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Journal Article

Ash Effects on Diesel Particulate Filter Pressure Drop Sensitivity to Soot and Implications for Regeneration Frequency and DPF Control

2010-04-12
2010-01-0811
Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.
Journal Article

Characteristics and Effects of Lubricant Additive Chemistry on Ash Properties Impacting Diesel Particulate Filter Service Life

2010-04-12
2010-01-1213
Ash accumulation in diesel particulate filters, mostly from essential lubricant additives, decreases the filter's soot storage capacity, adversely affects fuel economy, and negatively impacts the filter's service life. While the adverse effects of ash accumulation on DPF performance are well known, the underlying mechanisms controlling these effects are not. To address these issues, results of detailed measurements with specially formulated lubricants, correlating ash properties to individual lubricant additives and their effects on DPF pressure drop, are presented. Investigations using the specially-formulated lubricants showed ash consisting primarily of calcium sulfates to exhibit significantly increased flow resistance as opposed to ash primarily composed of zinc phosphates. Furthermore, ash accumulated along the filer walls was found to be packed approximately 25% denser than ash accumulated in the channel end-plugs.
Journal Article

Analysis of Ash in Low Mileage, Rapid Aged, and High Mileage Gasoline Exhaust Particle Filters

2017-03-28
2017-01-0930
To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.
Journal Article

New Particulate Matter Sensor for On Board Diagnosis

2011-04-12
2011-01-0302
The reduction of greenhouse gas is becoming increasingly important for humankind, and vehicles with low CO₂ emissions have a part to play in any reduction initiatives. Diesel engines emit 30% less CO₂ than gasoline engines, so diesel engines will make an important contribution to the overall decrease. Unfortunately diesel exhaust gas contains particulate matter (PM) which may cause health problems, and such PM emissions are regulated by law. In order to reduce PM, especially soot, diesel particulate filters (DPFs) are widely fitted to diesel vehicles. A DPF can remove more than 99% by weight of soot from exhaust gas under normal operating conditions, and they are one of the most important methods to achieve any regulation targets. But if the system malfunctions, the PM emissions may exceed the regulation limit. To detect such PM leakage, on-board diagnostics (OBD) are required.
Journal Article

Sensitivity Analysis of Ash Packing and Distribution in Diesel Particulate Filters to Transient Changes in Exhaust Conditions

2012-04-16
2012-01-1093
Current CJ-4 lubricant specifications place chemical limits on diesel engine oil formulations to minimize the accumulation of lubricant-derived ash in diesel particulate filters (DPF). While lubricant additive chemistry plays a strong role in determining the amount and type of ash accumulated in the DPF, a number of additional factors play important roles as well. Relative to soot particles, whose residence time in the DPF is short-lived, ash particles remain in the filter for a significant fraction of the filter's useful life. While it is well-known that the properties (packing density, porosity, permeability) of soot deposits are primarily controlled by the local exhaust conditions at the time of particle deposition in the DPF, the cumulative operating history of the filter plays a much stronger role in controlling the properties and distribution of the accumulated ash.
Journal Article

In-Situ Optical Analysis of Ash Formation and Transport in Diesel Particulate Filters During Active and Passive DPF Regeneration Processes

2013-04-08
2013-01-0519
The formation and transport processes governing the build-up of incombustible ash deposits in diesel particulate filters (DPF) are influenced to a large extent by the filter's operating history. More specifically, the regeneration process, whether active, passive, or some variation of the two, has long been assumed to exert significant influence on the resulting ash characteristics. Until recently, only limited circumstantial evidence was available to describe differences in ash properties and distribution impacting DPF performance for filters subjected to different regeneration strategies. This work presents, for the first time, results from a comprehensive series of evaluations with optically-accessible DPF core samples showing the processes controlling the formation, transport, and interaction of the soot and ash deposits over a range of DPF regeneration conditions.
Journal Article

