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This paper describes an exhaust system using a new air-fuel ratio (hereinafter, A/F) sensor that contributes to low emissions and low fuel consumption of gasoline engines. As the first technical feature, the water splash resistance of the A/F sensor has been substantially improved which allows A/F control to be enabled without delay during engine cold start. To realize this capability, it is important that the sensor characteristics are not affected by the condensed water generated in the exhaust pipe. Therefore, a technique that has the effectiveness of a water splash resistance layer with water repellent function is demonstrated. As the second technical feature, the power consumption of the sensor has been substantially reduced. This is achieved by improving thermal efficiency of the sensor that the element can be activated at a low temperature.

In recent years, catalyst systems such as a lean NOx trap (LNT) catalyst system and a urea selective catalytic reduction (SCR) system have been developed to obtain cleaner diesel emissions. At Nissan, we developed an emission control system for meeting Tier 2 Bin 5 requirements in 2003. On the basis of that technology, a new HC-NOx trap catalyst system has now been developed that complies with the SULEV standards without increasing the catalyst volume and precious metal loading. Compliance with the SULEV standards requires a further reduction of HC (NMHC) emissions by 84% and NOx by 60% compared with the emission performance Tier 2 Bin 5 compliant catalyst system. Consequently high conversion performance for both HCs and NOx is needed. An investigation of HC emission behavior under the FTP75 mode showed that a reduction of cold-phase HCs was critical for meeting the standard. Large quantities of HCs above C4 are emitted in the cold state.

To meet future stringent emission regulations such as Euro6, the design and control of diesel exhaust after-treatment systems will become more complex in order to ensure their optimum operation over time. Moreover, because of the strong pressure for CO₂ emissions reduction, the average exhaust temperature is expected to decrease, posing significant challenges on exhaust after-treatment. Diesel Oxidation Catalysts (DOCs) are already widely used to reduce CO and hydrocarbons (HC) from diesel engine emissions. In addition, DOC is also used to control the NO₂/NOx ratio and to generate the exothermic reactions necessary for the thermal regeneration of Diesel Particulate Filter (DPF) and NOx Storage and Reduction catalysts (NSR). The expected temperature decrease of diesel exhaust will adversely affect the CO and unburned hydrocarbons (UHC) conversion efficiency of the catalysts. Therefore, the development cost for the design and control of new DOCs is increasing.

The thermal fatigue resistance of engine exhaust system parts has conventionally been evaluated in thermal fatigue tests conducted with a restrained specimen. However, the test results have not always been consistent with data obtained in engine endurance tests. Two new evaluation methods have been developed to overcome this problem. One is a method of predicting thermal fatigue life on the basis of nonlinear elastic and plastic thermal analyses performed with a finite element model and the ABAQUS program. The other is a method of evaluating exhaust system parts using an exhaust system simulator. This paper describes the concepts underlying the two methods and their relative advantages.

Soot accumulation in diesel engine crankcase is the dominant factor which governs engine oil drain interval. So, efficient soot elimination from crankcase oil can be a practical way to achieve drain interval extension. Combination of high performance oil filter and low soot dispersancy oil results in an effective measure to trap soot efficiently. In this paper, the behavior of newly developed high performance diesel engine oil having low soot dispersancy is reported. Prior to oil development, an evaluation method of soot dispersancy in oil was elaborated. Based on relative viscosity defined as ratio of soot containing oil viscosity to soot eliminated oil viscosity, dispersancy parameter was determined. Oil dispersancy evaluated on this parameter agreed with the results obtained from particle size analyzer. Secondly, a method to obtain oil filter soot trap rate to total soot contaminated into crankcase (trap rate) was established.

Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

The purpose of this study is to clarify the state of heat loss to the cylinder liner of the tested engine of which piston and cylinder head were previously measured. The authors' group developed an original measurement technique of instantaneous surface temperature at the cylinder liner wall using thin-film thermocouples. The temperature was measured at 36 points in total. The instantaneous heat flux was calculated by heat transfer analysis using measurement results of the temperature at the wall. As a result, the heat loss ratio to all combustion chamber walls is evaluated except the intake and exhaust valves.

Comparison of net thermal efficiency and emission in two and four stroke gasoline HCCI engine has been carried out for various valve-timings as negative valve overlap and exhaust valve double opening. The valve timings could easily be converted from a mode to another by configuring schedule of electromagnetic valve-train. Extension of operable torque with high thermal efficiency had been expected in two-stroke HCCI operation, however friction and supercharger loss curtailed about half of the gain in indicated thermal efficiency. In four-stroke operation modes, exhaust valve double opening (‘reinduction’ or ‘rebreathing’) showed the best net thermal efficiency and emission, however the extension of high load limit could not be achieved considerably.

The demands on valve seat insert materials, in terms of providing greater wear-resistance at higher temperatures, enhanced machinability and using non-environmentally hazardous materials at a reasonably low cost have intensified in recent years. Due therefore to these strong demands in the market, research was made into the possibility of producing a new valve seat insert material. As a result a high speed steel based new improved material was developed, which satisfies the necessary required demands and the evaluation trials, using actual gasoline engine endurance tests, were found to be very successful.

An investigation was conducted into pressure pulsation in the exhaust port, which greatly affects volumetric efficiency and engine performance. From experiments using a single blow-down generator, it was established that the amplitude of the pressure pulsation increases as the manifold branch is lengthened and that large negative pressure synchronized with the timing of valve overlap can be obtained if a proper branch length is used. The performance of a 2ℓ test engine was optimized by varying the length of both the manifold branches and front pipe forks. It was found that whereas front pipe fork length affects engine performance over only a narrow range of engine speed, optimizing manifold branch length results in a considerable improvement over a wide engine speed range. In the course of optimizing the exhaust pipe manifold length of this two-degree-of-freedom exhaust system, abnormal exhaust noises were emitted at specific engine speeds during deceleration.

