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In recent years, catalyst systems such as a lean NOx trap (LNT) catalyst system and a urea selective catalytic reduction (SCR) system have been developed to obtain cleaner diesel emissions. At Nissan, we developed an emission control system for meeting Tier 2 Bin 5 requirements in 2003. On the basis of that technology, a new HC-NOx trap catalyst system has now been developed that complies with the SULEV standards without increasing the catalyst volume and precious metal loading. Compliance with the SULEV standards requires a further reduction of HC (NMHC) emissions by 84% and NOx by 60% compared with the emission performance Tier 2 Bin 5 compliant catalyst system. Consequently high conversion performance for both HCs and NOx is needed. An investigation of HC emission behavior under the FTP75 mode showed that a reduction of cold-phase HCs was critical for meeting the standard. Large quantities of HCs above C4 are emitted in the cold state.

Diesel particulate trap systems are one of the effective means for the control of particulate emission from diesel vehicles. Hino has been researching and developing various diesel particulate trap systems for city buses. This paper describes two of the systems. One uses a wall flow filter equipped with an electric heater and a sensing device for particulate loading for the purpose of filter regeneration. Another makes use of a special filter named “Cross Flow Filter” with an epoch-making regeneration method called “Reverse Jet Cleaning”, by which it becomes possible to separate the part for particulate burning from the filter. Both systems roughly have come to satisfy the functions of trap systems for city buses, but their durability and reliability for city buses are not yet sufficient.

The thermal fatigue resistance of engine exhaust system parts has conventionally been evaluated in thermal fatigue tests conducted with a restrained specimen. However, the test results have not always been consistent with data obtained in engine endurance tests. Two new evaluation methods have been developed to overcome this problem. One is a method of predicting thermal fatigue life on the basis of nonlinear elastic and plastic thermal analyses performed with a finite element model and the ABAQUS program. The other is a method of evaluating exhaust system parts using an exhaust system simulator. This paper describes the concepts underlying the two methods and their relative advantages.

Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

The purpose of this study is to clarify the state of heat loss to the cylinder liner of the tested engine of which piston and cylinder head were previously measured. The authors' group developed an original measurement technique of instantaneous surface temperature at the cylinder liner wall using thin-film thermocouples. The temperature was measured at 36 points in total. The instantaneous heat flux was calculated by heat transfer analysis using measurement results of the temperature at the wall. As a result, the heat loss ratio to all combustion chamber walls is evaluated except the intake and exhaust valves.

The demands on valve seat insert materials, in terms of providing greater wear-resistance at higher temperatures, enhanced machinability and using non-environmentally hazardous materials at a reasonably low cost have intensified in recent years. Due therefore to these strong demands in the market, research was made into the possibility of producing a new valve seat insert material. As a result a high speed steel based new improved material was developed, which satisfies the necessary required demands and the evaluation trials, using actual gasoline engine endurance tests, were found to be very successful.

Nissan Motor has put on the European SUV market a 2.2-L direct-injection diesel engine with a diesel particulate filter (DPF) system that complies with the EURO IV emission regulations. This paper describes the DPF system, cooperative control of a variable geometry turbo (VGT) and exhaust gas recirculation (EGR), and a high-accuracy lambda control adopted for this engine. In order to achieve a compact DPF, the high-accuracy lambda control was developed to reduce variation in engine-out particulate matter (PM) emissions. Moreover, the accuracy of the technique for predicting the quantity of PM accumulation was improved for reliable detection of the DPF regeneration. Prediction error for PM accumulation increases during transient operation. Control logic was adopted to correct the PM prediction according to lambda fluctuation detected by an observer for lambda at cylinder under transient operating conditions. The observer is corrected lambda sensor output.