Ash Accumulation and Impact on Sintered Metal Fiber Diesel Particulate Filters

2015-04-14
2015-01-1012
While metal fiber filters have successfully shown a high degree of particle retention functionality for various sizes of diesel engines with a low pressure drop and a relatively high filtration efficiency, little is known about the effects of lubricant-derived ash on the fiber filter systems. Sintered metal fiber filters (SMF-DPF), when used downstream from a diesel engine, effectively trap and oxidize diesel particulate matter via an electrically heated regeneration process where a specific voltage and current are applied to the sintered alloy fibers. In this manner the filter media essentially acts as a resistive heater to generate temperatures high enough to oxidize the carbonaceous particulate matter, which is typically in excess of 600°C.
Journal Article

Development of New High Porosity Diesel Particulate Filter for Integrated SCR Technology/Catalyst

2015-04-14
2015-01-1017
Since the implementation of Euro 6 in September 2014, diesel engines are facing another drastic reduction of NOx emission limits from 180 to only 80 mg/km during NEDC and real driving emissions (RDE) are going to be monitored until limit values are enforced from September 2017. Considering also long term CO2 targets of 95 g/km beyond 2020, diesel engines must become cleaner and more efficient. However, there is a tradeoff between NOx and CO2 and, naturally, engine developers choose lower CO2 because NOx can be reduced by additional devices such as EGR or a catalytic converter. Lower CO2 engine calibration, unfortunately, leads to lower exhaust gas temperatures, which delays the activation of the catalytic converter. In order to overcome both problems, higher NOx engine out emission and lower exhaust gas temperatures, new aftertreatment systems will incorporate close-coupled DeNOx systems.
Technical Paper

Thick Film ZrO2 NOx Sensor for the Measurement of Low NOx Concentration

1998-02-01
980170
A practical ZrO2 NOx sensor using dual oxygen pumping cells has been introduced for the control of NOx emitted from a lean-burn gasoline engine and diesel engine.(1),(2). However, the measuring accuracy was not high enough to be useful for controlling or monitoring a low level of NOx concentration such as several tens ppm behind a three way catalyst or lean NOx catalyst which is NOx adsorption or De-NOx catalyst. This paper describes improvement of the interference effect of oxygen in the exhaust gas from the lean-burn gasoline engine and diesel engine. The cause of oxygen dependency is analyzed/revealed and a method of improvement is introduced. The improved NOx sensor has an approximately · · 2% measuring error in the wide range of oxygen concentration on a model gas system, compared to the · ·10% of the previous one.
Technical Paper

Filtration Behavior of Diesel Particulate Filters (2)

2007-04-16
2007-01-0923
Due to its better fuel efficiency and low CO2 emissions, the number of diesel engine vehicles is increasing worldwide. Since they have high Particulate Matter (PM) emissions, tighter emission regulations will be enforced in Europe, the US, and Japan over the coming years. The Diesel Particulate Filter (DPF) has made it possible to meet the tighter regulations and Silicon Carbide and Cordierite DPF's have been applied to various vehicles from passenger cars to heavy-duty trucks. However, it has been reported that nano-size PM has a harmful effect on human health. Therefore, it is desirable that PM regulations should be tightened. This paper will describe the influence of the DPF material characteristics on PM filtration efficiency and emissions levels, in addition to pressure drop.
Technical Paper

Modeling and Measurement of Tribological Parameters between Piston Rings and Liner in Turbocharged Diesel Engine

2007-04-16
2007-01-1440
This paper presents tribological modeling, experimental work, and validation of tribology parameters of a single cylinder turbocharged diesel engine run at various loads, speeds, intake boost pressures, and cylinder liner temperatures. Analysis were made on piston rings and liner materials, rings mechanical and thermal loads, contact pressure between rings and liner, and lubricant conditions. The engine tribology parameters were measured, and used to validate the engine tribology models. These tribology parameters are: oil film thickness, coefficient of friction between rings and liner, friction force, friction power, friction torque, shear rate, shear stress and wear of the sliding surfaces. In order to measure the oil film thickness between rings and liner, a single cylinder AVL turbocharged diesel engine was instrumented to accept the difference in voltage drop method between rings, oil film, and liner.
Technical Paper

