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Lithium-Ion batteries are being considered as a high-energy density replacement for Nickel Metal Hydride (NiMH) batteries in Hybrid Electric Vehicles (HEVs) and in the new Plug-In Hybrids (PHEVs). Although these cells can result in significant reduction in weight and volume, they have several safety related issues that still need to be addressed. We report here on the thermal response of Li-ion cells specifically assembled in our laboratory to test new materials, electrolytes and additives. Improvements in the thermal abuse tolerance of cells will be presented and discussed in terms of the need for overall battery system safety.

Rare earths are a group of elements whose availability has been of concern due to monopolistic supply conditions and environmentally unsustainable mining practices. To evaluate the risks of rare earths availability to automakers, a first step is to determine raw material content and value in vehicles. This task is challenging because rare earth elements are used in small quantities, in a large number of components, and by suppliers far upstream in the supply chain. For this work, data on rare earth content reported by vehicle parts suppliers was assessed to estimate the rare earth usage of a typical conventional gasoline engine midsize sedan and a full hybrid sedan. Parts were selected from a large set of reported parts to build a hypothetical typical mid-size sedan. Estimates of rare earth content for vehicles with alternative powertrain and battery technologies were made based on the available parts' data.

We present a parametric analysis of electric vehicle (EV) adoption rates and the corresponding contribution to greenhouse gas (GHG) reduction in the US light-duty vehicle (LDV) fleet through 2050. The analysis is performed with a system dynamics based model of the supply-demand interactions among the fleet, its fuels, and the corresponding primary energy sources. The differentiating feature of the model is the ability to conduct global sensitivity and parametric trade-space analyses. We find that many factors impact the adoption rates of EVs. These include, in particular, policy initiatives that encourage consumers to consider lifetime ownership costs, the price of oil, battery performance, as well as the pace of technological development for all powertrains (conventional internal combustion engines included). Widespread EV adoption can have noticeable impact on petroleum consumption and GHG emissions by the LDV fleet.

Introduction of an array of new electrical and electronic features into future vehicles is generating vehicle electrical power requirements that exceed the capabilities of today's 14 volt electrical systems. In the near term (5 to 10 years), the existing 14V system will be marginally capable of supporting the expected additional loads with escalating costs for the associated charging system. However, significant increases in vehicle functional content are expected as future requirements to meet longer-term (beyond 10 years) needs in the areas of emission control, fuel economy, safety, and passenger comfort. A higher voltage electrical system will be required to meet these future requirements. This paper explores the functional needs that will mandate a higher voltage system and the benefits derivable from its implementation.

Sandia National Laboratories has been investigating a new, integrated approach to generating electricity with ultra low emissions and very high efficiency for low power (30 kW) applications such as hybrid vehicles and portable generators. Our approach utilizes a free piston in a double-ended cylinder. Combustion occurs alternately at each cylinder end, with intake/exhaust processes accomplished through a two stroke cycle. A linear alternator is mounted in the center section of the cylinder, serving to both generate useful electrical power and to control the compression ratio by varying the rate of electrical generation. Thus, a mechanically simple geometry results in an electronically controlled variable compression ratio configuration. The capability of the homogeneous charge compression ignition combustion process employed in this engine with regards to reduced emissions and improved thermal efficiency has been investigated using a rapid compression expansion machine.

The prime candidate for direct conversion from heat to electricity has historically been thermoelectric energy conversion. More recently, advances in thermophotovoltaic systems render them potentially interesting. Neither class of systems is used in automobiles to any significant extent today, and neither class of systems is poised on the brink of a large-scale adoption. In this paper, the characteristics of these types of energy conversion are discussed, with special emphasis on their utility in automobiles.

