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Technical Paper

Plate Type Methanol Steam Reformer Using New Catalytic Combustion for a Fuel Cell

2002-03-04
2002-01-0406
Methanol steam reforming, which is an endothermic reaction, needs some heating. Both methanol conversion ratio and carbon monoxide (CO) concentration increase when temperature is elevated. As CO poisons a typical polymer electrolyte of a fuel cell, the relationship between methanol conversion ratio and CO concentration is a trade-off one. It was found from preliminary researches that the reforming reaction speed is controlled by heat transfer rate at large methanol flow rate, where methanol conversion ratio becomes lower and CO concentration becomes higher. Therefore it is necessary to develop a new methanol reforming concept that provides stable combustion for heating and enhanced heat transfer for improving the trade-off relationship and making a compact reformer. Reforming catalyst using metal honeycomb support and a new catalytic combustion were applied to a new concept plate type methanol steam reformer, which is used in a fuel cell of 3 kW-class electric generation.
Technical Paper

Numerical Analysis of Fuel Behavior in a Port-Injection Gasoline Engine

1997-02-24
970878
Three-dimensional numerical analysis of fuel liquid and mixture behavior in a port-injection gasoline engine is assessed by comparing calculations with measurements. The fuel mass distributed in the intake port and cylinder is measured using an engine with hydraulic valve and gas sampling system. The experimental results show that about half of the fuel mass per injection enters the cylinder, and the rest stays in the port. The difference of the mass fraction of injected fuel directly entering the cylinder is small between the cases of single pulse injection and serial injection. Therefore, three-dimensional calculation presupposing single pulse injection has difficulty in predicting the in-cylinder mixture formation process, although it can analyze the amount of fuel wetting the port wall. The calculations are performed for a port-injection engine, and the differences of fuel behavior with respect to swirl control valve opening and wall temperature are discussed.
Technical Paper

Numerical Simulation of Deactivation Process of Three-way Catalytic Converters

2000-03-06
2000-01-0214
This paper presents the numerical simulation method to predict the deactivation process of three-way catalytic converters. Three-way catalytic converter's deactivation typically results from thermal and chemical mechanisms. The major factor of thermal deactivation is the sintering of noble metal particles, which is known to depend on the ageing temperature and the oxygen concentration in the exhaust gas. The chemical deactivation is mainly caused by the poisoning, which has two effects on the catalyst deactivation. One effect is the loss of the catalyst activity, which is expressed by reduced frequency factors of reaction rates. Another effect is the suppression of the noble metal sintering. Poison deposits prevent the noble metal particles from moving in the washcoat, assisted by the reduced thermal loading of reaction heats, which is caused by the loss of the catalyst activity. Modeling these deactivation factors, we propose the rate expression of noble metal sintering.
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