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The standard procedure for determining non-methane hydrocarbon (NMHC) emissions is to subtract measured methane emissions from total hydrocarbon emissions measured by flame ionization detector. The results of this method were compared to the results of direct GC speciation of hydrocarbon emissions. For gasoline vehicles using an all-hydrocarbon fuel, the two methods demonstrate nearly perfect correlation, with a linear regression coefficient near 1.0, and R2 = 0.999. The correlation using reformulated gasoline is only slightly worse. For natural gas vehicles, however, the correlation was poor, with R2 < 0.30. This poor correlation is attributed to the high methane content of natural gas, which results in NMHC emissions being very low compared to the level of methane. Both the total hydrocarbon and methane measurements contain some error, and the resulting combined error in the NMHC concentration is of the same order as the concentration itself.

Non-petroleum based liquid fuels are essential for reducing oil dependence and greenhouse gas generation. Increased substitution of alcohol fuel for petroleum based fuels could be achieved by 1) use in high efficiency spark ignition engines that are employed for heavy duty as well as light duty operation and 2) use of methanol as well as ethanol. Methanol is the liquid fuel that is most efficiently produced from thermo-chemical gasification of coal, natural gas, waste or biomass. Ethanol can also be produced by this process but at lower efficiency and higher cost. Coal derived methanol is in limited initial use as a transportation fuel in China. Methanol could potentially be produced from natural gas at an economically competitive fuel costs, and with essentially the same greenhouse gas impact as gasoline. Waste derived methanol could also be an affordable low carbon fuel.

The transportation sector in the United States is a major contributor to global energy consumption and carbon dioxide emission. To assess the future potentials of different technologies in addressing these two issues, we used a family of simulation programs to predict fuel consumption for passenger cars in 2020. The selected technology combinations that have good market potential and could be in mass production include: advanced gasoline and diesel internal combustion engine vehicles with automatically-shifting clutched transmissions, gasoline, diesel, and compressed natural gas hybrid electric vehicles with continuously variable transmissions, direct hydrogen, gasoline and methanol reformer fuel cell hybrid electric vehicles with direct ratio drive, and battery electric vehicle with direct ratio drive.

Long-haul and other heavy-duty trucks, presently almost entirely powered by diesel fuel, face challenges meeting worldwide needs for greatly reducing nitrogen oxide (NOx) emissions. Dual-fuel gasoline-alcohol engines could potentially provide a means to cost-effectively meet this need at large scale in the relatively near term. They could also provide reductions in greenhouse gas emissions. These spark ignition (SI) flexible fuel engines can provide operation over a wide fuel range from mainly gasoline use to 100% alcohol use. The alcohol can be ethanol or methanol. Use of stoichiometric operation and a three-way catalytic converter can reduce NOx by around 90% relative to emissions from diesel engines with state of the art exhaust treatment.

Natural gas vehicle (NGV) fuel energy storage density is a key issue, particularly in many heavy-duty applications where compressed natural gas may have unattractively low energy density. For these uses, benefits can be derived by using liquefied natural gas (LNG). From a market perspective, LNG can play a role for transportation because it is available in various areas of the United States and throughout the world. This paper provides a general overview of LNG use for vehicles and specifically an analysis of factors governing the behavior of this cryogenic fluid in a confined vessel. This is intended to provide an understanding of the cause/effect relation between LNG fuel composition, tank heat influx, and rate of fuel usage or storage time.

Methane emissions from lean-burn natural gas engines can be relatively high. As natural gas fueled vehicles become more prevalent, future regulations may restrict these emissions. Preliminary reports indicated that conventional, precious metal oxidation catalysts rapidly deactivate (in less than 50 hours) in lean-burn natural gas engine exhaust. This investigation is directed at quantifying this catalyst deactivation and understanding its cause. The results may also be relevant to oxidation of lean-burn propane and gasoline engine exhaust. A platinum/palladium on alumina catalyst and a palladium on alumina catalyst were aged in the exhaust of a lean-burn natural gas engine (Cummins B5.9G). The engine was fueled with compressed natural gas. Catalyst aging was accomplished through a series of steady state cycles and heavy-duty transient tests (CFR 40 Part 86 Subpart N) lasting 10 hours. Hydrocarbons in the exhaust were speciated by gas chromatography.

