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Journal Article

Removal of NOx from Diesel Exhausts: The New “Enhanced NH3-SCR” Reaction

2010-04-12
2010-01-1181
Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.
Journal Article

Towards the Use of Eulerian Field PDF Methods for Combustion Modeling in IC Engines

2014-04-01
2014-01-1144
Detailed chemistry and turbulence-chemistry interaction need to be properly taken into account for a realistic combustion simulation of IC engines where advanced combustion modes, multiple injections and stratified combustion involve a wide range of combustion regimes and require a proper description of several phenomena such as auto-ignition, flame stabilization, diffusive combustion and lean premixed flame propagation. To this end, different approaches are applied and the most used ones rely on the well-stirred reactor or flamelet assumption. However, well-mixed models do not describe correctly flame structure, while unsteady flamelet models cannot easily predict premixed flame propagation and triple flames. A possible alternative for them is represented by transported probability density functions (PDF) methods, which have been applied widely and effectively for modeling turbulent reacting flows under a wide range of combustion regimes.
Journal Article

NLMPC for Real Time Path Following and Collision Avoidance

2015-04-14
2015-01-0313
This paper presents a nonlinear control approach to achieve good performances in vehicle path following and collision avoidance when the vehicle is driving under cruise highway conditions. Nonlinear model predictive control (NLMPC) is adopted to achieve online trajectory control based on a simplified vehicle model. GMRES/Continuation algorithm is used to solve the online optimization problem. Simulations show that the proposed controller is capable of tracking the desired path as well as avoiding the obstacles.
Journal Article

Diesel Exhaust Fluid (DEF) Supply System Modelling for Control and Diagnosis Applications

2015-01-14
2015-26-0090
The Selective Catalytic Reduction (SCR) system installed on the exhaust line is currently widely used on Diesel heavy-duty trucks and it is considered a promising technique for light and medium duty trucks, large passenger cars and off-highway vehicles, to fulfill future emission legislation. Some vehicles of these last categories, equipped with SCR, have been already put on the market, not only in the US, where the emission legislation on Diesel vehicles is more restrictive, but also in Europe, demonstrating to be already compliant with the upcoming Euro 6. Moreover, new and more stringent emission regulations and homologation cycles are being proposed all over the world, with a consequent rapidly increasing interest for this technology. As a matter of fact, a physical model of the Diesel Exhaust Fluid (DEF) supply system is very useful, not only during the product development phase, but also for the implementation of the on-board real-time controller.
Technical Paper

Polycyclic Aromatic Hydrocarbons Evolution and Interactions with Soot Particles During Fuel Surrogate Combustion: A Rate Rule-Based Kinetic Model

2021-09-05
2021-24-0086
Modeling combustion of transportation fuels remains a difficult task due to the extremely large number of species constituting commercial gasoline and diesel. However, for this purpose, multi-component surrogate fuel models with a reduced number of key species and dedicated reaction subsets can be used to reproduce the physical and chemical traits of diesel and gasoline, also allowing to perform CFD calculations. Recently, a detailed surrogate fuel kinetic model, named C3 mechanism, was developed by merging high-fidelity sub-mechanisms from different research groups, i.e. C0-C4 chemistry (NUI Galway), linear C6-C7 and iso-octane chemistry (Lawrence Livermore National Laboratory), and monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs) (ITV-RWTH Aachen and CRECK modelling Lab-Politecnico di Milano).
Journal Article

Friction Estimation at Tire-Ground Contact

2015-04-14
2015-01-1594
The friction estimation at the tire-ground contact is crucial for the active safety of vehicles. Friction estimation is a key problem of vehicle dynamics and the ultimate solution is still unknown. However the proposed approach, based on a simple idea and on a simple hardware, provides an actual solution. The idea is to compare the tire characteristic at a given friction (nominal characteristic) with the actual characteristic that the tire has while running. The comparison among these two characteristics (the nominal one and the actual one) gives the desired friction coefficient. The friction coefficient is expressed in vector form and a number of running parameters are identified. The mentioned comparison is an efficient but complex algorithm based on a mathematical formulation of the tire characteristic. The actual tire characteristic is somehow measured in real time by a relatively simple smart wheel which is able to detect the three forces and the three moments acting at the hub.
Journal Article

