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Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.

Rare earths are a group of elements whose availability has been of concern due to monopolistic supply conditions and environmentally unsustainable mining practices. To evaluate the risks of rare earths availability to automakers, a first step is to determine raw material content and value in vehicles. This task is challenging because rare earth elements are used in small quantities, in a large number of components, and by suppliers far upstream in the supply chain. For this work, data on rare earth content reported by vehicle parts suppliers was assessed to estimate the rare earth usage of a typical conventional gasoline engine midsize sedan and a full hybrid sedan. Parts were selected from a large set of reported parts to build a hypothetical typical mid-size sedan. Estimates of rare earth content for vehicles with alternative powertrain and battery technologies were made based on the available parts' data.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

The fuel energy consumption of subsonic air transportation is examined. The focus is on identification and quantification of fundamental engineering design tradeoffs which drive the design of subsonic tube and wing transport aircraft. The sensitivities of energy efficiency to recent and forecast technology developments are also examined.

A rotating spacecraft which encloses an atmospheric pressure vessel poses unique challenges for thermal control. In any given location, the artificial gravity vector is directed from the center to the periphery of the vehicle. Its local magnitude is determined by the mathematics of centripetal acceleration and is directly proportional to the radius at which the measurement is taken. Accordingly, we have a system with cylindrical symmetry, featuring microgravity at its core and increasingly strong gravity toward the periphery. The tendency for heat to move by convection toward the center of the craft is one consequence which must be addressed. In addition, fluid flow and thermal transfer is markedly different in this unique environment. Our strategy for thermal control represents a novel approach to address these constraints. We present data to theoretically and experimentally justify design decisions behind the Mars Gravity Biosatellite's proposed payload thermal control subassembly.

This paper assesses the potential improvement of automotive powertrain technologies 25 years into the future. The powertrain types assessed include naturally-aspirated gasoline engines, turbocharged gasoline engines, diesel engines, gasoline-electric hybrids, and various advanced transmissions. Advancements in aerodynamics, vehicle weight reduction and tire rolling friction are also taken into account. The objective of the comparison is the potential of anticipated improvements in these powertrain technologies for reducing petroleum consumption and greenhouse gas emissions at the same level of performance as current vehicles in the U.S.A. The fuel consumption and performance of future vehicles was estimated using a combination of scaling laws and detailed vehicle simulations. The results indicate that there is significant potential for reduction of fuel consumption for all the powertrains examined.

Battery packs for Hybrids, Plug-in Hybrids, and Electric Vehicles are assembled from a system of modules (sheets) with a tight sheet metal casing around them. Each module consists of an array of individual cells which vary in the composition of electrodes and separator from one manufacturer to another. In this paper a general procedure is outlined on the development of a constitutive and computational model of a cylindrical cell. Particular emphasis is placed on correct prediction of initiation and propagation of a tearing fracture of the steel can. The computational model correctly predicts rupture of the steel can which could release aggressive chemicals, fumes, or spread the ignited fire to the neighboring cells. The initiation site of skin fracture depends on many factors such as the ductility of the casing material, constitutive behavior of the system of electrodes, and type of loading.

In order to satisfy tightening global emissions regulations, diesel truck manufacturers are striving to meet increasingly stringent Oxides of Nitrogen (NOx) reduction standards. The majority of heavy duty diesel trucks have integrated urea SCR NOx abatement strategies. To this end, aftertreatment systems need to be properly engineered to achieve high conversion efficiencies. A EuroV intent urea SCR system is evaluated and failed to meet NOx conversion targets with severe urea deposit formation. Systematic enhancements of the design have been performed to enable it to meet targets, including emission reduction efficiency via improved reagent mixing, evaporation, distribution, back pressure, and removing of urea deposits. Multiple urea mixers, injector mounting positions and various system layouts are developed and evaluated, including both CFD analysis and full scale laboratory tests.

With increasing applications of urea SCR for NOx emission reduction, improving the system performance and durability has become a high priority. A typical urea SCR system includes a urea injector, injector housing, mixer, and appropriate pipe configurations to allow continuous urea injection into the exhaust stream and evaporation of urea solution into gaseous products. Continuous operation at various conditions with high NOx reduction is possible, but one problem that threatens the life and performance of these systems is urea deposit. When urea or its byproducts become deposited on the inner surfaces of the system including walls, mixers, injector housings and substrates it can create concerns of backpressure and material deteriorations. In addition, deposits as a waste of reagents can negatively affect engine operation, emissions performance and DEF economy. Urea deposit behavior is explored in terms of heat transfer, pipe geometry, injector layout and mixing mechanisms.

The transportation sector in the United States is a major contributor to global energy consumption and carbon dioxide emission. To assess the future potentials of different technologies in addressing these two issues, we used a family of simulation programs to predict fuel consumption for passenger cars in 2020. The selected technology combinations that have good market potential and could be in mass production include: advanced gasoline and diesel internal combustion engine vehicles with automatically-shifting clutched transmissions, gasoline, diesel, and compressed natural gas hybrid electric vehicles with continuously variable transmissions, direct hydrogen, gasoline and methanol reformer fuel cell hybrid electric vehicles with direct ratio drive, and battery electric vehicle with direct ratio drive.

Determining the fundamental role of gravity in vital biological systems in space is one of six science and research areas that provides the philosophical underpinning for why NASA exists. The study of cells, tissues, and microorganisms in a spaceflight environment holds the promise of answering multiple intriguing questions about how gravity affects living systems. To enable these studies, specimens must be maintained in an environment similar to that used in a laboratory. Cell culture studies under normal laboratory conditions involve maintaining a highly specialized environment with the necessary temperature, humidity control, nutrient, and gas exchange conditions. These same cell life support conditions must be provided by the International Space Station (ISS) Cell Culture Unit (CCU) in the unique environment of space. The CCU is a perfusion-based system that must function in microgravity, at unit gravity (1g) on earth, and from 0.1g up to 2g aboard the ISS centrifuge rotor.

