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High-strength aluminum alloys such as 7075 can be formed using advanced manufacturing methods such as hot stamping. Hot stamping utilizes an elevated temperature blank and the high pressure stamping contact of the forming die to simultaneously quench and form the sheet. However, changes in the thermal history induced by hot stamping may increase this alloy’s stress corrosion cracking (SCC) susceptibility, a common corrosion concern of 7000 series alloys. This work applied the breaking load method for SCC evaluation of hot stamped AA7075-T6 B-pillar panels that had been artificially aged by two different artificial aging practices (one-step and two-step). The breaking load strength of the specimens provided quantitative data that was used to compare the effects of tensile load, duration, alloy, and heat treatment on SCC behavior.

A task group within the SAE Automotive Corrosion and Protection (ACAP) Committee continues to pursue the goal of establishing a standard test method for in-laboratory cosmetic corrosion evaluations of finished aluminum auto body panels. The program is a cooperative effort with OEM, supplier, and consultant participation and is supported in part by USAMP (AMD 309) and the U.S. Department of Energy. Numerous laboratory corrosion test environments have been used to evaluate the performance of painted aluminum closure panels, but correlations between laboratory test results and in-service performance have not been established. The primary objective of this project is to identify an accelerated laboratory test method that correlates with in-service performance. In this paper the type, extent, and chemical nature of cosmetic corrosion observed in the on-vehicle exposures are compared with those from some of the commonly used laboratory tests

Since 2000, an Aluminum Cosmetic Corrosion task group within the SAE Automotive Corrosion and Protection (ACAP) Committee has existed. The task group has pursued the goal of establishing a standard test method for in-laboratory cosmetic corrosion evaluations of finished aluminum auto body panels. A cooperative program uniting OEM, supplier, and consultants has been created and has been supported in part by USAMP (AMD 309) and the U.S. Department of Energy. Prior to this committee's formation, numerous laboratory corrosion test environments have been used to evaluate the performance of painted aluminum closure panels. However, correlations between these laboratory test results and in-service performance have not been established. Thus, the primary objective of this task group's project was to identify an accelerated laboratory test method that correlates well with in-service performance.

There is an increasing global realization about the need for fuel efficient vehicles. An inexpensive way to accomplish this is through mass reduction, and one of the most effective ways that this can occur is through substituting current materials with magnesium, the lightest structural metal. This document describes the results of a U.S. Automotive Materials Partnership (USAMP) sponsored study [1] that examines why magnesium use has only grown 10% per year and identifies how to promote more widespread commercial applications beyond the 5-6 kg of component currently in vehicles. The issues and concerns which have limited magnesium use are discussed via a series of research and development themes. These address concerns associated with corrosion, fastening, and minimal metalworking/non-traditional casting processing. The automotive and magnesium supplier industries have only a limited ability to develop implementation-ready magnesium components.

The effects of lubricant on lap shear strength of Spot Friction Welded (SFW) joints made of 6111-T4 alloys were studied. Taguchi L8 design of experiment methodology was used to determine the lubricant effects. The results showed that the lap shear strength increased by 9.9% when the lubricant was present at the top surface compared to that of the baseline (no lubricant) whereas the lap shear strength reduced by 10.2% and 10.9% when the lubricant was present in the middle and at the bottom surfaces compared to that of the baseline (no lubricant), respectively. The microstructure analysis showed a zigzag interface at the joint between the upper and the lower sheet metal for the baseline specimen, the specimens with the lubricant at the top and at the bottom. However, a straight line interface is exhibited at the joint between the upper and the lower sheet for the specimen with the lubricant in the middle. The weld nugget sizes of the lap shear tested specimens were measured.

The equipment for collecting dilute exhaust samples involves the use of bag materials (i.e., Tedlar®) that emit hydrocarbons that contaminate samples. This study identifies a list of materials and treatments to produce bags that reduce contamination. Based on the average emission rates, baked Tedlar®, Capran® treated with alumina deposition, supercritical CO2 extracted Kynar® and supercritical CO2 extracted Teflon NXT are capable of achieving the target hydrocarbon emission rate of less than 15 ppbC per 30 minutes. CO2 permeation tests were also performed. Tedlar, Capran, Kynar and Teflon NXT showed comparable average permeation rates. Based on the criteria of HC emission performance, changes in measured CO2 concentration, ease of sealing, and ease of surface treatment, none of the four materials could be distinguished from one another.

