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Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.

Gas-pressurized space suits are highly resistive to astronaut movement, and this resistance has been previously explained by volume and/or structural effects. This study proposed that an additional effect, pressure effects due to compressing/expanding the internal gas during joint articulation, also inhibits mobility. EMU elbow torque components were quantified through hypobaric testing. Structural effects dominated at low joint angles, and volume effects were found to be the primary torque component at higher angles. Pressure effects were found to be significant only at high joint angles (increased flexion), contributing up to 8.8% of the total torque. These effects are predicted to increase for larger, multi-axis joints. An active regulator system was developed to mitigate pressure effects, and was found to be capable of mitigating repeated pressure spikes caused by volume changes.

Non-petroleum based liquid fuels are essential for reducing oil dependence and greenhouse gas generation. Increased substitution of alcohol fuel for petroleum based fuels could be achieved by 1) use in high efficiency spark ignition engines that are employed for heavy duty as well as light duty operation and 2) use of methanol as well as ethanol. Methanol is the liquid fuel that is most efficiently produced from thermo-chemical gasification of coal, natural gas, waste or biomass. Ethanol can also be produced by this process but at lower efficiency and higher cost. Coal derived methanol is in limited initial use as a transportation fuel in China. Methanol could potentially be produced from natural gas at an economically competitive fuel costs, and with essentially the same greenhouse gas impact as gasoline. Waste derived methanol could also be an affordable low carbon fuel.

A new monitoring system predicts the progression of welding temperature fields during resistance spot welding. The system captures welding voltages and currents to predict contact diameters and simulate temperature fields. The system accurately predicts fusion lines and heat-affected zones. Accuracy holds even for electrode tips used for a few thousand welds of zinc coated steels.

The piston skirt is an important contributor of friction in the piston assembly. This paper discusses friction contributions from various aspects of the piston skirt. A brief study of piston skirt patterns is presented, with little gains being made by patterning the piston skirt coating. Next the roughness of the piston skirt coating is analyzed, and results show that reducing piston skirt roughness can have positive effects on friction reduction. Finally, an introductory study into the profile of the piston skirt is presented, with the outcome being that friction reduction is possible by optimizing the skirt profile.

Ethanol and acetaldehyde emissions from a direct ignition spark ignition were measured using mass spectrometry. Previous methods focused on eliminating or minimizing interference from exhaust species with identical atomic mass and fragment ions created in ionization process. This paper describes a new technique which exploits the fragment ions from ethanol and acetaldehyde. A survey of mass spectra of all major species of exhaust gas was conducted. It was found that ethanol contributes most ions in mass number 31 and that no other gas species produces ions at this mass number. Acetaldehyde detection suffers more interference. Nevertheless, it was estimated that detection at mass number 43 is possible with 10% error from 2-methylbutane. This new technique was validated in an engine experiment. By running the engine with pure gasoline and E85, the validity of the technique can be checked.

The fuel effects on HCCI operation in a spark assisted direct injection gasoline engine are assessed. The low load limit has been extended with a pilot fuel injection during the negative valve overlap (NVO) period. The fuel matrix consists of hydrocarbon fuels and various ethanol blends and a butanol blend, plus fuels with added ignition improvers. The hydrocarbon fuels and the butanol blend do not significantly alter the high or the low limits of operation. The HCCI operation appears to be controlled more by the thermal environment than by the fuel properties. For E85, the engine behavior depends on the extent that the heat release from the pilot injected fuel in the NVO period compensates for the evaporative cooling of the fuel.

Higher compression ratio and turbocharging, with engine downsizing can enable significant gains in fuel economy but require engine operating conditions that cause engine knock under high load. Engine knock can be avoided by supplying higher-octane fuel under such high load conditions. This study builds on previous MIT papers investigating Octane-On-Demand (OOD) to enable a higher efficiency, higher-boost higher compression-ratio engine. The high-octane fuel for OOD can be obtained through On-Board-Separation (OBS) of alcohol blended gasoline. Fuel from the primary fuel tank filled with commercially available gasoline that contains 10% by volume ethanol (E10) is separated by an organic membrane pervaporation process that produces a 30 to 90% ethanol fuel blend for use when high octane is needed. In addition to previous work, this paper combines modeling of the OBS system with passenger car and medium-duty truck fuel consumption and octane requirements for various driving cycles.

