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Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

Detailed chemistry and turbulence-chemistry interaction need to be properly taken into account for a realistic combustion simulation of IC engines where advanced combustion modes, multiple injections and stratified combustion involve a wide range of combustion regimes and require a proper description of several phenomena such as auto-ignition, flame stabilization, diffusive combustion and lean premixed flame propagation. To this end, different approaches are applied and the most used ones rely on the well-stirred reactor or flamelet assumption. However, well-mixed models do not describe correctly flame structure, while unsteady flamelet models cannot easily predict premixed flame propagation and triple flames. A possible alternative for them is represented by transported probability density functions (PDF) methods, which have been applied widely and effectively for modeling turbulent reacting flows under a wide range of combustion regimes.

In the next years, the upcoming emission legislations are expected to introduce further restrictions on the admittable level of pollutants from vehicles measured on homologation cycles and real drive tests. In this context, the strict control of pollutant emissions at the cold start will become a crucial point to comply with the new regulation standards. This will necessarily require the implementation of novel strategies to speed-up the light-off of the reactions occurring in the after-treatment system, since the cold start conditions are the most critical one for cumulative emissions. Among the different possible technological solutions, this paper focuses on the evaluation of the potential of a burner system, which is activated before the engine start. The hypothetical burner exploits the lean combustion of an air-gasoline mixture to generate a high temperature gas stream which is directed to the catalyst section promoting a fast heating of the substrate.

Modeling combustion of transportation fuels remains a difficult task due to the extremely large number of species constituting commercial gasoline and diesel. However, for this purpose, multi-component surrogate fuel models with a reduced number of key species and dedicated reaction subsets can be used to reproduce the physical and chemical traits of diesel and gasoline, also allowing to perform CFD calculations. Recently, a detailed surrogate fuel kinetic model, named C3 mechanism, was developed by merging high-fidelity sub-mechanisms from different research groups, i.e. C0-C4 chemistry (NUI Galway), linear C6-C7 and iso-octane chemistry (Lawrence Livermore National Laboratory), and monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs) (ITV-RWTH Aachen and CRECK modelling Lab-Politecnico di Milano).

Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.

The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.

Pursuing a sustainable energy scenario for transportation requires the blending of renewable oxygenated fuels such as alcohols into commercial hydrocarbon fuels. From a chemical kinetic perspective, this requires the accurate description of both hydrocarbon reference fuels (n-heptane, iso-octane, toluene, etc.) and oxygenated fuels chemistry. A recent systematic investigation of linear C2-C5 alcohols ignition in a rapid compression machine at p = 10-30 bar and T = 650- 900 K has extended the scarcity of fundamental data at such conditions, allowing for a revision of the low temperature chemistry for alcohol fuels in the POLIMI mechanism. Heavier alcohols such as n-butanol and n-pentanol present ignition characteristic of interest for application in HCCI engines, due to the presence of the hydroxyl moiety reducing their low temperature reactivity compared to the parent linear alkanes (i.e. higher octane number).

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

A computational, three-dimensional approach to investigate the behavior of diesel soot particles in the micro-channels of wall-flow Diesel Particulate Filters is presented. The KIVA3V CFD code, already extended to solve the 2D conservation equations for porous media materials [1], has been enhanced to solve in 2-D and 3-D the governing equations for reacting and compressible flows through porous media in non axes-symmetric geometries. With respect to previous work [1], a different mathematical approach has been followed in the implementation of the numerical solver for porous media, in order to achieve a faster convergency as source terms were added to the governing equations. The Darcy pressure drop has been included in the Navier-Stokes equations and the energy equation has been extended to account for the thermal exchange between the gas flow and the porous wall.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

Iso-stoichiometric ternary blends - in which three-component blends of gasoline, ethanol and methanol are configured to the same stoichiometric air-fuel ratio as an equivalent binary ethanol-gasoline blend - can function as invisible "drop-in" fuels suitable for the existing E85/gasoline flex-fuel vehicle fleet. This has been demonstrated for the two principal means of detecting alcohol content in such vehicles, which are considered to be a virtual, or software-based, sensor, and a physical sensor in the fuel line. Furthermore when using such fuels the tailpipe CO₂ emissions are essentially identical to those found when the vehicle is operated on E85. Because of the fact that methanol can be made from a wider range of feed stocks than ethanol and at a cheaper price, these blends then provide opportunities to improve energy security, to reduce greenhouse gas emissions and to produce a fuel blend which could potentially be cheaper on a cost-per-unit-energy basis than gasoline or diesel.

Modeling plume interaction and collapse for direct-injection gasoline sprays is important because of its impact on fuel-air mixing and engine performance. Nevertheless, the aerodynamic interaction between plumes and the complicated two-phase coupling of the evaporating spray has shown to be notoriously difficult to predict. With the availability of high-speed (100 kHz) Particle Image Velocimetry (PIV) experimental data, we compare velocity field predictions between plumes to observe the full temporal evolution leading up to plume merging and complete spray collapse. The target “Spray G” operating conditions of the Engine Combustion Network (ECN) is the focus of the work, including parametric variations in ambient gas temperature. We apply both LES and RANS spray models in different CFD platforms, outlining features of the spray that are most critical to model in order to predict the correct aerodynamics and fuel-air mixing.

