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Monitoring Urea Quantity Delivery for Diesel SCR After-treatment

2012-02-01
While providing significant benefits to vehicle operation and emissions, on board diagnosis comes at a cost. In many cases the additional cost comes in the form of reduced optimal performance. Often the additional cost can be mitigated by considering the OBD requirements early in the development stages. In this presentation we show these trade-offs in a number of case studies. We will point out where the ability to diagnose comes at the cost of suboptimal performance, and where system design decisions can facilate the OBD task. Presenter Michiel Van Nieuwstadt, Ford Motor Co.
Journal Article

Effects of Secondary Air Injection During Cold Start of SI Engines

2010-10-25
2010-01-2124
An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.
Journal Article

The Effects of Sulfur Poisoning and Desulfation Temperature on the NOx Conversion of LNT+SCR Systems for Diesel Applications

2010-04-12
2010-01-0300
A laboratory study was performed to assess the effects of sulfur poisoning and desulfation temperature on the NO conversion of a LNT+(Cu/SCR) in-situ system. Four LNT+(Cu/SCR) systems were aged for 4.5 hours without sulfur at 600, 700, 750, and 800°C using A/F ratio modulations to represent 23K miles of desulfations at different temperatures. NO conversion tests were performed on the LNT alone and on the LNT+SCR system using a 60 s lean/5 s rich cycle. The catalysts were then sulfur-poisoned at 400°C and desulfated four times and re-evaluated on the 60/5 tests. This test sequence was repeated 3 more times to represent 100K miles of desulfations. After simulating 23K miles of desulfations, the Cu-based SCR catalysts improved the NO conversion of the LNT at low temperatures (e.g., 300°C), although the benefit decreased as the desulfation temperature increased from 600°C to 800°C.
Journal Article

Occupant Preferred Back Angle Relative to Head Restraint Regulations

2010-04-12
2010-01-0779
Having, by now, introduced several new vehicles that comply with FMVSS 202a, manufacturers are reporting an increased number of complaints from consumers who find that the head restraint is too close; negatively affecting their posture. It is speculated that one of the reasons that head restraints meeting the new requirement are problematic is that the FMVSS backset measurement is performed at a back angle that is more reclined than the back angle most drivers choose and the back angle at which the seat / vehicle was designed. The objective of this paper is to confirm this hypothesis and elaborate on implications for regulatory compliance in FMVSS 202a.
Journal Article

The Impact of Biodiesel on Particle Number, Size and Mass Emissions from a Euro4 Diesel Vehicle

2010-04-12
2010-01-0796
New European emissions legislation (Euro5) specifies a limit for Particle Number (PN) emissions and therefore drives measurement of PN during vehicle development and homologation. Concurrently, the use of biofuel is increasing in the marketplace, and Euro5 specifies that reference fuel must contain a bio-derived portion. Work was carried out to test the effect of fuels containing different levels of Fatty Acid Methyl Ester (FAME) on particle number, size, mass and composition. Measurements were conducted with a Cambustion Differential Mobility Spectrometer (DMS) to time-resolve sub-micron particles (5-1000nm), and a Horiba Solid Particle Counting System (SPCS) providing PN data from a Euro5-compliant measurement system. To ensure the findings are relevant to the modern automotive business, testing was carried out on a Euro4 compliant passenger car fitted with a high-pressure common-rail diesel engine and using standard homologation procedures.
Journal Article

Ash Effects on Diesel Particulate Filter Pressure Drop Sensitivity to Soot and Implications for Regeneration Frequency and DPF Control

2010-04-12
2010-01-0811
Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.
Journal Article

Deformation Analysis of Incremental Sheet Forming

2010-04-12
2010-01-0991
Incremental Sheet Forming (ISF) is an emerging sheet metal prototyping technology where a part is formed as one or more stylus tools are moving in a pre-determined path and deforming the sheet metal locally while the sheet blank is clamped along its periphery. A deformation analysis of incremental forming process is presented in this paper. The analysis includes the development of an analytical model for strain distributions based on part geometry and tool paths; and numerical simulations of the forming process with LS-DYNA. A skew cone is constructed and used as an example for the study. Analytical and numerical results are compared, and excellent correlations are found. It is demonstrated that the analytical model developed in this paper is reliable and efficient in the prediction of strain distributions for incremental forming process.
Journal Article

