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A spark-assist homogeneous charge compression ignition (SA-HCCI) operating strategy is presented here that allows for stoichiometric combustion from 1000-3000 rpm, and at loads as high as 750 kPa net IMEP. A single cylinder gasoline engine equipped with direct fuel injection and fully variable hydraulic valve actuation (HVA) is used for this experimental study. The HVA system enables negative valve overlap (NVO) valve timing for hot internal EGR. Spark-assist stabilizes combustion over a wide range of engine speeds and loads, and allows for stoichiometric operation at all conditions. Characteristics of both spark-ignited combustion and HCCI are present during the SA-HCCI operating mode, with combustion analysis showing a distinctive spark ignited phase of combustion, followed by a much more rapid HCCI combustion phase. At high load, the maximum cylinder pressure rise rate is controlled by a combination of spark timing and retarding the intake valve closing angle.

In this study the authority of the available engine controls are characterized as the high load limit of homogeneous charge compression ignition (HCCI) combustion is approached. A boosted single-cylinder research engine is used and is equipped with direct injection (DI) fueling, a laboratory air handling system, and a hydraulic valve actuation (HVA) valve train to enable negative valve overlap (NVO) breathing. Results presented include engine loads from 350 to 650 kPa IMEPnet and manifold pressure from 98 to 190 kPaa. It is found that in order to increase engine load to 650 kPa IMEPnet, it is necessary to increase manifold pressure and external EGR while reducing the NVO duration. While both are effective at controlling combustion phasing, NVO duration is found to be a "coarse" control while fuel injection timing is a "fine" control.

The latent heat-of-vaporization (HoV) of blends of biofuel and hydrocarbon components into gasolines has recently experienced expanded interest because of the potential for increased HoV to increase fuel knock resistance in direct-injection (DI) engines. Several studies have been conducted, with some studies identifying an additional anti-knock benefit from HoV and others failing to arrive at the same conclusion. Consideration of these studies holistically shows that they can be grouped according to the level of fuel octane sensitivity variation within their fuel matrices. When comparing fuels of different octane sensitivity significant additional anti-knock benefits associated with HoV are sometimes observed. Studies that fix the octane sensitivity find that HoV does not produce additional anti-knock benefit. New studies were performed at ORNL and NREL to further investigate the relationship between HoV and octane sensitivity.

Numerous studies have demonstrated that exhaust gas recirculation (EGR) can attenuate knock propensity in spark ignition (SI) engines at naturally aspirated or lightly boosted conditions [1]. In this study, we investigate the role of cooled EGR under higher load conditions with multiple fuel compositions, where highly retarded combustion phasing typical of modern SI engines was used. It was found that under these conditions, EGR attenuation of knock is greatly reduced, where EGR doesn’t allow significant combustion phasing advance as it does under lighter load conditions. Detailed combustion analysis shows that when EGR is added, the polytropic coefficient increases causing the compressive pressure and temperature to increase. At sufficiently highly boosted conditions, the increase in polytropic coefficient and additional trapped mass from EGR can sufficiently reduce fuel ignition delay to overcome knock attenuation effects.

High Efficiency Clean Combustion (HECC) strategies such as homogenous charge compression ignition (HCCI) and pre-mixed charge compression ignition (PCCI) offer much promise for the reduction of NOx and PM from diesel engines. While delivering low PM and low NOx, these combustion modes often produce much higher levels of CO and HC than conventional diesel combustion modes. In addition, partially oxygenated species such as formaldehyde (an MSAT) and other aldehydes increase with HECC modes. The higher levels of CO and HCs have the potential to compromise the performance of the catalytic aftertreatment, specifically at low load operating points. As HECC strategies become incorporated into vehicle calibrations, manufacturers need to avoid producing MSATs in higher quantities than found in conventional combustion modes. This paper describes research on two different HECC strategies, HCCI and PCCI.

Compact heat exchangers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases, resulting in decreased NOx emissions. These exhaust gas recirculation (EGR) coolers experience fouling through deposition of particulate matter (PM) and hydrocarbons (HCs) that reduces the effectiveness of the cooler. Surrogate tubes have been used to investigate the impacts of gas flow rate and coolant temperature on the deposition of PM and HCs. The results indicate that mass deposition is lowest at high flow rates and high coolant temperatures. An oxidation catalyst was investigated and proved to effectively reduce deposition of HCs, but did not reduce overall mass deposition to near-zero levels. Speciation of the deposit HCs showed that a range of HCs from C15 - C25 were deposited and retained in the surrogate tubes.

The buildup of deposits in EGR coolers causes significant degradation in heat transfer performance, often on the order of 20-30%. Deposits also increase pressure drop across coolers and thus may degrade engine efficiency under some operating conditions. It is unlikely that EGR cooler deposits can be prevented from forming when soot and HC are present. The presence of cooled surfaces will cause thermophoretic soot deposition and condensation of HC and acids. While this can be affected by engine calibration, it probably cannot be eliminated as long as cooled EGR is required for emission control. It is generally felt that “dry fluffy” soot is less likely to cause major fouling than “heavy wet” soot. An oxidation catalyst in the EGR line can remove HC and has been shown to reduce fouling in some applications. The combination of an oxidation catalyst and a wall-flow filter largely eliminates fouling. Various EGR cooler designs affect details of deposit formation.

