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Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

The effects of using neat FAME (Fatty Acid Methyl Ester) in a modern small displacement passenger car diesel engine have been evaluated in this paper. In particular the effects on engine performance at full load with standard (i.e., without any special tuning) ECU calibration were analyzed, highlighting some issues in the low end torque due to the lower exhaust gas temperatures at the turbine inlet, which caused a remarkable decrease of the available boost, with a substantial decrease of the engine torque output, far beyond the expected engine derating due to the lower LHV of the fuel. However, further tests carried out after ECU recalibration, showed that the same torque levels measured under diesel operation can be obtained with neat biodiesel too, thus highlighting the potential for maintaining the same level of performance.

The rotary engine provides high power density compared to piston engine, but one of its downside is higher oil consumption. In order to better understand oil transport, a laser induced fluorescence technique is used to visualize oil motion on the side of the rotor during engine operation. Oil transport from both metered oil and internal oil is observed. Starting from inside, oil accumulates in the rotor land during inward motion of the rotor created by its eccentric motion. Oil seals are then scraping the oil outward due to seal-housing clearance asymmetry between inward and outward motion. Cut-off seal does not provide an additional barrier to internal oil consumption. Internal oil then mixes with metered oil brought to the side of the rotor by gas leakage. Oil is finally pushed outward by centrifugal force, passes the side seals, and is thrown off in the combustion chamber.

An innovative quasi-dimensional multizone combustion model for the spray formation, combustion and emission formation analysis in DI diesel engines was assessed and applied to an optical single cylinder engine. The model, which has been recently presented by the authors, integrates a predictive non stationary 1D spray model developed by the Sandia National Laboratory, with a diagnostic multizone thermodynamic model. The 1D spray model is capable of predicting the equivalence ratio of the fuel during the mixing process, as well as the spray penetration. The multizone approach is based on the application of the mass and energy conservation laws to several homogeneous zones identified in the combustion chamber. A specific submodel is also implemented to simulate the dilution of the burned gases. Soot formation is modeled by an expression which derives from Kitamura et al.'s results, in which an explicit dependence on the local equivalence ratio is considered.

An innovative 0D predictive combustion model for the simulation of the HRR (heat release rate) in DI diesel engines was assessed and implemented in a 1D fluid-dynamic commercial code for the simulation of a Fiat heavy duty diesel engine equipped with a Variable Geometry Turbocharger system, in the frame of the CORE (CO2 reduction for long distance transport) Collaborative Project of the European Community, VII FP. The 0D combustion approach starts from the calculation of the injection rate profile on the basis of the injected fuel quantities and on the injection parameters, such as the start of injection and the energizing time, taking the injector opening and closure delays into account. The injection rate profile in turn allows the released chemical energy to be estimated. The approach assumes that HRR is proportional to the energy associated with the accumulated fuel mass in the combustion chamber.

An investigation has been carried out on the spray penetration and soot formation processes in a research diesel engine by means of a quasi-dimensional multizone combustion model. The model integrates a predictive non stationary 1D spray model developed by the Sandia National Laboratory, with a diagnostic multizone thermodynamic model, and is capable of predicting the spray formation, combustion and soot formation processes in the combustion chamber. The multizone model was used to analyze three operating conditions, i.e., a zero load point (BMEP = 0 bar at 1000 rpm), a medium load point (BMEP = 5 bar at 2000 rpm) and a medium-high load point (BMEP = 10 bar at 2000 rpm). These conditions were experimentally tested in an optical single cylinder engine with the combustion system configuration of a 2.0L Euro4 GM diesel engine for passenger car applications.

The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.

One of the key technologies for the improvement of the diesel engine thermal efficiency is the reduction of the engine heat transfer through the thermal insulation of the combustion chamber. This paper presents a numerical investigation on the effects of the combustion chamber insulation on the heat transfer, thermal efficiency and exhaust temperatures of a 1.6 l passenger car, turbo-charged diesel engine. First, the complete insulation of the engine components, like pistons, liner, firedeck and valves, has been simulated. This analysis has showed that the piston is the component with the greatest potential for the in-cylinder heat transfer reduction and for Brake Specific Fuel Consumption (BSFC) reduction, followed by firedeck, liner and valves. Afterwards, the study has been focused on the impact of different piston Thermal Barrier Coatings (TBCs) on heat transfer, performance and wall temperatures.

Natural gas is a promising alternative fuel for internal combustion engine application due to its low carbon content and high knock resistance. Performance of natural gas engines is further improved if direct injection, high turbocharger boost level, and variable valve actuation (VVA) are adopted. Also, relevant efficiency benefits can be obtained through downsizing. However, mixture quality resulting from direct gas injection has proven to be problematic. This work aims at developing a mono-fuel small-displacement turbocharged compressed natural gas engine with side-mounted direct injector and advanced VVA system. An injector configuration was designed in order to enhance the overall engine tumble and thus overcome low penetration.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.

Co-Optimization of Fuels and Engines initiative (Co-Optima) of the U.S Department of Energy started investigations on several candidates of biofuels and blends for internal combustion engines. At this stage, only a few biomass-derived fuel blendstocks (including ethanol) for advanced spark-ignition engines have been selected using enhanced screening criteria, which included boiling point, toxicity, research octane number, octane sensitivity, and economical distribution system, etc. Ethanol, of which this paper is focused on, is also an important fuel because of its high-octane number which in turn promotes advance ignition timing and higher thermal efficiencies in reciprocating engines. Measurements of laminar burning velocity (LBV) is a key metric to understand fuel performance and applicability in engines. Furthermore, in order to quantify more complicated, and practical, burning regimes such as turbulent combustion much of the underlying theory requires knowledge of LBV.

