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The presence of liquid fuel inside the engine cylinder is believed to be a strong contributor to the high levels of hydrocarbon emissions from spark ignition (SI) engines during the warm-up period. Quantifying and determining the fate of the liquid fuel that enters the cylinder is the first step in understanding the process of emissions formation. This work uses planar laser induced fluorescence (PLIF) to visualize the liquid fuel present in the cylinder. The fluorescing compounds in indolene, and mixtures of iso-octane with dopants of different boiling points (acetone and 3-pentanone) were used to trace the behavior of different volatility components. Images were taken of three different planes through the engine intersecting the intake valve region. A closed valve fuel injection strategy was used, as this is the strategy most commonly used in practice. Background subtraction and masking were both performed to reduce the effect of any spurious fluorescence.

Measurements of particulate matter (PM) from spark ignition (SI) engine exhaust using dilution tunnels will become more prevalent as emission standards are tightened. Hence, a study of the dilution process was undertaken in order to understand how various dilution related parameters affect the accuracy with which PM sizes and concentrations can be determined. A SI and a compression ignition (CI) engine were separately used to examine parameters of the dilution process; the present work discusses the results in the context of SI exhaust dilution. A Scanning Mobility Particle Sizer (SMPS) was used to measure the size distribution, number density, and volume fraction of PM. Temperature measurements in the exhaust pipe and dilution tunnel reveal the degree of mixing between exhaust and dilution air, the effect of flowrate on heat transfer from undiluted and diluted exhaust to the environment, and the minimum permissible dilution ratio for a maximum sample temperature of 52°C.

This paper provides an overview of spark-ignition engine unburned hydrocarbon emissions mechanisms, and then uses this framework to relate measured engine-out hydrocarbon emission levels to the processes within the engine from which they result. Typically, spark-ignition engine-out HC levels are 1.5 to 2 percent of the gasoline fuel flow into the engine; about half this amount is unburned fuel and half is partially reacted fuel components. The different mechanisms by which hydrocarbons in the gasoline escape burning during the normal engine combustion process are described and approximately quantified. The in-cylinder oxidation of these HC during the expansion and exhaust processes, the fraction which exit the cylinder, and the fraction oxidized in the exhaust port and manifold are also estimated.

A one-dimensional model has been developed for the species and energy transfer over a thin (0.1-0.5 mm) layer of liquid fuel present on the wall of a spark-ignition engine. Time-varying boundary conditions during compression and flame passage were used to determine the rate of methanol vaporization and oxidation over a mid-speed, mid-load cycle, as a function of wall temperature. The heat of vaporization and the boiling point of the fuel were varied about a baseline to determine the effect of these characteristics, at a fixed operating point and lean conditions (ϕ = 0.9). The calculations show that the evaporation of fuels from layers on cold walls starts during flame passage, peaking a few milliseconds later, and continuing through the exhaust phase.

Optimal design of modern direct injection spark-ignition engines depends heavily on the characteristics and distribution of the fuel spray. This study was designed to compliment imaging experiments of changes in the spray structure due to fuel volatility and operating conditions. Use of phase-Doppler particle analysis (PDPA) allows quantitative point measurements of droplet diameter and velocity. In agreement with imaging experiments, the results show that the spray structure changes not only with ambient gas density, which is often measured, but also with fuel temperature and volatility. The mean droplet diameter was found to decrease substantially with increasing fuel temperature and decreasing ambient density. Under conditions of low potential for vaporization, the observed trends in mean droplet sizes agree with published correlations for pressure-swirl atomizers.

Optimal design of modern direct injection spark-ignition engines depends heavily on the characteristics and distribution of the fuel spray. This study was designed to investigate changes in the spray properties due to fuel volatility and operating conditions using a firing optically-accessible engine with planar laser-induced fluorescence (PLIF) imaging. The results show that the spray structure changes not only with ambient gas density, which is often measured, but also with fuel temperature and volatility. As ambient pressure decreases and fuel temperature increases, the volatile ends of multi-component fuels evaporate quickly, disrupting the spray structure and producing a vapor core along the axis of the spray. Beyond a certain point, evaporation is rapid enough to expand the initial cone angle of the spray while causing a decrease in the overall spray width.