While the potential emissions and efficiency benefits of HCCI combustion are well known, realizing the potentials on a production intent engine presents numerous challenges. In this study we focus on identifying challenges and opportunities associated with a production intent cam-based variable valve actuation (VVA) system on a multi-cylinder engine in comparison to a fully flexible, naturally aspirated, hydraulic valve actuation (HVA) system on a single-cylinder engine, with both platforms sharing the same GDI fueling system and engine geometry. The multi-cylinder production intent VVA system uses a 2-step cam technology with wide authority cam phasing, allowing adjustments to be made to the negative valve overlap (NVO) duration but not the valve opening durations. On the single-cylinder HVA engine, the valve opening duration and lift are variable in addition to the NVO duration. The content of this paper is limited to the low-medium operating load region at 2000 rpm.

Ethanol is a very attractive fuel from an end-use perspective because it has a high chemical octane number and a high latent heat of vaporization. When an engine is optimized to take advantage of these fuel properties, both efficiency and power can be increased through higher compression ratio, direct fuel injection, higher levels of boost, and a reduced need for enrichment to mitigate knock or protect the engine and aftertreatment system from overheating. The ASTM D5798 specification for high level ethanol blends, commonly called “E85,” underwent a major revision in 2011. The minimum ethanol content was revised downward from 68 vol% to 51 vol%, which combined with the use of low octane blending streams such as natural gasoline introduces the possibility of a lower octane “E85” fuel.

The effects of variable compression ratio (CR) and fuel composition on thermal efficiency were investigated in a homogeneous charge compression ignition (HCCI) engine using blends of n-heptane and toluene with research octane numbers (RON) of 0 to 90. Experiments were conducted by performing CR sweeps at multiple intake temperatures using both unthrottled operation, and constant Φ conditions by throttling to compensate for varying air density. It was found that CR is effective at changing and controlling the HCCI combustion phasing midpoint, denoted here as CA 50. Thermal efficiency was a strong function of CA 50, with overly advanced CA 50 leading to efficiency decreases. Increases in CR at a constant CA 50 for a given fuel composition did, in most cases, increase efficiency, but the relationship was weaker than the dependence of efficiency on CA 50.

The effect of biodiesel content on homogeneous charge compression ignition (HCCI) engine performance has been investigated both experimentally and by computer simulation. Combustion experiments were performed in a single cylinder HCCI engine using blends of soy biodiesel in ultra low sulfur diesel, with concentrations ranging from 0 to 50 vol% and equivalence ratios (Φ) from 0.38 to 0.48. Data from the engine tests included combustion analysis and exhaust composition analysis with standard gaseous emissions equipment. The engine utilized a custom port fuel injection strategy to provide highly premixed charges of fuel and air, making it possible to compare the results with single zone chemical kinetics simulations that were performed using CHEMKIN III, with a reaction set including 670 species and over 3000 reactions.

In this research, small, single cylinder engines have been used to simulate larger engines in the areas of aftertreatment, combustion, and fuel formulation effects. The use of small engines reduces overall research cost and allows more rapid experiments to be run. Because component costs are lower, it is also possible to investigate more variations and to sacrifice components for materials characterization and for subsequent experiments. Using small engines in this way is very successful in some cases. In other cases, limitations of the engines influence the results and need to be accounted for in the experimental design and data analysis. Some of the results achieved or limitations found may be of interest to the small engine market, and this paper is offered as a summary of the authors' research in these areas. Research is being conducted in two areas. First, small engines are being used to study the rapid aging and poisoning of exhaust aftertreatment catalysts.

On a gasoline engine platform, homogeneous charge compression ignition (HCCI) holds the promise of improved fuel economy and greatly reduced engine-out NOx emissions, without an increase in particulate matter emissions. In this investigation, a variable compression ratio (CR) engine equipped with a throttle and intake air heating was used to test the robustness of these control parameters to accommodate a series of fuels blended from reference gasoline, straight run refinery naphtha, and ethanol. Higher compression ratios allowed for operation with higher octane fuels, but operation could not be achieved with the reference gasoline, even at the highest compression ratio. Compression ratio and intake heat could be used separately or together to modulate combustion. A lambda of 2 provided optimum fuel efficiency, even though some throttling was necessary to achieve this condition. Ethanol did not appear to assist combustion, although only two ethanol-containing fuels were evaluated.

