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This review summarizes the latest developments in diesel emissions regarding regulations, engines, NOx (nitrogen oxides) control, particulate matter (PM) reductions, and hydrocarbon (HC) and CO oxidation. Regulations are advancing with proposals for PN (particle number) regulations that require diesel particulate filters (DPFs) for Euro VI in 2013-14, and SULEV (super ultra low emission vehicle) fleet average light-duty (LD) emissions likely to be proposed in California for ~2017. CO₂ regulations will also impact diesel engines and emissions, probably long into the future. Engine technology is addressing these needs. Heavy-duty (HD) research engines show 90% lower NOx at the same PM or fuel consumption levels as a reference 2007 production engine. Work is starting on HD gasoline engines with promising results. In light duty (LD), engine downsizing is progressing and deNOx is emerging as a fuel savings strategy.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

This review paper summarizes major and representative developments in vehicular emissions regulations and technologies from 2015. The paper starts with the key regulatory advancements in the field, including newly proposed Euro 6 type regulations for Beijing, China, and India in the 2017-20 timeframe. Europe is continuing developments towards real driving emissions (RDE) standards with the conformity factors for light-duty diesel NOx ramping down to 1.5X by 2021. The California heavy duty (HD) low-NOx regulation is advancing and may be proposed in 2017/18 for implementation in 2023+. LD (light duty) and HD engine technology continues showing marked improvements in engine efficiency. Key developments are summarized for gasoline and diesel engines to meet both the emerging criteria and greenhouse gas regulations. LD gasoline concepts are achieving 45% BTE (brake thermal efficiency or net amount of fuel energy gong to the crankshaft) and closing the gap with diesel.

A production calibrated GTDI 1.6L Ford Fusion was used to demonstrate low HC, CO, NOx, PM (particulate mass), and PN (particulate number) emissions using advanced catalyst technologies with newly developed high porosity substrates and coated GPFs (gasoline particulate filters). The exhaust system consisted of 1.2 liters of TWC (three way catalyst) in the close-coupled position, and 1.6L of coated GPF in the underfloor position. The catalysts were engine-aged on a dynamometer to simulate 150K miles of road aging. Results indicate that ULEV70 emissions can be achieved at ∼$40 of PGM, while also demonstrating PM tailpipe performance far below the proposed California Air Resources Board (CARB) LEV III limit of 1 mg/mi. Along with PM and PN analysis, exhaust system backpressure is also presented with various GPF designs.

Diesel particle filters (DPF) have become a standard aftertreatment component for all current and future on-road diesel engines used in the US. In Europe the introduction of EUVI is expected to also result in the broad implementation of DPF's. The anticipated general trend in engine technology towards higher engine-out NOx/PM ratios results in a somewhat changing set of boundary conditions for the DPF predominantly enabling passive regeneration of the DPF. This enables the design of a novel filter concept optimized for low pressure drop, low thermal mass for optimized regeneration and fast heat-up of a downstream SCR system, therefore reducing CO₂ implications for the DPF operation. In this paper we will discuss results from a next-generation cordierite DPF designed to address these future needs.

This review paper summarizes major developments in vehicular emissions regulations and technologies (light-duty, heavy-duty, gasoline, diesel) in 2011. First, the paper covers the key regulatory developments in the field, including proposed criteria pollutant tightening in California; and in Europe, the newly proposed PN (particle number) regulation for direct injection gasoline engines, test cycle development, and in-use testing discussions. The proposed US LD (light-duty) greenhouse gas (GHG) regulation for 2017-25 is reviewed, as well as the finalized, first-ever, US HD (heavy-duty) GHG rule for 2014-17. The paper then gives a brief, high-level overview of key emissions developments in LD and HD engine technology, covering both gasoline and diesel. Emissions challenges include lean NOx remediation for diesel and lean-burn gasoline to meet both the emerging NOx and GHG regulations.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

This paper gives a comprehensive overview of the current state-of-the-art in diesel emission control. The nature of diesel particulates is summarized. The variety of diesel particulate filter regeneration strategies that will become so important to filter application are reviewed. Filter retrofit and durability issues are addressed. DeNOx catalysts, SCR, NOx traps for diesel, and non-thermal plasma methods are summarized. Integrated NOx/PM systems are described. And reduction of exhaust toxics is discussed. The paper covers all major conferences in the year 2000 that occurred in the US and Europe. US and Europe.