Comparative Analysis of Automotive Powertrain Choices for the Next 25 Years

2007-04-16
2007-01-1605
This paper assesses the potential improvement of automotive powertrain technologies 25 years into the future. The powertrain types assessed include naturally-aspirated gasoline engines, turbocharged gasoline engines, diesel engines, gasoline-electric hybrids, and various advanced transmissions. Advancements in aerodynamics, vehicle weight reduction and tire rolling friction are also taken into account. The objective of the comparison is the potential of anticipated improvements in these powertrain technologies for reducing petroleum consumption and greenhouse gas emissions at the same level of performance as current vehicles in the U.S.A. The fuel consumption and performance of future vehicles was estimated using a combination of scaling laws and detailed vehicle simulations. The results indicate that there is significant potential for reduction of fuel consumption for all the powertrains examined.
Technical Paper

Oil Conditioning as a Means to Minimize Lubricant Ash Requirements and Extend Oil Drain Interval

2009-06-15
2009-01-1782
A novel approach to condition the lubricant at a fixed station in the oil circuit is explored as a potential means to reduce additive requirements or increase oil drain interval. This study examines the performance of an innovative oil filter which releases no additives into the lubricant, yet enhances the acid control function typically performed by detergent and dispersant additives. The filter chemically conditions the crankcase oil during engine operation by sequestering acidic compounds derived from engine combustion and lubricant degradation. Long duration tests with a heavy-duty diesel engine show that the oil conditioning with the strong base filter reduces lubricant acidity (TAN), improves Total Base Number (TBN) retention, and slows the rate of viscosity increase and oxidation. The results also indicate that there may be a reduction in wear and corrosion.
Technical Paper

Study on Next Generation Diesel Particulate Filter

2009-04-20
2009-01-0292
Although diesel engines are superior to gasoline engines in terms of the demand to reduce CO2 emissions, diesel engines suffer from the problem of emitting Particulate Matter (PM). Therefore, a Diesel Particulate Filter (DPF) has to be fitted in the engine exhaust aftertreatment system. From the viewpoint of reducing CO2 emissions, there is a strong demand to reduce the exhaust system pressure drop and for DPF designs that are able to help reduce the pressure drop. A wall flow DPF having a novel wall pore structure design for reducing pressure drop, increasing robustness and increasing filtration efficiency is presented. The filter offers a linear relationship between PM loading and pressure drop, offering lower pressure drop and greater accuracy in estimating the accumulated PM amount from pressure drop. First, basic experiments were performed on small plate test samples having various pore structure designs.
Technical Paper

Alcohol Fueled Heavy Duty Vehicles Using Clean, High Efficiency Engines

2010-10-25
2010-01-2199
Non-petroleum based liquid fuels are essential for reducing oil dependence and greenhouse gas generation. Increased substitution of alcohol fuel for petroleum based fuels could be achieved by 1) use in high efficiency spark ignition engines that are employed for heavy duty as well as light duty operation and 2) use of methanol as well as ethanol. Methanol is the liquid fuel that is most efficiently produced from thermo-chemical gasification of coal, natural gas, waste or biomass. Ethanol can also be produced by this process but at lower efficiency and higher cost. Coal derived methanol is in limited initial use as a transportation fuel in China. Methanol could potentially be produced from natural gas at an economically competitive fuel costs, and with essentially the same greenhouse gas impact as gasoline. Waste derived methanol could also be an affordable low carbon fuel.
Technical Paper

Dramatic Emissions Reductions with a Direct Injection Diesel Engine Burning Supercritical Fuel/Water Mixtures