Battery packs for Hybrids, Plug-in Hybrids, and Electric Vehicles are assembled from a system of modules (sheets) with a tight sheet metal casing around them. Each module consists of an array of individual cells which vary in the composition of electrodes and separator from one manufacturer to another. In this paper a general procedure is outlined on the development of a constitutive and computational model of a cylindrical cell. Particular emphasis is placed on correct prediction of initiation and propagation of a tearing fracture of the steel can. The computational model correctly predicts rupture of the steel can which could release aggressive chemicals, fumes, or spread the ignited fire to the neighboring cells. The initiation site of skin fracture depends on many factors such as the ductility of the casing material, constitutive behavior of the system of electrodes, and type of loading.

This paper evaluates the lag time in a turbocharged single cylinder engine in order to determine its viability in transient applications. The overall goal of this research is to increase the power output, reduce the fuel economy, and improve emissions of single cylinder engines through turbocharging. Due to the timing mismatch between the exhaust stroke, when the turbocharger is powered, and the intake stroke, when the engine intakes air, turbocharging is not conventionally used in commercial single cylinder engines. Our previous work has shown that it is possible to turbocharge a four stroke, single cylinder, internal combustion engine using an air capacitor, a large volume intake manifold in between the turbocharger compressor and engine intake. The air capacitor stores compressed air from the turbocharger during the exhaust stroke and delivers it during the intake stroke.

This paper describes the experimental evaluation of a prototype free piston engine - linear alternator (FPLA) system developed at Sandia National Laboratories. The opposed piston design was developed to investigate its potential for use in hybrid electric vehicles (HEVs). The system is mechanically simple with two-stroke uniflow scavenging for gas exchange and timed port fuel injection for fuel delivery, i.e. no complex valving. Electrical power is extracted from piston motion through linear alternators which also provide a means for passive piston synchronization through electromagnetic coupling. In an HEV application, this electrical power would be used to charge the batteries. The engine-alternator system was designed, assembled and operated over a 2-year period at Sandia National Laboratories in Livermore, CA.

A few years ago, the automobile industry agreed to adopt standards for a new voltage for the production and use of electrical power. The perception was near universal that 14 Volts was at the limits of its capability, and that 42 Volts would be adopted in a rush. The universal perception was wrong. Since then, much of the auto industry has encountered hard financial times. In a totally separate development, parts suppliers introduced innovations at 14 Volts, some of which a few years ago were thought to require 42 Volts. Today, there are 42-Volt cars and trucks for sale, but only at numbers far lower than necessary to begin to achieve economies of scale. But the factor which caused the industry to develop the 42 Volt standard, the growth of electricity use on motor vehicles, continues with no sign of letup. Further, the true technical obstacles to adoption of 42 Volts have been discovered and at least provisionally solved.

The Advanced Battery Readiness Ad Hoc Working Group, a government- industry forum sponsored by the United States Department of Energy, is charged with assessing environmental and safety issues associated with advanced batteries for electric and hybrid electric vehicles. Electric and hybrid electric vehicles require sophisticated advanced battery storage systems. Frequently, toxic, reactive, and flammable substances are used in the energy storage systems. Often, the substances have safety, recycling, and shipping implications with respect to U.S. Environmental Protection Agency and Department of Transportation regulations. To facilitate commercialization, reg-ulations must either be modified or newly developed. Government-industry coordination has expedited needed regulatory changes, and promoted other partnerships to achieve environmental and safety solutions.

This paper introduces a new design for alternator systems that provides dramatic increases in peak and average power output from a conventional Lundell alternator, along with substantial improvements in efficiency. Experimental results demonstrate these capability improvements. Additional performance and functionality improvements of particular value for high-voltage (e.g., 42 V) alternators are also demonstrated. Tight load-dump transient suppression can be achieved using this new design and the alternator system can be used to implement jump charging (the charging of the high-voltage system battery from a low-voltage source). Dual-output extensions of the technique (e.g., 42/14 V) are also introduced. The new technology preserves the simplicity and low cost of conventional alternator designs, and can be implemented within the existing manufacturing infrastructure.

