustion process, thereby extending the dilution limit. Hydrogen would be produced on-board the vehicle with a gasoline reforming device such as the plasmatron. High dilution at higher loads would necessitate boosting to meet the appropriate engine specific power requirements.

A study at MIT of the energy consumption and greenhouse gas emissions from advanced technology future automobiles has compared fuel cell powered vehicles with equivalent gasoline and diesel internal combustion engine (ICE) powered vehicles [1][2]. Current data regarding IC engine and fuel cell vehicle performance were extrapolated to 2020 to provide optimistic but plausible forecasts of how these technologies might compare. The energy consumed by the vehicle and its corresponding CO2 emissions, the fuel production and distribution energy and CO2 emissions, and the vehicle manufacturing process requirements were all evaluated and combined to give a well-to-wheels coupled with a cradle-to-grave assessment. The assessment results show that significant opportunities are available for improving the efficiency of mainstream gasoline and diesel engines and transmissions, and reducing vehicle resistances.