A modeling study was performed to investigate fuel-specific effects of exhaust gas recirculation (EGR) components on homogeneous charge compression ignition (HCCI) combustion at conditions relevant to the negative valve overlap (NVO) strategy using CHEMKIN-PRO. Four single-component fuels with well-established kinetic models were chosen: n-heptane, iso-octane, ethanol, and toluene. These fuels were chosen because they span a wide range of fuel chemistries, and produce a wide compositions range of complete stoichiometric products (CSP). The simulated engine conditions combined a typical spark ignition engine compression ratio (11.34) and high intake charge temperatures (500-550 K) that are relevant to NVO HCCI. It was found that over the conditions investigated, all the fuels had overlapping start of combustion (SOC) phasing, despite the wide range in octane number (RON = 0 to 120).

Exhaust gas recirculation (EGR) cooler fouling has emerged as an important issue in diesel engine development. Uncertainty about the level of impact that fuel chemistry may have upon this issue has resulted in a need to investigate the cooler fouling process with emerging non-traditional fuel sources to gage their impact on the process. This study reports experiments using both ultra-low sulfur diesel (ULSD) and 20% biodiesel (B20) at elevated exhaust hydrocarbon conditions to investigate the EGR cooler fouling process. The results show that there is little difference between the degradation in cooler effectiveness for ULSD and B20 at identical conditions. At lower coolant temperatures, B20 exhibits elevated organic fractions in the deposits compared with ULSD, but this does not appear to lead to incremental performance degradation under the conditions studied.

The exhaust chemistry of combustion regimes characterized by simultaneous low-NOX and low-PM emissions were investigated on a Mercedes 1.7-L diesel engine. Two approaches for entering low-NOX low-PM regimes were explored using a California specification low aromatic certification diesel fuel. Detailed characterizations of gas-phase hydrocarbons, particulate soluble organics, and aldehydes are presented for both approaches. Results indicate significant formation of partially oxygenated hydrocarbons and fuel reformation products during periods of low-NOX, low-PM combustion.

New regulations requiring increases in vehicle fuel economy are challenging automotive manufacturers to identify fuel-efficient engines for future vehicles. Lean gasoline direct injection (GDI) engines offer significant increases in fuel efficiency over the more common stoichiometric GDI engines already in the marketplace. However, particulate matter (PM) emissions from lean GDI engines, particularly during stratified combustion modes, are problematic for lean GDI technology to meet U.S. Environmental Protection Agency Tier 3 and other future emission regulations. As such, the control of lean GDI PM with wall-flow filters, referred to as gasoline particulate filter (GPF) technology, is of interest. Since lean GDI PM chemistry and morphology differ from diesel PM (where more filtration experience exists), the functionality of GPFs needs to be studied to determine the operating conditions suitable for efficient PM removal.

High-efficiency clean combustion (HECC) modes provide simultaneous reductions in diesel particulate matter and nitrogen-oxides emissions while retaining efficiencies characteristic of normal diesel engines. Fuel parameters may have significant impacts on the ability to operate in HECC modes and on the emissions produced in HECC modes. In this study, 3 diesel-range fuels and 2 oxygenated blends are burned in both normal and HECC modes at 3 different engine conditions. The results show that fuel effects play an important role in the emissions of hydrocarbons, particulate matter, and carbon monoxide but do not significantly impact NOx emissions in HECC modes. HECC modes are achievable with 5% biodiesel blends in addition to petroleum-based and oil-sands derived fuels. Soot precursor and oxygenated compound concentrations in the exhaust were observed to generally increase with the sooting tendency of the fuel in HECC modes.

As part of a multi-agency study concerning emissions and fuel consumption from heavy-duty diesel truck idling, Oak Ridge National Laboratory personnel measured CO, HC, NOx, CO2, O2, particulate matter (PM), aldehyde and ketone emissions from truck idle exhaust. Two methods of quantifying PM were employed: conventional filters and a Tapered Element Oscillating Microbalance (TEOM). A partial flow micro-dilution tunnel was used to dilute the sampled exhaust to make the PM and aldehyde measurements. The work was performed at the U.S. Army's Aberdeen Test Center's (ATC) climate controlled chamber. ATC performed 37 tests on five class-8 trucks (model years ranging from 1992 to 2001). One was equipped with an 11 hp diesel auxiliary power unit (APU), and another with a diesel direct-fired heater (DFH). The APU powers electrical accessories, heating, and air conditioning, whereas a DFH heats the cab in cold weather. Both devices offer an alternative to extended truck-engine idling.

A single cylinder engine was operated in HCCI mode with diesel-range fuels, spanning a range in cetane number (CN) from 34 to 62. In addition to measurements of standard gaseous emissions (CO, HC, and NOx), multiple sampling and analysis techniques were used to identify and measure the individual exhaust HC species including an array of oxygenated compounds. A new analytical method, using liquid chromatography (LC) with electrospray ionization-mass spectrometry (ESI-MS) in tandem with ultraviolet (UV) detection, was developed to analyze the longer chain aldehydes as well as carboxylic acids. Results showed an abundance of formic and butyric acid formation at or near the same concentration levels as formaldehyde and other aldehydes.