The engine of a high performance sports car has been converted to operation on E85, a high alcohol-blend fuel containing nominally 85% ethanol and 15% gasoline by volume. In addition to improving performance, the conversion resulted in significant improvement in full-load thermal efficiency versus operation on gasoline. This engine has been fitted in a test vehicle and made flex-fuel capable, a process which resulted in significant improvements in both vehicle performance and tailpipe CO2 when operating solely on ethanol blends, offering an environmentally-friendly approach to high performance motoring. The present paper describes some of the highlights of the development of the flex-fuel calibration to enable the demonstrator vehicle to operate on any mixture of 95 RON gasoline and E85 in the fuel tank. It also discusses how through detailed development, the vehicle has been made to comply with primary pollutant emissions legislation on any ethanol-gasoline mixture up to E85.

Concerns over energy security and global warming are beginning to be a serious issue for society and are also starting to drive customer purchasing decisions across many areas. Against this background there is an increasing call for motor sport to improve its environmental image, despite the fact that the global energy consumption and CO2 emissions attributable to motor sport are a very low proportion of the total. The real issue for motor sport in the face of the wider societal concerns is that, if it is truly at the cutting edge of relevant automotive engineering, it should be configured and managed in such a way as to drive technology for the betterment of mankind. The status quo is, it is contended, increasingly seen to be blatantly energy-profligate in the eyes of many people and this issue must be resolved if motor sport is to demonstrate the wider benefits of the technology developed by the huge financial investments committed to competing at the highest level.

Omnivore is a single cylinder spark ignition based research engine conceived to maximize the operating range of auto-ignition on a variety of fossil and renewable fuels. In order to maximize auto-ignition operation, the two-stroke cycle was adopted with two independent mechanisms for control. The charge trapping valve system is incorporated as a means of varying the quantity of trapped residuals whilst a variable compression ratio mechanism is included to give independent control over the end of compression temperature. The inclusion of these two technologies allows the benefits of trapped residual gas to be maximised (to minimize NOx formation) whilst permitting variation of the onset of auto-ignition. 2000rpm and idle are the main focus of concern whilst also observing the influence of injector location. This paper describes the rational behind the engine concept and presents the results achieved at the time of writing using 98ulg and E85 fuels.

The paper critiques proposals for de-carbonizing transport and offers a potential solution which may be attained by the gradual evolution of the current fleet of predominantly low-cost vehicles via the development of carbon-neutral liquid fuels. The closed-carbon cycles which are possible using such fuels offer the prospect of maintaining current levels of mobility with affordable transport whilst neutralizing the threat posed by the high predicted growth of greenhouse gas emissions from this sector. Approaches to de-carbonizing transport include electrification and the adoption of molecular hydrogen as an energy carrier. These two solutions result in very expensive vehicles for personal transport which mostly lie idle for 95% of their life time and are purchased with high-cost capital.

The purpose of the European « SPACE LIGHT » (Whole SPACE combustion for LIGHT duty diesel vehicles) 3-year project launched in 2001 is to research and develop an innovative Homogeneous internal mixture Charged Compression Ignition (HCCI) for passenger cars diesel engine where the combustion process can take place simultaneously in the whole SPACE of the combustion chamber while providing almost no NOx and particulates emissions. This paper presents the whole project with the main R&D tasks necessary to comply with the industrial and technical objectives of the project. The research approach adopted is briefly described. It is then followed by a detailed description of the most recent progress achieved during the tasks recently undertaken. The methodology adopted starts from the research study of the in-cylinder combustion specifications necessary to achieve HCCI combustion from experimental single cylinder engines testing in premixed charged conditions.

Controlled auto ignition (CAI) is a form of combustion which uses an auto-ignited homogeneous air/fuel mixture but is controlled (or moderated) by regulating the quantity of internal exhaust gas residuals. In this paper, using a fully variable valve train and a newly developed exhaust valve control strategy, we substituted EGR with hot nitrogen or hot air. We found that the internal exhaust gas residuals have both thermal and chemical effects on CAI combustion. To investigate the thermal effect, nitrogen was used as it is a chemically inert gas. Although its temperature was raised to that of the internal exhaust gas residuals during testing, CAI combustion could not be promoted without assistance from a spark in a form of hybrid CAI, thus indicating that exhaust gas residuals have a chemical effect as well.

Designers are under increasing pressure to provide powertrain systems which meet tougher market and legislative requirements for:- performance, emissions and economy reliability and durability noise and refinement To meet increasing competition, powertrain products need to be “fast to market and right first time”. This implies the evolution of existing technology, comprising multicylinder reciprocating engines and gear transmissions, drawing on a database of decades of powerplant design experience. It is with this background that CAE has proven engineering value supporting key areas of powertrain engineering to meet these technological challenges in a cost effective and timely manner. This paper follows the analytical engineering of a typical component, the exhaust system. Particular emphasis is given to the manifold and downpipe components which duct gas from the cylinder head to the catalyst.

The paper investigates the interaction between soil and tractor tires through a 2D numerical model. The tire is schematized as a rigid ring presenting a series of rigid tread bars on the external circumference. The outer profile of the tire is divided into a series of elements, each one able to exchange a normal and a tangential contact force with the ground. A 2D soil model was developed to compute the forces at the ground-tire interface: the normal force is determined on the basis of the compression of the soil generated by the sinking of the tire. The soil is modeled through a layer of springs characterized by two different stiffness for the loading (lower stiffness) and unloading (higher stiffness) condition. This scheme allows to introduce a memory effect on the soil which results stiffer and keeps a residual sinking after the passage of the tire. The normal contact force determines the maximum value of tangential force provided before the soil fails.