To reduce NOx and Particulate Matter (PM) emissions from a heavy-duty diesel engine, the effects of urea selective catalytic reduction (SCR) systems were studied. Proto type urea SCR system was composed of NO oxidation catalyst, SCR catalyst and ammonia (NH3) reduction catalyst. The NOx reduction performance of urea SCR system was improved by a new zeolite type catalyst and mixer for urea distribution at the steady state operating conditions. NOx and PM reduction performance of the urea SCR system with DPF was evaluated over JE05 mode of Japan. The NOx reduction efficiency of the urea SCR catalyst system was 72% at JE05 mode. The PM reduction efficiency of the urea SCR catalyst system with DPF was 93% at JE05 mode. Several kinds of un-regulated matters were detected including NH3 and N2O leak from the exhaust gas. It is necessary to have further study for detailed measurements for un-regulated emissions from urea solution.

Nissan Motor Company has developed a compact and simple new variable valve actuation system called VVEL (Variable Valve Event and Lift) that can vary intake valve lift and valve event angle in a wide range, and adopted it on a newly developed 3.7L, V6 engine. This system combined with a variable valve timing (VTC) mechanism (or a cam phaser) has substantially enhanced engine performance attributes, namely, fuel economy, exhaust emissions, and engine output, because the system has the ability to freely control all of intake valve lift, event duration angle and phasing between intake and exhaust valves. This paper describes an outline of the VVEL system, the principle of system operation, and effects on engine performance attributes by this technology.

Biodiesel Fuel (BDF) Research Work Group works on identifying technological issues on the use of high biodiesel blends (over 5 mass%) in conventional diesel vehicles under the Japan Auto-Oil Program started in 2007. The Work Group conducts an analytical study on the issues to develop measures to be taken by fuel products and vehicle manufacturers, and to produce new technological findings that could contribute to the study of its introduction in Japan, including establishment of a national fuel quality standard covering high biodiesel blends. For evaluation of the impacts of high biodiesel blends on performance of diesel particulate filter system, a wide variety of biodiesel blendstocks were prepared, ranging from some kinds of fatty acid methyl esters (FAME) to another type of BDF such as hydrotreated biodiesel (HBD). Evaluation was mainly conducted on blend levels of 20% and 50%, but also conducted on 10% blends and neat FAME in some tests.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

The Diesel Particulate Filter (DPF) system has been developed as one of key technologies to comply with tight diesel PM emission regulations. For the DPF control system, it is necessary to maintain temperature inside the DPF below the allowable service temperature, especially during soot regeneration to prevent catalyst deterioration and cracks. Therefore, the evaluation of soot regeneration is one of the key development items for the DPF system. On the other hand, regeneration evaluation requires a lot of time and cost since many different regeneration conditions should be investigated in order to simulate actual driving. The simulation tool to predict soot regeneration behavior is a powerful tool to accelerate the development of DPF design and safe regeneration control strategies. This paper describes the soot regeneration model applied to fuel additive and catalyzed types, and shows good correlation with measured data.

Generally, cobalt-contained sintered materials have mainly been applied for exhaust valve seat inserts (VSI). However, there is a trend to restrict the use of cobalt as well as lead environmental law, and cobalt is expensive. To solve these problems, a new exhaust VSI on the assumption of being cobalt and lead free, applicable for conventional engines, having good machinability, and with a reduced cost was developed. The new exhaust VSI is a material dispersed with two types of hard particles, Fe-Cr-C and Fe-Mo-Si, in the matrix of an Fe-3.5mass%Mo at the ratio of 15 mass % and 10 mass % respectively.

To reduce ultra fine particle number concentration from a heavy-duty diesel engine, the effects of diesel fuel property and after-treatment systems were studied. The reduction of ultra fine particle number concentration over steady state mode using an 8 liter turbocharged and after-cooled diesel engine was evaluated. PM size distribution was measured by a scanning mobility particle sizer (SMPS). The evaluation used a commercially available current diesel fuel (Sulfur Content: 0.0036 wt%), high sulfur diesel fuel (Sulfur Content: 0.046 wt%) and low sulfur diesel fuel (Sulfur Content: 0.007 wt%). The after-treatment systems were an oxidation catalyst, a wire-mesh type DPF (Diesel Particle Filter) and a wall-flow type catalyzed DPF. The results show that fine particle number concentration is reduced with a low sulfur fuel, an oxidation catalyst, a wire-mesh type DPF (Diesel Particulate Filter) and wall flow type catalyzed DPF, respectively.

