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The introduction of alternative fuels is crucial to limit greenhouse gases. CNG is regarded as one of the most promising clean fuels given its worldwide availability, its low price and its intrinsic properties (high knocking resistance, low carbon content...). One way to optimize dedicated natural gas engines is to improve the CNG slow burning velocity compared to gasoline fuel and allow lean burn combustion mode. Besides optimization of the combustion chamber design, hydrogen addition to CNG is a promising solution to boost the combustion thanks to its fast burning rate, its wide flammability limits and its low quenching gap. This paper presents an investigation of different methane/hydrogen blends between 0% and 40 vol. % hydrogen ratio for three different combustion modes: stoichiometric, lean-burn and stoichiometric with EGR.

The development of hydrogen-fueled vehicles has created the need for established fuel consumption testing methods. Until now the EPA has only accepted three methods of hydrogen fuel consumption testing, gravimetric, PVT (stabilized pressure, volume and temperature), and Coriolis mass flow; all of which necessitate physical measurements of the fuel supply [1]. BMW has developed an equation and subsequent testing methods to accurately and effectively determine hydrogen fuel consumption in light-duty vehicles using only exhaust emissions. Known as “Hydrogen-Balance”, the new equation requires no changes to EPA procedures and only slight modifications to most existing chassis dynamometers and CVS (Constant Volume Sampling) systems. The SAE 2008-01-1036, also written by BMW, explains the background as well as required equipment and changes to the CVS testing system. This paper takes hydrogen balance further by testing it against the three EPA established forms of fuel consumption.

The Hydrogen-Balance equation makes it possible to calculate the fuel economy or fuel consumption of hydrogen powered vehicles simply by analyzing exhaust emissions. While the benefits of such a method are apparent, it is important to discuss possible influencing factors that may decrease Hydrogen-Balance accuracy. Measuring vehicle exhaust emissions is done with a CVS (Constant Volume Sampling) system. While the CVS system has proven itself both robust and precise over the years, utilizing it for hydrogen applications requires extra caution to retain measurement accuracy. Consideration should be given to all testing equipment, as well as the vehicle being tested. Certain environmental factors may also play a role not just in Hydrogen-Balance accuracy, but as also in other low emission testing accuracy.

The reduction of vehicle exhaust particle emissions is a success story of European legislation. Various particle number (PN) counters and calibration procedures serve as tools to enforce PN emission limits during vehicle type approval (VTA) or periodical technical inspection (PTI) of in-use vehicles. Although all devices and procedures apply to the same PN-metric, they were developed for different purposes, by different stakeholder groups and for different target costs and technical scopes. Furthermore, their calibration procedures were independently defined by different stakeholder communities. This frequently leads to comparability and interpretation issues. Systematic differences of stationary and mobile PN counters (PN-PEMS) are well-documented. New, low-cost PTI PN counters will aggravate this problem. Today, tools to directly compare different instruments are scarce.

To meet LEV and EU Stage III emission requirements, it is necessary for new catalytic converters to be designed which exceed light-off temperature as quickly as possible. The technical solutions are secondary air injection, active heating systems such as the electrically heated catalytic converter, and the close coupled catalytic converter. Engine control functions are extensively used to heat the converter and will to play a significant role in the future. The concept of relocating the converter to a position close to the engine in an existing vehicle involves new conflicts. Examples include the space requirements, the thermal resistance of the catalytic coating and high temperature loads in the engine compartment.

Mexican automobile manufacturers will begin to phase in catalytic converters on new models during the early 1990's. A more immediate concern that needs to be addressed is the large remaining older car population that will continue to pollute the air. Retrofitting these vehicles with catalytic converters is one of the alternatives being considered in a collective effort to improve Mexico City's air quality. In collaboration with Mexico City government officials, a vehicle demonstration was designed to show the benefits of an oxidation catalyst retrofit. This paper presents emission results of Mexico City's taxi fleet vehicles and displays the effectiveness of a Pt/Pd oxidation catalyst system in lowering emission levels. Two fleet vehicles were emission tested before and after catalyst retrofit modifications with the U.S. FTP-75 vehicle test method. Carburetor modifications were also included to study the effects of engine tuning on engine emissions and catalyst performance.

The adoption of significantly more stringent tailpipe emission standards is leading the domestic car manufacturers and oil companies to reexamine the composition of commercial gasolines. One offshoot of this examination is a cooperative inter-industry Auto/Oil Air Quality Improvement Research Program. This study will attempt to determine the potential reductions in total vehicle emissions and resultant improvements in air quality from the use of reformulated gasolines. One important aspect of the program is to determine the effect of variable aromatic and olefinic hydrocarbon content as well as variable levels of oxygenates on emission levels from a statistically-designed vehicle program. Much laboratory, engine and vehicle emission data has been generated over the past two decades that is potentially useful in interpreting the tailpipe emission patterns associated with proposed fuel composition changes.

