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A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Magnesium and aluminum alloys offer lightweighting opportunities in automotive applications. Joining of dissimilar materials, however, generally requires methods that do not involve fusion. This paper explores the use of self-pierce riveting (SPR) to join magnesium to aluminum alloys for structural and closure applications. The preliminary results indicate that SPR is a viable option for joining aluminum extrusions to magnesium die castings, as well as stamped sheet aluminum to quick-plastic-formed (QPF) sheet magnesium.

Experimental decklids for the Cadillac STS sedan were made with Al AA5083 sheet outer panels and Mg AZ31B sheet inner panels using regular-production forming processes and hardware. Joining and coating processes were developed to accommodate the unique properties of Mg. Assembled decklids were evaluated for dimensional accuracy, slam durability, and impact response. The assemblies performed very well in these tests. Explicit and implicit finite element simulations of decklids were conducted, and showed that the Al/Mg decklids have good stiffness and strength characteristics. These results suggest the feasibility of using Mg sheet closure panels from a structural perspective.

Organic acid degradation products and other anions in engine oil were speciated by capillary electrophoresis (CE) and liquid chromatography-mass spectrometry (LCMS) with electrospray ionization. The sample preparation procedure involved selectively extracting the acids and other water soluble salts into 0.05M aqueous potassium hydroxide. Samples of engine-aged mineral oil and synthetic engine oil contained formic acid, acetic acid, and complex mixtures of fatty acid degradation products. CE analysis of formic acid, acetic acid and selected fatty acids is proposed as a new chemical analysis method for evaluating the condition of engine oil and for studying the effects of high temperature-high load (HTHL) oxidation. Because the overall pattern of CE peaks in the electropherogram changes with oil age or condition, CE-fingerprint (i.e., pattern recognition) techniques may also be useful for evaluating an aged oil's condition or remaining service life.

One of the issues in stamping of advanced high strength steels (AHSS) is the stretch bending fracture on a sharp radius (commonly referred to as shear fracture). Shear fracture typically occurs at a strain level below the conventional forming limit curve (FLC). Therefore it is difficult to predict in computer simulations using the FLC as the failure criterion. A modified Mohr-Coulomb (M-C) fracture criterion has been developed to predict shear fracture. The model parameters for several AHSS have been calibrated using various tests including the butter-fly shaped shear test. In this paper, validation simulations are conducted using the modified (M-C) fracture criterion for a dual phase (DP) 780 steel to predict fracture in the stretch forming simulator (SFS) test and the bending under tension (BUT) test. Various deformation fracture modes are analyzed, and the range of usability of the criterion is identified.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

This article is concerned with identification of true stress-strain curve under biaxial tension of thermoplastic polymers. A new type of biaxial tension attachment was embedded first in a universal material test machine, which is able to transform unidirectional loading of the test machine to biaxial loading on the specimen with constant velocity. Cruciform specimen geometry was optimized via FE modeling. Three methods of calculating true stress in biaxial tension tests were compared, based on incompressibility assumption, linear elastic theory and inverse engineering method, respectively. The inverse engineering method is more appropriate for thermoplastic polymers since it considers the practical volume change of the material during biaxial tension deformation. The strategy of data processing was established to obtain biaxial tension true stress-strain curves of different thermoplastic polymers.

This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.

A new ring pack model has been developed based on the curved beam finite element method. This paper describes the first part of this model: simulating gas pressure in different regions above piston skirt and ring dynamic behavior of two compression rings and a twin-land oil control ring. The model allows separate grid divisions to resolve ring structure dynamics, local force/pressure generation, and gas pressure distribution. Doing so enables the model to capture both global and local processes at their proper length scales. The effects of bore distortion, piston secondary motion, and groove distortion are considered. Gas flows, gas pressure distribution in the ring pack, and ring structural dynamics are coupled with ring-groove and ring-liner interactions, and an implicit scheme is employed to ensure numerical stability. The model is applied to a passenger car engine to demonstrate its ability to predict global and local effects on ring dynamics and oil transport.

Cast aluminum alloys are increasingly used in cyclically loaded automotive structural applications for light weight and fuel economy. The fatigue resistance of aluminum castings strongly depends upon the presence of casting flaws and characteristics of microstructural constituents. The existence of casting flaws significantly reduces fatigue crack initiation life. In the absence of casting flaws, however, crack initiation occurs at the fatigue-sensitive microstructural constituents. Cracking and debonding of large silicon (Si) and Fe-rich intermetallic particles and crystallographic shearing from persistent slip bands in the aluminum matrix play an important role in crack initiation. This paper presents fatigue life models for aluminum castings free of casting flaws, which complement the fatigue life models for aluminum castings containing casting flaws published in [1].

There is an increasing demand in automated manufacturability analysis of metal castings at the initial stages of their design. This paper presents a system developed for virtual manufacturability analysis of casting components. The system can be used by a casting designer to evaluate manufacturability of a part designed for various manufacture processes including casting, heat treatment, and machining. The system uses computational geometrics and geometric reasoning to extract manufacturing features and geometry characteristics from a part CAD model. It uses an expert system and a design database consisting of metal casting, heat treatment and machining process knowledge and rules to present manufacturability analysis results and advice to the designer. Application of the system is demonstrated for the manufacturability assessment of automotive cast aluminum components.

