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A simultaneous multi-composition analyzing (SMCA) resonance enhanced multi-photon ionization (REMPI) system was used to investigate gasoline engine exhaust. Observed peaks for exhaust were smaller mass numbers than those from diesel exhaust. However, large species up to three ring aromatics were observed suggesting that soot precursor forms even in the gasoline engine. At low catalyst temperature condition, the reduction efficiencies of a three-way catalyst were higher for higher mass numbers. This result indicates that the larger species accumulate in the catalyst or elsewhere due to their lower vapor pressures. To evaluate the emission of low volatility species, the accumulation should be taken into account. In the hot mode, reduction efficiencies for aromatic species of three-way catalyst were almost 99.5% however, they fall to 70% in the cold start condition.

Particulate matter (PM) trapping and oxidation in regeneration on the surface of a diesel particulate catalyst-membrane filter (DPMFs) were investigated in detail using an all-in-focus optical microscope. The DPMF consists of two-layer sintered filters, where a SiC-nanoparticle membrane (made from a mixture of 80 nm and 500 nm powders) covers the surface of a conventional SiC filter. Using a visualization experiment, it was shown that PMs were trapped homogeneously along fine surface pores of the membrane's top surface, whereas in the regeneration process, the particulates in contact with the membrane may have been oxidized with some catalytic effect of the SiC nanoparticles. A soot cake was reacted continuously on the nanoparticles since pushed by a gas flow. The oxidation temperature of particulate trapped on the SiC-nanoparticle membrane was about 75 degrees lower than that on the conventional diesel particulate filters (DPF) without a catalyst.

Detailed chemical kinetics is essential for accurate prediction of combustion performance as well as emissions in practical combustion engines. However, implementation of that is challenging. In this work, dynamic adaptive chemistry (DAC) is integrated into large eddy simulations (LES) of an n-heptane spray flame in a constant volume chamber (CVC) with realistic application conditions. DAC accelerates the time integration of the governing ordinary differential equations (ODEs) for chemical kinetics through the use of locally (spatially and temporally) valid skeletal mechanisms. Instantaneous flame structures and global combustion characteristics such as ignition delay time, flame lift-off length (LOL) and emissions are investigated to assess the effect of DAC on LES-DAC results. The study reveals that in LES-DAC simulations, the auto-ignition time and LOL obtain a well agreement with experiment data under different oxygen concentrations.

Due to the rapid development of road infrastructure and vehicle population in China, the fuel consumption and emission of on-road vehicles tested in China World Transient Vehicle Cycle (C-WTVC) cannot indicate the real driving results. But the test results in China Heavy-duty Commercial Vehicle Test Cycle-Coach (CHTC-C) based on the road driving conditions in China are closer to the actual driving data. In this paper, the model for predicting the performance of heavy-duty vehicles is established and validated. The fuel consumption and NOx emission of a Euro VI heavy-duty coach under C-WTVC and CHTC-C tests are calculated by employing the developed model. Furthermore, the fuel consumption of the test coach is optimized and its sensitivity to the driving factors is analyzed.

The diesel particulate membrane filter (DPMF) is a good solution to the problem of high pressure drop that exists across diesel particulate filters (DPFs) as a result of the soot trapping process. Moreover, DPMFs that have a membrane layer composed of SiC nanoparticles can reduce the oxidation temperature of soot and the apparent activation energy. The SiC nanoparticles have an oxide layer on their surface, with a thickness less than 10 nm. From the visualization of soot oxidation on the surface of SiC nanoparticles by an environmental transmission electron microscope (ETEM), soot oxidation is seen to occur at the interface between the soot and oxide layers. The soot oxidation temperature dependency of the contact area between soot and SiC nanoparticles was evaluated using a temperature programmed reactor (TPR). The contact area between soot and SiC nanoparticles was varied by changing the ratio of SiC nanoparticles and carbon black (CB), which was used as an alternative to soot.

Homogeneous Charge Induced Ignition (HCII) combustion utilizes a port injection of high-volatile fuel to form a homogeneous charge and a direct injection of high ignitable fuel near the Top Dead Center (TDC) to trigger combustion. Compared to Conventional Diesel Combustion (CDC) with high injection pressures, HCII has the potential to achieve diesel-like thermal efficiency with significant reductions in NOx and PM emissions with relatively low-pressure injections, which would benefit the engine cost saving remarkably. In the first part of current investigation, experiments were conducted at medium load with single diesel injection strategy. HCII exhibited great potential of using low injection pressures to achieve low soot emissions. But the engine load for HCII was limited by high heat release rate. Thus, in the second and third part, experiments were performed at high and low load with double diesel injection strategy.

