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Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Fracture split forged steel connecting rods are utilized in many new high performance automotive engines to increase durability. Higher strength levels are needed as the power density increases. Fracture splitting without plastic deformation is necessary for manufacturability. Metallurgical design is a key for achieving the required performance levels. Several medium carbon steels containing 0.07 wt pct P, 0.06 wt pct S and various amounts of Mn, Si, V, and N were produced by vacuum induction melting laboratory heats and hot working the cast ingots into plates. The plates were cooled at varying rates to simulate typical cooling methods after forging. Microstructures were generally ferrite and pearlite as evaluated by light optical and scanning electron microscopy. Mechanical properties were determined by standard tensile tests, high strain rate notched tensile tests, and Charpy V-notch impact tests to assess “splittability”.

Quenching and partitioning (Q&P) is a novel heat treatment to produce third generation advanced high-strength steels (AHSS). The influence of carbon on mechanical properties of Q&P treated CMnSi-steels was studied using 0.3C-1.5Mn-1.5Si and 0.4C-1.5Mn-1.5Si alloys. Full austenitization followed by two-step Q&P treatments were conducted using varying partitioning times and a fixed partitioning temperature of 400 °C. The results were compared to literature data for 0.2C-1.6Mn-1.6Si, 0.2-3Mn-1.6Si and 0.3-3Mn-1.6Si Q&P treated steels. The comparison showed that increasing the carbon content from 0.2 to 0.4 wt pct increased the ultimate tensile strength by 140 MPa per 0.1 wt pct C up to 1611 MPa without significantly decreasing ductility for the partitioning conditions used. Increased alloy carbon content did not substantially increase the retained austenite fractions. The best combinations of ultimate tensile strength and total elongation were obtained using short partitioning times.

This study simulates soot formation processes in diesel combustion using a large eddy simulation (LES) model, based on a one-equation subgrid turbulent kinetic energy model. This approach was implemented in the KIVA4 code, and used to model diesel spray combustion within a constant volume chamber. The combustion model uses a direct integration approach with a fast explicit ordinary differential equation (ODE) solver, and is additionally parallelized using OpenMP. The soot mass production within each computation cell was determined using a phenomenological soot formation model developed by Waseda University. This model was combined with the LES code mentioned above, and included the following important steps: particle inception during which acenaphthylene (A2R5) grows irreversibly to form soot; surface growth with driven by reactions with C2H2; surface oxidation by OH radical and O2 attack; and particle coagulation.

Owing to the small size of engines and high injection pressures, it is difficult to avoid the fuel spray impingement on the combustion cylinder wall and piston head in Direct Injection Spark Ignition (DISI) engine, which is a possible source of hydrocarbons and soot emission. As a result, the droplets size and distribution are significantly important to evaluate the atomization and predict the impingement behaviors, such as stick, spread or splash. However, the microscopic behaviors of droplets are seldom reported due to the high density of small droplets, especially under high pressure conditions. In order to solve this problem, a “spray slicer” was designed to cut the spray before impingement as a sheet one to observe the droplets clearly. The experiment was performed in a constant volume chamber under non-evaporation condition, and a mini-sac injector with single hole was used.

This article is concerned with identification of true stress-strain curve under biaxial tension of thermoplastic polymers. A new type of biaxial tension attachment was embedded first in a universal material test machine, which is able to transform unidirectional loading of the test machine to biaxial loading on the specimen with constant velocity. Cruciform specimen geometry was optimized via FE modeling. Three methods of calculating true stress in biaxial tension tests were compared, based on incompressibility assumption, linear elastic theory and inverse engineering method, respectively. The inverse engineering method is more appropriate for thermoplastic polymers since it considers the practical volume change of the material during biaxial tension deformation. The strategy of data processing was established to obtain biaxial tension true stress-strain curves of different thermoplastic polymers.

In today's highly competitive automotive markets manufacturers must provide high quality products to survive. Manufacturers can achieve higher levels of quality by changing or improving their manufacturing process and/or by product inspection where many strategies with different cost implications are often available. Cost of Quality (CoQ) reconciles the competing objectives of quality maximization and cost minimization and serves as a useful framework for comparing available manufacturing process and inspection alternatives. In this paper, an analytic CoQ framework is discussed and some key findings are demonstrated using a set of basic inspection strategy scenarios. A case of a welded automotive assembly is chosen to explore the CoQ tradeoffs in inspection strategy selection and the value of welding process improvement. In the assembly process, many individual components are welded in series and each weld is inspected for quality.