Natural gas presents several challenges to engine manufacturers for use as a heavy-duty, lean burn engine fuel. This is because natural gas can vary in composition and the variation is large enough to produce significant changes in the stoichiometry of the fuel and its octane number. Similarly, operation at high altitude can present challenges. The most significant effect of altitude is lower barometric pressure, typically 630 mm Hg at 1600 m compared to a sea level value of 760 mm. This can lower turbocharger boost at low speeds leading to mixtures richer than desired. The purpose of this test program was to determine the effect of natural gas composition and altitude on regulated emissions and performance of a Cummins B5.9G engine. The engine is a lean-burn, closed loop control, spark ignited, dedicated natural gas engine. For fuel composition testing the engine was operating at approximately 1600 m (5,280 ft) above sea level.

Valve wear has been identified as a major durability problem in natural gas fueled reciprocating engines. Over the years, progress has been made to alleviate this problem through improved valve design and materials development. Recently high performance ceramics have shown promise for wear component applications. This paper presents the results of a valve train component materials investigation supported by the Gas Research institute. Testing tools and methods are described. The testing program culminated in a 300 hour component test in a full size turbocharged natural gas engine. Results of the engine test appeared to confirm preceding laboratory tests. Sintered silicon nitride valve seat inserts and Stellite 6 coated 21-12 stainless steel valves appeared to be the most promising material combination evaluated.

Studies have been published which address fast filling of Natural Gas Vehicle (NGV) fuel containers. Diggins states that NGV fuel containers cannot be fully filled during a fast fill, and that all-composite fuel containers cannot be filled as full as other types of fuel containers. There are issues in this prior work which may have a significant effect on the author’s conclusions. Fast fill testing conducted by Powertech Labs shows the Lincoln Composites’ fuel container has significantly better fill performance than projected by Diggins. Testing of a dispenser control system by Kountz and Blazek demonstrates all types of fuel containers can be properly filled with proper dispenser control algorithms and performance.

The objective of the work described here is to test the performance of closed-loop controlled, heavy-duty CNG engines in-use, on fuels of different methane content; and to compare their performance with similar diesel vehicles. Performance is measured in terms of pollutant emissions, fuel economy, and driveability. To achieve this objective, three buses powered by closed-loop controlled, dedicated natural gas engines were tested on the heavy-duty chassis dynamometer facility at the Colorado Institute for Fuels and High Altitude Engine Research (CIFER). Emissions of regulated pollutants (CO, NOx, PM, and THC or NMHC), as well as emissions of alde-hydes for some vehicles, are reported. Two fuels were employed: a high methane fuel (90%) and a low methane fuel (85%). It was found that the NOx, CO, and PM emissions for a given cycle and vehicle are essentially constant for different methane content fuels.

Emissions of six 32 passenger transit buses were characterized using one of the West Virginia University (WVU) Transportable Heavy Duty Emissions Testing Laboratories, and the fixed base chassis dynamometer at the Colorado Institute for Fuels and High Altitude Engine Research (CIFER). Three of the buses were powered with 1997 ISB 5.9 liter Cummins diesel engines, and three were powered with the 1997 5.9 liter Cummins natural gas (NG) counterpart. The NG engines were LEV certified. Objectives were to contrast the emissions performance of the diesel and NG units, and to compare results from the two laboratories. Both laboratories found that oxides of nitrogen and particulate matter (PM) emissions were substantially lower for the natural gas buses than for the diesel buses. It was observed that by varying the rapidity of pedal movement during accelerations in the Central Business District cycle (CBD), CO and PM emissions from the diesel buses could be varied by a factor of three or more.