The US Air Force (USAF) has evolved a policy for the acquisition of fighter jet engines (FJE). In the 1970s and 1980s that policy placed a premium on FJE performance primarily measured by the metric: thrust/engine weight. In the 1990s, the USAF policy changed from an emphasis on performance to reduced life-cycle cost with a premium on sustainment. This paper reports the results of a study of how the USAF and Corporation Alpha (Alpha) have adapted their processes, practices, and policies to design, develop, manufacture, test, and sustain a family of FJEs. Each member of the family of FJEs is sequentially linked relative to insertion of technology designed to reduce sustainment costs. In addition to the technology linkages, the development of the family of FJEs selected for this case study is also tracked relative to US Department of Defense and USAF policy and industry design, build, and maintain processes, methods, and tools.

To meet EPA Tier IV large diesel engine emission targets, intensive development efforts are necessary to achieve NOx reduction and Particulate Matter (PM) reduction targets [1]. With respect to NOx reduction, liquid urea is typically used as the reagent to react with NOx via SCR catalyst [2]. Regarding to PM reduction, additional heat is required to raise exhaust temperature to reach DPF active / passive regeneration performance window [3]. Typically the heat can be generated by external diesel burners which allow diesel liquid droplets to react directly with oxygen in the exhaust gas [4]. Alternatively the heat can be generated by catalytic burners which enable diesel vapor to react with oxygen via DOC catalyst mostly through surface reactions [5].

It is important to quantitatively characterize the automotive events in order to not only accurately interpret their past but also to reliably predict and forecast their short-term, medium-term, and even long-term future. In this paper, several automotive industry related events, i.e. vehicle safety, vehicle weight/HP ratio, the emissions of CO2, HC, CO, and NOx, are analyzed to find their general trends. Exponential and power law functions are used to empirically fit and quantitatively characterize these data with an emphasis on the two functions’ effectiveness in predictability. Finally, three empirical emission laws based on the historical HC, CO, and NOx data are proposed and the impact of these laws on emission control is discussed.

Higher compression ratio and turbocharging, with engine downsizing can enable significant gains in fuel economy but require engine operating conditions that cause engine knock under high load. Engine knock can be avoided by supplying higher-octane fuel under such high load conditions. This study builds on previous MIT papers investigating Octane-On-Demand (OOD) to enable a higher efficiency, higher-boost higher compression-ratio engine. The high-octane fuel for OOD can be obtained through On-Board-Separation (OBS) of alcohol blended gasoline. Fuel from the primary fuel tank filled with commercially available gasoline that contains 10% by volume ethanol (E10) is separated by an organic membrane pervaporation process that produces a 30 to 90% ethanol fuel blend for use when high octane is needed. In addition to previous work, this paper combines modeling of the OBS system with passenger car and medium-duty truck fuel consumption and octane requirements for various driving cycles.

In today's competitive market, noise and vibration are among the most important parameters that impact the success of a vehicle. In body-on-frame construction vehicles, elastomeric body mounts play a major role in isolating the passenger compartment from road noise, harshness, shake, and other vibrations in the chassis as well as improving ride quality across a wide frequency range. This paper describes the work carried out to design a fluid filled mount with high lateral stiffness that can alter the perceived Noise, Vibration and Harshness (NVH) performance of current production body-on-frame trucks. It was found that the quietness and ride qualities can be significantly improved by positioning the glycol-filled mounts at the anti-node of the frame first vertical bending mode; under the C-pillar intersection with the frame. The performance of mounts in this area is known to be critical to ride quality.

To meet the 2010 diesel engine emission regulations, an aftertreatment system was developed to reduce HC, CO, NOx and soot. In NOx reduction, a baseline SCR module was designed to include urea injector, mixing decomposition tube and SCR catalysts. However, it was found that the baseline decomposition tube had unacceptable urea mixing performance and severe deposit issues largely because of poor hardware design. The purpose of this article is to describe necessary development work to improve the baseline system to achieve desired mixing targets. To this end, an emissions Flow Lab and computational fluid dynamics were used as the main tools to evaluate urea mixing solutions. Given the complicated urea spray transport and limited packaging space, intensive efforts were taken to develop pre-injector pipe geometry, post-injector cone geometry, single mixer design modifications, and dual mixer design options.

Long-haul and other heavy-duty trucks, presently almost entirely powered by diesel fuel, face challenges meeting worldwide needs for greatly reducing nitrogen oxide (NOx) emissions. Dual-fuel gasoline-alcohol engines could potentially provide a means to cost-effectively meet this need at large scale in the relatively near term. They could also provide reductions in greenhouse gas emissions. These spark ignition (SI) flexible fuel engines can provide operation over a wide fuel range from mainly gasoline use to 100% alcohol use. The alcohol can be ethanol or methanol. Use of stoichiometric operation and a three-way catalytic converter can reduce NOx by around 90% relative to emissions from diesel engines with state of the art exhaust treatment.

Two critical milestones that must be achieved during concept design are 1) definition of a product architecture that meets performance, producibility, and strategic objectives, and 2) estimation of the integration risk in each candidate concept. This paper addresses these issues by describing the role played by the producibility members of an Integrated Product Team (IPT) during concept design. Our focus is on the execution of the what we call the “chain method”, which illustrates the structure of function delivery in a concept in a simple pictorial way and helps the IPT to understand the advantages or disadvantages of using a modular or an integral product architecture. The producibility members play a central role in capturing and evaluating the chains for different candidate concepts and decompositions.