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Since the advent of the spark ignition engine, the maximum engine efficiency has been knock limited. Knock is a phenomena caused by the rapid autoignition of fuel/air mixture (endgas) ahead of the flame front. The propensity of a fuel to autoignite corresponds to its autoignition chemistry at the local endgas temperature and pressure. Since a fuel blend consists of many components, its autoignition chemistry is very complex. The octane index (OI) simplifies this complex autoignition chemistry by comparing a fuel to a Primary Reference Fuel (PRF), a binary blend of iso-octane and n-heptane. As more iso-octane is added into the blend, the PRF is less likely to autoignite. The OI of a fuel is defined as the volumetric percentage of iso-octane in the PRF blend that exhibits similar knocking characteristics at the same engine conditions.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

In order to understand better the operation of spark-ignition engines during the warm-up period, a computer model had been developed which simulates the thermal processes of the engine. This model is based on lumped thermal capacitance methods for the major engine components, as well as the exhaust system. Coolant and oil flows, and their respective heat transfer rates are modeled, as well as friction heat generation relations. Piston-liner heat transfer is calculated based on a thermal resistance method, which includes the effects of piston and ring material and design, oil film thickness, and piston-liner crevice. Piston/liner crevice changes are calculated based on thermal expansion rates and are used in conjunction with a crevice-region unburned hydrocarbon model to predict the contribution to emissions from this source.

The flow and heat transfer phenomena in the intake port of a spark ignition engine with port fuel injection play a significant role in the mixture preparation process, especially at part load. The backflow of the hot burned gas from the cylinder into the intake port when the intake valve is opened breaks up any liquid film around the inlet valve, influences gas and wall temperatures, and has a major effect on the fuel vaporization process. The backflow of in-cylinder mixture with its residual component during the compression stroke prior to inlet valve closing fills part of the port with gas at higher than fresh mixture temperature. To quantify these phenomena, time-resolved measurements of the hydrocarbon concentration profile along the center-line of the intake port were made with a fast-response flame ionization detector, and of the gas temperature with a fine wire resistance thermometer, in a single-cylinder engine running with premixed propane/air mixture.

Spark Ignited Direct Injection (SI DI) of fuel extends engine knock limits compared to Port Fuel Injection (PFI) by utilizing the large in-cylinder charge cooling effect due to fuel evaporation. The use of gasoline/ethanol blends in direct injection (DI) is therefore especially advantageous due to the high heat of vaporization of ethanol. In addition to the thermal benefit due to charge cooling, ethanol blends also display superior chemical resistance to autoignition, therefore allowing the further extension of knock limits. Unlike the charge cooling benefit which is realized mostly in SI DI engines, the chemical benefit of ethanol blends exists in Port Fuel Injected (PFI) engines as well. The aim of this study is to separate and quantify the effect of fuel chemistry and charge cooling on knock. Using a turbocharged SI engine with both PFI and DI, knock limits were measured for both injection types and five gasoline-ethanol blends.

Time-resolved heat flux and gas temperature measurements in the intake port of a spark ignition engine are presented. Experiments were pursued for motored, propane fired, and liquid fuel operation. Heat transfer coefficients were built from the dry data. Also, heat transfer rates in the port and off the back of the intake valve were integrated over the main flow phases. For a typical low-load propane-fired operating condition, heat transfer in the port caused a mean intake air temperature increase of approximately 10°C. The main different intake flow phases, induction or forward flow, displacement backflow, and valve overlap backflow, contributed approximately 10°C, 3°C, and negative 3°C, respectively. These mixture temperature changes are expected to be also applicable for liquid fuel injected cases. While the heat flux instrumentation was primarily intended for dry operation of the engine, liquid fuel experiments were also pursued.

Experiments were carried out to collect in-cylinder pressure data and microphone signals from a single-cylinder test engine using spark timingsbefore, at, and after knock onset for toluene reference fuels. The objective was to gain insight into the phenomena that determine knock onset, detected by an external microphone. In particular, the study examines how the end-gas autoignition process changes as the engine's spark timing is advanced through the borderline knock limit into the engine's knocking regime. Fast Fourier transforms (FFT) and bandpass filtering techniques were used to process the recorded cylinder pressure data to determine knock intensities for each cycle. Two characteristic pressure oscillation frequencies were detected: a peak just above 6 kHz and a range of peaks in the 15-22 kHz range. The microphone data shows that the audible knock signal has the same 6 kHz peak.