Various noble metal compositions are used for three-way catalyst applications. The most typical composition contains platinum and rhodium at various loadings and ratios. Recently palladium and rhodium compositions have received considerable attention by automobile companies. The strengths and weaknesses of the various noble metal use strategies have been widely discussed. Unfortunately, the content for much of the discussion has been based on information generated in the early to mid-1970s with catalysts of relatively simple formulation when compared to today's higher technology products. The present study compares the relative durability performance of modern platinum/rhodium and palladium/rhodium catalysts of identical loading under a variety of aging and evaluation conditions. These conditions were chosen to simulate some of the operating conditions encountered in U.S. and European driving applications.

Although hydrogen ICE engines have existed in one sort or another for many years, the testing of fuel consumption by way of exhaust emissions is not yet a proven method. The current consumption method for gasoline- and diesel-fueled vehicles is called the Carbon-Balance method, and it works by testing the vehicle exhaust for all carbon-containing components. Through conservation of mass, the carbon that comes out as exhaust must have gone in as fuel. Just like the Carbon-Balance method for gas and diesel engines, the new Hydrogen-Balance equation works on the principle that what goes into the engine must come out as exhaust components. This allows for fuel consumption measurements without direct contact with the fuel. This means increased accuracy and simplicity. This new method requires some modifications to the testing procedures and CVS (Constant Volume Sampling) system.

The study of oil emission is of essential interest for the engine development of modern cars, as well as for the understanding of hydrocarbon emissions especially during cold start conditions. A laser mass spectrometer has been used to measure single aromatic hydrocarbons in unconditioned exhaust gas of a H2-fueled engine at stationary and transient motor operation. These compounds represent unburned oil constituents. The measurements were accompanied by FID and GC-FID measurements of hydrocarbons which represent the burned oil constituents. The total oil consumption has been determined by measuring the oil sampled by freezing and weighing. It has been concluded that only 10 % of the oil consumption via exhaust gas has burned in the cylinders. A correlation of the emission of single oil-based components at ppb level detected with the laser mass spectrometer to the total motor oil emission has been found.

Among the existing concepts that help to improve the efficiency of spark-ignition engines at part load, Controlled Auto-Ignition™ (CAI™) is an effective way to lower both fuel consumption and pollutant emissions. This combustion concept is based on the auto-ignition of an air-fuel-mixture highly diluted with hot burnt gases to achieve high indicated efficiency and low pollutant emissions through low temperature combustion. To minimize the costs of conversion of a standard spark-ignition engine into a CAI engine, the present study is restricted to a Port Fuel Injection engine with a cam-profile switching system and a cam phaser on both intake and exhaust sides. In a 4-stroke engine, a large amount of burnt gases can be trapped in the cylinder via early closure of the exhaust valves. This so-called Negative Valve Overlap (NVO) strategy has a key parameter to control the amount of trapped burnt gases and consequently the combustion: the exhaust valve-lift profile.

Nowadays, due to the high competitiveness in the automotive market, the car manufacturers and the engine developers are concentrating as many efforts as possible in order to diminish the lead-time to production and to promote cost reductions of their engine developments. As a consequence, many systems and component tests are being substituted by numerical simulations, allowing a significant reduction in the amount of engine and bench tests. The integration of individual numerical simulation tools generates the philosophy of Virtual Engine Development, which is based on the concept of simulating as much as possible the entire engine as well as its components behaviors. This paper presents the application of Virtual Engine Development (VED) in a PSA 1.4l SI engine development. Theoretical results of engine performance as well as powercell components behavior such as piston, rings, conrod, bearings, liner, engine block and cylinder head, among others, are presented and discussed.

Changing of emission levels leads to an increasing demand for a satisfying solution to measure mass emissions of motor vehicles on both, engine and chassis dynamometers. Partial flow systems may fit to the demands. These systems require an exact determination of exhaust volume flow and time aligned concentration measurement. This paper will address these issues and problems related with partial flow sampling. Several exhaust flow measurement systems have been studied and integrated mass results have been checked against the full flow CVS. As the investigations indicate, modal mass calculation from sampling direct exhaust at the end of tailpipe is feasible but not a satisfying solution in equivalency and repeatability in comparison to CVS-results. This is especially the case on emission levels near or below ULEV.