2001-09-24
2001-01-3526
Research conducted at the Supercritical (SC) facility of MIT's Energy Laboratory provided visual confirmation of a single phase, homogeneous water/fuel mixture near the critical temperature and pressure of water. Equal volumes of water and diesel fuel were observed to be completely miscible, and high temperature polymerization of fuel molecules was not found. This is believed to be the first observation of a solution of diesel fuel and water. This mixture was subsequently burned under atmospheric spray conditions with very low NOx, smoke, CO, and HC. The results suggested that in-cylinder combustion in a compression ignition engine was warranted. Tests were conducted in a single cylinder, air-cooled, naturally aspirated, 3.5 horsepower Yanmar diesel engine. The compressibility of this new fuel composition necessitated a modified injector to provide smooth operation.
Technical Paper

Determination of Engine Cylinder Pressures from Crankshaft Speed Fluctuations

1992-02-01
920463
An experimental test of a non-contact method for determining simultaneously the pressure in each cylinder of a reciprocating engine is reported. The method exploits a pattern recognition technique to compare crankshaft speed fluctuations to reference patterns in a knowledge base. The crankshaft speed is measured by timing the passage of gear teeth on the engine's flywheel. The experiment was carried out on a Detroit Diesel Corporation 6V-92TA engine. The baseline operating condition was 75 percent rated load at 1200 rpm. The engine's six cylinders were individually under-fuelled from the baseline operating condition to achieve peak pressure reductions of 5 to 20 percent. The required reference angular velocity waveforms were obtained by measuring the effect of under-fuelling individual cylinders to reduce their peak pressures by 10 percent. The experimental results show that the method evaluates the cylinder pressures with an RMS error of less than 6 percent.
Technical Paper

Particle Number Emission Reduction for GDI Engines with Gasoline Particulate Filters

2017-10-08
2017-01-2378
In order to meet the challenging CO2 targets beyond 2020 despite keeping high performance engines, Gasoline Direct Injection (GDI) technology usually combined with charged aspiration is expanding in the automotive industry. While providing more efficient powertrains to reduce fuel consumption one side effect of GDI is the increased particle formation during the combustion process. For the first time for GDI from September 2014 there is a Particle Number (PN) limit in EU of 6x10 sup 12 #/km, which will be further reduced by one order of magnitude to 6x10 sup 11 #/km effective from September 2017 to be the same level as applied to Diesel engines. In addition to the PN limit of the certification cycle NEDC further certification of Real Driving Emissions (RDE) including portable PN measurements are under discussion by the European Commission. RDE test procedure requires stable and low emissions in a wide range of engine operations and durable over a distance of 160 000 km.
Technical Paper

High Porosity DPF Design for Integrated SCR Functions

2012-04-16
2012-01-0843
Diesel engines are more fuel efficient due to their high thermal efficiency, compared to gasoline engines and therefore, have a higher potential to reduce CO2 emissions. Since diesel engines emit higher amounts of Particulate Matter (PM), DPF systems have been introduced. Today, DPF systems have become a standard technology. Nevertheless, with more stringent NOx emission limits and CO2 targets, additional NOx emission control is needed. For high NOx conversion efficiency, SCR catalysts technology shows high potential. Due to higher temperature at the close coupled position and space restrictions, an integrated SCR concept on the DPFs is preferred. A high SCR catalyst loading will be required to have high conversion efficiency over a wide range of engine operations which causes high pressure for conventional DPF materials.
Technical Paper

Measurements of Gas Temperature in a HCCI Engine Using a Fourier Domain Mode Locking Laser

2006-04-03
2006-01-1366
Initial measurements of water vapor temperature using a Fourier domain mode locking (FDML) laser were performed in a carefully controlled homogenous charge compression ignition engine with optical access. The gas temperature was inferred from water absorption spectra that were measured each 0.25 crank angle degrees (CAD) over a range of 150 CAD. Accuracy was tested in a well controlled shock tube experiment. This paper will validate the potential of this FDML laser in combustion applications.
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