A new multidimensional calculation method has been developed to simulate the warm-up characteristics of close-coupled catalytic converter systems. First, a one-dimensional gas exchange simulation and a three-dimensional exhaust gas flow calculation are combined to simulate the pulsation gas flow caused by the gas exchange process. The gas flow calculation and a heat transfer calculation are then combined to simulate heat transfer in the exhaust manifold and the catalyst honeycomb under pulsation flow. The predicted warm-up characteristics of the systems examined agreed well with the experimental data. In this simulation, CPU time was reduced greatly through the use of new calculation methods. Finally, the warm-up process of close-coupled catalysts is analyzed in detail with this simulation method. The design requirements for improving warm-up characteristics have been made clear.

Impact of oil-derived ash on the pressure drop of continuous regeneration-type diesel particulate filter (CR-DPF) was investigated through 600hrs running test at maximum power point on a 6.9L diesel engine, which meets the Japanese long-term emission regulations enacted in 1998, using approximately 50ppm sulfur content fuel. Sulfated ash content of test oils were varied as 0.96, 1.31, and 1.70 mass%, respectively. During the running test, the exhaust pressure drop through CR-DPF was measured. And after the test, the ventilation resistance through CR-DPF was also evaluated before and after the baking process, which was applied to eliminate the effect of soot accumulated in CR-DPF. The results revealed that the less sulfated ash in oil gave rise to lower pressure drop across CR-DPF. According to microscope examination of the baked DPF, ash was mainly accumulated on the wall surface of CR-DPF, and that seemed to be related to the magnitude of pressure drop caused by ash.

A combined computational fluid dynamics (CFD) and finite element (FE) analysis approach has been developed to simulate in the early stages of design the temperature distribution and estimate the thermal fatigue life of an engine exhaust manifold. To simulate the temperature distribution under actual operating conditions, we considered the external and internal flow fields. Digital mock-ups of the vehicle and engine were used to define the geometry of the engine compartment. External-air-flow simulation using in-house CFD code was used to predict the flow fields in the engine compartment and the heat transfer coefficients between the air and the exhaust manifold wall at various vehicle speeds. Unsteady-gas-flow calculation using the STAR-CD thermal- fluids analysis code was to predict the heat transfer coefficients between the exhaust gas and the manifold wall under various operating conditions.

To reduce NOx emissions from a heavy-duty engine at low exhaust temperature conditions, the plasma-assisted SCR (Selective Catalytic Reduction) system was evaluated. The plasma-assisted SCR system is mainly composed of an ammonia gas supply system and a plasma reactor including a pellet type SCR catalyst. The preliminary test with simulated gases of diesel exhaust showed an improvement in the NOx reduction performance by means of the plasma-assisted SCR system, even below 150°C conditions. Furthermore, NOx reduction ratio was improved up to 77% at 110°C with increase in the catalyst volume. Also NOx emissions from a heavy-duty diesel engine over the transient test mode in Japan (JE05) were reduced by the plasma-assisted SCR system. However, unregulated emissions, e.g., aldehydes, were increased with the plasma environment. This paper reports the advantages and disadvantages of the plasma-assisted SCR system for a heavy-duty diesel engine.

EPA 2010 emissions regulations - currently the strictest standards in the world - place particular emphasis on exhaust gas thermal control technology. The Burner System, a device developed to control exhaust gas temperatures, is the most effective means of raising exhaust gas temperature, as this system can function under any engine conditions, including low engine speed and torque. The Burner System begins operating immediately when the engine is started, activating the Diesel Exhaust Fluid (DEF) - Selective Catalytic Reduction (SCR) System immediately, because the Burner System is active, it enables the diesel particulate filter active regeneration under any engine operating conditions as well. This technical paper reports Burner System (ActiveClean™ Thermal Regenerator) development results.