Study of On-Board Ammonia (NH3) Generation for SCR Operation

2010-04-12
2010-01-1071
Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.
Journal Article

Characteristics and Effects of Lubricant Additive Chemistry on Ash Properties Impacting Diesel Particulate Filter Service Life

2010-04-12
2010-01-1213
Ash accumulation in diesel particulate filters, mostly from essential lubricant additives, decreases the filter's soot storage capacity, adversely affects fuel economy, and negatively impacts the filter's service life. While the adverse effects of ash accumulation on DPF performance are well known, the underlying mechanisms controlling these effects are not. To address these issues, results of detailed measurements with specially formulated lubricants, correlating ash properties to individual lubricant additives and their effects on DPF pressure drop, are presented. Investigations using the specially-formulated lubricants showed ash consisting primarily of calcium sulfates to exhibit significantly increased flow resistance as opposed to ash primarily composed of zinc phosphates. Furthermore, ash accumulated along the filer walls was found to be packed approximately 25% denser than ash accumulated in the channel end-plugs.
Journal Article

A Study of Active and Passive Regeneration Using Laboratory Generated Soot on a Variety of SiC Diesel Particulate Filter Formulations

2010-04-12
2010-01-0533
In this study an attempt to understand and demonstrate the effects of various washcoat technologies under active and passive regeneration conditions was performed. Six different formulations, on 1.0" D. x 3.0" L. SiC wall flow filters at the laboratory level were used at various test conditions, including variable NO₂/NO ratios and O₂ concentrations. Samples were regenerated using active and passive conditions to evaluate regeneration rates and the potential impact of regeneration at the vehicle level. Results were applied to vehicle operating conditions to determine passive functionality and potential benefits. Active regenerations at 2% O₂ and 5% O₂ showed no significant difference in time to complete regeneration and soot burn rates. Active regenerations performed at 1% O₂ and 5% O₂ concentration showed that the regeneration temperature was shifted by approximately 50°C.
Journal Article

Laboratory and Vehicle Demonstration of “2nd-Generation” LNT + in-situ SCR Diesel NOx Emission Control Systems

2010-04-12
2010-01-0305
This study extends research previously reported from our laboratory [SAE 2009-01-0285] on diesel NOx control utilizing a new generation of Lean NOx Trap (LNT) plus in-situ Selective Catalytic Reduction (SCR) catalyst systems. Key findings from this work include 1) evidence for a “non-ammonia” reduction pathway over the SCR catalyst (in addition to the conventional ammonia pathway), 2) high NOx conversions utilizing LNT formulations with substantially lower platinum group metal (PGM) loadings than utilized in earlier systems, 3) ability of the downstream SCR catalyst to maintain high overall system NOx efficiency with aged LNTs, and 4) effectiveness of both Cu- and Fe-zeolite SCR formulations to enhance overall system NOx efficiency. FTP NOx conversion efficiencies in excess of 95% were obtained on two light-duty vehicle platforms with lab-aged catalyst systems, thus showing potential of the LNT+SCR approach for achieving the lowest U.S. emissions standards
Journal Article

Compressive Behavior of Representative Volume Element Specimens of Lithium-Ion Battery Cells under Different Constrained Conditions

2014-04-01
2014-01-1987
The compressive behavior of lithium-iron phosphate battery cells is investigated by conducting in-plane constrained compression tests and out-of-plane compression tests of representative volume element (RVE) specimens. The results for cell RVE specimens under in-plane constrained compression tests without pre-strains and with pre-strains in the out-of-plane direction indicate that the load carrying capacity is characterized by the buckling of cell specimens. As the pre-strain increases, the nominal compressive stress-strain curve becomes higher. The nominal stress-strain curves in the out-of-plane direction were also obtained and used to determine the elastic moduli for the elastic buckling analyses of the cell components in the cell RVE specimens with different pre-strains. Based on the elastic buckling analyses for a beam with different lateral constraints due to different pre-strains in the out-of-plane direction, the number of half waves and the buckling stresses were obtained.
Journal Article