The International Lubricant Standardization and Approval Committee (ILSAC) ATF subcommittee members have compared the two oxidation bench test methods, Aluminum Beaker Oxidation Test (ABOT) and Indiana Stirring Oxidation Stability Test (ISOT), using a number of factory-fill and service-fill ATFs obtained in Japan and in the US. In many cases, the ATFs were more severely oxidized after the ABOT procedure than after the same duration of the ISOT procedure. The relative severity of these two tests was influenced by the composition of the ATFs. The bench test oxidation data were compared with the transmission and the vehicle oxidation test data.

Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. In a previous study, we used a variety of pure liquid hydrocarbon fuels to examine the influence of fuel volatility and structure on the HC emissions due to piston wetting. It was shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs. All of these prior tests of fuel effects were performed at a single operating condition: the Ford World Wide Mapping Point (WWMP). In the present study, the effects of load and engine speed are examined.

The history behind Polymer Class “A” Body Panels for automotive applications is very interesting. The driving factors behind these applications have not changed significantly over the past sixty years. Foremost among these factors is the need for corrosion and dent resistance. Beginning with Saturn in 1990, interest in polymer body panels grew and continues to grow up to the present day, with every new global application. Today, consumers and economic factors drive the industry trend towards plastic body panels. These include increased customization and fuel economy on the consumer side. Economic factors such as lower unit build quantities, reduced vehicle mass, investment cost, and tooling lead times influence material choice for industry. The highest possible performance, and fuel economy, at the lowest price have always been a goal.

Residual stresses in metals are caused by a number of processes such as inhomogeneous deformation, phase changes and temperature gradients. This investigation focuses on the residual stresses caused by plastic deformation of automotive metals. Such stresses are responsible for part springback and shape distortion in many manufacturing and assembly processes. Tensile residual stresses may lead to stress cracking and, in some alloys, to stress corrosion cracking which may ultimately lead to premature product failure. The residual stress potential of metals can be evaluated by using the Split Ring Test Method. The test can be used to evaluate the effect of materials on residual stresses in cup drawing. Drawn cups are used because they produce large amounts of residual stresses and, therefore, increase measurement accuracy and reduce experimental error. A closed form analytical solution is used to estimate residual stresses in split rings taken from sections cut from the drawn cups.

The relationship between engine oil formulations and catalyst performance was investigated by comparatively testing five engine oils. In addition to one baseline production oil with a calcium plus magnesium detergent system, the remaining four oils were specifically formulated with different additive combinations including: one worst case with no detergent and production level zinc dialkyldithiophosphate (ZDTP), one with calcium-only detergent and two best cases with zero phosphorus. Emissions performance, phosphorus loss from the engine oil, phosphorus-capture on the catalyst and engine wear were evaluated after accumulating 100,000 miles of taxi service in twenty vehicles. The intent of this comparative study was to identify relative trends.

The Automotive Aluminum Alliance in conjunction with SAE ACAP founded a corrosion task group in 2000 with a goal to establish an in-laboratory cosmetic corrosion test for finished aluminum auto body panels, which provides a good correlation with in-service performance. Development of this test involves a number of key steps that include: (1) Establishing a reservoir of standard test materials to provide a well-defined and consistent frame of reference for comparing test results; (2) Defining a real-world performance for the reference materials through on-vehicle tests conducted in the U.S. and Canada; (3) Evaluating existing laboratory, proving ground, and outdoor tests; (4) Conducting statistically designed experiments to evaluate the effects of cyclic-test variables; (5) Comparing corrosion mechanisms of laboratory and on-vehicle tests; and (6) Conducting a round robin test program to determine the precision of the new test. Several of these key steps have been accomplished.

General corrosion protection of sheet materials such as steel used in automobile construction has reached a high level of performance, due primarily to the incorporation of mill-applied treatments such as electrogalvanizing, galvannealing and other coil-coating processes developed over the last half century. While such treatments have greatly extended the corrosion resistance of steel and its various body constructs, attention is now focused on aspects of the manufacturing process wherein these intended protections are compromised by such features as weldments, joins, cut edges and extreme metal deformations such as hems. A novel metal deposition process, based on high-velocity impact fusion of solid metal particles, has been used to extend the corrosion resistance of base steel and pre-galvanized sheet, by selectively placing highly controlled depositions of zinc and other sacrificial materials in close proximity to critical manufacturing details.