During sheet metal forming, the friction and surface roughness change as the sheet slides, bends and stretches against the tools. This study assessed evolution of friction and surface roughness changes on aluminum sheet with two surface finish conditions, mill finish (MF) and electron discharge texture (EDT), in both the longitudinal and the transverse rolling directions of the sheet. The sheets were tested using a three pin Draw Bead Simulator (DBS). Surface roughness of the sheet evolved as a result of bending at the first shoulder, reverse bending at the middle pin, bending at the second shoulder and unbending at the exit. Stretching conditions and sheet-pin contact were also varied to see the impact on surface roughness. In general, the largest surface roughness change for the transverse direction was observed at the convex side of the exit shoulder pin and on the convex side of the first shoulder for the longitudinal direction.

Aluminum sheet is commercially available in three surface finishes, mill finish (MF), electric discharge texture (EDT), and dull finish (DF). This surface finish impacts the friction behavior during sheet metal forming. A study was done to compare ten commercially available sheet samples from several suppliers. The friction behavior was characterized in the longitudinal and transverse directions using a Draw Bead Simulator (DBS) test, resulting in a coefficient of friction (COF) value for each material. Characterization of the friction behavior in each direction provides useful data for formability analysis. To quantitatively characterize the surface finish, three-dimensional MicroTexture measurements were done with a WYKO NT8000 instrument. In general, the MF samples have the smoothest surface, with Sa values of 0.20-0.30 μm and the lowest COF values. The EDT samples have the roughest surface, with Sa values of 0.60-1.00 μm, and the highest COF values.

The preform annealing process is a two-stage stamping method for shaping non age-hardenable (i.e. 5000 series) aluminum sheet panels in which the panel is heat treated in between the two steps to improve overall formability of the material. The intermediate annealing heat treatment eliminates the cold work accumulated in the material during the first draw. The process enables the ability to form more complex parts than a conventional aluminum stamping process. A demonstration of local annealing for this process was conducted to form a one-piece aluminum liftgate inner panel for a large sport utility vehicle using the steel product geometry without design concessions. In prior work, this process was demonstrated by placing the entire panel in a convection oven for several minutes to completely anneal the cold work.

Cast aluminum alloys are normally quenched after solution treatment or solidification process to improve aging responses. Rapid quenching can lead to high residual stress and severe distortion which significantly affects dimension stability, functionality and particularly performance of the product. To simulate residual stress and distortion induced during quenching, a finite element based approach was developed by coupling an iterative zone-based transient heat transfer algorithm with material thermo-viscoplastic constitutive model. With the integrated models, the numeric predictions of residual stresses and distortion in the quenched aluminum castings are in a good agreement with experimental measurements.

It is important to understand the accuracy level of the formability analysis for any new process so that correct predictions can be made in product and die design. This report focuses on the formability analysis methodology developed for the preform anneal process. In this process, the aluminum panel is partially formed, annealed to eliminate the cold work from the first step, and then formed to the final shape using the same die. This process has the ability to form more complex parts than conventional aluminum stamping, and has been demonstrated on a complex one-piece door inner and a complex one-piece liftgate inner with AA5182-O3. Both panels only required slight design modifications to the original steel product geometry. This report focuses on the formability analysis correlation with physical panels for the liftgate inner, considering both full panel anneal in a convection oven and local annealing of critical areas.

In recent years, there has been a sustained effort by the automotive OEMs and suppliers to improve the vehicle driveline efficiency. This has been in response to customer demands for greater vehicle fuel economy and increasingly stringent government regulations. The automotive rear axle is one of the major sources of power loss in the driveline, and hence represents an area where power loss improvements can have a significant impact on overall vehicle fuel economy. Both the friction induced mechanical losses and the spin losses vary significantly with the operating temperature of the lubricant. Also, the preloads in the bearings can vary due to temperature fluctuations. The temperatures of the lubricant, the gear tooth contacting surfaces, and the bearing contact surfaces are critical to the overall axle performance in terms of power losses, fatigue life, and wear.

To investigate the effect of aeration on fluid-elastomer compatibility, 4 types of elastomers were aged in three gear lubes. The four types of elastomers include a production fluorinated rubber (FKM) and production hydrogenated nitrile rubber (HNBR) mixed by the part fabricator, a standard low temperature flexible fluorinated rubber (FKM, ES-4) and a standard ethylene-acrylic copolymer (AEM, ES-7) mixed by SAE J2643 approved rubber mixer. The three gear lubes are Fluid a, Fluid b and Fluid c, where Fluid b is a modified Fluid with additional friction modifier, and Fluid c is friction modified chemistry from a different additive supplier. The aeration effect tests were performed at 125°C for 504 hours. The aerated fluid aging test was performed by introducing air into fluid aging tubes as described in General Motors Company Materials Specification GMW16445, Appendix B, side-by-side with a standard ASTM D471 test.

This article reports on the potential of negative valve overlap (NVO) for improving the net indicated thermal efficiency (η NIMEP) of gasoline engines during part load. Three fixed fuel flow rates, resulting in indicated mean effective pressures of up to 6 bar, were investigated. At low load, NVO significantly reduces the pumping loses during the gas exchange loop, achieving up to 7% improvement in indicated efficiency compared to the baseline. Similar efficiency improvements are achieved by positive valve overlap (PVO), with the disadvantage of worse combustion stability from a higher residual gas fraction (xr). As the load increases, achieving the wide-open throttle limit, the benefits of NVO for reducing the pumping losses diminish, while the blowdown losses from early exhaust valve opening (EVO) increase.