A Copula-Based Approach for Model Bias Characterization

2014-04-01
2014-01-0735
Available methodologies for model bias identification are mainly regression-based approaches, such as Gaussian process, Bayesian inference-based models and so on. Accuracy and efficiency of these methodologies may degrade for characterizing the model bias when more system inputs are considered in the prediction model due to the curse of dimensionality for regression-based approaches. This paper proposes a copula-based approach for model bias identification without suffering the curse of dimensionality. The main idea is to build general statistical relationships between the model bias and the model prediction including all system inputs using copulas so that possible model bias distributions can be effectively identified at any new design configurations of the system. Two engineering case studies whose dimensionalities range from medium to high will be employed to demonstrate the effectiveness of the copula-based approach.
Journal Article

Model-Based Parameter Identification of Healthy and Aged Li-ion Batteries for Electric Vehicle Applications

2015-04-14
2015-01-0252
Electric vehicles are receiving considerable attention because they offer a more efficient and sustainable transportation alternative compared to conventional fossil-fuel powered vehicles. Since the battery pack represents the primary energy storage component in an electric vehicle powertrain, it requires accurate monitoring and control. In order to effectively estimate the battery pack critical parameters such as the battery state of charge (SOC), state of health (SOH), and remaining capacity, a high-fidelity battery model is needed as part of a robust SOC estimation strategy. As the battery degrades, model parameters significantly change, and this model needs to account for all operating conditions throughout the battery's lifespan. For effective battery management system design, it is critical that the physical model adapts to parameter changes due to aging.
Journal Article

Turbocharger Turbine Inlet Isentropic Pressure Observer Model

2015-04-14
2015-01-1617
Exhaust pressures (P3) are hard parameters to measure and can be readily estimated, the cost of the sensors and the temperature in the exhaust system makes the implementation of an exhaust pressure sensor in a vehicle control system a costly endeavor. The contention with measured P3 is the accuracy required for proper engine and vehicle control can sometimes exceed the accuracy specification of market available sensors and existing models. A turbine inlet exhaust pressure observer model based on isentropic expansion and heat transfer across a turbocharger turbine was developed and investigated in this paper. The model uses 4 main components; an open loop P3 orifice flow model, a model of isentropic expansion across the turbine, a turbine and pipe heat transfer models and an integrator with the deviation in the downstream turbine outlet parameter.
Journal Article

NVH Development of the Ford 2.7L 4V-V6 Turbocharged Engine

2015-06-15
2015-01-2288
A new turbocharged 60° 2.7L 4V-V6 gasoline engine has been developed by Ford Motor Company for both pickup trucks and car applications. This engine was code named “Nano” due to its compact size; it features a 4-valves DOHC valvetrain, a CGI cylinder block, an Aluminum ladder, an integrated exhaust manifold and twin turbochargers. The goal of this engine is to deliver 120HP/L, ULEV70 emission, fuel efficiency improvements and leadership level NVH. This paper describes the upfront design and optimization process used for the NVH development of this engine. It showcases the use of analytical tools used to define the critical design features and discusses the NVH performance relative to competitive benchmarks.
Journal Article

Reduction of Cold-Start Emissions through Valve Timing in a GDI Engine

2016-04-05
2016-01-0827
This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.
Journal Article

Lubricant-Derived Ash Impact on Gasoline Particulate Filter Performance

2016-04-05
2016-01-0942
The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.
Journal Article

Analysis of Ash in Low Mileage, Rapid Aged, and High Mileage Gasoline Exhaust Particle Filters

2017-03-28
2017-01-0930
To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.
Journal Article

On-Board Particulate Filter Failure Prevention and Failure Diagnostics Using Radio Frequency Sensing

2017-03-28
2017-01-0950
The increasing use of diesel and gasoline particulate filters requires advanced on-board diagnostics (OBD) to prevent and detect filter failures and malfunctions. Early detection of upstream (engine-out) malfunctions is paramount to preventing irreversible damage to downstream aftertreatment system components. Such early detection can mitigate the failure of the particulate filter resulting in the escape of emissions exceeding permissible limits and extend the component life. However, despite best efforts at early detection and filter failure prevention, the OBD system must also be able to detect filter failures when they occur. In this study, radio frequency (RF) sensors were used to directly monitor the particulate filter state of health for both gasoline particulate filter (GPF) and diesel particulate filter (DPF) applications.
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