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This paper gives a thorough review of the HC/CO emissions challenge and discusses the effects of different diesel oxidation catalyst designs in a pre turbine and post turbine position on steady state and transient turbo charger performance as well as on HC and CO tailpipe emissions, fuel economy and performance of modern Diesel engines. Results from engine dynamometer testing are presented. Both classical diffusive and advanced premixed Diesel combustion modes are investigated to understand the various effects of possible future engine calibration strategies.

The Hydrogen-Balance equation makes it possible to calculate the fuel economy or fuel consumption of hydrogen powered vehicles simply by analyzing exhaust emissions. While the benefits of such a method are apparent, it is important to discuss possible influencing factors that may decrease Hydrogen-Balance accuracy. Measuring vehicle exhaust emissions is done with a CVS (Constant Volume Sampling) system. While the CVS system has proven itself both robust and precise over the years, utilizing it for hydrogen applications requires extra caution to retain measurement accuracy. Consideration should be given to all testing equipment, as well as the vehicle being tested. Certain environmental factors may also play a role not just in Hydrogen-Balance accuracy, but as also in other low emission testing accuracy.

The reduction of vehicle exhaust particle emissions is a success story of European legislation. Various particle number (PN) counters and calibration procedures serve as tools to enforce PN emission limits during vehicle type approval (VTA) or periodical technical inspection (PTI) of in-use vehicles. Although all devices and procedures apply to the same PN-metric, they were developed for different purposes, by different stakeholder groups and for different target costs and technical scopes. Furthermore, their calibration procedures were independently defined by different stakeholder communities. This frequently leads to comparability and interpretation issues. Systematic differences of stationary and mobile PN counters (PN-PEMS) are well-documented. New, low-cost PTI PN counters will aggravate this problem. Today, tools to directly compare different instruments are scarce.

State of the art technologies of 2 and 4 stroke engines have to fulfill severe future exhaust emission regulations, with special focus on the aspects of rising performance and low cost manufacturing, leading to an important challenge for the future. In special fields of applications (e.g. mopeds, hand held or off-road equipment) mainly engines with simple mixture preparation systems, partially without exhaust gas after treatment are used. The comparison of 2 and 4 stroke concepts equipped with different exhaust gas after treatment systems provides a decision support for applications in a broad field of small capacity engine classes.

Diesel engine emission regulations throughout the world have progressed over the last 20 years. In the U.S. the most stringent medium/heavy duty standard will be implemented for on highway vehicles starting in 2010. Although changes to engine design will improve engine out emissions, in order to meet both PM and NOx regulations, combination systems including PM and NOx aftertreatment, are planned to be utilized. In order to achieve the required regulations, a new substrate technology has been developed using advanced “turbulent” flow characteristics, and it has been combined with a novel approach to reduce system complexity: the “SCRi™” or “SCR integrated” system. Such a system uses a continuously operating PM-Metalit with advanced “turbulent” SCR-catalysts in a unique configuration. The reduction of both PM and NOx also has to be seen in context with its effect on CO2 emissions.

Although hydrogen ICE engines have existed in one sort or another for many years, the testing of fuel consumption by way of exhaust emissions is not yet a proven method. The current consumption method for gasoline- and diesel-fueled vehicles is called the Carbon-Balance method, and it works by testing the vehicle exhaust for all carbon-containing components. Through conservation of mass, the carbon that comes out as exhaust must have gone in as fuel. Just like the Carbon-Balance method for gas and diesel engines, the new Hydrogen-Balance equation works on the principle that what goes into the engine must come out as exhaust components. This allows for fuel consumption measurements without direct contact with the fuel. This means increased accuracy and simplicity. This new method requires some modifications to the testing procedures and CVS (Constant Volume Sampling) system.

Particulates in Diesel Exhaust Gas have become a major concern of Environment Protection Agencies in the recent years. The main focus was placed on the so called Nano Particles which are the most harmful to human beeings. OEMs for car, light and heavy commercial vehicle industries have been working on different technologies for a number of years to meet the stringent emission legislations. At the same time some countries have started schemes to retrofit older vehicles that are still on the road and greatly contribute to air pollution. The government of Korea took the worldwide lead and defined 3 categories of required PM reduction rates and incentives to LDV and HDV owners who are prepared to retrofit their vehicles.