Acoustic Emission Processing for Turbocharged GDI Engine Control Applications

2015-04-14
2015-01-1622
In the field of passenger car engines, recent research advances have proven the effectiveness of downsized, turbocharged and direct injection concepts, applied to gasoline combustion systems, to reduce the overall fuel consumption while respecting particularly stringent exhaust emissions limits. Knock and turbocharger control are two of the most critical factors that influence the achievement of maximum efficiency and satisfactory drivability, for this new generation of engines. The sound emitted from an engine encloses many information related to its operating condition. In particular, the turbocharger whistle and the knock clink are unmistakable sounds. This paper presents the development of real-time control functions, based on direct measurement of the engine acoustic emission, captured by an innovative and low cost acoustic sensor, implemented on a platform suitable for on-board application.
Journal Article

Assessment of the Influence of GDI Injection System Parameters on Soot Emission and Combustion Stability through a Numerical and Experimental Approach

2015-09-06
2015-24-2422
The next steps of the current European and US legislation, EURO 6c and LEV III, and the incoming new test cycles will impose more severe restrictions on pollutant emissions for Gasoline Direct Injection (GDI) engines. In particular, soot emission limits will represent a challenge for the development of this kind of engine concept, if injection and after-treatment systems costs are to be minimized at the same time. The paper illustrates the results obtained by means of a numerical and experimental approach, in terms of soot emissions and combustion stability assessment and control, especially during catalyst-heating conditions, where the main soot quantity in the test cycle is produced. A number of injector configurations has been designed by means of a CAD geometrical analysis, considering the main effects of the spray target on wall impingement.
Journal Article

Experimental and Numerical Study of Flame Kernel Formation Processes of Propane-Air Mixture in a Pressurized Combustion Vessel

2016-04-05
2016-01-0696
Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.
Journal Article

A Progress Review on Soot Experiments and Modeling in the Engine Combustion Network (ECN)

2016-04-05
2016-01-0734
The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.
Journal Article

Assessment of Advanced SGS Models for LES Analysis of ICE Wall-Bounded Flows - Part I: Basic Test Case

2016-03-14
2016-01-9041
Large Eddy Simulation (LES) represents nowadays one of the most promising techniques for the evaluation of the dynamics and evolution of turbulent structures characterizing internal combustion engines (ICE). In the present paper, subdivided into two parts, the capabilities of the open-source CFD code OpenFOAM® v2.3.0 are assessed in order to evaluate its suitability for engine cold flow LES analyses. Firstly, the code dissipative attitude is evaluated through an inviscid vortex convection test to ensure that the levels of numerical dissipation are compatible with LES needs. Quality and completeness estimators for LES simulations are then proposed. In particular the Pope M parameter is used as a LES completeness indicator while the LSR parameter provides useful insights far calibrating the grid density. Other parameters such as the two-grid LESIQk index are also discussed.
Technical Paper

Numerical Optimization of a SCR System Based on the Injection of Pure Gaseous Ammonia for the NOx Reduction in Light-Duty Diesel Engines

2020-04-14
2020-01-0356
Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.
Journal Article

Multi-Dimensional Modeling of the Soot Deposition Mechanism in Diesel Particulate Filters

2008-04-14
2008-01-0444
A computational, three-dimensional approach to investigate the behavior of diesel soot particles in the micro-channels of wall-flow Diesel Particulate Filters is presented. The KIVA3V CFD code, already extended to solve the 2D conservation equations for porous media materials [1], has been enhanced to solve in 2-D and 3-D the governing equations for reacting and compressible flows through porous media in non axes-symmetric geometries. With respect to previous work [1], a different mathematical approach has been followed in the implementation of the numerical solver for porous media, in order to achieve a faster convergency as source terms were added to the governing equations. The Darcy pressure drop has been included in the Navier-Stokes equations and the energy equation has been extended to account for the thermal exchange between the gas flow and the porous wall.
Journal Article

The NH3 Inhibition Effect in the Standard SCR Reaction over a Commercial Fe-zeolite Catalyst for Diesel Exhaust Aftertreatment: An Experimental and Modeling Study

2011-04-12
2011-01-1319
Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.
Journal Article

A Numerical Model for Flash Boiling of Gasoline-Ethanol Blends in Fuel Injector Nozzles

2011-09-11
2011-24-0003
Fuels are formulated by a variety of different components characterized by chemical and physical properties spanning a wide range of values. Changing the ratio between the mixture component molar fractions, it is possible to fulfill different requirements. One of the main properties that can be strongly affected by mixture composition is the volatility that represents the fuel tendency to vaporize. For example, changing the mixture ratio between alcohols and hydrocarbons, it is possible to vary the mixture saturation pressure, therefore the fuel vaporization ratio during the injection process. This paper presents a 1D numerical model to simulate the superheated injection process of a gasoline-ethanol mixture through real nozzle geometries. In order to test the influence of the mixture properties on flash atomization and flash evaporation, the simulation is repeated for different mixtures characterized by different gasoline-ethanol ratio.
Journal Article