In this work different internal and external EGR strategies, combined with extreme Miller cycles, were analyzed by means of a one-dimensional CFD simulation code for a Wärtsilä 6-cylinder, 4-strokes, medium-speed marine diesel engine, to evaluate their potential in order to reach the IMO Tier 3 NOx emissions target. By means of extreme Miller cycles, with Early Intake Valve Closures (up to 100 crank angle degrees before BDC), a shorter compression stroke and lower charge temperatures inside the cylinder can be achieved and thanks to the cooler combustion process, the NOx-specific emissions can be effectively reduced. EIVC strategies can also be combined with reductions of the scavenging period (valve overlap) to increase the amount of exhaust gases in the combustion chamber. However, the remarkably high boost pressure levels needed for such extreme Miller cycles, require mandatorily the use of two-stage turbocharging systems.

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.

The fuel injection plays a crucial role in determining the mixture formation process in Gasoline Direct Injection (GDI) engines. Pollutant emissions, and soot emissions in particular, as well as phenomena affecting engine reliability, such as oil dilution and injector coking, are deeply influenced by the injection system features, such as injector geometric characteristics (such as injector type, injector position and targeting within the combustion chamber) and operating characteristics (such as injection pressure, injection phasing, etc.). In this paper, a new CFD methodology is presented, allowing a preliminary assessment of the mixture formation quality in terms of expected soot emissions, oil dilution and injector coking risks for different injection systems (such as for instance multihole or swirl injectors) and different injection strategies, from the early stages of a new engine design.

The effects of cooled exhaust gas recirculation (EGR) on a boosted direct-injection (DI) spark ignition (SI) engine operating at stoichiometric equivalence ratio, gross indicated mean effective pressure of 14-18 bar, and speed of 1500-2500 rpm, are studied under constant fuel condition at each operating point. In the presence of EGR, burn durations are longer and combustion is more retard. At the same combustion phasing, the indicated specific fuel consumption improves because of a decrease in heat loss and an increase in the specific heat ratio. The knock limited spark advance increases substantially with EGR. This increase is due partly to a slower combustion which is equivalent to a spark retard, as manifested by a retarded value of the 50% burn point (CA50), and due partly to a slower ignition chemistry of the diluted charge, as manifested by the knock limited spark advance to beyond the value offered by the retarded CA50.

A quasi-dimensional multizone combustion model, that was previously developed by the authors, has been refined and applied for the analysis of combustion and emission formation in a EURO V diesel engine equipped with a piezo indirect-acting injection system. The model is based on the integration of the predictive non-stationary variable-profile 1D spray model recently presented by Musculus and Kattke, with a diagnostic multizone thermodynamic model specifically developed by the authors. The multizone approach has been developed starting from the Dec conceptual scheme, and is based on the identification of several homogeneous zones in the combustion chamber, to which mass and energy conservation laws have been applied: an unburned gas zone, made up of air, EGR (Exhaust Gas Recirculation) and residual gas, several fuel/unburned gas mixture zones, premixed combustion burned gas zones and diffusive combustion burned gas zones.

This article reports on the potential of negative valve overlap (NVO) for improving the net indicated thermal efficiency (η NIMEP) of gasoline engines during part load. Three fixed fuel flow rates, resulting in indicated mean effective pressures of up to 6 bar, were investigated. At low load, NVO significantly reduces the pumping loses during the gas exchange loop, achieving up to 7% improvement in indicated efficiency compared to the baseline. Similar efficiency improvements are achieved by positive valve overlap (PVO), with the disadvantage of worse combustion stability from a higher residual gas fraction (xr). As the load increases, achieving the wide-open throttle limit, the benefits of NVO for reducing the pumping losses diminish, while the blowdown losses from early exhaust valve opening (EVO) increase.

The biofuel and engine co-development framework was initiated at Sandia National Labs. Here, the synthetic biologists develop and engineer a new platform for drop-in fuel production from lignocellulosic biomass, using several endophytic fungi. Hence this process has the potential advantage that expensive pretreatment and fuel refining stages can be optimized thereby allowing scalability and cost reduction; two major considerations for widespread biofuel utilization. Large concentrations of ketones along with other volatile organic compounds were produced by fungi grown over switchgrass media. The combustion and emission properties of these new large ketones are poorly known.

The 2,4-dimethyl-3-pentanone (DIPK) is a promising biofuel candidate for automotive applications that is produced by the endophytic fungal conversion process which can be optimized for widespread utilization. There are some studies in the literature on combustion properties of DIPK, such as ignition delay times and laminar burning velocity (LBV) measurements. However, most studies are conducted one atmospheric (atm) pressure which are far away from the high-pressure conditions present inside reciprocating engines. Therefore, we present LBV measurements at high pressures up to 10 atm for this fuel using a spherical flame speed facility. It is known that the flame in a constant volume chamber develops cellular structure (hydrodynamic instability) as the initial pressure increases because of the reduction in flame thickness. In addition, the diffusional-thermal instability prevents experiments for rich mixtures because of the reduction of Lewis number (Le).