Emission legislations for the light / medium and heavy duty vehicles are becoming more and more stringent worldwide. Tightening of NOx and Particulate Matter (PM) limits further from Euro III to Euro IV levels has provoked the need of either controlling NOx from the engine measures and use PM control after-treatment devices such as Partial Flow Filters, or, controlling PM from the engine measures and use NOx control devices such as Selective Catalytic Reduction (SCR) systems. Manufacturers have adopted different strategies, depending upon the suitability, cost factors, infrastructure development and ease of maintenance of these systems. PM Metalit®, is a partial flow filter, which captures particulates coming out of the exhaust and re-generates on a continuous basis with the help of Nitrogen Dioxide (NO2) in the exhaust.

The study of oil emission is of essential interest for the engine development of modern cars, as well as for the understanding of hydrocarbon emissions especially during cold start conditions. A laser mass spectrometer has been used to measure single aromatic hydrocarbons in unconditioned exhaust gas of a H2-fueled engine at stationary and transient motor operation. These compounds represent unburned oil constituents. The measurements were accompanied by FID and GC-FID measurements of hydrocarbons which represent the burned oil constituents. The total oil consumption has been determined by measuring the oil sampled by freezing and weighing. It has been concluded that only 10 % of the oil consumption via exhaust gas has burned in the cylinders. A correlation of the emission of single oil-based components at ppb level detected with the laser mass spectrometer to the total motor oil emission has been found.

Nearly all real Diesel engine operation is leading to low exhaust temperatures. Standard catalyst technique remains therefore for significant time below light off. To improve the conversion behavior two approaches were made: placement of tailor fitted catalysts as close as possible to the engine exhaust port before turbocharger and usage of close coupled catalysts with the so-called hybrid design. Both measures are providing visible progress in reducing Diesel engine emissions. Tests were made with modern Diesel engines both for passenger cars and heavy duty vehicles.

1 An experimental study has been carried out on a production vehicle by means of roller-bench emission tests in order to optimize alternative aftertreatment systems. To this aim different comparisons between the production exhaust system and new strategies are discussed in the present paper with aid of both modal emission data and bag tailpipe figures. The present work shows the application of a alternative solution that complies with future emission legislation with regard both to HC, CO, NOx and PM without any major engine power output or fuel consumption penalty.

Nearly all real diesel engines operations are leading to low exhaust temperatures. Standard catalyst technique remains therefore for significant time below light-off. To improve the conversion behavior two approaches were made: placement of tailor-fitted catalysts as close as possible to the engine exhaust port before turbocharger and usage of close coupled catalysts with the so-called hybrid design. Both measures are providing visible progress in reducing diesel engine emissions. Tests were made with modern diesel engines both for passenger cars and heavy-duty vehicles.

Soot filtration represents a major problem for the complete exploiting of Diesel engines characteristics in terms of global efficiency and CO2 emissions. Even though the engines development in the last years let the engine performances improve, exhaust gas after treatment is still required to respect the foreseen limits for soot and NOx emissions. A flow-through particle trap has been presented with a great potential in soot removal without major penalties in terms of exhaust back pressure. The device performance is strictly connected to channel geometry. This paper deals with that relation by means of an experimental-numerical approach.

Changing of emission levels leads to an increasing demand for a satisfying solution to measure mass emissions of motor vehicles on both, engine and chassis dynamometers. Partial flow systems may fit to the demands. These systems require an exact determination of exhaust volume flow and time aligned concentration measurement. This paper will address these issues and problems related with partial flow sampling. Several exhaust flow measurement systems have been studied and integrated mass results have been checked against the full flow CVS. As the investigations indicate, modal mass calculation from sampling direct exhaust at the end of tailpipe is feasible but not a satisfying solution in equivalency and repeatability in comparison to CVS-results. This is especially the case on emission levels near or below ULEV.