Innovative Techniques for On-Board Exhaust Gas Dynamic Properties Measurement

2013-04-08
2013-01-0305
The purpose of this paper is to present some innovative techniques developed for an unconventional utilization of currently standard exhaust sensors, such as HEGO, UEGO, and NOx probes. In order to comply with always more stringent legislation about pollutant emissions, intake-exhaust systems are becoming even more complex and sophisticated, especially for CI engines, often including one or two UEGO sensors and a NOx sensor, and potentially equipped with both short-route and long-route EGR. Within this context, the effort to carry out novel methods for measuring the main exhaust gas dynamic properties exploiting sensors installed for different purposes, could be useful both for control applications, such as EGR rates estimation, or cost reduction, minimizing the on-board devices number. In this work, a gray-box model for measuring the gas mass flow rate, based on standard NOx sensor operating parameters of its heating circuit, is analyzed.
Journal Article

A Comparison of Experimental and Modeled Velocity in Gasoline Direct-Injection Sprays with Plume Interaction and Collapse

2017-03-28
2017-01-0837
Modeling plume interaction and collapse for direct-injection gasoline sprays is important because of its impact on fuel-air mixing and engine performance. Nevertheless, the aerodynamic interaction between plumes and the complicated two-phase coupling of the evaporating spray has shown to be notoriously difficult to predict. With the availability of high-speed (100 kHz) Particle Image Velocimetry (PIV) experimental data, we compare velocity field predictions between plumes to observe the full temporal evolution leading up to plume merging and complete spray collapse. The target “Spray G” operating conditions of the Engine Combustion Network (ECN) is the focus of the work, including parametric variations in ambient gas temperature. We apply both LES and RANS spray models in different CFD platforms, outlining features of the spray that are most critical to model in order to predict the correct aerodynamics and fuel-air mixing.
Technical Paper

Dynamic Tests of Racing Seats and Simulation with Vedyac Code

1998-11-16
983059
Dynamic tests have been performed on carbon fiber racing seats following the FIA regulations. The tests have shown, in rear impact tests, a relatively strong rebound leading to large forward bending of neck, and, in side impact tests, very large lateral displacement of the head, the latter protruding dangerously towards hard portions of the car structure. Stiffening the seat back by steel struts results in reducing strongly both the motion and the acceleration of the head. Simulations of the dynamics of the tests have been done with multi-body models, including the Hybrid III dummy and seat deflection, by means of the program VEDYAC. It has been found that computer simulation can predict very accurately the result of a test, provided the numerical models have been carefully calibrated to match the dummy tolerance bands. Once they have been calibrated and validated with a number of tests, the computer models can be very useful to extend the test results to different test conditions.
Technical Paper

Progress in Diesel HCCI Combustion Within the European SPACE LIGHT Project

2004-06-08
2004-01-1904
The purpose of the European « SPACE LIGHT » (Whole SPACE combustion for LIGHT duty diesel vehicles) 3-year project launched in 2001 is to research and develop an innovative Homogeneous internal mixture Charged Compression Ignition (HCCI) for passenger cars diesel engine where the combustion process can take place simultaneously in the whole SPACE of the combustion chamber while providing almost no NOx and particulates emissions. This paper presents the whole project with the main R&D tasks necessary to comply with the industrial and technical objectives of the project. The research approach adopted is briefly described. It is then followed by a detailed description of the most recent progress achieved during the tasks recently undertaken. The methodology adopted starts from the research study of the in-cylinder combustion specifications necessary to achieve HCCI combustion from experimental single cylinder engines testing in premixed charged conditions.
Technical Paper

Design and Construction of a Test Rig for Assessing Tyre Characteristics at Rollover

2002-07-09
2002-01-2077
The paper presents a new test rig (named RuotaVia) composed basically by a drum (2,6 m diameter), providing a running contact surface for vehicle wheels. A number of measurements on either full vehicles or vehicle sub-systems (single suspension system or single tyre) can be performed. Tire characteristics influencing rollover can be assessed. The steady-state maximum loads are as follows: Radial: 100kN, tangential: 100kN, lateral (axial with respect to the drum): 100kN. The superstructure carrying a measuring hub can excite the wheel under test up to 20 Hz in lateral and vertical directions. The steer angle range is ± 25 deg, the camber range is ± 80 deg. The minimum eigenfrequency of the drum is higher than 90 Hz and its maximum tangential speed is 440 km/h.
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