Flame Ionization Detectors (FID) can be used to detect organic hydrocarbons that occur in plastics, lacquers, adhesives, solvents and gasoline. These substances are ionized in the hydrogen flame of the FID. The ionization current that is produced depends on the amount of hydrocarbon in the sample. With the lowering of emissions limits, measuring instruments, including the FID, have to be able to detect very low values. For SULEV (Super-Ultra Low Emissions Vehicle) measurements the accuracy and also the general applicability of the CVS (Constant Volume Sampling) measuring technique are now questioned. Basic understanding is necessary to ask the right questions. One important issue is the science behind the measurement principle of the FID. And in this case especially the influence of contamination of the operating gases, cross sensitivity and data processing on the Limit of Detection (LOD).

The successful design and especially the control of the SCR system is a challenging process that can be supported by the application of simulation tools. As a first step, we employ physico-chemically informed ‘off-line’ models that are calibrated with the help of targeted small- and full-scale tests. Despite their high level of sophistication, this SCR model is able to be integrated in a control-oriented simulation software platform and connected to other powertrain simulation blocks. The target is to use this simulation platform as a virtual environment for the development and optimization of SCR control strategies. The above process is demonstrated in the case of a passenger car SCR. The model is calibrated at both fresh and aged catalyst condition and validated using experimental data from the engine bench under a wide variety of operating conditions. Next, the calibrated model was coupled with embedded control models, developed for Euro 6 passenger car powertrains.

In studying H2S emissions, it is desirable to have an analytical technique which is rapid, continuous, accurate and easy to use in a laboratory or vehicle exhaust environment. Typically, H2S has been measured using the EPA impinger method with collection times on the order of 1 to 2 minutes. Other techniques have been developed with significantly shorter response times. However, it has been shown that the major release of H2S occurs in less than 20 seconds after a vehicle changes from rich to lean operation. Therefore, it is highly desirable to have an H2S analytical technique with a response time of less than 10 seconds. In this paper, the benefits of use of a chemical ionization mass spectrometer (CIMS) to continuously monitor H2S and SO2, emissions are reported. Using the CIMS technique, the effects of several operating parameters on the release of H2S and SO2 from automotive catalysts were studied.

Two models for the forecast of road traffic emissions, independently developed in parallel, are comparatively presented and assessed: EPROG developed by BMW and enlarged by VDA for a national application (Germany) and FOREMOVE, developed for application on European Community scale. The analysis of the methodological character of the two algorithms proves that the models are fundamentally similar with regard to the basic calculation schemes used for the emissions. The same holds true as far as the significant dependencies of the emission factors, and the recognition and incorporation of the fundamental framework referring to traffic important parameters (speeds, mileage and mileage distribution etc) are concerned.

Post-treatment of diesel exhaust was studied on a laboratory scale, using a reactor to simulate the post-combustion of soot collected inside a monolithic particulate trap. A parametric study of the trap regeneration was carried out. A periodic hydrocarbon injection system was developed to assist the catalyzed trap regeneration. This technique led to the trap regeneration with a temperature of the entering gas of 150°C, which is very low. An optimization of the injection process allowed one to minimize the injected amount of hydrocarbons and to have good control of the trap temperature. Another advantage of the hydrocarbon injection is to provide good conditions for reducing NO in an oxidizing atmosphere (10% O2). The importance of the hydrocarbon content was pointed out by a parametric study of NO conversion under a wide range of hydrocarbon concentrations (1000 ppm to 2.5% in CH4 equivalents).

Apart from the reduction of engine-out emissions from the powerplant, the development of an efficient and reliable catalytic converter heating system is an important task of automotive engineering in the future to meet standards that will require reduction of cold start emissions. Carrying out a comprehensive study in this field, BMW has tested and evaluated possible solutions to this challenge. In additon to the electrically heated catalytic converter (E-cat) and the afterburner chamber, an incorporated burner system would meet the requirement for fast catalyst light-off in the future, particularly in the case of larger engines.

In order to achieve the emission levels required for Low Emission Vehicles (LEV) and Ultra Low Emission Vehicles (ULEV) it is necessary to obtain insight into emission reactions to the motor management systems during transient engine performance. The optimisation of transients in typical driving profiles, such as shifting, acceleration load reversal, necessitates suitable gas measurement equipment. A technique capable to resolve one combustion cycle consists in spectroscopic gas analysis by using tunable infrared diode lasers. This paper describes the available equipment and demonstrates that a diode laser system fulfils the specific demands for the analysis of transient operating characteristics of engine management systems.