Metal based Diesel Particulate Filters (PM-TRAPs) could represent a short time solution to face with particulate (and NOx) emissions with a small influence on CO2 emission. In fact, the operation principle of the PM-TRAP, based on fluid dynamical behavior of exhaust flow in “ad hoc” shaped geometries, allows to separate the particle content of exhaust-gases but needs to be carefully assessed to optimize filter performances. In this paper a mixed numerical and experimental procedure has been developed; it allows to finely tune the design parameters which can be used to achieve pre-defined targets in terms of particulate matter and fuel consumption. By adopting the previously declared procedure, a PM-TRAP “optimal” geometry has been chosen. Its performance has been verified with respect to experimental data. Results are encouraging and suggest further development of the system.

In order to achieve ultra low emission levels with three-way catalysts, an early accurate air/fuel ratio control is essential. Positioning the oxygen sensor in the first part of the substrate helps to protect the oxygen sensor from being splashed by water during cold start, so that early heating and activation becomes a less limiting factor. For emission control purpose, a position of a rear sensor in the warm part of the catalyst gives improved possibilities for oxygen buffer control during catalyst warming up conditions. This enhances balancing HC and NOx in an early phase. In addition, for OBD reasons it is possible to locate the sensor in any axial position in the catalyst, which improves design possibilities for cold start detection, even for single brick catalyst systems. The paper describes the construction of the catalyst with an integrated oxygen sensor.

Flame Ionization Detectors (FID) can be used to detect organic hydrocarbons that occur in plastics, lacquers, adhesives, solvents and gasoline. These substances are ionized in the hydrogen flame of the FID. The ionization current that is produced depends on the amount of hydrocarbon in the sample. With the lowering of emissions limits, measuring instruments, including the FID, have to be able to detect very low values. For SULEV (Super-Ultra Low Emissions Vehicle) measurements the accuracy and also the general applicability of the CVS (Constant Volume Sampling) measuring technique are now questioned. Basic understanding is necessary to ask the right questions. One important issue is the science behind the measurement principle of the FID. And in this case especially the influence of contamination of the operating gases, cross sensitivity and data processing on the Limit of Detection (LOD).

On one hand, latest worldwide emissions legislation developments aim to reduce NOx and Particulate Matter (PM) emissions of all diesel engines, while on the other hand lower fuel consumption diesel engines are still required for lower fleet average CO₂ emissions. As a consequence of the chosen CO₂ optimized combustion mode, the raw NOx emission increases and as such Selective Catalytic Reduction (SCR) technology will be the future choice for high efficiency NOx aftertreatment. This paper deals with SCR technology and its derivative SCRi® technology, when diesel particle reduction is required, especially for heavy-duty applications. Alongside the developed metal catalyst technologies, a complete SCR reducing agent dosing system is presented. Emission results gained with the SCR or SCRi® technologies on European commercial engines illustrate the potential of these technologies for conversion of NOx and PM emissions.

The clear objective of future powertrain development is strongly characterized by lowest emission impact and minimum overall system cost penalty to the customer. In the past decades emission impact has been primarily related to both optimization of combustion process and exhaust after-treatment system efficiency. Nowadays, weight reduction is one of the main objectives for vehicular applications, considering the related improvements both in fuel consumption (i.e. CO2 production) and engine-out emissions. The state of the art of catalytic converter systems for automotive ZEV-oriented applications has yet to be introduces into mass production. This paper investigates the successful application o metallic turbulent structures for catalytic converters along with innovative packaging considerations, such as structured outer mantle, which lead to significant weight reductions, exhaust backpressure minimization and improved overall emission conversion efficiency.

More efficient and durable catalytic converters for the two- and three-wheeler industry in developing countries are required at an affordable cost to reduce vehicle emissions, to maintain them at a low level and therefore to participate in a cleaner and healthier environment. This particularly is true nowadays, because the demand and prices of Platinum Group Metal (PGM) for catalyst are continuously increasing due to i) the worldwide progressive implementation of motorcycles emission legislations similar to Euro 3 Stage requiring catalysts, ii) the need for non-road diesel vehicles to be equipped now with catalyst systems, and iii) the constant increase of the worldwide automobile market. A new generation of metallic substrates with structured foils for catalytic converters is proven to be capable of improving conversion behavior, even with smaller catalyst size.