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This session focuses on particle emissions from combustion engines, including measurement methods and fuel effects. Presenter Leonidas D. Ntziachristos, Aristotle University Thessaloniki

The reduction of greenhouse gas is becoming increasingly important for humankind, and vehicles with low CO₂ emissions have a part to play in any reduction initiatives. Diesel engines emit 30% less CO₂ than gasoline engines, so diesel engines will make an important contribution to the overall decrease. Unfortunately diesel exhaust gas contains particulate matter (PM) which may cause health problems, and such PM emissions are regulated by law. In order to reduce PM, especially soot, diesel particulate filters (DPFs) are widely fitted to diesel vehicles. A DPF can remove more than 99% by weight of soot from exhaust gas under normal operating conditions, and they are one of the most important methods to achieve any regulation targets. But if the system malfunctions, the PM emissions may exceed the regulation limit. To detect such PM leakage, on-board diagnostics (OBD) are required.

When truck tires have a deformation such as radial runout, flat spot, and abnormal wear as a result of panic braking, they affect vehicle vibration in the form of displacement input whose spectrum involves higher order terms of tire revolution. While a truck has vibration modes of frame bending as well as pitching and unsprung-mass viberation in the input frequency range, the tire displacement input induces vehicle vibration as a combination of these modes. Results of calculations and experiments of a 4x2 medium-duty truck are analyzed and an example of means for improving ride comfort is described in this paper.

In order to meet increasing demands for safety and comfort in a vehicle compartment, automatic adjustment of seat, mirrors, steering wheel has been developed. The multiplex wiring system was constructed for the automatic adjustment of the cockpit elements to drivers preferred positions or to physique-matched settings based on ergonomic data. This paper describes the construction of the multiplex system and functions of automatic adjustment of the cockpit elements for comfortable driving position and better visibility.

Beta Ti alloy valve spring retainers are newly developed for use in mass produced automobiles for the first time. Ti alloy valve spring retainers vith a weight saving of 42%, compared to steel retainers, have reduced the inertial weight of the valve train components by 6%. And this weight reduction has the benefit of increasing the upper limit of the engine speed, which improves the engine performance. Ti alloy valve spring retainers are cold forged by the conventional fabrication facilities for steel retainers, using Ti-22V-4Al (the beta Ti alloy) which possesses excellent cold workability in a solution treated condition. Oxygen surface hardening is applied to protect Ti alloy valve spring retainers from wear damage. In addition, aging treatment and shot blasting are performed to improve strength and stiffness of valve retainers.

Austempered ductile iron (ADI) is a material having excellent mechanical properties and damping capacity. However practical mass production of ADI gears has not been possible due to ADI's poor machinability and distortion during the austempering heat treatment. With a new process method of carrying out hobbing before austempering when the material is in its soft condition, then austempering it and lastly, conducting the shave finishing process, we have diminished the above defects and developed practical ADI gears. These new gears generate less noise than ordinary nitrocarburized steel gears and are superior in pitting resistance.

This paper describes the calculative verification of the effect of the right-and-left torque vectoring system in various types of drivetrain, namely, the front wheels only, the rear wheels only, and both front and rear wheels in FWD, RWD, and AWD vehicles. The effect is evaluated by calculating the vehicle dynamics limit; maximum acceleration and cornering ability. The right-and-left vectoring torque, which is needed for expanding the vehicle dynamics limit, is also calculated. And finally, the paper evaluates the suitable wheels for which the system should be applied in each drivetrain. The application to the front wheels is more effective for FWD vehicles. On the other hand, the application to the rear wheels is more effective for RWD and AWD vehicles.

Several different steel sheets were tested for energy absorption, using hat square columns and dynamic crash testing. Results indicate that steel sheets containing large volume fraction of retained austenite have relatively high energy absorption. The relationship between retained austenite and energy absorption was analyzed. These special steel sheets have already been successfully used for production body parts, such a front-side-member, without difficulties arising in volume production.

