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Well-mixed lean SI engine operation can provide improvements of the fuel economy relative to that of traditional well-mixed stoichiometric SI operation. This work examines the use of two methods for improving the stability of lean operation, namely multi-pulse transient plasma ignition and intake air preheating. These two methods are compared to standard SI operation using a conventional high-energy inductive ignition system without intake air preheating. E85 is the fuel chosen for this study. The multi-pulse transient plasma ignition system utilizes custom electronics to generate 10 kHz bursts of 10 ultra-short (12ns), high-amplitude pulses (200 A). These pulses were applied to a custom spark plug with a semi-open ignition cavity. High-speed imaging reveals that ignition in this cavity generates a turbulent jet-like early flame spread that speeds up the transition from ignition to the main combustion event.

It is well known that ultra-lean combustion can result in higher thermal efficiency, better fuel economy, and greatly reduced NOx emissions. Accomplishing ultra-lean combustion is very difficult with a conventional spark plug, and ignition instability can be cited as one of the factors. Therefore, it is thought that ignition system innovation is important for the achievement of ultra-lean combustion in gasoline engines. This study investigated high-speed plasma ignition as a new ignition system for internal combustion engines. High-speed plasma refers to the transient (non-equilibrated) phase of plasma before formation of an arc discharge; it is obtained by applying high voltage with an ultra-short pulse between coaxial cylindrical electrodes. High-speed plasma can inherently form a multi-channel discharge, with the electrical discharge spreading over a much larger volume than a spark discharge does.

In February 2004 NASA released “The Vision for Space Exploration.” The important goals outlined in this document include extending human presence in the solar system culminating in the exploration of Mars. Unprocessed waste poses a biological hazard to crew health and morale. The waste processing methods currently under consideration include incineration, microbial oxidation, pyrolysis and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this project is to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. In the Phase I project, TDA Research, Inc. demonstrated the potential of a low temperature oxidation process using ozone. In the current Phase II project, TDA and NASA Ames Research Center are developing a pilot scale low temperature ozone oxidation system.

The development of surrogate mixtures that represent gasoline combustion behavior is reviewed. Combustion chemistry behavioral targets that a surrogate should accurately reproduce, particularly for emulating homogeneous charge compression ignition (HCCI) operation, are carefully identified. Both short and long term research needs to support development of more robust surrogate fuel compositions are described. Candidate component species are identified and the status of present chemical kinetic models for these components and their interactions are discussed. Recommendations are made for the initial components to be included in gasoline surrogates for near term development. Components that can be added to refine predictions and to include additional behavioral targets are identified as well. Thermodynamic, thermochemical and transport properties that require further investigation are discussed.

Of the many competing technologies for resource recovery from solid wastes for long duration manned missions such as a lunar or Mars base, incineration technology is one of the most promising and certainly the most well developed in a terrestrial sense. Various factors are involved in the design of an optimum fluidized bed incinerator for inedible biomass. The factors include variability of moisture in the biomass, the ash content, and the amount of fuel nitrogen in the biomass. The crop mixture in the waste will vary; consequently the nature of the waste, the nitrogen content, and the biomass heating values will vary as well. Variation in feed will result in variation in the amount of contaminants such as nitrogen oxides that are produced in the combustion part of the incinerator. The incinerator must be robust enough to handle this variability. Research at NASA Ames Research Center using the fluidized bed incinerator has yielded valuable data on system parameters and variables.

Kantor model showing that prior-cycle effects resulting from exhaust gas residuals are a significant factor in cyclic variability of combustion in IC engines is due to a number of model assumptions that misrepresent the thermodynamic process experienced by the mixture of fresh combustible gas plus exhaust residual in important ways. In particular we show that exhaust blowdown process and variable exhaust residual gas mass fraction, neglected in the Kantor model, significantly reduce cyclic variability. However, unburned fuel not considered in the Kantor model apparently aggravates cyclic variability. These three factors cancel each other resulting in cyclic variation appeased. Using modified Kantor models, we examine the effects of all major engine operating parameters on mean and fluctuating exhaust residual temperature and indicated work. No significant cyclic variability is predicted for realistic ranges of these parameters.

Pyrolysis is a very versatile waste processing technology which can be tailored to produce a variety of solid liquid and/or gaseous products. The main disadvantages of pyrolysis processing are: (1) the product stream is more complex than for many of the alternative treatments; (2) the product gases cannot be vented directly into the cabin without further treatment because of the high CO concentrations. One possible solution is to combine a pyrolysis step with catalytic oxidation (combustion) of the effluent gases. This integration takes advantage of the best features of each process, which is insensitivity to product mix, no O2 consumption, and batch processing, in the case of pyrolysis, and simplicity of the product effluent stream in the case of oxidation. In addition, this hybrid process has the potential to result in a significant reduction in Equivalent System Mass (ESM) and system complexity.

Pyrolysis is a technology that can be used on future space missions to convert wastes to an inert char, water, and gases. The gases can be easily vented overboard on near term missions. For far term missions the gases could be directed to a combustor or recycled. The conversion to char and gases as well as the absence of a need for resupply materials are advantages of pyrolysis. A major disadvantage of pyrolysis is that it can produce tars that are difficult to handle and can cause plugging of the processing hardware. By controlling the heating rate of primary pyrolysis, the secondary (cracking) bed temperature, and residence time, it is possible that tar formation can be minimized for most biomass materials. This paper describes an experimental evaluation of two versions of pyrolysis reactors that were delivered to the NASA Ames Research Center (ARC) as the end products of a Phase II and a Phase III Small Business Innovation Research (SBIR) project.

Pyrolysis is a very versatile waste processing technology which can be tailored to produce a variety of solid, liquid, and/or gaseous products. The main disadvantages of pyrolysis processing are: (1) the product stream is more complex than for many of the alternative treatments; (2) the product gases cannot be vented directly into the cabin without further treatment because of the high CO concentrations. One possible solution is to combine a pyrolysis step with catalytic oxidation (combustion) of the effluent gases. This integration takes advantage of the best features of each process. The advantages of pyrolysis are: insensitivity to feedstock composition, no oxygen consumption, and batch operation. The main advantage of oxidation is the simplicity and consistency of the product stream. In addition, this hybrid process has the potential to result in a significant reduction in Equivalent System Mass (estimated at 10-40%) and system complexity.

In February 2004 NASA released “The Vision for Space Exploration.” The goals outlined in this document include extending the human presence in the solar system, culminating in the exploration of Mars. A key requirement for this effort is to identify a safe and effective method to process waste. Methods currently under consideration include incineration, microbial oxidation, pyrolysis, drying, and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this work is to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. Previously, TDA Research, Inc. demonstrated the potential of a low temperature dry oxidation process using ozone in a small laboratory reactor.