The combustion characteristics and soot emissions of three types of fuels were studied in a high pressure and temperature vessel. In order to achieve better volatility, proper cetane number and high oxygen content, the newly designed WDEP fuel was proposed and investigated. It is composed of wide distillation fuel (WD), PODE3-6 mixture (PODEn) and ethanol. For comparison, the test on WD and the mixture of PODEn-ethanol (EP) are also conducted. OH* chemiluminescence during the combustion was measured and instantaneous PLII was also applied to reveal the soot distribution. Abel transformation was adopted to calculate the total soot of axisymmetric flame. The results show that WDEP has similar ignition delays and flame lift-off lengths to those of WD at 870-920 K. But the initial ignition locations of WDEP flame in different cycles were more concentrated, particularly under the condition of low oxygen atmosphere.

Plug-in electric vehicle (PHEV) has a promising prospect to reduce greenhouse gas (GHG) emission and optimize engine operating in high-efficiency region. According to the maximum electric power and all-electric range, PHEVs are divided into two categories, including “all-electric PHEV” and “blended PHEV” and the latter provides a potential for more rational energy distribution because engine participates in vehicle driving during aggressive acceleration not just by motor. However, the frequent use of engine may result in severe emissions especially in low state of charge (SOC) and ahead of catalyst light-off. This study quantitatively investigates the impact of oil viscosity and driving mode (hybrid/conventional) on oil dilution and emissions including particle number (PN).

Trapping and regeneration processes in a SiC wall-flow diesel particulate filter (DPF) without a catalyst were investigated in detail through microscopic visualization. By microscopic observation of the cross section and surface, the transition from depth filtration to surface filtration could be observed clearly. The open pores on the wall surface were strongly related to the filtration depth of diesel particulate matter (PM). During the regeneration process, after the soot cake was burnt out, the particulates trapped inside the surface pores were oxidized. As a result, the particulate trapping and oxidation behaviors were strongly dependent on the microstructural surface pores.

Through microscopic visualization experiments, a process generally known as depth filtration was shown to be caused by surface pores. Moreover, the existence of a soot cake layer was an important advantage for filtration performance because it could trap most of the particulates. We proposed an ideal diesel particulate filter (DPF), in which a silicon carbide (SiC) nanoparticle membrane (made from a mixture of 80 nm and 500 nm powders) instead of a soot cake was sintered on the DPF wall surface; this improved the filtration performance at the beginning of the trapping process and reduced energy consumption during the regeneration process. The proposed filter was called a diesel particulate membrane filter (DPMF). A diesel fuel lamp was used in the trapping process to verify the trapping and oxidation mechanisms of ultrafine particulate matter. Thus, the filtration performance of the membrane filters was shown to be better than that of conventional DPFs.

Transient emissions of a turbocharged three-litre V6 diesel engine fuelled by hydrogenated vegetable oil (HVO) blends were experimentally investigated and compared with transient emissions of diesel as reference. The transient emissions measurements were made by highly-dynamic emissions instrumentations including Cambustion HFR500, CLD500 and DMS500 particulate analyzer. The HVO blends used in this study were 30% and 60% of HVO in diesel by volume. The transient conditions were simulated by load increases over 5 s, 10 s and 20 s durations at a constant engine speed. The particulate, NO, HC concentrations were measured to investigate the mechanism of emission formation under such transient schedules. The results showed that as the load increased, NO concentrations initially had a small drop before dramatically increasing for all the fuels investigated which can be associated with the turbocharger lag during the load transient.

The first several cycles determine the quality of an engine start. Low temperatures and air/fuel ratio cause incomplete combustion of the fuel. This can lead to dramatic increases in HC and PM emissions. In order to meet Euro V legislation requirements which have stricter cold start emission levels, it is critical to study the characteristics of cold and warm starting of engines in order to develop an optimized operation. The NO and THC emissions were measured by fast CLD and Fast FID gas analyzers respectively and PM in both nucleation and accumulation modes were measured by DMS500. The coolant temperature was controlled in order to guarantee the experiment repeatability. The results show that at cold start using RME60 produced higher NO and lower THC than the other tested fuels while combustion of HVO60 produced a similar level of NO but lower THC compared with mineral diesel. Meanwhile, the nucleation mode of mineral diesel was similar to RME60 but higher than HVO60.

The effects of different biodiesel blends on engine-out emissions under various transient conditions were investigated in this study using fast response diagnostic equipment. The experimental work was conducted on a modern 3.0 L, V6 high pressure common rail diesel engine fuelled with mineral diesel (B0) and three different blends of rapeseed methyl esters (RME) (B30, B60, B100 by volume) without any modifications of engine parameters. DMS500, Fast FID and Fast CLD were used to measure particulate matter (PM), total hydrocarbon (THC) and nitrogen monoxide (NO) respectively. The tests were conducted during a 12 seconds period with two tests in which load and speed were changed simultaneously and one test with only load changing. The results show that as biodiesel blend ratio increased, total particle number (PN) and THC were decreased whereas NO was increased for all the three transient conditions.