With the introduction of the current EU5 standards the diesel particulate filter has become a key element in the aftertreatment of diesel passenger cars. The upcoming future emission standards target primarily a further reduction in NOx emission as well as reduced fleet average CO₂ emissions. Although the particulate filter has no direct influence on the reduction of these species, the needs of future aftertreatment systems impose additional requirements on advanced filter technologies. In this paper we are introducing two new filter products based on a new low porosity aluminum titanate family that complement the current DuraTrap® AT filter products. The new products offer the potential for an increased soot mass limit or a significant reduction in pressure drop. The enhanced performance of the new filter products is discussed and demonstrated in a large number of experimental data obtained in engine bench tests.

Long-haul and other heavy-duty trucks, presently almost entirely powered by diesel fuel, face challenges meeting worldwide needs for greatly reducing nitrogen oxide (NOx) emissions. Dual-fuel gasoline-alcohol engines could potentially provide a means to cost-effectively meet this need at large scale in the relatively near term. They could also provide reductions in greenhouse gas emissions. These spark ignition (SI) flexible fuel engines can provide operation over a wide fuel range from mainly gasoline use to 100% alcohol use. The alcohol can be ethanol or methanol. Use of stoichiometric operation and a three-way catalytic converter can reduce NOx by around 90% relative to emissions from diesel engines with state of the art exhaust treatment.

The development of a cycle simulation model for the jet ignition prechamber stratified charge engine is described. Given the engine geometry, load, speed, air-fuel ratios and pressures and temperatures in the two intakes, flow ratio and a suitable combustion model, the cycle simulation predicts engine indicated efficiency and NO emissions. The relative importance of the parameters required to define the combustion model are then determined, and values for ignition delay and burn angle are obtained by matching predicted and measured pressure-time curves. The variation in combustion parameters with engine operating variables is then examined. Predicted and measured NO emissions are compared, and found to be in reasonable agreement over a wide range of engine operation. The relative contribution of the prechamber NO to total exhaust NO is then examined, and in the absence of EGR, found to be the major source of NO for overall air-fuel ratios leaner than 22:1.

The use of hydrogen as a fuel supplement for lean-burn engines at higher compression ratios has been studied extensively in recent years, with good promise of performance and efficiency gains. With the advances in reformer technology, the use of a gaseous fuel stock, comprising of substantially higher fractions of hydrogen and other flammable reformate species, could provide additional improvements. This paper presents the performance and emission characteristics of a gas mixture of equal volumes of hydrogen, CO, and methane. It has recently been reported that this gas mixture can be produced by reforming of ethanol at comparatively low temperature, around 300C. Experiments were performed on a 1.8-liter passenger-car Nissan engine modified for single-cylinder operation. Special pistons were made so that compression ratios ranging from CR= 9.5 to 17 could be used. The lean limit was extended beyond twice stoichiometric (up to lambda=2.2).

One approach to the remediation of NOx generated under lean automotive engine conditions is its controlled storage and then periodic release and reaction under enriched conditions. This process is being considered for automotive exhaust systems that will be operated pre–dominantly lean for reasons of fuel economy. Because of the special characteristics of alkali and alkaline earth elements in the presence of NOx, they are being considered for use, in conjunction with γ–alumina–based washcoats and precious metal catalysts, as NOx catalyst coatings on cellular supports. It is known that alumino–silicates will react with alkali and alkaline earth elements to form stable ceramic phases when mixtures of the components are held in direct contact at elevated temperatures.

The Cu-zeolite (CuZ) SCR catalyst enables higher NOx conversion efficiency in part because it can store a significant amount of NH3. “NH3 storage control”, where diesel exhaust fluid (DEF) is dosed in accord with a target NH3 loading, is widely used with CuZ catalysts to achieve very high efficiency. The NH3 loading actually achieved on the catalyst is currently estimated through a stoichiometric calculation. With future high-capacity CuZ catalyst designs, it is likely that the accuracy of this NH3 loading estimate will become limiting for NOx conversion efficiency. Therefore, a direct measurement of NH3 loading is needed; RF sensing enables this. Relative to RF sensing of soot in a DPF (which is in commercial production), RF sensing of NH3 adsorbed on CuZ is more challenging. Therefore, more attention must be paid to the “microwave resonance cavity” created within the SCR assembly. The objective of this study was to develop design guidelines to enable and enhance RF sensing.