Experiments were performed to identify the knock trends of lean hydrocarbon-air mixtures, and such mixtures enhanced with hydrogen (H2) and carbon monoxide (CO). These enhanced mixtures simulated 15% and 30% of the engine's gasoline being reformed in a plasmatron fuel reformer [1]. Knock trends were determined by measuring the octane number (ON) of the primary reference fuel (mixture of isooctane and n-heptane) supplied to the engine that just produced audible knock. Experimental results show that leaner operation does not decrease the knock tendency of an engine under conditions where a fixed output torque is maintained; rather it slightly increases the octane requirement. The knock tendency does decrease with lean operation when the intake pressure is held constant, but engine torque is then reduced.

The effects of combustion chamber and intake valve deposit build-up on the knocking characteristics of a spark ignition engine were studied. A Chrysler 2.2 liter engine was run continuously for 180 hours to build up intake valve and combustion chamber deposits. In the tests reported here, the gasoline used contained a deposit controlling fuel additive. The engines's octane requirement increased by 10 research octane numbers during this extended engine operating period. At approximately 24 hour intervals during these tests, the engine was audibly knock rated to determine its octane requirement. Cylinder pressure data was collected during knocking conditions to investigate the knocking characteristics of each cylinder, and deposit build-up effects on those statistics. Cylinder-to-cylinder variations in knock statistics were studied. Analysis of the data indicated that some 20 to 40 percent of cycles knock before the knock is audibly detected.

Gasoline/ethanol fuel blends have significant synergies with Spark Ignited Direct Injected (SI DI) engines. The higher latent heat of vaporization of ethanol increases charge cooling due to fuel evaporation and thus improves knock onset limits and efficiency. Realizing these benefits, however, can be challenging due to the finite time available for fuel evaporation and mixing. A methodology was developed to quantify how much in-cylinder charge cooling takes place in an engine for different gasoline/ethanol blends. Using a turbocharged SI engine with both Port Fuel Injection (PFI) and Direct Injection (DI), knock onset limits were measured for different intake air temperatures for both types of injection and five gasoline/ethanol blends. The superior charge cooling in DI compared to PFI for the same fuel resulted in pushing knock onset limits to higher in-cylinder maximum pressures. Knock onset is used as a diagnostic of charge cooling.

Higher compression ratio and turbocharging, with engine downsizing can enable significant gains in fuel economy but require engine operating conditions that cause engine knock under high load. Engine knock can be avoided by supplying higher-octane fuel under such high load conditions. This study builds on previous MIT papers investigating Octane-On-Demand (OOD) to enable a higher efficiency, higher-boost higher compression-ratio engine. The high-octane fuel for OOD can be obtained through On-Board-Separation (OBS) of alcohol blended gasoline. Fuel from the primary fuel tank filled with commercially available gasoline that contains 10% by volume ethanol (E10) is separated by an organic membrane pervaporation process that produces a 30 to 90% ethanol fuel blend for use when high octane is needed. In addition to previous work, this paper combines modeling of the OBS system with passenger car and medium-duty truck fuel consumption and octane requirements for various driving cycles.

A set of experiments was performed to investigate the effects of relative air-fuel ratio, inlet boost pressure, and compression ratio on engine knock behavior. Selected operating conditions were also examined with simulated hydrogen rich fuel reformate added to the gasoline-air intake mixture. For each operating condition knock limited spark advance was found for a range of octane numbers (ON) for two fuel types: primary reference fuels (PRFs), and toluene reference fuels (TRFs). A smaller set of experiments was also performed with unleaded test gasolines. A combustion phasing parameter based on the timing of 50% mass fraction burned, termed “combustion retard”, was used as it correlates well to engine performance. The combustion retard required to just avoid knock increases with relative air-fuel ratio for PRFs and decreases with air-fuel ratio for TRFs.

A conventional spark plug and a spark plug with smaller electrodes were studied in M.I.T.'s transparent square piston engine. The purpose was to learn more about how the electrode geometry affects the heat losses to the electrodes and the electrical performance of the ignition system, and how this affects the flame development process in an engine. A schlieren system which provides two orthogonal views of the developing flame was used to define the initial flame growth process, for as many as 100 consecutive cycles. Voltage and current waveforms were recorded to characterize the spark discharge, and cylinder pressure data were used to characterize the engine performance. The spark plug with the smaller electrodes was shown to reduce the heat losses to the electrodes, and thereby extend the stable operating regime of the engine. At conditions close to the stable operating limit, cycle-by-cycle variations in heat losses cause significant cyclic variations in flame development.