An obliquely incident X-ray radiography was developed to measure the greatest depths, orientations and locations of corrosion pits in automobile metallic plates. This technique can also be used on-site for components in use. The corrosion depth profile and the greatest depth can be calculated with the established relations. A 3-D rotational microscope and surface profiler were utilized to evaluate the sensitivities and accuracies of the technique for aluminum and steel plates, respectively.

A simple and rapid immersion type corrosion test has been successfully developed that discriminates corrosion performance in condensers from various suppliers and with differing manufacturing processes. The goal is to develop a test specification that will be included in the Ford corrosion specification for condensers so that condensers received from various suppliers may be evaluated rapidly for their relative corrosion performance to each other. Sections from condensers from Supplier A (tube is silfluxed), Supplier B (tube is zinc arc sprayed), and Supplier C (bare folded tube with no zinc for corrosion protection) were tested in 2% v/v hydrochloric acid for 16, 24 and 48 hours. The results showed that in terms of corrosion performance, zinc arc sprayed Supplier B condenser performed the worst while Supplier C condenser performed the best with Supplier A in between. It was also observed that the fins, and fin-to-tube joints were first to corrode followed by the tube in all cases.

Corrosion failures of aluminum air conditioner evaporator cores have been reported in regions where the climate is relatively warm and humid. Microbiologically-influenced corrosion [MIC] has been implicated in these failures. Application of surface-treatment chemicals may inhibit microbiological (bacterial) growth and/or attachment, thereby reducing the potential for MIC. In this study, two laboratory methods were developed to evaluate selected surface-treatment chemicals for their ability to inhibit bacterial growth and reduce bacterial attachment to treated surfaces. Using the developed methods, two controlled-atmosphere brazed aluminum core materials and three surface-treatment chemicals were evaluated. Neither of the untreated core materials was found to inhibit the growth of the bacteria tested.

A number of metallic oxidation catalyst substrates with advanced internal structures have emerged in the past few years. In an aftertreatment application, these structures improve gas mixing by increasing turbulence within the substrate's matrix. Modeling results show these advanced structures, under some operating conditions, can be correlated to reductions in catalyst substrate volume and precious metal 1,2. Three structured metallics were compared to a baseline ceramic substrate in a designed experiment to understand the effect of advanced metallic substrates on diesel oxidation catalyst (DOC) sizing and performance. The results showed that smaller metallic DOCs coated with up to 30% less precious metal (PM) catalyst performed on par or better than the baseline ceramic DOC in terms of hydrocarbon conversion, heat-up, and pressure drop.

There is an ongoing effort in the industry to develop an accelerated corrosion test for automotive heat exchangers. This has become even more important as automakers are focusing on corrosion durability of 15 years in the field versus current target of 10 years. To this end an acid immersion test was developed and reported in a previous paper for condensers (1). This paper extends those results to evaporators and establishes the efficacy of the test using these results and those reported in the literature. The paper also discusses variability in corrosion test results as observed in tests such as ASTM G85:A3 Acidified Synthetic Sea Water Test (SWAAT), and its relation to field durability.

As automobile power needs increase 42-volt electrical systems are being proposed for use in consumer vehicles. One concern when using these new systems is the corrosion resistance of these components, especially in underhood environments. Corrosion is an electrochemical phenomenon and as such can be altered (increased or decreased) by the application of an external current or voltage. Although unintentional, the use of a higher voltage electrical system has the ability to increase corrosion through its normal use. This program evaluated the impact of corrosion on electrical components powered by 14 and 42-volt DC systems. Accelerated corrosion test findings suggested that 42-volt systems may be more susceptible to corrosion, but without proper environmental shielding both supply system can have unacceptable degradation.

This paper presents a comparison of aqueous corrosion rates in 5% NaCl solution for eight experimental creep-resistant magnesium alloys considered for automotive powertrain applications, as well as three reference alloys (pure magnesium, AM50B and AZ91D). The corrosion rates were measured using the techniques of titration, weight loss, hydrogen evolution, and DC polarization. The corrosion rates measured by these techniques are compared with each other as well as with those obtained with salt-spray testing using ASTM B117. The advantages and disadvantages of the various corrosion measurement techniques are discussed.