The fuel energy consumption of subsonic air transportation is examined. The focus is on identification and quantification of fundamental engineering design tradeoffs which drive the design of subsonic tube and wing transport aircraft. The sensitivities of energy efficiency to recent and forecast technology developments are also examined.

The windage tray effect on aeration in the engine sump was assessed by replacing much of the windage tray materials with wire meshes of various blockages. The mesh was to prevent direct impact of the oil drops spinning off the crank shaft onto the sump oil, and simultaneously, to provide sufficient drainage so that there was no significant build up of windage tray oil film that would interact with these droplets. Aeration at the oil pump inlet was measured by X-ray absorption in a production V-6 SI engine motoring at 2000 to 6000 rpm. Within experimental uncertainty, these windage tray changes had no effect on aeration. Thus activities in the sump such as the interaction of the oil drops spun from the crank shaft with the sump oil or with the windage tray, and the agitation of the sump oil by the crank case gas, were not major contributors to aeration at the pump inlet.

We present results which verify the design parameters and suggest performance capabilities/limitations of the Mars Gravity Biosatellite's proposed atmospherics control subassembly. Using a combination of benchtop prototype testing and analytic techniques, we derive control requirements for ammonia. Further, we demonstrate the dehumidification performance of our proposed partial gravity condensing heat exchanger. Ammonia production is of particular concern in rodent habitats. The contaminant is released following chemical degradation of liquid waste products. The rate of production is linked to humidity levels and to the design of habitat modules in terms of bedding substrate, air flow rates, choice of structural materials, and other complex factors. Ammonia buildup can rapidly lead to rodent health concerns and can negatively impact scientific return.

This paper describes a calculating method to predict the quasi-static collapsing behaviors of spot-welded closed-hat section curved beams under axial compression. The overall deformat ions and the local buckling modes of beams were calculated using a geometrical model. Force-displacement relations were predicted by a elastic-plastic structural analysis method using the ‘plastic hinge’ concept. Collapsing tests were made on beams which are differenting section size, rotation angle, and metal sheet thickness. Comparisons between the calculated and experimental results of deformed shapes of beams, the local buckling modes and the force displacement relations are discussed.

A series of bending fatigue tests were conducted and S-N data were obtained for two groups of 4320 steel samples: (1) carburized, quenched and tempered, (2) carburized, quenched, tempered and shot peened. Shot peening improved the fatigue life and endurance limit. The S-N data exhibited large scatter, especially for carburized samples and at the high cycle life regime. Sample characterization work was performed and scatter bands were established for residual stress distributions, in addition to fracture and fatigue properties for 4320 steel. Moreover, a fatigue life analysis was performed using fracture mechanics and strain life fatigue theories. Scatter in S-N curves was established computationally by using the lower bound and upper bound in materials properties, residual stress and IGO depth in the input data. The results for fatigue life analysis, using either computational fracture mechanics or strain life theory, agreed reasonably well with the test data.

In this research, the feasibility of FSW dissimilar magnesium alloys was investigated. Specifically, die cast MRI-153M and wrought AZ31 were butt-welded. The effects of weld parameters such as tool rotation and weld speed on the weld quality have been characterized in terms of macrostructure, microstructure, hardness profile as well as tensile strength. A relatively wide FSW process window exists to achieve void-free welds. In the stir zone MRI-153M transforms from cast structure to fine grain structure during FSW, while AZ31 transforms from originally twinned grains to equi-axed grains without twins. MRI-153M in the stir zone becomes stronger than the base metal and the stir zone on the AZ31 side becomes weaker than the base metal. Tensile coupons failed in the base metal of MRI-153M, and the tensile strength was found to depend on the quality of the base metal of MRI-153M.