Ceramic honeycomb wall flow diesel particulate filters (DPF) have been investigated for use in exhaust gas control of diesel vehicles. However, before they can be used, prevention of thermal shock failure during combustion regeneration is necessary. Studies were conducted on thermal shock failures on 9-inch diameter large volume DPF during regeneration by finite element analyses (FEA). These studies reveal that, within safe limits, maximum thermal stress is almost constant even at different gas flow rates and oxygen concentrations. Regeneration tests were also conducted on large volume DPF of several materials having different pore size distributions. FEA thermal stress was compared with mechanical strength of the material at safe levels.

This paper describes a calculating method to predict the quasi-static collapsing behaviors of spot-welded closed-hat section curved beams under axial compression. The overall deformat ions and the local buckling modes of beams were calculated using a geometrical model. Force-displacement relations were predicted by a elastic-plastic structural analysis method using the ‘plastic hinge’ concept. Collapsing tests were made on beams which are differenting section size, rotation angle, and metal sheet thickness. Comparisons between the calculated and experimental results of deformed shapes of beams, the local buckling modes and the force displacement relations are discussed.

The authors developed, for use in diesel engines, ceramic tappets cast in aluminum alloy that drastically improved wear resistance and valve train dynamics. The ceramic tappets consist of two parts: a ceramic head, which contacts the cam and push rod, and a tappet body made of aluminum alloy. Concerning the ceramic, silicon nitride was the best material of the three ceramics evaluated in the tests and the sliding surface, in contact with the cam and push rod, was left unground. As for the aluminum alloy, hyper-eutectic aluminum-silicon alloy with a controlled pro-eutectic silicon size was selected. A reliability analysis using the finite-element method (FEM) was also made on the structure of the ceramic tappet for enhanced durability and reliability. The combination of this tappet and a cam made of hardened ductile cast iron, hardened steel, or chilled cast iron, respectively exhibits excellent wear resistance.

Ceramic honeycombs have been used as automotive catalyst supports in US, Japan, Europe and other highly urbanized countries. Now, engine output is a great concern for automanufacturers, and reduction of the wall thickness of honeycomb substrates became indespensable for maintenance of gas flow restriction to a certain low level. To reduce wall thickness, material should be strong to maintain canning strength of substrates. Mechanical strength was improved with high density cordierite. However, isostatic strength of whole substrates was still insufficient with reduced thin walls for canning in spite of the material's high mecanical strength. Discussion is carried out on further possibility of improving canning performance of thin wall substrates as well as flow restriction, and warm up characteristics.

Vulcanized rubber hoses are difficult to recycle and have a complicated manufacturing process. Recently, we have developed the vacuum hose for engine control out of thermoplastic elastomers. As a result of this development, scrap material from the manufacturing process can be recycled and, in addition, about a 30 percent weight reduction and a 20 percent cost reduction are achievable by virtue of the lower specific gravity and by the more simplified manufacturing process. In order to assess the feasibility of using thermoplastic elastomers for vacuum hoses, we developed a heat aging simulation test method. This was achieved by first investigating the actual vehicle environmental conditions of currently used vacuum hoses by retrieving and examining these hoses from used vehicles. We then extrapolated what the condition of such hoses would be after being subjected to heat aging for 200,000 km of service in an actual vehicle, and applied this calculation to our newly developed hoses.

Among the durability items of the DPF (Diesel Particulate Filter), high accumulated soot mass limit is important for the low fuel consumption and also for the robustness. In case of catalyzed DPF, it depends on the following two properties during soot regeneration. One is the lower maximum-temperature inside of the DPF during usual regeneration in order to preserve the catalyst performance. The other is the higher thermal resistance against the unusual regeneration of excess amount of soot. This paper presents the improvement in the soot mass limit of Si bonded SiC DPF. Maximum-temperature inside of the DPF was lowered by the improvement of thermal conductivity of the material, resulted from the controlling of the microstructure. Additionally the thermal resistance was improved by the surface treatment of the Si and SiC.

