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An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Diesel particulate filters are designed to reduce the mass emissions of diesel particulate matter and have been proven to be effective in this respect. Not much is known, however, about their effects on other unregulated chemical species. This study utilized source dilution sampling techniques to evaluate the effects of a catalyzed diesel particulate filter on a wide spectrum of chemical emissions from a heavy-duty diesel engine. The species analyzed included both criteria and unregulated compounds such as particulate matter (PM), carbon monoxide (CO), hydrocarbons (HC), inorganic ions, trace metallic compounds, elemental and organic carbon (EC and OC), polycyclic aromatic hydrocarbons (PAHs), and other organic compounds. Results showed a significant reduction for the emissions of PM mass, CO, HC, metals, EC, OC, and PAHs.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

The effects of load, speed, exhaust gas recirculation (EGR) level and hydrogen addition level on the emissions from a diesel engine have been investigated. The experiments were performed on a 2.0 litre, 4 cylinder, direct injection engine with a high pressure common-rail injection system. Injection timing was varied between 14° BTDC and TDC and injection pressures were varied from 800 bar to 1400 bar to find a suitable base point. EGR levels were then varied from 0% to 40%. Hydrogen induction was varied between 0 and 6% vol. of the inlet charge. In the case of using hydrogen and EGR, the hydrogen replaced air. The load was varied from 0 to 5.4 bar BMEP at two engine speeds, 1500 rpm and 2500 rpm. For this investigation the carbon monoxide (CO), total unburnt hydrocarbons (THC), nitrogen oxides (NOx) and the filter smoke number (FSN) were all measured.

The application of controlled auto-ignition (CAI) combustion in gasoline direct injection (GDI) engines is becoming of more interest due to its great potential of reducing both NOx emissions and fuel consumption. Injection timing has been known as an important parameter to control CAI combustion process. In this paper, the effect of injection timing on mixture and CAI combustion is investigated in a single-cylinder GDI engine with an air-assisted injector. The liquid and vapour phases of fuel spray were measured using planar laser induced exciplex fluorescence (PLIEF) technique. The result shows that early injection led to homogeneous mixture but late injection resulted in serious stratification at the end of compression. CAI combustion in this study was realized by using short-duration camshafts and early closure of the exhaust valves. During tests, the engine speed was varied from 1200rpm to 2400rpm and A/F ratio from stoichiometric to lean limit.

About 50-90 percent of the hydrocarbons that escape combustion during flame passage in spark-ignition engine operation are oxidized in the cylinder before leaving the system. The process involves the transport of unreacted fuel from cold walls towards the hotter burned gas regions and subsequent reaction. In order to understand controlling factors in the process, a transient one-dimensional reactive-diffusive model has been formulated for simulating the oxidation processes taking place in the reactive layer between hot burned gases and cold unreacted air/fuel mixture, with initial and boundary conditions provided by the emergence of hydrocarbons from the piston top land crevice. Energy and species conservation equations are solved for the entire process, using a detailed chemical kinetic mechanism for propane.

Having achieved CAI-combustion in a 4-cylinder four-stroke gasoline DI engine the effects of ignition timing on the CAI combustion process were investigated through the introduction of spark. By varying the start of fuel injection, the effects on Indicated Specific values for NOx, HC, CO emissions and fuel consumption were investigated for CAI combustion. The CAI combustion process was then assisted by spark and three different ignition timings were studied. The effect on engine performance and the emission specific values were investigated further. The engine speed was maintained at 1500 rpm and lambda was kept constant at 1.2. It was found that with spark-assisted CAI, IMEP and ISNOx values increased as compared with typical CAI. ISHC values were lower for spark-assisted CAI as compared to typical CAI. Heat release data was studied to better understand this phenomenon.

Measurements were made of exhaust histories of the following species: unburned hydrocarbons (HC), carbon monoxide, carbon dioxide, oxygen, and nitric oxide (NO). The measurements show that the exhaust flow can be divided into two distinct phases: a leading gas low in HC and high in NO followed by a trailing gas high in HC and low in NO. Calculations of time resolved equivalence ratio throughout the exhaust process show no evidence of a stratified combustion. The exhaust mass flow rate is time resolved by forcing the flow to be locally quasi-steady at an orifice placed in the exhaust pipe. The results with the quasi-steady assumption are shown to be consistent with the measurements. Predictions are made of time resolved mass flow rate which compare favorably to the experimental data base. The composition and flow histories provide sufficient information to calculate the time resolved flow rates of the individual species measured.

The purpose of the 4-SPACE (4-Stroke Powered gasoline Auto-ignition Controlled combustion Engine) industrial research project is to research and develop an innovative controlled auto-ignition combustion process for lean burn automotive gasoline 4-stroke engines application. The engine concepts to be developed could have the potential to replace the existing stoichiometric / 3-way catalyst automotive spark ignition 4-stroke engines by offering the potential to meet the most stringent EURO 4 emissions limits in the year 2005 without requiring DeNOx catalyst technology. A reduction of fuel consumption and therefore of corresponding CO2 emissions of 15 to 20% in average urban conditions of use, is expected for the « 4-SPACE » lean burn 4-stroke engine with additional reduction of CO emissions.

Controlled Auto-Ignition (CAI), also known as Homogeneous Charge Compression Ignition (HCCI), has the potential to improve gasoline engines’ efficiency and simultaneously achieve ultra-low NOx emissions. Two of the primary obstacles for applying CAI combustion are the control of combustion phasing and the maximum heat release rate. To solve these problems, dimethyl ether (DME) was directly injected into the cylinder to generate multi-point micro-flame through compression in order to manage the entire heat release of gasoline in the cylinder through port fuel injection, which is known as micro-flame ignited (MFI) hybrid combustion.

Controlled Auto-Ignition (CAI), also known as Homogeneous Charge Compression Ignition (HCCI), can improve the fuel economy of gasoline engines and simultaneously achieve ultra-low NOx emissions. However, the difficulty in combustion phasing control and violent combustion at high loads limit the commercial application of CAI combustion. To overcome these problems, stratified mixture, which is rich around the central spark plug and lean around the cylinder wall, is formed through port fuel injection and direct injection of gasoline. In this condition, rich mixture is consumed by flame propagation after spark ignition, while the unburned lean mixture auto-ignites due to the increased in-cylinder temperature during flame propagation, i.e., stratified flame ignited (SFI) hybrid combustion.

U.S. and European nonroad diesel emissions regulations have led to the implementation of various exhaust aftertreatment solutions. One approved configuration, a vanadium-based selective catalytic reduction catalyst followed by an ammonia oxidation catalyst (V-SCR + AMOX), does not require the use of a diesel oxidation catalyst (DOC) or diesel particulate filter (DPF). While certification testing has shown the V-SCR + AMOX system to be capable of meeting the nitrogen oxides, carbon monoxide, and particulate matter requirements, open questions remain regarding the efficacy of this aftertreatment for volatile and nonvolatile organic emissions removal, especially since the removal of this class of compounds is generally attributed to both the DOC and DPF.

Internal combustion engines are subjected to part-load operation more than in full load during a typical vehicle driving cycle. The problem with the Spark Ignition (SI) engine is its inherent low part-load efficiency. This problem arises due to the pumping loses that occur when the throttle closes or partially opens. One way of decreasing the pumping losses is to operate the engine lean or by adding residual gases. It is not possible to operate the engine unthrottled at very low loads due to misfire. However, the load can also be controlled by changing the intake valve closing timing - either early or late intake valve closing. Both strategies reduce the pumping loses and hence increase the efficiency. However the early intake valve closure (EIVC) can be used as mode transition from SI to CAI combustion.