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Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

Although the application of cylinder pressure sensors to gain insight into the combustion process is not a novel topic itself, the recent availability of inexpensive in-cylinder pressure sensors has again prompted an upcoming interest for the utilization of the cylinder pressure signal within engine control and monitoring. Besides the use of the in-cylinder pressure signal for combustion analysis and control the information can also be used to determine related quantities in the exhaust or intake manifold. Within this work two different methods to estimate the pressure inside the exhaust manifold are proposed and compared. In contrary to first principle based approaches, which may require time extensive parameterization, alternative data driven approaches were pursued. In the first method a Principle Component Analysis (PCA) is applied to extract the cylinder pressure information and combined with a polynomial model approach.

In this work a multilevel CFD analysis have been applied for the design of an intake air-box with improved characteristics of noise reduction and fluid dynamic response. The approaches developed and applied for the optimization process range from the 1D to fully 3D CFD simulation, exploring hybrid approaches based on the integration of a 1D model with quasi-3D and 3D tools. In particular, the quasi-3D strategy is exploited to investigate several configurations, tailoring the best trade-off between noise abatement at frequencies below 1000 Hz and optimization of engine performances. Once the best configuration has been defined, the 1D-3D approach has been adopted to confirm the prediction carried out by means of the simplified approach, studying also the impact of the new configuration on the engine performances.

Lean-burn combustion is an effective method for increasing the thermal efficiency of gasoline engines fueled with stoichiometric fuel-air mixture, but leads to an unacceptable level of high cyclic variability before reaching ultra-low nitrogen oxide (NOx) emissions emitted from conventional gasoline engines. Multi-point micro-flame ignited (MFI) hybrid combustion was proposed to overcome this problem, and can be can be grouped into double-peak type, ramp type and trapezoid type with very low frequency of appearance. This research investigates the micro-flame ignition stages of double-peak type and ramp type MFI combustion captured by high speed photography. The results show that large flame is formed by the fast propagation of multi-point flame occurring in the central zone of the cylinder in the double-peak type. However, the multiple flame sites occur around the cylinder, and then gradually propagate and form a large flame accelerated by the independent small flame in the ramp type.

In recent years, the increase of gasoline fuel injection pressure is a way to improve thermal efficiency and lower engine-out emissions in GDI homogenous combustion concept. The challenge of controlling particulate formation as well in mass and number concentrations imposed by emissions regulations can be pursued improving the mixture preparation process and avoiding mixture inhomogeneity with ultra-high injection pressure values up to 100 MPa. The increase of the fuel injection pressure in GDI homogeneous systems meets the demand for increased injector static flow, while simultaneously improves the spray atomization and mixing characteristics with consequent better combustion performance. Few studies quantify the effects of high injection pressure on transient gasoline spray evolution. The aim of this work was to simulate with OpenFOAM the spray morphology of a commercial gasoline injected in a constant volume vessel by a prototypal GDI injector.

In the last decades numerical simulations have become reliable tools for the design and the optimization of silencers for internal combustion engines. Different approaches, ranging from simple 1D models to detailed 3D models, are nowadays commonly applied in the engine development process, with the aim to predict the acoustic behavior of intake and exhaust systems. However, the acoustic analysis is usually performed under the hypothesis of infinite stiffness of the silencer walls. This assumption, which can be regarded as reasonable for most of the applications, can lose validity if low wall thickness are considered. This consideration is even more significant if the recent trends in the automotive industry are taken into account: in fact, the increasing attention to the weight of the vehicle has lead to a general reduction of the thickness of the metal sheets, due also to the adoption of high-strength steels, making the vibration of the components a non negligible issue.

Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.

Metallic foams or sponges are materials with a cell structure suitable for many industrial applications, such as reformers, heat catalytic converters, etc. The success of these materials is due to the combination of various characteristics such as mechanical strength, low density, high specific surface, good thermal exchange properties, low flow resistance and sound absorption. Different materials and manufacturing processes produce different type of structure and properties for various applications. In this work a genetic algorithm has been developed and applied to support the design of catalytic devices. In particular, two substrates were considered, namely the traditional honeycomb and an alternative open-cell foam type. CFD simulations of pressure losses and literature based correlations for the heat and mass transfer were used to support the genetic algorithm in finding the best compromise between flow resistance and pollutant abatement.

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

The Gasoline direct-injection (GDI) engine can emit high levels of particulate matter and unburned Hydrocarbons when operating under stratified charge combustion mode. Injecting late in the compression stroke means the fuel has insufficient time to atomise and evaporate. This could cause fuel film accumulation on the piston surface and combustion liner. Locally fuel rich diffusion combustion could also result in the formation of soot particles. Employing a split-injection strategy can help tackle these issues. The first injection is initiated early in the intake stroke and could ensure a global homogeneous charge. The second injection during the compression stroke could help form a fuel-rich charge in the vicinity of the spark plug. Many studies have established the crucial role that a split-injection strategy plays in the stratified charge operation of GDI engines.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

Today, Direct-Injection systems are widely used on Spark-Ignition engines in combination with turbo-charging to reduce the fuel-consumption and the knock risks. In particular, the spread of Gasoline Direct Injection (GDI) systems is mainly related to the use of new generations of multi-hole, high-pressure injectors whose characteristics are quite different with respect to the hollow-cone, low-pressure injectors adopted in the last decade. This paper presents the results of an experimental campaign conducted on the spray produced by a GDI six-holes injector into a constant volume vessel with optical access. The vessel was filled with air at atmospheric pressure. Different operating conditions were considered for an injection pressure ranging from 3 to 20 MPa. For each operating condition, spray images were acquired by a CCD camera and then post processed to evaluate the spray penetration and cone angles.