Modern filter systems allow a significant reduction of diesel particulate emissions. The new silicon bonded silicon carbide particulate filters (Si-SiC filters) play an important role in this application, because they provide flexibility in terms of mean pore size and porosity and also have a high thermal shock capability to meet both engineering targets and emission limits for 2005 and beyond. Particulate filters are exposed to high temperatures and a harsh chemical environment in the exhaust gas of diesel vehicles. This paper will present further durability evaluation results of the new Si bonded SiC particulate filters which have been collected in engine bench tests and vehicle durability runs. The Si-SiC filters passed both 100 and 200 regeneration cycles under severe ageing conditions and without any problems. The used filters were subjected to a variety of analytical tests. The back pressure and ash distribution were determined. The filter material was also analysed.

Further stringent emission legislation requires advanced technologies, such as sophisticated engine management and advanced catalyst and substrate to achieve high catalytic performance, especially during the light-off phase. This paper presents the results of calculations and measurements of hydrocarbon and carbon monoxide light-off performance for substrates of different wall thickness, cell density and cell shapes. The experimental data from catalyst light-off testing on an engine dynamometer are compared with theoretical results of computer modeling under different temperature ramps and flow rates. The reaction kinetics in the computer modeling are derived from the best fit for the performance of conventional ceramic substrate (6mil/400cpsi), by comparing the theoretical and experimental results on both HC and CO emissions. The calibrated computer model predicts the effects of different wall thickness, cell density and cell shape.

The future emission limits for gasoline fuelled passenger cars require more and more efficient exhaust gas aftertreatment devices - the catalytic converter being one essential part of the complex system design. The present paper summarizes the results of several basic research programs putting major emphasis on the application of highly sophisticated three-way catalyst technologies being taylored for the utilization on ultra thin-wall ceramic substrates. In the first part of the investigation the following effects were examined in detail: Different washcoat loadings at constant PGM-loadings Different volumes of catalysts for constant amounts of PGM and washcoat Similar washcoat technologies at different ratios of WC-loading to precious metal concentration in the washcoat.

A computational model which describes the combustion and heat transfer that takes place during forced regeneration of honeycomb structured wall flow type diesel particulate filter was developed. In this model, heat released by the soot- oxygen reaction, convection heat transfer in the gas phase, conductive heat transfer in solid walls, and heat transfer between the gas and wall of each honeycomb cell at various radial positions in a filter are calculated. Each honeycomb cell was modeled as one solid phase and two gas phases and these three phases were divided in the axial direction into small elements. Conductive heat transfer between the small solid elements and convection heat transfer between the small gas elements were calculated for each small time increment. Conductive radial heat transfer between honeycomb cells was also calculated.

A characteristic mechanism of in-cylinder combustion is “time-domain mixing” which mixes up unburned gas, products in the different stages of combustion process, and burned gas, by “eddy”, a flow component with its scales of several to 10 mm. It seems to play a role in completing the combustion. Now that direct injection is a central engine technology, a keyword to combustion control is “freedom of mixing”, that is, no restriction on mixture formation, realized by direct injection. Various kinds of combustion control technologies utilizing it, have been presented. After combustion control for a premixed leanburn gasoline engine, and a direct injection gasoline engine, was achieved by turbulence control, and mixing control, respectively, the next target of combustion control will be ignition control. It will be possible, by controlling some boundary condition on combustion and fuel chemistry. Time-domain mixing and freedom of mixing will support it.

NOx adsorber has already been used for the after-treatment system of series production vehicle installed with a lean burn or direct injection engine [1,2,3]. In order to improve NOx adsorbability at high temperatures, many researchers have recently been trying an addition of potassium (K) as well as other conventional NOx adsorbents. Potassium, however, reacts easily with the cordierite honeycomb substrate at high temperatures, and not only causes a loss in NOx adsorbability but also damages the substrate. Three new technologies have been proposed in consideration of the above circumstances. First, a new concept of K-capture is applied in washcoat design, mixed with zeolite, to improve thermal stability of K and to keep high NOx conversion efficiency, under high temperatures, of NOx adsorber catalyst. Second, another new technology, pre-coating silica over the boundary of a substrate and washcoat, is proposed to prevent the reaction between potassium and cordierite.