Time-lapse images of particulate matter (PM) deposition on diesel particulate filters (DPFs) at the PM-particle scale were obtained via field-emission scanning electron microscopy (FE-SEM). This particle scale time-series visualization showed the detailed processes of PM accumulation inside the DPF. First, PM introduced into a micro-pore of the DPF wall was deposited onto the surface of SiC grains composing the DPF, where it formed dendritic structures. The dendrite structures were locally grown at the contracted flow area between the SiC grains by accumulation of PM, ultimately constructing a bridge and closing the porous channel. To investigate the dominant parameters governing bridge formation, the filtration efficiency by Brownian diffusion and by interception obtained using theoretical filtration efficiency analysis of a spherical collector model were compared with the visualization results.

In this study, the combustion characteristics of diesel flame achieved in a rapid compression and expansion machine (RCEM) at various patterns of oxygen distribution in the chamber are investigated in order to clarify the effect of heterogeneity of oxygen distribution in diesel engines induced by EGR on the soot and NOx emissions. To make the heterogeneous distribution of oxygen in a combustion chamber, the mixtures with different oxygen concentrations are injected through the each different port located on the cylinder wall. Results indicate that the amount of oxygen entrained into the spray upstream the luminous flame region affects the NO emission from diesel flame strongly.

Trapping of diesel particulates and phenomena of chemical reaction in regeneration were investigated by visualization through the cross-sectional area of a diesel-particulate-filter wall, using a digital-microscope with a high focusing depth. Herein, SiC-DPF walls were polished up to make a uniform height and to create a mirror-like surface on each SiC-particle-grain. At the beginning of the trapping process, it was observed that large particulates were trapped once in the small pores inside the wall, and then, since the flow-pattern was changed drastically, the trapped particulates were pushed out and blown off again, and finally, trapped in a region further downstream. As time passed, image analysis disclosed that since fine particulates were deposited around the SiC-particle-grain surface, the flow-channels became increasingly narrow.

In this paper, a hybrid combustion mode in four-stroke gasoline direct injection engines was studied. Switching cam profiles and injection strategies simultaneously was adopted to obtain a rapid and smooth switch between SI mode and HCCI mode. Based on the continuous pressure traces and corresponding emissions, HCCI steady operation, HCCI transient process (combustion phase adjustment, SI-HCCI, HCCI-SI, HCCI cold start) were studied. In HCCI mode, HCCI combustion phase can be adjusted rapidly by changing the split injection ratio. The HCCI control strategies had been demonstrated in a Chery GDI2.0 engine. The HCCI engine simulation results show that, oxygen and active radicals are stored due to negative valve overlap and split fuel injection under learn burn condition. This reduces the HCCI sensitivity on inlet boundary conditions, such as intake charge and intake temperature. The engine can be run from 1500rpm to 4000rpm in HCCI mode without spark ignition.

A simple real-time measurement system for the components of volatile organic compounds (VOCs) and polyaromatic hydrocarbons (PAHs) in automobile exhaust gas using a laser ionization method was developed. This method was used to detect VOCs and PAHs in the exhaust gas of a diesel truck while idling, at 60 km/h, and in the Japanese driving mode JE05. As a result, various VOCs and PAHs, such as xylene and naphthalene, were simultaneously detected, and real-time changes in their concentration were obtained at 1 s intervals.

Real-time analysis of benzene in automobile exhaust gas was performed using the Jet-REMPI (supersonic jet / resonance enhanced multi-photon ionization) method. Real-time benzene concentration of two diesel trucks and one gasoline vehicle driving in Japanese driving modes were observed under ppm level at 1 s intervals. As a result, it became obvious that there were many differences in their emission tendencies, because of their car types, driving conditions, and catalyst conditions. In two diesel vehicle, benzene emission tendencies were opposite. And, in a gasoline vehicle, emission pattern were different between hot and cold conditions due to the catalyst conditions.

Advanced compression ignition combustion system which reduces simultaneously both nitride oxides (NOx) and particulate matter (PM) is a promising approach to meet future emission regulations. In order to achieve advanced compression ignition, flexible fuel injection is required for ultra-early and post-TDC injections, which conventional injector fails to accomplish due to wall-wetting effect. In this work, special injectors with the spray angle of 60 degree are applied on a 4 cylinder mass-production diesel engine without modification of the engine configuration. For application-oriented study, sweep experiments of injection timings and durations, fuel injection pressure and the boost pressure are carried out to investigate the relationships between the control parameters and the engine performance. Model based calibration and real application tests validate the maximum applicable operation range of maximum speed of 2200 RPM and IMEP of 8.0 bar.