The life of an automotive engine is often limited by the ability of its components to resist wear. Zinc dialkyldithiophosphate (ZDDP) is an engine oil additive that reduces wear in an engine by forming solid antiwear films at points of moving contact. The effects of this additive are fairly well understood, but there is little theory behind the kinetics of antiwear film formation and removal. This lack of dynamic modeling makes it difficult to predict the effects of wear at the design stage for an engine component or a lubricant formulation. The purpose of this discussion is to develop a framework for modeling the formation and evolution of ZDDP antiwear films based on the relevant chemical pathways and physical mechanisms at work.

Spot friction welding (SFW) is a cost-effective spot joining technology for aluminum sheets compared with resistance spot welding (RSW) [1]. In this study, coated mild steel was spot friction welded to 6000 series aluminum using a tool with shoulder diameter of 10 mm and welding conditions of 1500-2000 rpm and time of 5 s. Testing showed that tensile shear strength increased as the solidus temperature of the coating on the steel decreased. Microstructure characterizations of steel/Al joint interfaces showed that zinc from the coatings was incorporated into the stir nuggets and that intermetallic phases may have formed but not in continuous layers. Some Al-Zn oxides that appeared to be amorphous were also found in the joint interfaces.

Fine water mist has become a commercial technology for fire suppression in multiple applications. With funding from NASA, ADA Technologies, Inc. (ADA) is developing a handheld fine water mist fire extinguisher for use on manned spacecraft and in future planetary habitats. This design employs only water and nitrogen as suppression agents to allow local refill and reuse. The prototype design incorporates features to generate a uniform fine water mist regardless of the direction of the gravitational vector or lack of gravity altogether. The system has been proven to extinguish open fires and hidden fire scenarios in tests conducted at the Colorado School of Mines (CSM). This design can be deployed as a portable extinguisher or as an automated system for local fire protection in instrument racks or storage spaces. Continued development will result in prototype hardware suitable for use on future manned spacecraft.

Friction stir welding (FSW) shows advantages for joining lightweight alloys for automotive applications. In this research, the feasibility of friction stir welding aluminum for an automotive component application was studied. The objective of this research was to improve the Friction Stir Spot Welding (FSSW) technique used to weld an aluminum closure panel (CP). The spot welds were made using the newly designed swing-FSSW technique. In a previous study (unpublished), the panel was welded from the thin to thick side using both an 8 mm and a 10 mm diameter tool. The 10 mm tool passed various fatigue tests; however, the target was to improve performance of the 8 mm tool, especially to increase the number of cycle before the first crack appearance during fatigue testing. In this study fatigue tests and static strength was recorded for weld specimens that were welded from thick-to-thin with an 8 mm diameter tool.

This paper illustrates a methodology in which complete material-manufacturing process cases for closure panels, reinforcements, and assembly are modeled and compared in order to identify the preferred option for a lightweight closure design. First, process-based cost models are used to predict the cost of lightweighting the closure set of a sample midsized sports utility vehicle (SUV) via material and process substitution. Weight savings are then analyzed using a powertrain simulation to understand the impact of lightweighting on fuel economy. The results are evaluated in the context of production volume and total mass change.

Selective NOx recirculation (SNR), involving adsorption, selective external recirculation and decomposition of the NOx by the combustion process, is itself a promising technique to abate NOx emissions. Three types of materials containing Ba: barium aluminate, barium tin perovskite and barium Y-zeolites have been developed to adsorb NOx under lean-burn or Diesel conditions, with or without the presence of S02. All these materials adsorb NO2 selectively (lean-burn conditions), and store it as nitrate/nitrite species. The desorption takes place by decomposition of these species at higher temperatures. Nitrate formation implies also sulfate formation in the presence of SO2 and SO3, while the NO2/SO2 competition governs the poisoning of such catalysts.

In the past there has been a concentration on performing LCAs of car components. Based on the increasing experience and know-how gained in the past by performing LCAs of car components truck designers get the chance to make a statement about the ecological impact of each alternative. The most significant difference between LCAs of car and truck components is the use phase. This paper describes a Life-Cycle-Assessment (LCA) of different air deflection systems made of composite materials. The actually used system is produced by Resin Transfer Molding (RTM) while a possible alternative could be made out of Sheet Molding Compound (SMC). The calculations have shown that there exists a potential to improve the ecological profiles of composite components by replacing glass fibers with natural fibers.