Nissan Motor has put on the European SUV market a 2.2-L direct-injection diesel engine with a diesel particulate filter (DPF) system that complies with the EURO IV emission regulations. This paper describes the DPF system, cooperative control of a variable geometry turbo (VGT) and exhaust gas recirculation (EGR), and a high-accuracy lambda control adopted for this engine. In order to achieve a compact DPF, the high-accuracy lambda control was developed to reduce variation in engine-out particulate matter (PM) emissions. Moreover, the accuracy of the technique for predicting the quantity of PM accumulation was improved for reliable detection of the DPF regeneration. Prediction error for PM accumulation increases during transient operation. Control logic was adopted to correct the PM prediction according to lambda fluctuation detected by an observer for lambda at cylinder under transient operating conditions. The observer is corrected lambda sensor output.

Nissan Motor Company has developed a compact and simple new variable valve actuation system called VVEL (Variable Valve Event and Lift) that can vary intake valve lift and valve event angle in a wide range, and adopted it on a newly developed 3.7L, V6 engine. This system combined with a variable valve timing (VTC) mechanism (or a cam phaser) has substantially enhanced engine performance attributes, namely, fuel economy, exhaust emissions, and engine output, because the system has the ability to freely control all of intake valve lift, event duration angle and phasing between intake and exhaust valves. This paper describes an outline of the VVEL system, the principle of system operation, and effects on engine performance attributes by this technology.

One primary result of the reduction of platinum group metals (PGM) within a catalytic converter is the decline in NOx conversion efficiency. This paper hypothesizes that the primary factor of this decline to be hydrocarbon (HC) poisoning. To maintain high NOx conversion efficiency as the PGM reduces, Rh activation improvement becomes significant to overcome the HC poisoning. Analysis of the Rh deterioration mechanism found that it is effective to separately arrange Rh and CeO2 on the converter, avoiding the Rh deactivation. By this improvement, we improved the catalyst activity at less than 25% of the original Rh loading.

Diesel particulate and NOx reduction system (DPNR) is an effective technology for the diesel after-treatment system, which can reduce particulate matter (PM) and nitrogen oxides (NOx) simultaneously. Further improvement of the DPNR is expected for cleaner air in the future. The catalyst for the DPNR (called DPNR catalyst) consists of a NOx Storage Reduction (NSR) catalyst coated onto a Diesel Particulate Filter (DPF). The development of the DPNR catalyst for the decrease of exhaust weight has been considered before now with respect to the PM combustion. But it will be necessary to focus on PM particle number emissions in the future. In this study, the relationship between the pore structure of the DPNR catalyst and the trapping of PM to lower particle number was clarified by evaluating a high-porosity, large-pore cordierite DPF with an average pore size of 20 μm or greater. Furthermore, the optimal pore structure to trap PM particles in a highly effective manner was discussed.

Biodiesel Fuel (BDF) Research Work Group works on identifying technological issues on the use of high biodiesel blends (over 5 mass%) in conventional diesel vehicles under the Japan Auto-Oil Program started in 2007. The Work Group conducts an analytical study on the issues to develop measures to be taken by fuel products and vehicle manufacturers, and to produce new technological findings that could contribute to the study of its introduction in Japan, including establishment of a national fuel quality standard covering high biodiesel blends. For evaluation of the impacts of high biodiesel blends on performance of diesel particulate filter system, a wide variety of biodiesel blendstocks were prepared, ranging from some kinds of fatty acid methyl esters (FAME) to another type of BDF such as hydrotreated biodiesel (HBD). Evaluation was mainly conducted on blend levels of 20% and 50%, but also conducted on 10% blends and neat FAME in some tests.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

The Diesel Particulate Filter (DPF) system has been developed as one of key technologies to comply with tight diesel PM emission regulations. For the DPF control system, it is necessary to maintain temperature inside the DPF below the allowable service temperature, especially during soot regeneration to prevent catalyst deterioration and cracks. Therefore, the evaluation of soot regeneration is one of the key development items for the DPF system. On the other hand, regeneration evaluation requires a lot of time and cost since many different regeneration conditions should be investigated in order to simulate actual driving. The simulation tool to predict soot regeneration behavior is a powerful tool to accelerate the development of DPF design and safe regeneration control strategies. This paper describes the soot regeneration model applied to fuel additive and catalyzed types, and shows good correlation with measured data.

We, at Toyota, have been working to develop a new DPNR (Diesel Particulate-NOx Reduction) system to decrease both PM and NOx emissions by combining the NOx storage-reduction catalyst for direct injection gasoline engines with the most advanced engine control technologies. The purpose of the DPNR catalyst is to decrease PM and NOx in order to purify automotive exhaust gas. To reduce PM emissions, the PM trapping rate and PM oxidizing performance must be improved. Since the deposition of PM increases the pressure drop across the catalytic converter, it should also be suppressed. To attain these objectives, we have developed a new DPNR catalyst by the adoption of a new porous substrate structure and the improvement of the catalyst coating technique. The new DPNR catalyst will be mounted on the Avensis for commercial use in the European market.

Generally, cobalt-contained sintered materials have mainly been applied for exhaust valve seat inserts (VSI). However, there is a trend to restrict the use of cobalt as well as lead environmental law, and cobalt is expensive. To solve these problems, a new exhaust VSI on the assumption of being cobalt and lead free, applicable for conventional engines, having good machinability, and with a reduced cost was developed. The new exhaust VSI is a material dispersed with two types of hard particles, Fe-Cr-C and Fe-Mo-Si, in the matrix of an Fe-3.5mass%Mo at the ratio of 15 mass % and 10 mass % respectively.