Special coatings are being developed and tested to contend with the effects of dust on the lunar surface. These coatings will have wide applicability ranging from prevention of dust buildup on solar arrays and radiator surfaces to protection of EVA space suit fabrics and visors. They will be required to be durable and functional based on application. We have started preparing abrasion-resistant transparent conductive coatings ∼40 nm thick were formed by co-deposition of titanium dioxide (TiO2) and titanium (Ti) on room-temperature glass and polycarbonate substrates using two RF magnetron sputtering sources. By adjusting Ti content, we obtained sheet resistivities in the range 104-1010 ohms/square. We have also started conducting a series of environmental tests that simulate the exposure of coated samples to dust under relevant conditions, beginning with abrasion tests using regolith simulant materials.

Painting is the most expensive unit operation in automobile manufacturing and the source of over 90 percent of the air, water and solid waste emissions at the assembly plant. While innovative paint technologies such as waterborne or powder paints can potentially improve plant environmental performance, implementing these technologies often requires major capital investment. A process-based technical cost model was developed for examining the environmental and economic implications of automotive painting at the unit operation level. The tradeoffs between potential environmental benefits and their relative costs are evaluated for current and new technologies.

The autoignition characteristics of methanol, ethanol and MTBE (methyl tert-butyl ether) have been investigated in a rapid compression machine at pressures in the range 20-40 atm and temperatures within 750-1000 K. All three oxygenated fuels tested show higher autoignition temperatures than paraffins, a trend consistent with the high octane number of these fuels. The autoignition delay time for methanol was slightly lower than predicted values using reported reaction mechanisms. However, the experimental and measured values for the activation energy are in very good agreement around 44 kcal/mol. The measured activation energy for ethanol autoignition is in good agreement with previous shock tube results (31 kcal/mol), although ignition times predicted by the shock tube correlation are a factor of three lower than the measured values. The measured activation energy for MTBE, 41.4 kcal/mol, was significantly higher than the value previously observed in shock tubes (28.1 kcal/mol).

This paper investigates theoretically the effects of heat transfer characteristics, such as crank-angle phasing and wall temperature swings, on the thermodynamic efficiency of an IC engine. The objective is to illustrate the fundamental physical basis of applying thin thermal barrier coatings to improve the performance of military and commercial IC engines. A simple model illustrates how the thermal impedance and thickness of coatings can be manipulated to control heat transfer and limit the high temperatures in engine components. A friction model is also included to estimate the overall improvement in engine efficiency by the proper selection of coating thickness and material.

Frictional losses in the piston ring-pack of an engine account for approximately half of the total frictional losses within the power cylinder of an engine. Three-dimensional honing groove texture was modeled, and its effect on piston ring-pack friction and engine brake thermal efficiency was investigated. Adverse effects on engine oil consumption and durability were also considered. Although many non-conventional cylinder liner finishes are now being developed to reduce friction and oil consumption, the effects of surface finish on ring-pack performance is not well understood. A rough surface flow simulation program was developed to calculate flow and stress factors that adjust the solution of the Reynolds equation for the effects of surface roughness as has been done in the literature. Rough surface contact between the ring and liner was modeled using a previously published methodology for asperity contact pressure estimation between rough surfaces.

Zinc coating integrity, composition, thickness, roughness, and the presence of Fe-Zn intermetallics are being investigated with regard to the mechanisms of weld nugget formation. This information is being used in conjunction with the optimization of the weld process parameters; such as upsloping, down-sloping, preheating, postheating, and double pulsing, to provide the widest range of acceptable welding conditions. Dynamic inspection monitoring of the welding current, voltage, force, and nugget displacement is being used to follow the progression of nugget formation and to assist in the evaluation of optimum process and material characteristics. It has been found that hot-dipped galvanized materials with coatings which have a very thin Fe-Zn alloy layer, have a wider range of acceptable welding conditions than the commercial galvannealed products, which have a fully alloyed Fe-Zn coating.