In this paper a three-dimensional time-domain CFD approach has been employed to predict and analyze the acoustic attenuation performance of complex perforated muffler geometries, where strong 3D effects limit the validity of the use of one-dimensional models. A pressure pulse has been imposed at the inlet to excite the wave motion, while unsteady flow computation have been performed to acquire the time histories of the pressures upstream and downstream of the silencer. Pressures in the time domain have been then transformed to acoustic pressures in the frequency domain, to predict the transmission loss.

This paper is a complementary to previous investigations by the authors (1,2,3,4) on the different effects of EGR on combustion and emissions in DI diesel engine. In addition to the several effects that cold EGR has on combustion and emissions the application of hot EGR results in increasing the inlet charge temperature, thereby, for naturally aspirated engines, lowering the inlet charge mass due to thermal throttling. An associated consequence of thermal throttling is the reduction in the amount of oxygen in the inlet charge. Uncooled EGR, therefore, affects combustion and emissions in two ways: through the reduction in the inlet charge mass and through the increase in inlet charge temperature. The effect on combustion and emissions of increasing the inlet charge temperature (without reducing the inlet charge mass) has been dealt with in ref. (1).

The effects of load, speed, exhaust gas recirculation (EGR) level and hydrogen addition level on the emissions from a diesel engine have been investigated. The experiments were performed on a 2.0 litre, 4 cylinder, direct injection engine with a high pressure common-rail injection system. Injection timing was varied between 14° BTDC and TDC and injection pressures were varied from 800 bar to 1400 bar to find a suitable base point. EGR levels were then varied from 0% to 40%. Hydrogen induction was varied between 0 and 6% vol. of the inlet charge. In the case of using hydrogen and EGR, the hydrogen replaced air. The load was varied from 0 to 5.4 bar BMEP at two engine speeds, 1500 rpm and 2500 rpm. For this investigation the carbon monoxide (CO), total unburnt hydrocarbons (THC), nitrogen oxides (NOx) and the filter smoke number (FSN) were all measured.

Controlled Auto-Ignition (CAI), also known as HCCI (Homogeneous Charge Compression Ignition), is increasingly seen as a very effective way of lowering both fuel consumption and emissions from gasoline engines. Therefore, it's seen as one of the best ways to meet future engine emissions and CO2 legislations. This combustion concept was achieved in a Ford production, port-injected, 4 cylinder gasoline engine. The only major modification to the original engine was the replacement of the original camshafts by a new set of custom made ones. The CAI operation was accomplished by means of using residual gas trapping made possible by the use of VCT (variable cam timing) on both intake and exhaust camshafts. When running on CAI, the engine was able to achieve CAI combustion with in a load range of 0.5 to 4.5 BMEP, and a speed range of 1000 to 3500 rpm. In addition, spark assisted CAI operation was employed to extend the operational range of low NOx and low pumping loss at part-load conditions.

The purpose of the European « SPACE LIGHT » (Whole SPACE combustion for LIGHT duty diesel vehicles) 3-year project launched in 2001 is to research and develop an innovative Homogeneous internal mixture Charged Compression Ignition (HCCI) for passenger cars diesel engine where the combustion process can take place simultaneously in the whole SPACE of the combustion chamber while providing almost no NOx and particulates emissions. This paper presents the whole project with the main R&D tasks necessary to comply with the industrial and technical objectives of the project. The research approach adopted is briefly described. It is then followed by a detailed description of the most recent progress achieved during the tasks recently undertaken. The methodology adopted starts from the research study of the in-cylinder combustion specifications necessary to achieve HCCI combustion from experimental single cylinder engines testing in premixed charged conditions.

For vibration and acoustics vehicle development, one of the main challenges is the identification and the analysis of the noise sources, which is required in order to increase the driving comfort and to meet the stringent legislative requirements for the vehicle noise emission. Transfer Path Analysis (TPA) is a fairly well established technique for estimating and ranking individual low-frequency noise or vibration contributions via the different transmission paths. This technique is commonly applied on test measurements, based on prototypes, at the end of the design process. In order to apply such methodology already within the design process, a contribution analysis method based on dynamic substructuring of a multibody system is proposed with the aim of improving the quality of the design process for vehicle NVH assessment and to shorten development time and cost.

The spark-assisted compression ignition (SACI) is widely used to expend the high load limit of homogeneous charge compression ignition (HCCI), as it can reduce the high heat release rate effectively while partially maintain the advantage of high thermal efficiency and low NOx emission. But as engine load increases, the SACI combustion traditionally using negative valve overlap strategy (NVO) faces the drawback of higher pumping loss and limited intake charge availability, which lead to a restricted load expansion and a finite improvement of fuel economy. In this paper, research is focused on the SACI combustion using positive valve overlap (PVO) strategy. The characteristics of SACI combustion employing PVO strategy with external exhaust gas recirculation (eEGR) are investigated. Two types of PVO strategies are analyzed and compared to explore their advantages and defects, and the rules of adjusting SACI combustion with positive valve overlap are concluded.

The acoustic simulation of internal combustion engine exhaust systems is an important aspect to meet customer expectations and legislation targets. One dimensional gas dynamic simulation tools are used for the calculation of the exhaust orifice noise in the early stages of the engine development process. This includes the prediction of the acoustic performance of individual components in the exhaust line. One common element used in exhaust systems to increase the acoustic damping is the plug flow muffler. This study looks at the prediction of acoustic performance of various plug mufflers at different flow velocities. These include a single plug muffler, a double plug muffler and an eccentric plug muffler with different porosities for the perforated sections. To this purpose a generic 3D cell approach was developed and applied.