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Currently used instruments for the analysis of total inorganic carbon (TIC) and total organic carbon (TOC) in water and wastewater samples require the use of hazardous chemicals which is not acceptable in their application for long-term space missions. A new design concept of the “reagentless” carbon analyzer (RCA) for determination of both TIC and TOC for water quality monitoring in space is proposed and tested. The concept is based on generating all the chemicals needed for the TIC and TOC analysis within the instrument, and avoiding the need for storing a supply of chemicals. The chemicals are either generated or recirculated in the instrument, or an alternative approach for their use is developed, such as using photocatalytic oxidation instead of oxidizing chemicals for TOC analysis. The fully developed miniaturized instrument will incorporate microfluidic based design principles.

This paper addresses the development of a novel technology to simultaneously reduce total organic carbon (TOC) and microbial count (MC) in biological water processor (BWP) processed water. This approach also creates a biocidal environment in BWP processed water before being fed into the reverse osmosis (RO) and post processing systems. The technology is based on an advanced oxidation process using an on-demand oxidizer generator, which does not require consumable chemicals. The SBIR (Small Business Innovation Research) Phase I feasibility studies successfully demonstrated the process efficacy in the reduction of both TOC and MC of the BWP effluent. Also, the residual disinfectant and reduced TOC in the treated effluent minimized fouling the RO membrane and water lines. In the Phase II project, a prototype is being fabricated and evaluated for its ability to reduce TOC and MC, and extend RO membrane life.