The prediction of knock onset in spark-ignition engines requires a chemical model for the autoignition of the hydrocarbon fuel-air mixture, and a description of the unburned end-gas thermal state. Previous studies have shown that a reduced chemistry model developed by Keck et al. adequately predicts the initiation of autoignition. However, the combined effects of heat transfer and compression on the state of the end gas have not been thoroughly investigated. The importance of end-gas heat transfer was studied with the objective of improving the ability of our knock model to predict knock onset over a wide range of engine conditions. This was achieved through changing the thermal environment of the end gas by either varying the inlet air temperature or the coolant temperature. Results show that there is significant heating of the in-cylinder charge during intake and a substantial part of the compression process.

A single-zone burn-rate analysis based on measured cylinder pressure data proposed by Gatowski et al. in 1984 was evaluated over the full load and speed range of a spark-ignition engine. The analysis, which determines the fuel mass burning rate based on the First Law of Thermodynamics, includes sub-models for the effects of residual fraction, heat transfer, and crevices. Each of these sub-models was assessed and calibrated. Cylinder pressure data over the full engine operating range obtained from two different engines were used to examine the robustness of the analysis. The sensitivity of predictions to the parameters wall temperature, heat transfer model coefficients and exponent, swirl ratio, motoring polytropic constant, in-cylinder mass, and to uncertainty in pressure data was evaluated.

A computational fluid dynamics (CFD) prediction of the transient flow in the intake system of a spark ignition engine is compared to experimental data. The calculation was performed for a single cylinder version of a pre-1995 Ford two-valve production engine, while experiments were carried out on a single cylinder Ricardo Mark 3 research engine with similar overall geometric parameters. While the two engines have somewhat different geometries, this was not considered to be a significant problem for our study of flow features. Both set-ups employed gaseous fuel. The calculation was performed using the commercially available Star-CD code incorporating the complete intake manifold runner and cylinder into the mesh. Cylinder pressures were in good agreement with experiment indicating that wave dynamics were well captured. Comparison was also made to the measured instantaneous gas temperatures along the intake system.

A performance model of a Wankel engine is developed which performs a leakage mass balance, accounts for heat transfer and flame quenching, and predicts the mass fraction burned as a function of chamber pressure. Experiments were performed on a production Wankel engine to obtain chamber pressure-time diagrams, and engine performance and emissions data. Model predictions of mass burned, global heat transfer, and hydrocarbon emission gave good agreement with measurements. Predictions of oxides of nitrogen are higher than measurements, especially at low loads. This is thought to be due to the adiabatic core gas assumption in the model. The need for a Wankel boundary layer study is identified.

A computer simulation of the four-stroke spark-ignition engine cycle has been used to examine the effects of turbocharging and reduced heat transfer on engine performance, efficiency and NOx emissions. The simulation computes the flows into and out of the engine, calculates the changes in thermodynamic properties and composition of the unburned and burned gas mixtures within the cylinder through the engine cycle due to work, heat and mass transfers, and follows the kinetics of NO formation and decomposition in the burned gas. The combustion process is specified as an input to the program through use of a normalized rate of mass burning profile. From this information, the simulation computes engine power, fuel consumption and NOx emissions. Wide-open-trottle predictions made with the simulation were compared with experimental data from a 5.7ℓ naturally-aspirated and a 3.8ℓ turbocharged production engine.

A model for predicting the performance and emissions characteristics of Wankel engines has been developed and tested. Each chamber is treated as an open thermodynamic system and the effects of turbulent flame propagation, quench layer formation, gas motion, heat transfer and seal leakage are included. The experimental tests were carried out on a Toyo Kogyo 12B engine under both motoring and firing conditions and values for the effective seal leakage area and turbulent heat transfer coefficient were deduced. The agreement between the predicted and measured performances was reasonable. Parametric studies of the effects of reductions in seal leakage and heat transfer were carried out and the results are presented.

The fate of hydrocarbon species in the exhaust systems of spark-ignition engines is an important part of the overall hydrocarbon emissions problem. In this investigation models were developed for the instantaneous heat transfer, fluid mixing, and hydrocarbon oxidation in an engine exhaust port. Experimental measurements were obtained for the instantaneous cylinder pressure and instantaneous gas temperature at the exhaust port exit for a range of engine operating conditions. These measurements were used to validate the heat transfer model and to provide data on the instantaneous cylinder gas state for a series of illustrative exhaust port hydrocarbon oxidation computations as a function of engine operating and design variables. During much of the exhaust process, the exhaust port heat transfer was dominated by large-scale fluid motion generated by the jet-like flow at the exhaust valve.