Advanced rechargeable lithium-ion batteries are presently being developed and commercialized worldwide for use in consumer electronics, military and space applications. The motivation behind these efforts involves, among other things, a favorable combination of energy and power density. For some of the applications the power sources may need to perform at a reasonable rate at subambient temperatures. Given the nature of the lithium-ion cell chemistry the low temperature performance of the cells may not be very good. At Sandia National Laboratories, we have used different electrochemical techniques such as impedance and charge/discharge at ambient and subambient temperatures to probe the various electrochemical processes that are occurring in Li-ion cells. The purpose of this study is to identify the component that reduces the cell performance at subambient temperatures.

Thermal batteries are normally constructed using pressed-powder anode, separator, and cathode pellets (discs). However, parts less than 0.010” thick are difficult to press from the starting powders. The use of plasma spraying to deposit thin pyrite films onto a stainless steel substrate was examined as an alternative to pressed-powder cathodes. The electrodes were tested under isothermal conditions and constant-current discharge over a temperature range of 400°C to 550°C using a standard LiSi anode and a separator based on the LiCIKCI eutectic. The plasma-sprayed cathodes were also evaluated in similar 5-cell thermal batteries. Cells and batteries using pressed-powder cathodes were tested under the same conditions for comparative purposes.

Silica aerogels have 1/3 the thermal conductivity of the best commercial composite insulations, or ~13 mW/m-K at 25 °C. However, aerogels are transparent in the near IR region of 4-7 μm, which is where the radiation peak from a thermal-battery stack occurs. Titania and carbon-black powders were examined as thermal opacifiers, to reduce radiation at temperatures between 300°C and 600°C, which spans the range of operating temperature for most thermal batteries. The effectiveness of the various opacifiers depended on the loading, with the best overall results being obtained using aerogels filled with carbon black. Fabrication and strength issues still remain, however.

This paper describes a post-race analysis of team KOMMIT EVT’s electric motorcycle data collected during the 2016 Pikes Peak International Hill Climb (PPIHC). The motorcycle consumed approximately 4 kWh of battery energy with an average and maximum speed of 107 km/h and 149 km/h, respectively. It was the second fastest electric motorcycle with a finishing time of 11:10.480. Data was logged of the motorcycle’s speed, acceleration, motor speed, power, currents, voltages, temperatures, throttle position, GPS position, rider’s heart rate and the ambient environment (air temperature, pressure and humidity). The data was used to understand the following factors that may have prevented a faster time: physical fitness of the rider, thermal limits of the motor and controller, available battery energy and the sprocket ratio between the motor and rear wheel.

As a part of NASA’s efforts in space, options are being examined for an Artemis moon base project to be deployed. This project requires a system of interconnected, but separate, DC microgrids for habitation, mining, and fuel processing. This in-place use of power resources is called in-situ resource utilization (ISRU). These microgrids are to be separated by 9-12 km and each contains a photovoltaic (PV) source, energy storage systems (ESS), and a variety of loads, separated by level of criticality in operation. The separate microgrids need to be able to transfer power between themselves in cases where there are generation shortfall, faults, or other failures in order to keep more critical loads running and ensure safety of personnel and the success of mission goals. In this work, a 2 grid microgrid system is analyzed involving a habitation unit and a mining unit separated by a tie line.

Ground impact caused by road debris can result in very severe fire accident of Electric Vehicles (EV). In order to study the ground impact accidents, a Finite Element model of the battery pack structure is carefully set up according to the practical designs of EVs. Based on this model, the sequence of the deformation process is studied, and the contribution of each component is clarified. Subsequently, four designs, including three enhanced shield plates and one enhanced housing box, are investigated. Results show that the BRAS (Blast Resistant Adaptive Sandwich) shield plate is the most effective structure to decrease the deformation of the battery cells. Compared with the baseline case, which adopts a 6.35-mm-thick aluminum sheet as the shield plate, the BRAS can reduce the shortening of cells by more than 50%. Another type of sandwich structure, the NavTruss, can also improve the safety of battery pack, but not as effectively as the BRAS.