This review summarizes the latest developments in diesel emissions regarding regulations, engines, NOx (nitrogen oxides) control, particulate matter (PM) reductions, and hydrocarbon (HC) and CO oxidation. Regulations are advancing with proposals for 70% tightening of fleet average light-duty (LD) criteria emissions likely to be proposed in California for ~2016-22. CO₂ regulations in both the heavy- and light-duty sectors will also tighten and impact diesel engines and emissions, probably long into the future. Engine technology is addressing these needs. Light-duty diesel engines are making incremental gains with combustion enhancements that allow downsizing for CO₂ savings. Heavy-duty (HD) engine show trade-offs between hardware recipes, exhaust deNOx control, and fuel consumption.

This review paper covers major regulatory and technology developments in 2018 pertinent to tailpipe emissions of greenhouse gases and criteria pollutants. Europe has proposed ambitious reductions in CO2 limits for both light- and heavy-duty sectors. The challenge is compounded with changing measurement norms and a significant shift away from fuel efficient diesels in the light-duty (LD) space. Both incremental and step changes are being made to advance internal combustion. New studies show that in-use NOx emissions from diesels can be much lower than required by the Euro 6 regulation. Discussions have already started on Euro 7 regulations, and the leading regulatory concepts and proposed technical solutions are provided. In the heavy-duty (HD) sector, the progress is outlined in improving engine and vehicle fuel efficiency through the US Department of Energy’s (DOE’s) SuperTruck II program and other representative studies.

The key diesel emission control papers of the last 12 months have been summarized. In addition, the emerging US and European light-duty and heavy-duty tailpipe regulations are compared. Results are reported on light-duty diesel filtration regeneration systems and experiences, including effects of ash build-up and some recent modeling work. On the heavy-duty side, optimization of SCR catalysts and systems are described, as well as experiences with the first integrated SCR/filter systems, which are already achieving “Euro V” 2008 standards. An update on NOx adsorbers is also provided. The results with new NOx formulations are described, as well as the system performance in a light-duty diesel application.

Internal combustion engines for plug-in hybrid heavy duty trucks, especially long haul trucks, could play an important role in facilitating use of battery power. Power from a low carbon electricity source could thereby be employed without an unattractive vehicle cost increase or range limitation. The ideal engine should be powered by a widely available affordable liquid fuel, should minimize air pollutant emissions, and should provide lower greenhouse gas emissions. Diesel engines could fall short in meeting these objectives, especially because of high emissions. In this paper we analyze the potential for a flex fuel gasoline-alcohol engine approach for a series hybrid powertrain. In this approach the engine would provide comparable (or possibly greater) efficiency than a diesel engine while also providing 90 around lower NOx emissions than present cleanest diesel engine vehicles. Ethanol or methanol would be employed to increase knock resistance.

The NOx emissions during the crank-start and cold fast-idle phases of a GDI engine are analyzed in detail. The NOx emissions of the first 3 firing cycles are studied under a wide set of parameters including the mass of fuel injected, start of injection, and ignition timing. The results show a strong dependence of the NOx emissions with injection timing; they are significantly reduced as the mixture is stratified. The impact of different valve timings on crank-start NOx emissions was analyzed. Late intake and early exhaust timings show similar potential for NOx reduction; 26-30% lower than the baseline. The combined strategy, resulting in a large symmetric negative valve overlap, shows the greatest reduction; 59% lower than the baseline. The cold fast-idle NOx emissions were studied under different equivalence ratios, injection strategies, combustion phasing, and valve timings. Slightly lean air-fuel mixtures result in a significant reduction of NOx.

The NOx emission and knock characteristics of a PFI engine operating on ethanol/gasoline mixtures were assessed at 1500 and 2000 rpm with λ =1 under Wide-Open-Throttle condition. There was no significant charge cooling due to fuel evaporation. The decrease in NOx emission and exhaust temperature could be explained by the change in adiabatic flame temperature of the mixture. The fuel knock resistance improved significantly with the gasohol so that ignition could be timed at a value much closer or at MBT timing. Changing from 0% to 100% ethanol in the fuel, this combustion phasing improvement led to a 20% increase in NIMEP and 8 percentage points in fuel conversion efficiency at 1500 rpm. At 2000 rpm, where knocking was less severe, the improvement was about half (10% increase in NIMEP and 4 percentage points in fuel conversion efficiency).