A linearized lumped parameter heat balance model was developed and is discussed for the general case of resistance welding to see the effects of each parameter on the lobe shape. The parameters include material properties, geometry of electrodes and work piece, weld time and current, and electrical and thermal contact characteristics. These are then related to heat dissipation in the electrodes and the work piece. The results indicate that the ratio of thermal conductivity and heat capacity to electrical resistivity is a characteristic number which is representative of the ease of spot weldability of a given material. The increases in thermal conductivity and heat capacity of the sheet metal increase the lobe width while increases in electrical resistivity decrease the lobe width. Inconsistencies in the weldability of thin sheets and the wider lobe width at long welding times can both be explained by the heat dissipation characteristics.

The use of hydrogen as a fuel supplement for lean-burn engines at higher compression ratios has been studied extensively in recent years, with good promise of performance and efficiency gains. With the advances in reformer technology, the use of a gaseous fuel stock, comprising of substantially higher fractions of hydrogen and other flammable reformate species, could provide additional improvements. This paper presents the performance and emission characteristics of a gas mixture of equal volumes of hydrogen, CO, and methane. It has recently been reported that this gas mixture can be produced by reforming of ethanol at comparatively low temperature, around 300C. Experiments were performed on a 1.8-liter passenger-car Nissan engine modified for single-cylinder operation. Special pistons were made so that compression ratios ranging from CR= 9.5 to 17 could be used. The lean limit was extended beyond twice stoichiometric (up to lambda=2.2).

Knock in gasoline engines at higher loads is a significant constraint on torque and efficiency. The anti-knock property of a fuel is closely related to its research octane number (RON). Ethanol has superior RON compared to gasoline and thus has been commonly used to blend with gasoline in commercial gasolines. However, as the RON of a fuel is constant, it has not been used as needed in a vehicle. To wisely use the RON, an On-Board Separation (OBS) unit that separates commercial gasoline with ethanol content into high-octane fuel with high ethanol fraction and a lower octane remainder has been developed. Then an onboard Octane-on-demand (OOD) concept uses both fuels in varying proportion to provide to the engine a fuel blend with just enough RON to meet the ever changing octane requirement that depends on driving pattern.

Topology of liner finish is critical to the performance of internal combustion engines. Proper liner finish simulation processes lead to efficient engine design and research. Fourier methods have been well studied to numerically generate liner topology. However, three major issues wait to be addressed to make the generation processes feasible and reliable. First, in order to simulate real plateau honed liners, approaches should be developed to calculate accurate liner geometric parameters. These parameters are served as the input of the generation algorithm. Material ratio curve, the common geometry calculation method, should be modified so that accurate root mean square of plateau height distribution could be obtained. Second, the set of geometric parameters used in generating liner finish (ISO 13565-2) is different from the set of parameters used in manufacturing industry (ISO 13565-3). Quantitative relations between these two sets should be studied.

The focus of this study was the characterization and comparison of power-specific exhaust emission rates from a closed-loop small spark-ignited engine fuelled with ethanol and isobutanol gasoline blends. A 4-cycle Kohler ECH-630 engine certified to the Phase 3 emissions standards was operated over the G2 test cycle, a six-mode steady-state test cycle, in its original configuration. This engine was equipped with electronic ignition, electronic fuel injection and an oxygen sensor. Certification gasoline fuel was splash-blended by percent volume with ethanol and isobutanol to result in the test blend levels of E10, E15, iB16 and iB8-E10. Reductions in emission rates of carbon monoxide (up to 12.0% with the ethanol blends and up to 11.4% with the isobutanol blends) were achieved along with a reduction in total hydrocarbons (up to 10.9% with the ethanol blends and up to 8.2% with the isobutanol blends). Nitrogen oxide emissions were decreased by up to 9.8% with the ethanol blends.